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Many body dispersion effects in the binding of adsorbates on metal surfaces

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Figure

FIG. 1. Binding energy curve showing the adsorption energyEads as a function of vertical distance d for Xe on Ag(111)calculated with the HSE+vdWsurf (blue line) and HSE+MBD(green line) methods
FIG. 2. Differential static polarizability ∆¯αmonolayer as calculated with the HSE+MBD method
FIG. 3. PTCDA overlayer adsorbed to Ag(111) surface withthe supercell geometry shown as a dotted line.
FIG. 4.Binding energy curve showing the adsorption en-PBE+MBD (green line) methods. The distanceAg(111) calculated with the PBE+vdWergy Eads as a function of vertical distance d for PTCDA onsurf (blue line) and d is evalu-ated with respect to the position
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