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A generic π* shape resonance observed in energy dependent photoelectron angular distributions from two colour, resonant multiphoton ionization of difluorobenzene isomers

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Figure

TABLE II. S1 vibrational levels used as intermediate states.
FIG. 2. Photoelectron angular distribution parameters, btions are also shown for differing assumed Sdifluorobenzene via Sa2, for para- (top),meta- (middle), and ortho-difluorobenzene (bottom)
FIG. 3. Measured and calculated b4 coefficients (see Fig. 2 for key).
FIG. 6. Iso-surface representations of: the resonant eigenchannels α in thethree isomers at a common energy 0.35 eV above the respective threshold(left column); the S0 LUMO orbitals from a minimal basis Hartree-Fock cal-culation (right column).

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