metal-organic papers
Acta Cryst.(2005). E61, m469–m470 doi:10.1107/S1600536805003405 Xiaoet al. [Ni(C
14H8O5)(C10H8N2)]
m469
Acta Crystallographica Section E Structure Reports
Online
ISSN 1600-5368
catena
-Poly[[(2,2
000-bipyridine)nickel(II)]-l
-4,4
000-oxydibenzoato]
Hong-Ping Xiao,* Ya-Qian Cheng and Xin-Hua Li
School of Chemistry and Materials Science, Wenzhou Normal College, Zhejiang Wenzhou 325027, People’s Republic of China
Correspondence e-mail: hp_xiao@yahoo.com.cn
Key indicators
Single-crystal X-ray study
T= 298 K
Mean(C–C) = 0.004 A˚
Rfactor = 0.046
wRfactor = 0.098
Data-to-parameter ratio = 13.1
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
#2005 International Union of Crystallography Printed in Great Britain – all rights reserved
In the title compound, [Ni(C14H8O5)(C10H8N2)]n, the Ni
II
atom is coordinated by four O atoms of two 4,40
-oxydi-benzoate (oba) dianions and two N atoms of a chelate 2,20
-bipyridine ligand to furnish a distorted octahedral coordina-tion environment. The V-shaped oba dianion acts as a bridge between two Ni atoms to form a zigzag chain coordination polymer.
Comment
The versatility of the flexible ligand H2oba (H2oba is 4,40
-oxydibenzoic acid) is manifested by the interesting polymeric structures that it forms (Liu et al., 2002; Skakle et al., 2001; Wang et al., 2004). In our previous work, the reaction of nickel(II) acetate, H2oba and phen (phen is
1,10-phenan-throline) afforded polymeric {[Ni(phen)(oba)]0.25H2O}n
(Xiaoet al., 2005). We used 2,20-bipyridine (2,20-bipy) in place
of phen and obtained the title compound, (I).
In (I), the NiIIatom is coordinated by four O atoms of two oba ligands and two N atoms of a chelate 2,20-bipy ligand to
furnish a distorted octahedral coordination environment (Fig. 1). The NiIIatoms are linked by the oba ligands to form zigzag chains running along [201]. The 2,20-bipy ligands
protrude on both sides of the zigzag chain (Fig. 2). The dihedral angle between the planes of the two benzene rings of the oba dianion is 82.7 (1). The mean plane of the 2,20-bipy
ligand forms dihedral angles of 87.7 (1) and 94.1 (1),
respectively, with the C12–C17 and C18–C23 benzene rings, indicating that the 2,20-bipy plane is perpendicular to the two
benzene rings of the oba ligand.
Experimental
The title compound was synthesized by the hydrothermal method from a mixture of 4,40-oxybis(benzoic acid) (0.5 mmol), Ni(CH3COO)24H2O (0.5 mmol), 2,2’-bipyridine (0.5 mmol) and
water (8.0 ml) in a 15.0 ml Teflon-lined stainless steel reactor. The solution was heated at 423 K for four days. On completion of the reaction, the system was cooled slowly to room temperature, and green crystals were collected.
Crystal data
[Ni(C14H8O5)(C10H8N2)]
Mr= 471.10 Monoclinic,P21=c a= 12.2223 (18) A˚
b= 15.017 (2) A˚
c= 11.3182 (16) A˚
= 92.026 (3) V= 2076.1 (5) A˚3
Z= 4
Dx= 1.507 Mg m
3
MoKradiation Cell parameters from 2159
reflections
= 2.3–22.3 = 0.97 mm1
T= 298 (2) K Block, green
0.190.160.14 mm
Data collection
Bruker APEX area-detector diffractometer
’and!scans
Absorption correction: multi-scan (SADABS; Bruker, 2002)
Tmin= 0.837,Tmax= 0.876
11 073 measured reflections
3792 independent reflections 3075 reflections withI> 2(I)
Rint= 0.036
max= 25.3
h=13!14
k=13!18
l=13!13
Refinement
Refinement onF2
R[F2> 2(F2)] = 0.046
wR(F2) = 0.098
S= 1.06 3792 reflections 289 parameters
H-atom parameters constrained
w= 1/[2(F
o2) + (0.0372P)2
+ 0.4839P]
whereP= (Fo2+ 2Fc2)/3
(/)max< 0.001 max= 0.29 e A˚
3
min=0.24 e A˚ 3
Extinction correction: none
Table 1
Selected geometric parameters (A˚ ,).
Ni1—N1 1.990 (2) Ni1—N2 2.000 (2) Ni1—O1 1.993 (2)
Ni1—O2 2.389 (2) Ni1—O4i 1.9885 (19) Ni1—O5i
2.418 (2)
N1—Ni1—N2 80.93 (10) N1—Ni1—O1 91.67 (9) N1—Ni1—O2 92.49 (8) N2—Ni1—O1 155.03 (8) N2—Ni1—O2 96.46 (8) O1—Ni1—O2 59.85 (8) O1—Ni1—O5i
106.95 (8) O2—Ni1—O5i
158.81 (7) O4i
—Ni1—N1 163.29 (9) O4i
—Ni1—N2 97.19 (9) O4i
—Ni1—O1 96.44 (8) O4i—Ni1—O2 104.22 (8) O5i
—Ni1—N1 105.02 (9) O5i
—Ni1—N2 98.02 (9) O4i
—Ni1—O5i
58.63 (8)
Symmetry code: (i)xþ1;yþ1
2;zþ 1 2.
H atoms were included in the refinement in calculated positions in the riding-model approximation [C—H = 0.93 A˚ and Uiso(H) =
1.2Ueq(C)].
Data collection:SMART(Bruker, 2002); cell refinement:SAINT
(Bruker, 2002); data reduction:SAINT; program(s) used to solve structure:SHELXS97(Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: XP
(Bruker, 2002); software used to prepare material for publication:
SHELXL97.
We acknowledge financial support by the Wenzhou Science and Technology Project of China (No. S2003A008) and Zhejiang Provincial Natural Science Foundation of China (No. 202137).
References
Bruker (2002). SMART, SAINT, SADABS and XP. Bruker AXS Inc., Madison, Wisconsin, USA.
Liu, G. F., Qiao, Z. P., Wang, H. Z., Chen, X. M. & Yang, G. (2002).New J. Chem.26, 791–795.
Sheldrick, G. M. (1997). SHELXS97 and SHELXL97. University of Go¨ttingen, Germany.
Skakle, J. M. S., Foreman, M. R. St J. & Plater, M. J. (2001).Acta Cryst.E57, m169–m171.
Wang, Y. B., Wang, Z. M., Yan, C. H. & Jin, L. P. (2004).J. Mol. Struct.692, 177–186.
[image:2.610.317.566.72.202.2]Xiao, H.-P., Wang, J.-G., Li, X.-H., Hu, M. L. & Zhang, W.-B. (2005).Acta Cryst.E61, m257–m259.
Figure 2
The zigzag chain of (I). Figure 1
[image:2.610.314.565.247.375.2]supporting information
sup-1 Acta Cryst. (2005). E61, m469–m470
supporting information
Acta Cryst. (2005). E61, m469–m470 [https://doi.org/10.1107/S1600536805003405]
catena
-Poly[[(2,2
′
-bipyridine)nickel(II)]-
µ
-4,4
′
-oxydibenzoato]
Hong-Ping Xiao, Ya-Qian Cheng and Xin-Hua Li
catena-Poly[[(2,2′-bipyridine)nickel(II)]-µ-4,4′-oxydibenzoato]
Crystal data
[Ni(C14H8O5)(C10H8N2)] Mr = 471.10
Monoclinic, P21/c
Hall symbol: -P 2ybc a = 12.2223 (18) Å b = 15.017 (2) Å c = 11.3182 (16) Å β = 92.026 (3)° V = 2076.1 (5) Å3 Z = 4
F(000) = 968 Dx = 1.507 Mg m−3
Mo Kα radiation, λ = 0.71073 Å Cell parameters from 2159 reflections θ = 2.3–22.3°
µ = 0.97 mm−1 T = 298 K Block, green
0.19 × 0.16 × 0.14 mm
Data collection
Bruker APEX area-detector diffractometer
Radiation source: fine-focus sealed tube Graphite monochromator
φ and ω scan
Absorption correction: integration (SADABS; Bruker, 2002) Tmin = 0.837, Tmax = 0.876
11073 measured reflections 3792 independent reflections 3075 reflections with I > 2σ(I) Rint = 0.036
θmax = 25.3°, θmin = 1.7° h = −13→14
k = −13→18 l = −13→13
Refinement Refinement on F2
Least-squares matrix: full R[F2 > 2σ(F2)] = 0.046 wR(F2) = 0.098 S = 1.06 3792 reflections 289 parameters 0 restraints
Primary atom site location: structure-invariant direct methods
Secondary atom site location: difference Fourier map
Hydrogen site location: inferred from neighbouring sites
H-atom parameters constrained w = 1/[σ2(F
o2) + (0.0372P)2 + 0.4839P]
where P = (Fo2 + 2Fc2)/3
(Δ/σ)max < 0.001
Δρmax = 0.29 e Å−3
Δρmin = −0.24 e Å−3
Special details
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2,
conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used
only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2
are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)
x y z Uiso*/Ueq
Ni1 0.61514 (3) 0.05986 (2) 0.79313 (3) 0.04012 (14)
O1 0.49510 (16) 0.11844 (13) 0.87899 (17) 0.0490 (5)
O2 0.50408 (16) 0.17099 (14) 0.69694 (18) 0.0537 (5)
O3 0.04701 (17) 0.33318 (16) 0.83212 (18) 0.0646 (7)
O4 −0.26269 (16) 0.37183 (13) 0.37038 (18) 0.0542 (6)
O5 −0.26358 (19) 0.50757 (15) 0.4409 (2) 0.0677 (7)
N1 0.51615 (19) −0.03797 (15) 0.7379 (2) 0.0437 (6)
N2 0.69440 (18) 0.02205 (16) 0.6498 (2) 0.0436 (6)
C1 0.4289 (3) −0.0678 (2) 0.7939 (3) 0.0579 (9)
H1 0.4126 −0.0428 0.8664 0.069*
C2 0.3623 (3) −0.1342 (2) 0.7481 (3) 0.0630 (9)
H2 0.3028 −0.1546 0.7894 0.076*
C3 0.3858 (3) −0.1697 (2) 0.6396 (3) 0.0570 (9)
H3 0.3415 −0.2140 0.6061 0.068*
C4 0.4750 (2) −0.13938 (18) 0.5811 (3) 0.0474 (8)
H4 0.4910 −0.1622 0.5073 0.057*
C5 0.5404 (2) −0.07461 (18) 0.6335 (2) 0.0396 (7)
C6 0.6424 (2) −0.04008 (18) 0.5833 (2) 0.0403 (7)
C7 0.6831 (3) −0.0687 (2) 0.4780 (3) 0.0554 (8)
H7 0.6466 −0.1120 0.4331 0.067*
C8 0.7787 (3) −0.0320 (3) 0.4408 (3) 0.0685 (10)
H8 0.8079 −0.0508 0.3702 0.082*
C9 0.8316 (3) 0.0323 (3) 0.5073 (3) 0.0696 (10)
H9 0.8959 0.0582 0.4823 0.084*
C10 0.7871 (3) 0.0573 (2) 0.6115 (3) 0.0577 (9)
H10 0.8227 0.1005 0.6574 0.069*
C11 0.4562 (2) 0.16481 (19) 0.7923 (3) 0.0433 (7)
C12 0.3479 (2) 0.20919 (17) 0.8047 (2) 0.0378 (6)
C13 0.3142 (2) 0.27215 (19) 0.7210 (2) 0.0437 (7)
H13 0.3597 0.2864 0.6597 0.052*
C14 0.2140 (2) 0.31377 (18) 0.7279 (3) 0.0447 (7)
H14 0.1922 0.3564 0.6723 0.054*
C15 0.1471 (2) 0.2913 (2) 0.8182 (3) 0.0451 (7)
C16 0.1788 (2) 0.2292 (2) 0.9026 (3) 0.0513 (8)
H16 0.1328 0.2148 0.9634 0.062*
C17 0.2801 (2) 0.18895 (19) 0.8954 (2) 0.0456 (7)
H17 0.3027 0.1477 0.9525 0.055*
C18 −0.0122 (2) 0.3562 (2) 0.7287 (3) 0.0503 (8)
C19 −0.0481 (3) 0.2923 (2) 0.6506 (3) 0.0612 (9)
supporting information
sup-3 Acta Cryst. (2005). E61, m469–m470
C20 −0.1148 (2) 0.3169 (2) 0.5544 (3) 0.0542 (8)
H20 −0.1384 0.2739 0.5002 0.065*
C21 −0.1466 (2) 0.4038 (2) 0.5380 (3) 0.0419 (7)
C22 −0.1068 (3) 0.4672 (2) 0.6169 (3) 0.0567 (8)
H22 −0.1259 0.5266 0.6057 0.068*
C23 −0.0391 (3) 0.4435 (2) 0.7120 (3) 0.0594 (9)
H23 −0.0121 0.4868 0.7642 0.071*
C24 −0.2286 (2) 0.4309 (2) 0.4434 (3) 0.0435 (7)
Atomic displacement parameters (Å2)
U11 U22 U33 U12 U13 U23
Ni1 0.0342 (2) 0.0425 (2) 0.0428 (2) 0.00222 (16) −0.00895 (15) −0.00669 (17) O1 0.0492 (12) 0.0514 (13) 0.0456 (12) 0.0120 (10) −0.0106 (10) −0.0020 (10) O2 0.0496 (13) 0.0640 (14) 0.0474 (13) 0.0063 (10) −0.0004 (10) −0.0025 (11) O3 0.0532 (14) 0.0984 (18) 0.0417 (12) 0.0317 (12) −0.0061 (10) 0.0022 (12) O4 0.0540 (13) 0.0462 (12) 0.0607 (14) −0.0017 (10) −0.0222 (11) 0.0033 (11) O5 0.0834 (17) 0.0537 (15) 0.0636 (15) 0.0180 (12) −0.0307 (13) −0.0059 (12) N1 0.0401 (14) 0.0443 (14) 0.0466 (15) 0.0023 (11) −0.0015 (12) −0.0044 (11) N2 0.0343 (14) 0.0471 (14) 0.0490 (15) 0.0022 (11) −0.0063 (11) 0.0008 (12)
C1 0.055 (2) 0.060 (2) 0.059 (2) −0.0054 (16) 0.0078 (17) −0.0044 (17)
C2 0.053 (2) 0.057 (2) 0.080 (3) −0.0101 (16) 0.0111 (18) 0.0019 (19)
C3 0.049 (2) 0.0444 (19) 0.076 (2) −0.0050 (15) −0.0102 (18) 0.0000 (17)
C4 0.052 (2) 0.0415 (17) 0.0478 (18) 0.0049 (14) −0.0131 (15) −0.0023 (14)
C5 0.0401 (16) 0.0364 (16) 0.0415 (16) 0.0078 (12) −0.0104 (13) 0.0009 (13) C6 0.0395 (16) 0.0397 (16) 0.0407 (16) 0.0082 (12) −0.0104 (13) 0.0008 (13)
C7 0.056 (2) 0.060 (2) 0.050 (2) 0.0036 (16) −0.0029 (16) −0.0052 (16)
C8 0.063 (2) 0.086 (3) 0.057 (2) 0.004 (2) 0.0131 (19) −0.005 (2)
C9 0.049 (2) 0.088 (3) 0.073 (3) −0.0057 (19) 0.0108 (19) 0.001 (2)
C10 0.0443 (19) 0.064 (2) 0.065 (2) −0.0031 (16) −0.0059 (17) −0.0002 (17)
C11 0.0429 (17) 0.0393 (17) 0.0469 (18) −0.0004 (13) −0.0096 (15) −0.0080 (14) C12 0.0401 (16) 0.0363 (15) 0.0363 (16) −0.0015 (12) −0.0115 (13) −0.0052 (12) C13 0.0433 (18) 0.0488 (18) 0.0383 (16) −0.0031 (14) −0.0064 (13) 0.0015 (13) C14 0.0479 (18) 0.0444 (17) 0.0407 (17) 0.0040 (14) −0.0125 (14) 0.0045 (13) C15 0.0406 (17) 0.0555 (19) 0.0384 (17) 0.0070 (14) −0.0102 (14) −0.0048 (14) C16 0.0447 (18) 0.069 (2) 0.0403 (17) 0.0043 (15) −0.0007 (14) 0.0080 (15) C17 0.0492 (18) 0.0483 (18) 0.0385 (17) 0.0030 (14) −0.0087 (14) 0.0050 (14) C18 0.0381 (17) 0.071 (2) 0.0408 (17) 0.0167 (15) −0.0050 (13) 0.0029 (16)
C19 0.061 (2) 0.057 (2) 0.065 (2) 0.0120 (17) −0.0162 (18) 0.0044 (18)
C20 0.0491 (19) 0.050 (2) 0.062 (2) 0.0022 (15) −0.0184 (16) −0.0023 (16)
C21 0.0309 (15) 0.0506 (18) 0.0439 (17) −0.0004 (13) −0.0034 (13) 0.0047 (14)
C22 0.059 (2) 0.054 (2) 0.056 (2) 0.0076 (16) −0.0126 (17) 0.0032 (16)
C23 0.056 (2) 0.067 (2) 0.054 (2) 0.0085 (16) −0.0142 (16) −0.0086 (17)
Geometric parameters (Å, º)
Ni1—N1 1.990 (2) C7—H7 0.9300
Ni1—N2 2.000 (2) C8—C9 1.372 (5)
Ni1—O1 1.993 (2) C8—H8 0.9300
Ni1—O2 2.389 (2) C9—C10 1.368 (5)
Ni1—O4i 1.9885 (19) C9—H9 0.9300
Ni1—O5i 2.418 (2) C10—H10 0.9300
O1—C11 1.281 (3) C11—C12 1.493 (4)
O2—C11 1.249 (3) C12—C17 1.376 (4)
O3—C15 1.389 (3) C12—C13 1.390 (4)
O3—C18 1.397 (3) C13—C14 1.379 (4)
O4—C24 1.272 (3) C13—H13 0.9300
O4—Ni1ii 1.9885 (19) C14—C15 1.374 (4)
O5—C24 1.229 (3) C14—H14 0.9300
N1—C1 1.336 (4) C15—C16 1.380 (4)
N1—C5 1.347 (4) C16—C17 1.383 (4)
N2—C10 1.336 (4) C16—H16 0.9300
N2—C6 1.345 (3) C17—H17 0.9300
C1—C2 1.377 (4) C18—C23 1.364 (4)
C1—H1 0.9300 C18—C19 1.367 (4)
C2—C3 1.379 (5) C19—C20 1.387 (4)
C2—H2 0.9300 C19—H19 0.9300
C3—C4 1.373 (4) C20—C21 1.372 (4)
C3—H3 0.9300 C20—H20 0.9300
C4—C5 1.380 (4) C21—C22 1.382 (4)
C4—H4 0.9300 C21—C24 1.497 (4)
C5—C6 1.482 (4) C22—C23 1.381 (4)
C6—C7 1.375 (4) C22—H22 0.9300
C7—C8 1.372 (5) C23—H23 0.9300
N1—Ni1—N2 80.93 (10) C10—C9—H9 120.9
N1—Ni1—O1 91.67 (9) C8—C9—H9 120.9
N1—Ni1—O2 92.49 (8) N2—C10—C9 122.6 (3)
N2—Ni1—O1 155.03 (8) N2—C10—H10 118.7
N2—Ni1—O2 96.46 (8) C9—C10—H10 118.7
O1—Ni1—O2 59.85 (8) O2—C11—O1 122.0 (3)
O1—Ni1—O5i 106.95 (8) O2—C11—C12 119.5 (3)
O2—Ni1—O5i 158.81 (7) O1—C11—C12 118.5 (3)
O4i—Ni1—N1 163.29 (9) C17—C12—C13 119.1 (3)
O4i—Ni1—N2 97.19 (9) C17—C12—C11 122.1 (3)
O4i—Ni1—O1 96.44 (8) C13—C12—C11 118.8 (3)
O4i—Ni1—O2 104.22 (8) C14—C13—C12 120.8 (3)
O5i—Ni1—N1 105.02 (9) C14—C13—H13 119.6
O5i—Ni1—N2 98.02 (9) C12—C13—H13 119.6
O4i—Ni1—O5i 58.63 (8) C15—C14—C13 118.9 (3)
C15—O3—C18 116.7 (2) C15—C14—H14 120.5
supporting information
sup-5 Acta Cryst. (2005). E61, m469–m470
C1—N1—C5 118.9 (3) C14—C15—C16 121.4 (3)
C1—N1—Ni1 125.8 (2) C14—C15—O3 121.5 (3)
C5—N1—Ni1 115.3 (2) C16—C15—O3 117.0 (3)
C10—N2—C6 118.8 (3) C15—C16—C17 119.0 (3)
C10—N2—Ni1 126.3 (2) C15—C16—H16 120.5
C6—N2—Ni1 114.74 (19) C17—C16—H16 120.5
N1—C1—C2 122.4 (3) C12—C17—C16 120.7 (3)
N1—C1—H1 118.8 C12—C17—H17 119.6
C2—C1—H1 118.8 C16—C17—H17 119.6
C1—C2—C3 118.4 (3) C23—C18—C19 121.0 (3)
C1—C2—H2 120.8 C23—C18—O3 118.0 (3)
C3—C2—H2 120.8 C19—C18—O3 120.9 (3)
C4—C3—C2 119.7 (3) C18—C19—C20 119.1 (3)
C4—C3—H3 120.2 C18—C19—H19 120.4
C2—C3—H3 120.2 C20—C19—H19 120.4
C3—C4—C5 119.0 (3) C21—C20—C19 121.1 (3)
C3—C4—H4 120.5 C21—C20—H20 119.5
C5—C4—H4 120.5 C19—C20—H20 119.5
N1—C5—C4 121.5 (3) C20—C21—C22 118.4 (3)
N1—C5—C6 114.1 (2) C20—C21—C24 122.3 (3)
C4—C5—C6 124.4 (3) C22—C21—C24 119.1 (3)
N2—C6—C7 121.6 (3) C23—C22—C21 120.9 (3)
N2—C6—C5 114.5 (2) C23—C22—H22 119.5
C7—C6—C5 123.9 (3) C21—C22—H22 119.5
C8—C7—C6 118.6 (3) C18—C23—C22 119.4 (3)
C8—C7—H7 120.7 C18—C23—H23 120.3
C6—C7—H7 120.7 C22—C23—H23 120.3
C9—C8—C7 120.2 (3) O5—C24—O4 122.2 (3)
C9—C8—H8 119.9 O5—C24—C21 119.6 (3)
C7—C8—H8 119.9 O4—C24—C21 118.1 (3)
C10—C9—C8 118.2 (3)