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5.1 Molecular Models for Methane Burning

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(1)

Carbon: Transformations in Matter and Energy

Environmental Literacy Project

Michigan State University

Systems and Scale

Unit

(2)

Unit Map

You

are

here

(3)

3

The bottom of flame at atomic-molecular scale

Oxygen

Carbon Dioxide

Water

(4)

The top of flame at atomic-molecular scale

Oxygen

Carbon Dioxide

Water

(5)

5

What happened between the bottom and the top of the flame?

Bottom of the

flame

Top of the flame

Oxygen

Carbon Dioxide

Water

(6)

Oxygen

Carbon Dioxide

Water

Methane

What’s the hidden

chemical change

when methane burns?

(7)

Answer each of the questions (numbered 1-4) below to explain how matter and energy move and change in a system. Note that matter movement is

addressed at both the beginning (1) and end (4) of your explanation.

Evidence We

Can Observe

BTB can indicate CO2 in the air.

Organic materials are made up of molecules containing carbon atoms:

• fuels • foods • living and dead plants and animals

•decomposers

Question

What is happening

to energy?

What forms of energy are involved?

What energy transformations take place during the chemical change?

Evidence We

Can Observe

We can observe indicators of different forms of energy before and after chemical changes:

• light energy • heat energy • chemical energy stored in organic

materials

• motion energy

Rules to Follow

All materials (solids, liquids, and gases) are made of atoms that are bonded together in molecules.

Scale: The matter movement question can be answered at the atomic-molecular, cellular, or macroscopic scale.

Question

Where are molecules

moving?

How do molecules move to the location of the chemical change?

How do molecules move away from the location of the chemical change?

Evidence We

Can Observe

Moving solids, liquids, and gases are made of moving molecules. A change in mass shows that molecules are moving

.

Question

How are atoms in molecules

being rearranged into

different molecules?

What molecules are carbon atoms in before and after the chemical change? What other molecules are involved?

Rules to Follow

Atoms last forever in combustion and living systems.

Atoms can be rearranged to make new molecules, but not created or destroyed.

Carbon atoms are bound to other atoms in molecules.

Scale: The matter change question is always answered at the atomic-molecular scale.

Rules to Follow

Energy lasts forever in combustion and living systems.

Energy can be transformed, but not created or destroyed.

C-C and C-H bonds have more stored chemical energy than C-O and H-O bonds.

(8)

Making the Reactant Molecules: Methane and

Oxygen

The flame of burning methane comes when methane (CH

4

) reacts with

oxygen (O

2

). Make a molecules of methane and oxygen on the reactant side

of your

Process Tool for Molecular Models 11 x 17 Poster:

1. Get the atoms you will need to make your molecules. Can you figure out

from the formula for methane how many C, H, and O atoms you will

need?

2. Use the bonds to make models of an methane molecule (CH

4

) and at

least 2 oxygen molecules (O

2

, with a double bond)

3. Identify the

high-energy bonds

(C-C and C-H) by putting twist ties on

them. How many high energy bonds does a molecule of methane have?

4. Compare your molecules to the pictures on the next slide. Are they the

(9)

9

Photo of reactant molecules: CH

4

(methane) and O

2

(oxygen)

Start by making the molecules and energy units of the reactants and putting them on the

reactants side, then rearrange the atoms and energy units to show the products.

Remember:

Atoms last foreve

r (so you can rearrange atoms into new molecules, but can’t add or

subtract atoms).

Energy lasts forever

(so you can change forms of energy, but energy units can’t

appear or go away)

Reactants

Products

Chemical

change

(10)

Important:

When you are

finished constructing

the reactants, put all

(11)

Rearranging the Atoms to Make Product

Molecules: Carbon Dioxide and Water

The flame of burning methane comes when methane (CH

4

) reacts with oxygen (O

2

)

to produce carbon dioxide (CO

2

) and water (H

2

O). Show how this can happen:

1. The heat of the flame breaks the bonds in the molecules, so their bonds can

break. Now they can recombine into carbon dioxide (CO

2

) and water vapor

(H

2

O). Make as many of these molecules as you can from one methane

molecule and oxygen.

2. Figure out numbers of molecules:

a) How many O

2

molecules do you need to combine with one methane molecule?

b) How many CO

2

and H

2

O molecules are produced by burning one molecule?

3. Remember,

atoms last forever.

So you can make and break bonds, but you still

need the same atoms.

4. Remember,

energy lasts forever.

What forms of energy do the twist ties

represent now?

5. Compare your molecules to the pictures on the next slide. Are they the same?

(12)

Photo of product molecules: H

2

O (water) and CO

2

(carbon dioxide)

Start by making the molecules and energy units of the reactants and putting them on the

reactants side, then rearrange the atoms and energy units to show the products.

Remember:

Atoms last foreve

r (so you can rearrange atoms into new molecules, but can’t add or

subtract atoms).

Energy lasts forever

(so you can change forms of energy, but energy units can’t

Reactants

Products

Chemical

change

Water

(13)

13

Comparing photos of reactant and product molecules

Start by making the molecules and energy units of the reactants and putting them on the

reactants side, then rearrange the atoms and energy units to show the products.

Remember:

Atoms last foreve

r (so you can rearrange atoms into new molecules, but can’t add or

subtract atoms).

Energy lasts forever

(so you can change forms of energy, but energy units can’t

appear or go away)

Reactants

Products

Chemical

change

Water

Carbon

dioxide

(14)

Reactants

Products

Chemical change

What happens

to atoms and energy

when methane

burns?

Methane

(15)

Reactants

Products

Chemical change

Oxygen

Water

Heat and light energy

Carbon Dioxide

What happens

to carbon atoms

when methane

burns?

Methane

Carbon atoms in

methane become

part of carbon

dioxide molecules.

(16)

Reactants

Products

Chemical change

Water

Carbon Dioxide

Methane

What happens

to oxygen atoms

when methane

burns?

Oxygen atoms

become part of

carbon dioxide and

(17)

Reactants

Products

Chemical change

Oxygen

Water

Heat and light energy

Carbon Dioxide

Methane

What happens

to hydrogen atoms

when methane

burns?

Hydrogen atoms

become part of

water molecules.

(18)

Reactants

Products

Chemical change

Water

Carbon Dioxide

Methane

What happens

to chemical energy

when methane

burns?

Chemical energy is

transformed into heat

(19)

Reactants

Products

Chemical change

What happens

to atoms and energy

when methane

burns?

Methane

Oxygen

Water

Heat and light energy

Carbon Dioxide

(20)

Writing a Chemical Equation

Chemists use

chemical equations

to show how atoms of reactant

molecules are rearranged to make product molecules

Writing the equation in symbols: Chemists use an arrow to show

how reactants change into products:

[reactant molecule formulas]

[product molecule formulas]

Saying it in words: Chemists read the arrow as “yield” or “yields:”

[reactant molecule names] yield [product molecule names]

Equations must be

balanced:

Atoms last forever, so reactant and

product molecules must have the same number of each kind of

atom

Try it: can you write a balanced chemical equation to show the

(21)

21

Chemical equation for methane

burning

CH

4

+ 2O

2

CO

2

+ 2 H

2

O

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