Version 2.6 SDS Number: Revision Date: 04/06/2018

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SECTION 1. IDENTIFICATION

Product name : Ag-Cu-Zn-Ni(>10%)-Mn

Trade name : BrazeTec 49/NIN, BrazeTec 49/NIN42, BrazeTec 49/CU/NI/FE

Product code : 300000000157

Manufacturer or supplier's details

Company name of supplier : SAXONIA Technical Materials GmbH

Address : SAXONIA Technical Materials GmbH

Rodenbacher Chaussee 4 63457 Hanau

Germany E-mail address of person re-

sponsible for the SDS

: [email protected]

Poison Center

Telephone : 1 800 222 1222

Hours of operation : 24HRS Supplier

Emergency telephone number

: For transport in Europe, Central- and South America, Israel and Africa (Non-Arabic speaking countries):+32 3 213 15 70 For transport in the Middle East (Israel excluded) & Arabic speaking Africa:+32 3 213 33 79

For transport in the USA and Canada:1-877 986 4267

For transport in Asian and the Pacific (China excluded):+65 62 64 78 36

For transport in China:(+86) 400 88 71 190

Hours of operation : This telephone number is available 24 hours per day, 7 days per week.

Recommended use of the chemical and restrictions on use Recommended use : brazing

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with 29 CFR 1910.1200 Skin sensitisation : Category 1

Carcinogenicity : Category 2 Specific target organ toxicity

- repeated exposure

: Category 1

Acute aquatic toxicity : Category 3

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GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H317 May cause an allergic skin reaction.

H351 Suspected of causing cancer.

H372 Causes damage to organs through prolonged or repeated exposure.

H402 Harmful to aquatic life.

Precautionary statements :

Prevention:

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/

face protection.

Response:

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P308 + P313 IF exposed or concerned: Get medical advice/

attention.

P333 + P313 If skin irritation or rash occurs: Get medical advice/

attention.

P363 Wash contaminated clothing before reuse.

Storage:

P405 Store locked up.

Disposal:

P501 Dispose of contents/ container to an approved waste disposal plant.

Additional Labelling

The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity:

27.5 %

The following percentage of the mixture consists of ingredient(s) with unknown hazards to the aquatic environment: 100 %

Other hazards

The classification in the safety data sheet may deviate from the classification on the label due to exemption 1.3.4 annex I of CLP.

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SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture

Hazardous components

Chemical name CAS-No. Concentration (% w/w)

Copper. 7440-50-8 <= 70

silver 7440-22-4 <= 70

zinc 7440-66-6 <= 50

manganese 7439-96-5 <= 30

Nickel 7440-02-0 <= 30

silicon 7440-21-3 <= 3

SECTION 4. FIRST AID MEASURES

General advice : Show this safety data sheet to the doctor in attendance.

Do not leave the victim unattended.

If inhaled : Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion.

If symptoms persist, call a physician.

In case of skin contact : Cover wound with sterile dressing.

If on skin, rinse well with water.

If on clothes, remove clothes.

In case of eye contact : Remove contact lenses.

Flush eyes with water as a precaution.

Protect unharmed eye.

Keep eye wide open while rinsing.

If eye irritation persists, consult a specialist.

If swallowed : Induce vomiting immediately and call a physician.

Keep respiratory tract clear.

Do not give milk or alcoholic beverages.

Never give anything by mouth to an unconscious person.

If symptoms persist, call a physician.

Take victim immediately to hospital.

Most important symptoms and effects, both acute and delayed

: Skin contact may provoke the following symptoms:

Allergic reactions

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Not combustible.

Unsuitable extinguishing media

: High volume water jet

Specific hazards during fire- : Do not allow run-off from fire fighting to enter drains or water

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fighting courses.

Hazardous combustion products

: Metal oxides Nickel compounds

Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Special protective equipment for firefighters

: Wear self-contained breathing apparatus for firefighting if nec- essary.

SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec-

tive equipment and emergency procedures

: Use personal protective equipment.

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.

If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and materials for containment and cleaning up

: Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE Advice on protection against

fire and explosion

: Normal measures for preventive fire protection.

Advice on safe handling : Avoid contact with skin and eyes.

For personal protection see section 8.

Smoking, eating and drinking should be prohibited in the application area.

Dispose of rinse water in accordance with local and national regulations.

Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place.

Observe label precautions.

Materials to avoid : Do not store near acids.

Further information on storage stability

: Keep in a dry place.

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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type

(Form of exposure)

Control parameters / Permissible concentration

Basis

Copper. 7440-50-8 TWA

(dust/mist)

1 mg/m3 (Copper)

ACGIH TWA

(Fumes)

0.2 mg/m3 (Copper)

ACGIH AGW (Fume,

alveolate part)

DE TRGS 900 Further information: Recommended Limit

TWA (Dust and mist)

1 mg/m3 (Copper)

ACGIH TWA

(Fumes)

0.2 mg/m3 (Copper)

ACGIH TWA (Dust

and mist)

1 mg/m3 (Copper)

ACGIH TWA

(Fumes)

0.2 mg/m3 (Copper)

ACGIH TWA (Dust) 1 mg/m3

(Copper)

NIOSH REL TWA (Mist) 1 mg/m3

(Copper)

NIOSH REL TWA (dusts

and mists)

1 mg/m3 (Copper)

OSHA Z-1 TWA

(Fumes)

0.1 mg/m3 (Copper)

OSHA Z-1 TWA

(Fumes)

0.1 mg/m3 (Copper)

OSHA P0 TWA (Dust

and mist)

1 mg/m3 (Copper)

OSHA P0

silver 7440-22-4 TWA 0.01 mg/m3

(Silver)

OSHA Z-1

zinc 7440-66-6 TWA (Total

dust)

15 mg/m3 OSHA/Z2

TWA 3 mg/m3 ACGIH

TWA 10 mg/m3 ACGIH

TWA (Total dust)

15 mg/m3 OSHA/Z2

TWA 3 mg/m3 ACGIH

TWA 10 mg/m3 ACGIH

manganese 7439-96-5 C (Fumes) 5 mg/m3 OSHA Z-1

TWA (Fumes)

1 mg/m3 (Manganese)

NIOSH REL ST (Fumes) 3 mg/m3

(Manganese)

NIOSH REL TWA

(Fumes)

1 mg/m3 (Manganese)

OSHA P0

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STEL (Fumes)

3 mg/m3 (Manganese)

OSHA P0 TWA (Inhal-

able fraction)

0.1 mg/m3 (Manganese)

ACGIH TWA (Res-

pirable fraction)

0.02 mg/m3 (Manganese)

ACGIH

Nickel 7440-02-0 TWA 1 mg/m3 OSHA P0

TWA (Inhal- able fraction)

1.5 mg/m3 ACGIH

TWA 1 mg/m3

(Nickel)

OSHA Z-1

TWA 0.015 mg/m3

(Nickel)

NIOSH REL

silicon 7440-21-3 TWA (Res-

pirable)

5 mg/m3 NIOSH REL

TWA (total) 10 mg/m3 NIOSH REL TWA (total

dust)

15 mg/m3 OSHA Z-1

TWA (respir- able fraction)

5 mg/m3 OSHA Z-1

TWA (Total dust)

10 mg/m3 OSHA P0

TWA (respir- able dust fraction)

5 mg/m3 OSHA P0

Personal protective equipment Hand protection

Material : Leather gloves

Eye protection : Safety glasses with side-shields conforming to EN166 Skin and body protection : Choose body protection according to the amount and con-

centration of the dangerous substance at the work place.

Hygiene measures : When using do not eat or drink.

When using do not smoke.

Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : massive form

Colour : metallic

Odour : odourless

Melting point/range : 670 - 890 °C Boiling point/boiling range : not determined

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Flash point : Method: closed cup does not flash

Flammability (solid, gas) : The product is not flammable.

Vapour pressure : not determined

Density : 9 g/cm3

Solubility(ies)

Water solubility : insoluble Auto-ignition temperature : not determined

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Stable

Chemical stability : No decomposition if stored and applied as directed.

Possibility of hazardous reactions

: No decomposition if stored and applied as directed.

Conditions to avoid : None known.

Incompatible materials : Acids

Oxidizing agents Hazardous decomposition

products

: No decomposition if stored normally.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity Product:

Acute oral toxicity : Acute toxicity estimate: 3,539 mg/kg Method: Calculation method

Acute inhalation toxicity : Remarks: No data available Acute dermal toxicity : Remarks: No data available

Components:

Copper.:

Acute oral toxicity : LD50 (Rat): > 2,500 mg/kg Method: OECD Test Guideline 401

Assessment: The substance or mixture has no acute oral toxicity

Remarks: Based on read across from structural related substance

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Acute inhalation toxicity : LC50 (Rat, male and female): > 4.74 mg/l Exposure time: 4 h

Test atmosphere: dust/mist

Method: OECD Test Guideline 403

Assessment: The substance or mixture has no acute inhalation toxicity

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

Assessment: The substance or mixture has no acute dermal toxicity

silver:

LD50 (Rat, female): > 2,000 mg/kg Method: OECD Test Guideline 423 LD50 (Mouse): > 5,000 mg/kg

Method: OECD Test Guideline 425 Acute inhalation toxicity : LC50 (Rat): > 5.16 mg/l

Exposure time: 4 h

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

Assessment: The substance or mixture has no acute dermal toxicity

zinc:

Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 5.4 mg/l Exposure time: 4 h

Acute dermal toxicity : Assessment: The substance or mixture has no acute dermal toxicity

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manganese:

Acute oral toxicity : Assessment: No data available Acute inhalation toxicity : Assessment: No data available Acute dermal toxicity : Assessment: No data available

Nickel:

Acute inhalation toxicity : No observed adverse effect level (Rat): > 10.2 mg/l Exposure time: 66 min

Acute dermal toxicity : Remarks: data waiving in REACH dossier

silicon:

Acute oral toxicity : LD50 (Rat): 3,160 mg/kg Acute inhalation toxicity : Assessment: No data available Acute dermal toxicity : Assessment: No data available

Skin corrosion/irritation Product:

Remarks: May cause skin irritation in susceptible persons.

Components:

Copper.:

Species: Rabbit Exposure time: 48 h

Method: OECD Test Guideline 404 Result: No skin irritation

silver:

Species: Rabbit Exposure time: 72 h

Nickel:

Species: Rabbit

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Serious eye damage/eye irritation Product:

Remarks: No data available

Components:

Copper.:

Species: Rabbit

Result: No eye irritation Exposure time: 72 h

Remarks: Based on read across from structural related substance

silver:

Species: Guinea pig Result: No eye irritation Exposure time: 72 h

Nickel:

Species: Rabbit

Result: No eye irritation Exposure time: 48 h

Respiratory or skin sensitisation Product:

Remarks: May cause sensitisation of susceptible persons by skin contact.

Components:

Copper.:

Exposure routes: Skin contact Species: Guinea pig

Result: Does not cause skin sensitisation.

silver:

Exposure routes: Skin contact Species: Guinea pig

Method: OPPTS 870.2600

Result: Does not cause skin sensitisation.

Remarks: Based on read across from structural related substance Exposure routes: Skin contact

Species: Guinea pig

Method: OECD Test Guideline 406 Result: Does not cause skin sensitisation.

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Nickel:

Exposure routes: Inhalation Species: Humans

Result: Does not cause respiratory sensitisation.

Exposure routes: Skin contact Species: Humans

Result: May cause sensitisation by skin contact.

Germ cell mutagenicity Product:

Genotoxicity in vitro : Remarks: No data available

Components:

Copper.:

Genotoxicity in vitro : Test system: Bacteria

Method: OECD Test Guideline 471 Result: negative

Genotoxicity in vivo : Species: Mammalian-Animal Method: OECD Test Guideline 486 Result: negative

Species: Mammalian-Animal Method: OECD Test Guideline 474 Result: negative

silver:

Genotoxicity in vitro : Test Type: Ames test Test system: Bacteria

Test system: mammalian cells Method: OECD Test Guideline 476 Result: positive

Test Type: Micronucleus test Test system: mammalian cells Method: OECD Test Guideline 487 Result: negative

Genotoxicity in vivo : Test Type: Micronucleus test Species: Mammalian-Animal

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Germ cell mutagenicity - Assessment

: Overall, there is no consistent evidence of induction of genetic toxicity with relevance to humans.

Nickel:

Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro Result: negative

Genotoxicity in vivo : Species: Mammalian-Animal Method: OECD Test Guideline 475 Result: negative

Carcinogenicity Product:

Components:

Nickel:

Species: Rat, (male and female)

Application Route: inhalation (dust/mist/fume) Exposure time: 24 month(s)

Dose: 0; 0,1; 0,4; 1 mg/m³ 0.1 mg/m³

Method: OECD Test Guideline 451 Species: Rat, (male and female) Application Route: Oral

Exposure time: 104 weeks

Dose: 10; 30; 50 mg/kg body weight Frequency of Treatment: daily NOAEL: 11 mg/kg bw/day

GLP: yes

Remarks: unit expressed as mg metal/kg

Based on read across from structural related substance

IARC Group 1: Carcinogenic to humans

Nickel 7440-02-0

Group 2B: Possibly carcinogenic to humans

OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP Reasonably anticipated to be a human carcinogen

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Nickel 7440-02-0

Reproductive toxicity Product:

Effects on fertility : Remarks: No data available

Components:

silver:

Effects on fertility : Species: Rat, male and female Application Route: Oral

Dose: 62,5; 125, 250 milligram per kilogram Duration of Single Treatment: 28 days

General Toxicity - Parent: NOAEL: > 250 mg/kg body weight General Toxicity F1: NOAEL: > 250 mg/kg body weight Method: OECD Test Guideline 422

Result: No effects on fertility and early embryonic develop- ment were detected.

GLP: yes Effects on foetal develop-

ment

: Species: Rat

Strain: Sprague-Dawley Application Route: Oral

Dose: 6,5; 19,4; 64,6 milligram per kilogram

General Toxicity Maternal: LOAEL: 19.4 mg/kg body weight Developmental Toxicity: NOAEL: > 64.6 mg/kg body weight Method: OECD Test Guideline 414

Result: No teratogenic effects, Maternal toxicity GLP: yes

Based on read across from structural related substance Species: Rat

Strain: Sprague-Dawley Application Route: Oral

Dose: 6,5; 19,4; 64,6 milligram per kilogram

General Toxicity Maternal: NOAEL: 6.5 mg/kg body weight Method: OECD Test Guideline 414

Result: No teratogenic effects GLP: yes

Nickel:

Effects on fertility : Species: Rat

Application Route: Oral

Dose: 0; 1; 2,5; 5;10 milligram per kilogram

General Toxicity - Parent: NOAEL: 10 mg/kg body weight General Toxicity F1: NOAEL: 10 mg/kg body weight Method: OECD Test Guideline 416

Remarks: Based on read across from structural related sub-

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stance Species: Rat

Application Route: inhalation (dust/mist/fume) Duration of Single Treatment: 13 Weeks General Toxicity - Parent: NOAEL: 0.45 mg/m³ Remarks: unit expressed as mg metal/m³

STOT - single exposure Product:

STOT - repeated exposure Product:

Components:

Nickel:

Exposure routes: Inhalation

Assessment: Causes damage to organs through prolonged or repeated exposure.

Exposure routes: Skin contact

Exposure routes: Ingestion

Repeated dose toxicity Components:

silver:

Species: Rat NOAEL: 30 mg/kg LOAEL: 300 mg/kg Application Route: Oral Exposure time: 28 d Dose: 30; 300; 1000

Method: OECD Test Guideline 407 Species: Rat

NOAEL: 30 mg/kg LOAEL: 125 mg/kg Application Route: Oral Exposure time: 90 d Number of exposures: 1/d Dose: 30; 125; 500

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Species: Rat, male and female NOAEL: 133 µg/m³

LOAEL: 515 µg/m³

Application Route: inhalation (dust/mist/fume) Exposure time: 6 h/d 90 d

Number of exposures: 5/7 d Method: OECD Test Guideline 413 Species: Rat

NOAEL: 9 mg/kg Application Route: Oral Exposure time: 28 d Dose: 2,25; 4,5; 9

Nickel:

Species: Rat, male and female LOAEL: 4 mg/m³

Application Route: inhalation (dust/mist/fume) Exposure time: 28 days

Dose: 0; 4; 8; 24

Method: OECD Test Guideline 412 Species: Rat, male and female LOAEL: 1 mg/m³

Application Route: inhalation (dust/mist/fume) Exposure time: 13 weeks

Dose: 0; 1; 4; 8

Further information Product:

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity Product:

Components:

Copper.:

Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.02 mg/l Exposure time: 48 h

Test Type: flow-through test

Not applicable to the specific form of the product.

Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 0.052 mg/l

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aquatic invertebrates Exposure time: 48 h Test Type: static test Remarks: Fresh water

Toxicity to fish (Chronic toxicity)

: NOEC (Pimephales promelas (fathead minnow)): 0.0225 mg/l Exposure time: 7 d

Remarks: Fresh water

Toxicity to daphnia and other aquatic invertebrates (Chron- ic toxicity)

: NOEC (Daphnia magna (Water flea)): 0.122 mg/l Exposure time: 7 d

Remarks: Not applicable to the specific form of the product.

Ecotoxicology Assessment

Acute aquatic toxicity : No data available

silver:

Toxicity to fish : Remarks: No toxicity at the limit of solubility Toxicity to daphnia and other

aquatic invertebrates

: Remarks: No toxicity at the limit of solubility

Toxicity to soil dwelling or- ganisms

: EC10 (Eisenia fetida (earthworms)): 5.3 mg/kg Exposure time: 28 d

NOEC (Eisenia fetida (earthworms)): 22.5 mg/kg Exposure time: 28 d

Plant toxicity : (Lactuca sativa (lettuce)): 0.13 mg/kg Sediment toxicity : NOEC (Hyalella azteca): 12 mg/kg

Duration: 10 d

zinc:

manganese:

Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 28 mg/l Exposure time: 96 h

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Remarks: Fresh water Toxicity to daphnia and other

: EC50 (Daphnia magna (Water flea)): 40 mg/l Exposure time: 48 h

Toxicity to algae : EC50 (Lemna minor (duckweed)): 31 mg/l Exposure time: 4 DAYS

Chronic aquatic toxicity : This product has no known ecotoxicological effects.

Nickel:

Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 15.3 mg/l Exposure time: 96 h

Remarks: unit expressed as mg metal/l Fresh water

Based on read across from structural related substance Toxicity to daphnia and other

: LC50 (Ceriodaphnia dubia (water flea)): 0.013 mg/l Exposure time: 48 h

Based on read across from structural related substance LC50 (Ceriodaphnia dubia (water flea)): 0.121 mg/l

Exposure time: 48 h Remarks: Fresh water

Based on read across from structural related substance Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (algae)): > 0.0815 - <

0.148 mg/l

Exposure time: 72 h

Method: OECD Test Guideline 201 Remarks: Fresh water

Based on read across from structural related substance EC50 (Pseudokirchneriella subcapitata (algae)): > 0.0253 - <

0.365 mg/l

Exposure time: 72 h

Method: OECD Test Guideline 201 Remarks: Fresh water

Based on read across from structural related substance NOEC: 0.0123 mg/l

Exposure time: 72 h

Method: OECD Test Guideline 201 Remarks: unit expressed as mg metal/l Fresh water

Based on read across from structural related substance NOEC (Desmodesmus sp.): 0.0225 mg/l

Exposure time: 72 h

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Based on read across from structural related substance EC10 (Champia parvula (marine algae)): 0.144 mg/l

Exposure time: 48 h

Remarks: unit expressed as mg metal/l Marine water

Based on read across from structural related substance EC10 (Lemna minor (duckweed)): 0.0082 mg/l

Exposure time: 7 d

Remarks: unit expressed as mg metal/l Fresh water

Based on read across from structural related substance M-Factor (Acute aquatic tox-

icity)

: 10

: NOEC (Pimephales promelas (fathead minnow)): 0.057 mg/l Exposure time: 32 DAYS

Based on read across from structural related substance NOEC (Danio rerio (zebra fish)): 0.04 mg/l

Exposure time: 8 days Remarks: Fresh water

Based on read across from structural related substance NOEC (Oncorhynchus mykiss (rainbow trout)): 0.134 mg/l Exposure time: 32 days

Based on read across from structural related substance EC10 (Cyprinodon variegatus (sheepshead minnow)): 20.76 mg/l

Exposure time: 28 days

Based on read across from structural related substance EC10 (Atherinops affinis (Topsmelt)): 3.599 mg/l Exposure time: 40 days

unit expressed as mg metal/l Marine water

: NOEC (Daphnia magna (Water flea)): 0.04 mg/l Exposure time: 42 days

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NOEC (Ceriodaphnia dubia (Water flea)): 0.0037 mg/l Exposure time: 10 days

Based on read across from structural related substance NOEC (Mysidopsis bahia (opossum shrimp)): 0.061 mg/l Exposure time: 36 days

Based on read across from structural related substance EC10: 0.089 mg/l

Exposure time: 72 h

Based on read across from structural related substance M-Factor (Chronic aquatic

toxicity)

: 10

Toxicity to microorganisms : EC50: 33 mg/l

Exposure time: 30 min Method: ISO 8192

unit expressed as mg metal/l Toxicity to soil dwelling or-

ganisms

: NOEC (Eisenia fetida (earthworms)): 180 mg/kg Exposure time: 21 days

Based on read across from structural related substance NOEC: 320 mg/kg

Exposure time: 28 days

Based on read across from structural related substance Plant toxicity : NOEC (Avena sativa (oats)): 88 mg/kg

Exposure time: 60 d

Based on read across from structural related substance EC10 (Lactuca sativa (lettuce)): 34 mg/kg

Exposure time: 63 d

Based on read across from structural related substance Sediment toxicity : EC10 (Chironomus riparius): 762 mg/kg

Remarks: unit expressed as mg metal/kg Fresh water

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EC10 (Tubifex tubifex): 1103 mg/kg Remarks: unit expressed as mg metal/kg Fresh water

Based on read across from structural related substance EC10 (Hyalella azteca): 82 mg/kg

Remarks: unit expressed as mg metal/kg Fresh water

Based on read across from structural related substance Toxicity to terrestrial organ-

isms

: NOEC (Anas platyrhynchos (Mallard duck)): 800 Exposure time: 90 days

Acute aquatic toxicity : This product has no known ecotoxicological effects., No toxicity at the limit of solubility, Dissolved metal concentration (in TDp) < acute Environmental Reference Value (ERV)

Chronic aquatic toxicity : This product has no known ecotoxicological effects., No toxicity at the limit of solubility, Dissolved metal concentration (in TDp) < chronic Environmental reference value (ERV)

silicon:

Persistence and degradability No data available

Bioaccumulative potential Components:

silver:

Bioaccumulation : Bioconcentration factor (BCF): 70

Nickel:

Bioaccumulation : Bioconcentration factor (BCF): > 1,631 Method: field study

Remarks: terrestrial environment

Based on read across from structural related substance Bioconcentration factor (BCF): 270

Method: field study Remarks: Fresh water

silicon:

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Partition coefficient: n- octanol/water

: log Pow: 57 - 77

Mobility in soil No data available Other adverse effects Product:

Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro- tection of Stratospheric Ozone - CAA Section 602 Class I Substances

Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S.

Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological information

: Harmful to aquatic life.

Components:

Nickel:

Results of PBT and vPvB assessment

: not applicable for inorganic substances

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : The product should not be allowed to enter drains, water courses or the soil.

Dispose of in accordance with the European Directives on waste and hazardous waste.

In accordance with local and national regulations.

Do not contaminate ponds, waterways or ditches with chemical or used container.

According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.

Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.

Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International Regulations UNRTDG

Not regulated as a dangerous good

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IATA-DGR

Not regulated as a dangerous good IMDG-Code

Not regulated as a dangerous good

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.

National Regulations 49 CFR - DOT

Not regulated as a dangerous good Special precautions for user

Not applicable

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Components CAS-No. Component RQ

(lbs)

Calculated product RQ (lbs)

Nickel 7440-02-0 100 400

SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ.

SARA 311/312 Hazards : Respiratory or skin sensitisation Carcinogenicity

Specific target organ toxicity (single or repeated exposure) SARA 313 : The following components are subject to reporting levels es-

tablished by SARA Title III, Section 313:

Copper. 7440-50-8 >= 50 - < 70 % silver 7440-22-4 >= 50 - < 70 %

zinc 7440-66-6 >= 30 - < 50 %

manganese 7439-96-5 >= 20 - < 30 % Nickel 7440-02-0 >= 20 - < 30 %

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Clean Air Act

This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):

manganese 7439-96-5 25 %

Nickel 7440-02-0 25 %

This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).

This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).

Clean Water Act

This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A.

This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3.

This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section 307

Copper. 7440-50-8 62 %

silver 7440-22-4 51 %

zinc 7440-66-6 37 %

Nickel 7440-02-0 25 %

US State Regulations

Massachusetts Right To Know

Copper. 7440-50-8

silver 7440-22-4

zinc 7440-66-6

manganese 7439-96-5

Nickel 7440-02-0

Pennsylvania Right To Know

Copper. 7440-50-8

silver 7440-22-4

zinc 7440-66-6

manganese 7439-96-5

Nickel 7440-02-0

silicon 7440-21-3

California List of Hazardous Substances

Copper. 7440-50-8

silver 7440-22-4

zinc 7440-66-6

manganese 7439-96-5

Nickel 7440-02-0

California Permissible Exposure Limits for Chemical Contaminants

Copper. 7440-50-8

silver 7440-22-4

manganese 7439-96-5

Nickel 7440-02-0

silicon 7440-21-3

The components of this product are reported in the following inventories:

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CH INV : On the inventory, or in compliance with the inventory DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory NZIoC : Not in compliance with the inventory

ENCS : Not in compliance with the inventory ISHL : Not in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory TCSI : On the inventory, or in compliance with the inventory

TSCA : On TSCA Inventory

TSCA list

No substances are subject to a Significant New Use Rule.

The following substance(s) is/are subject to TSCA 12(b) export notification requirements:

zinc 7440-66-6

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS® IV:

HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. The "*" represents a chronic hazard, while the "/" represents the absence of a chronic hazard.

Full text of other abbreviations

ACGIH : US. ACGIH Threshold Limit Values

ACGIH : USA. ACGIH Threshold Limit Values (TLV) Flammability

Health Instability

2 1

0

Special hazard.

FLAMMABILITY

1

PHYSICAL HAZARD HEALTH

0 * 3

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DE TRGS 900 : Germany. TRGS 900 - Occupational exposure limit values.

NIOSH REL : USA. NIOSH Recommended Exposure Limits

OSHA P0 : USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000

OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants

OSHA/Z2 : US. OSHA Table Z-2 (29 CFR 1910.1000) ACGIH / TWA : Time weighted average

ACGIH / TWA : 8-hour, time-weighted average DE TRGS 900 / AGW : Occupational Exposure Limit

NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek

NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday

OSHA P0 / TWA : 8-hour time weighted average OSHA P0 / STEL : Short-term exposure limit OSHA Z-1 / TWA : 8-hour time weighted average

OSHA Z-1 / C : Ceiling

OSHA/Z2 / TWA : Time weighted average

AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensa- tion, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Har- monized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan- gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - In- ternational Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Indus- trial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population;

LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Admin- istration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;

NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop- ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu- lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc- es; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub- stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;

UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative

The classification in the safety data sheet may deviate from the classification on the label due to exemption 1.3.4 annex I of CLP.

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Revision Date : 04/06/2018

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

US / EN