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Rotaxane synthesis exploiting the M(i)/M(iii) redox couple

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Figure

Fig. 1Solid-state structures of2.3035(7); Ir11phine ligands diIr1 4+. Left: Selected independent cation from the X-ray structure of 4b[BArF4] (Z’ = 2) with thermal ellipsoids drawn atthe 50% probability level; non-hydridic hydrogen atoms omitted for clarit
Fig. 2Solid-state structure of2.017(2); P312.213(2); Ir1C19), 2.072(3); P312.262(2); Rh1 5b
Fig. 3Solid-state structure ofIr1 1b. Thermal ellipsoids drawn at the 50% probability level; anions, most hydrogen atoms, and minor disordered com-ponents omitted for clarity

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