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WSRC-TR-964186

Unclassified

INTERIM SANITARY LAN

DFlLL

GROUNDWATER MONITORING

REPORT (U)

FIRST AND SECOND QUARTERS 1996

Publication Date: July 1996

Key Words

barium

LFW

wells

specific conuctance

trichlomfluoromethane

zinc

Westinghouse Savannah River Company Savannah River Site

Aiken,

SC

29808

(5)

WSRC-TR-96-0186

Unclassified

Interim Sanitary Landfill

ii

First and Second Quarters

1996

(6)

First and Second Quarters

1996

Data

Review

This report is for the first half of 1996. The wells in Table 1 were not sampled during second quarter 1996.

Key to Reading the Tables

The following abbreviations may appear in the data tables: Constituents 1,2,3,4,6,7,8-HPCDD 1,2,3,4,6,7,8*HPCDF 1,2,3,4,7,8-HXCDD 1,2,3,4,7,8-HXCDF Lindane

PCB

1,2,3,7,8-PCDD 1,2,3,7,8-PCDF Sp. conductance TCDD TCDF Laboratories CN

EM

GE and GP

sc

SP TM WA and WS

Sampling

Codes

L

N

1,2,3,4,6,7,8-heptachlorodibenzo-p-dioxin

1,2,3,4,6,7,8-heptachlorodibenzo-p-furan

1,2,3,4,7,8-hexachlordibenzo-pdioxin

1,2,3,4,7,8-hexachlorodibenzo-p-furan gamma-benzene hexachloride polychlorinated biphenyl 1,2,3,7,8-pentachlorodibenzo-pdioxin

1,2,3,7,8-pentachbrodibenzo-p-furan

specific conductance

tetrachlorodibenzo-pdioxin

tetrachlorodibenzo-p-furan

Clemson Technical Center, Inc.

Environmental Protection DepattmentEnvironmental Monitoring

Section

(EPDEMS) Laboratory

General Engineering Laboratories,

Inc.

Savannah River Technology Center Spencer Testing Services, Inc. TMAEbertine

Roy F. Weston, Inc.

blank sample was collected well was pumping continuousl! well was dry

equipment blank was collected

well went dry during sampling; insufficient water to collect all samples

well went dry before sampling began; only depth to water can be determined

well was not stabilized before sampling began

(7)

WSRCTR-964186

Unclassified

P

S

W

X

Sampling Methods

6

P

S

v

Units mgR msl MSL

NTU

p C i pCimL

PH

Pa

pSkm Other

cs

DF

E

H

Mod PDWS PVC ST TOC

inaccessibiii or mechanical failure prevented sample collection and field analysis of the water

no water in standpipe; for water-level events only purged water must be cantainerized; only water-level measurements were obtained

well went dry during purging; samples collected after well recovered

sample collected using an open-bucket bailer sample collected using a bladder pump

sample collected using a single-speed centrifugal downhole pump sample collected using

a

variable-speed pump

milligrams per liter mean sea level

million structures per liter nephelometric turbidity unit picocuries per liter

picocuries per milliliter pH unit

micrograms per iter

microsiemens per centimeter

carbon steel

dilution

factor

column in data tables

exponential notation (e.g., 1.1

E 4 9 = I.

1

x

10" = 0.000000001 1 ) holding time column in data tables

modifier column in data tables primary drinking water standard polyvinyl chloride

exceeded the final PDWS or screening level column in data tables Top of casing

Holding Times

Standard analytical methods include a limit, called holding time, on the maximum elapsed time between sample collection and extraction or analysis by the laboratory. In the data tables, a large bullet (.) in the

H

(holding time) column indicates that holding time was exceeded. Analyses performed beyond holding times may not yield valid results.

(8)

WSRGTR-96-07 86 Unclassified The South Carolina Department of Health and Environmental Control (SCDHEC) allows only 15 minutes to elapse between sampling and analysis for pH. Thus, only field pH measurements can meet the holding time criterion; laboratory pH analyses always will exceed it.

The laboratory procedure used for the determination of specific conductance allows one day to elapse between sampling and analysis. Thus, laboratory specific conductance measurements may exceed the holding time criterion.

Data

Rounding

Constituent results in analytical results tables that appear to equal the final PDWS but are not marked in the ST(exceeded the final PDWS or screening level) column are below the final PDWS in the database. Values stored in the database contain more significant digits than the reported results. Apparent discrepancies in the tables are due to the rounding of reported results.

Data Qualification

The contract laboratories submit sample-

or

batch-specific quality assurance/quality control information either at the same time as analytical results or in a quarterly summary. Properly defined and used data modifiers (also referred to as qualifiers) can be a key component in assessing data usability. Modifiers designed by EPDEMS and provided to the primary

laboratories are defined below. These modifiers appear in the data tables under the column

Mod.

The lettered modifiers are based on EPA's STORET codes.

Modifiers

(Blank)

I

J L

M

R

T

U V Y 1

2

3

Data are not qualified. Numbers should be interpreted exactly

as

reported. The value in the result field is the instrument reading, not the sample quantitation limit. Always used with the result qualifier

U.

Value is estimated because quantitation in the sample or in associated quality control samples did not meet specifications.

Value is off-scale high. The actual value is not known but is known to be greater than the value shown.

Presence of the analyte is verified but not quantified.

Result was rejected because performance requirements

in

the sample analysis or associated quality control analyses were not met.

Analyte was not detected; if present, it was below the criteria for detection. Material analyzed for but not detected. Analytical result reported is less than the sample quantitation limit.

Analyte was detected in an associated method blank.

Result was obtained from an unpreserved or improperly preserved sample. Data may not

be

accurate.

Result may

be

an underestimation of the true value due to analytical bias. Result may be an overestimation

of

the true value due to analytical bias. The associated result may be of poor precision (high variability) due to analytical bias.

Note: These are only some of the qualifers present in the database. All modifiers associated with the data are published in the result tables of EPDEMS' quarterly groundwater monitoring reports, the official

repository of the data.

(9)

WSRCTR-96-0186

Unclassified

Table 1. Groundwater Monitoring Results

for

Individual Wells

WELL LFW 28 m n a i t u d e N86079.6 33.290475 'N €45555.3 81.714056 W 03/01/96 mE 163.1 5.2 46 24.0 6 0 0.069 X

m

C l 0 4 0 ~5.0 1.9 31 e2.0 0.033 Brohochloromethane Brodichloromethane c2.0 Acetone Acrylonitrile

Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene

Bervllium. total recoverable

SAMPLE DATE FIELD DATA Parameter Water elevation PH Sp. conductance Water temperature Alkalinity as CaCO, Turbidity Volume purged Sampling code ANALYTICAL DATA Parameter Bromoform Bromomethane

Cadmium, total recoverable Carbon disulfide

Carbon tetrachloride Chlorobenzene Chloroethane

Chloroethene (Vinyl chloride) Chloroform

Chloromethane

Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromcchloromethane 1.2-Dibrom~3-chloropmpane 1 ,P-Dibrornoethane Dibromomethane 1 ,P-Dichlorobenzene 1 .4-Dichlorobenzene trans-l.4-Dichloro-2-butene 1 ,I-Dichloroethane 1.2-Dichlomethane 1,l-Dichloroethylene cis-I ,2-Dichloroethylene trans-I .2-Dichloroethylene Dichloromethane 1.2-Dichloropmpane CIS-1 ,3-Dichloropropene trans-I ,3-Dichloropropene Ethylbenzene 2-Hexanone

lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable PH c2.0 <2.0 (2.0 ~ 5 . 0 c2.0 -3.0 c2.0 Q.O <2.0 c2.0 1.4 0.22 37 <2.0 c2.0 c2.0 c2.0 <2.0 42.0 c2.0 c2.0 c2.0 4 0 C2.0 c2.0 c2.0 4 0 <lo ~ 5 . 0 4 0 4 0 0.3 5.6 Zone Fievation 162.1-141.1 RWl

Too of Cas il)g !am

BIm2screenzone

192.4 R msl 4"

Pvc

S Upper Steed Pond

Yli! R ins1 PH ~ S l a n 'C well vol

KL

Note: See Appendix 0 for flagging criteria.

0 = exceeded holding time.

= exceeded standard.

Interim Sanitary Landfill

M

1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 ~ S I Y E I a o 0 0 0 J 0 V . 0 0 J 0 0 0 0 0 0 0 0 0 0 0 0 J 0 J 0 V . 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 J 0 0 0 0 J1 0 0 4

I&

GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE

(10)

WSRCTR-964186 Unclassified WELL LFW 28 (cont)

Parameter lQ23

Selenium. total moverable Silver, total recoverattie

Spedfic conductance

Styrene

I ,I ,I .2-Tetrachloroethane 1.1.2.2-Tetrachloroethane Tetrachloroethylene Thallium. total recowrable Toluene 1.1 ,I-Trichloroethane I ,I ,2-Trichloroethane Trichloroethylene Trichlorolluoromethane 1,2,3-Trichbmpmpane

Vanadium, total recoverable Vinyl acetate

Xylenes

Zinc. total recoverable

45.0 c2.0 50 c2.0 42.0 42.0 e2.0 c2.0 42.0 c2.0 c2.0 42.0 c2.0 410 4 0 4.0 435 4 . 8 WELL LFW 32

SRS Coord. Latn onalhrde

~ a 5 t w . a 33.za8927 *N E44935.9 a1.715214 w SAMPLE DATE 01115/96 FIELD DATA Parameter Water elevation Sp. conductance Water temperature Alkalinity as CaCO, Turbidity volume purged Sampling code PH ANALYTICAL DATA Parameta Acetone Acrylonitrile

Antimony, total recoverable Arsenic, total recoverable

Barium, total recoverable Benzene

Beryllium, total recoverable Bromochloromethane Bromodichloromethane Bromoform

Bromomethane

Cadmium, total recoverable Carbon disulfide

Carbon tetrachloride Chlorobenzene Chloroethane

Chloroethene (Vinyl chloride) Chbrofwm

Chloromethane

Chromium, total recoverable cobalt. total recoverable

Copper. total moverable Dibromochloromethane s9.S 162.7 4.6 22 23.0 3 0 7.6 lQ23 410 4 0 1.7 45.0 7.8 c2.0 c3.0 42.0 e2.0 e2.0 c2.0 4 . 0 c2.0 42.0 c2.0 42.0 42.0 c2.0 4 . 0 4.7 e2.0 0.63 1.2-Dibromo-3chloroprpane 4.0 I ,2-Dibromoethane 42.0 Dibromomethane c2.0

E

1 1 I 1 I I I 1 I 1 I 1 I 1 I 1 1 1 V V W E C H r n 0 0 rn 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

Screen 7one Elevation 185.3-144.3 R mSl

Too of Casillg

223.7 ft msl

&&g B!!w Sueen Zone 4" Pvc S Upper Steed Pond

E

1 1 1 1 I 1 1 I I 1 1 1 1 1 1 I 1 1 1 1 1 I I I 1

Note: See Appendix B for flagging criteria.

0 = exceeded holding time.

H = exceeded standard.

Interim Sanitary Landfill

J V J V b ! k X ! s I H U 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5

m

GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE

(11)

WELL LFW

32

(cont) Parameter m9!3 I .2-Dchlorobenzene 1 ,QDichlwobenzene trans-I ,QDichloro-2-butene I ,I-Dichlomethane 1.2-Dichlomethane 1 ,I-Dichlomethylene cis-I ,2-Dichloroethylene trans-I ,2-Didrlomethylene Dichloromethane I ,2-Dichloropmpane cis-I ,bDichloropropene trans-1 .IDichloropropene Ethylbenzene 2-Hexanone

lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable PH

Selenium. total recoverable Silver, total recoverable Specificconductance Styrene

1.1 ,I ,2-Tetrachlomethane

1.1.2,2-Tetrachlomethane

Tetrachloroethylene Thallium, total recoverable Toluene l,l,l-Trichlomethane 1 ,I ,2-Trichlomethane Trichloroethylene Trichlorofiuoromethane 1,2,3-Trichloropropane Vanadium, total recoverable Vinyl acetate

Xylenes

Zinc, total recoverable

c2.0 c2.0 c2.0 c2.0 c2.0 4 . 4 C2.0 c2.0 c2.0 e10 c1 0 ~ 5 . 0 C5.0 e10 e1 0 5.3 ~ 5 . 0 e2.0 24 c2.0 c2.0 c2.0 c2.0 6 0 e2.0 e2.0 c2.0 96 c2.0 e10 4 0 c2.0 c6.0 7.9 WELL LFW 43C SRS Cwrd. N86480.6 €45234.9 SAMPLE DATE FIELD DATA Parameter Water elevation PH Sp. conductance Water temperature Alkalinity as CaCO, Turbidity Volume purged Sampling code ANALYTICAL DATA I aULonaitude 33.290838 "N 81.71 5679 "w 03/05/96 165.4 5.4 20 19.0 A

d

2.7 Parameter XlS Acetone e2.7 Acrylonitrile c1 0

Antimony, total recoverable ~0.20 Arsenic, total recoverable e3.0

Barium, total recoverable 4.8

Benzene c2.0 Unit 1 1 1 I I I V 1 1 I 1 1 1 J 1 I I 1 J1 I 1 1 I 1 1 I 1 1 1 I 1 1 1 I 1 I 1 v m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 e o 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE

Screen Zone Elevation 138.5-128.5 R mSl p E ! ! ! w s I Y E l a Q 1 v 0 I 0 1 0 1 J 0 1 J v 0 1 J 0

TOD of Casing Sueen 7one

202.6 R msl 4"WC S Middle Steed Pond

!ab WA WA GE GE GE GE Note: See Appendix B for flagging criteria.

0 = exceeded holding time. W = exceeded standard.

Interim Sanitary LandfiIl 6

Sk

well vol

(12)

WSRC-TR-96-07 86

Unclassified WELL LFW 43C (cont)

Para- r

Beryllium, total recoverable Bromochloromethane Bromodichloromethane ErottlOfOml

Bromomethane

Cadmium, total recoverable Carbon disulfide

Carbon tetrachloride Chlorobenzene Chiomethane

Chloroethene (Wnyl chloride) Chloroform

Chloromethane

Chromium, total recoverable Cobalt, total recoverable Dibromochloromethane 1,2-Dibromo-3-chloropropane I ,2-Dibromoethane Dibromomethane 1.2-Dilorobenrene I .4-Diilorobenzene trans-I +Diloro-2-butene I ,I-Dichlomethane 1,2-Dichlomthane 1,l-Dichlomethykne as-I .2-Diiloroethylene trans-I ,2-Dichloroethylene Diiloromethane I .2-Dichloropmpane us-I ,3-Dichloropmpene trans-I ,3-Dichloropropene Ethylbenzene 2-Hexanone

lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable

PH

Selenium. total recoverable Silver, total recoverable Specific conductance Styrene

1.1,1.2-Tetrachloroethane

1 ,I ,2.2-Tetrachloroethane Tetrachloroethylene Thallium. total recoverable Toluene I,l,l-Tnchloroethane 1,l .P-Trichloroethane Tnchloroethylene Trichlorofluoromethane 1,2,3-Tnchloropropane Vanadium, total recoverable Vinyl acetate

Xylenes

Zinc, total recoverable copper, total recoverable

m

0.090 4 . 0 (2.0 42.0 c2.0 S0.40 1.1 e2.0 (2.0 e2.0 e2.0 e2.0 %O 4 . 5 e2.0 (2.0 e2.0 c2.0 (5.0 4 . 0 e2.0 e2.0 c2.0 c2.0 ~ 5 . 0 e2.0 -4.0 (2.0 c2.0 c2.0 <IO ~ 5 . 0 2.5 0.79 4.5 e5.0 4 0 0.36 5.4 0.076 170 e2.0 c2.0 4 . 0 e2.0 e2.0 e2.0 e2.0 e2.0 e2.0 e2.0 e2.0 46.9 4 0 c2.0 0.029 6.6

DE

1 I 1 1 I 1 1 I I 1 1 1 1 1 I 1 I 1 I 1 1 1 1 I 1 1 I 1 1 1 I 1 1 1 I 1 1 1 1 1 1 1 I 1 1 I 1 1 1 1 1 I 1 I I 1 1

Note: See Appendix B for flagging criteria. 0 = exceeded holding time.

=exceeded standard.

Interim Sanitary Landfill

MQd J J J V J J1 J J S L H E t a S 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 I d 2 GE WA GE GE GE GE WA GE GE GE GE GE GE GE WA GE GE GE GE GE WA WA GE GE GE GE WA GE GE GE GE GE GE WA GE GE GE GE GE GE GE WA GE GE GE GE GE GE GE GE GE GE GE WA GE GE GE

(13)

WSRCTR-964186 Unclassified WELL

L W

43D SRS Coord. N88443.2 33.200771 'N E45244.5 81.715581 W SAMPLE DATE FIELD DATA parameter Water elevation PH Sp. conductance Water temperature Alkalinity as CaCO, Turbidity volume purged Sampling code ANALYTICAL DATA Parameter Acetone Acrylonltnle

Antrmony, total recoverable Arsenic, total recoverable Banum, total recoverable Benzene

Beryllium, total recoverable Bromochloromethane Bromodichlommethane Bromoform

Bromomethane

Cadmium, total recoverable

Carbon disulfde Carbon tetrachlonde Chlorobenzene Chloroethane

Chlomthene (Vinyl chlonde) Chloroform

Chloromethane

Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochloromethane 1 ,2-Dibromo-Xhloropropane 1.2-Dibromoethane Dibromomethane 1 .2-Dichlorobenzene 1 +Dichlorobenzene trans-l,4-Dichloro-2-butene 1 ,I-Dichloroethane 1,2-Dichloroethane 1 .l-Dichloroethylene cis-1,2-Dichloroethylene trans-I ,2-Dichloroethylene Dichloromethane 1.2-Dichloropropane us-I ,3-Dlchloropropene trans-I .3-Dichloropmpene Ethylbenzene 2-Hexanone

lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable PH

Selenium, total recoverable Silver, total recoverable

Speak conductance 03/01/96 IQB 165.5 4.8 12 24.0 3 I 9.0 e10 4 0 ~0.098 4 . 0 7.3 c2.0 ~0.30 e2.0 e2.0 e2.0 <0.40 e5.0 c2.0 c2.0 -3.0 e2.0 c2.0 c2.0 0.74 4.9 c2.0 c2.0 e2.0 42.0 e2.0 e2.0 e . 0 e2.0 c2.0 1.4 e2.0 c2.0 -2.0 4 0 4 0 4 . 0 410 0.89 0.37 5.3 e2.0 co.042 14 Zone Elevation 170.9-150.9 fl mJ

PE

I I I 1 1 1 1 1 1 I I I 1 1 I I I 1 $ 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1

Jv

J

Jv

J J V JV J1 V

Note: See Appendix B for flagging criteria.

0 = exceeded holding time.

I =exceeded standard.

lnteritn Sanitary Landfill

S I Y r n 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 e o 0 0 0

JOD Of tau GasiQg mnRScreenZone

202.9 it msl 4" wc S Upper Steed Pond

!ab GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE

(14)

WSRCTR-964186 Undassfied WELL LFW

43D

(cont) Parameter

m

Styrene 1,1.1,2-Tetrachloroethane 1 .1,2,2-Tetrachloroethane Tetrachloroethylene Thallium, total recoverable Toluene l,l,l-Trichloroethane 1 ,I ,2-Trichloroethane Trichloroethylene Trichlorofluoromethane I ,2.3-Trichloropropane Vanadium, total recoverable Vinyl acetate

Xylenes

Zinc, total recoverable

c2.0 c2.0 c2.0 c2.0 c0.20 c2.0 e2.0 C2.0 Q.O c2.0 e . 0 < I 0 c2.0 4.7 WELL LFW 74C SRS Coord. WLonaitude N85813.8 33.289140 "N E45097.8 81.714743 W SAMPLE DATE FIELD DATA Parameter Water elevation PH Sp. conductance Water temperature Alkalinity as CaCO, Turbidity Sampling code ANALYTICAL DATA Parameter Volume purged 03/05/96

rn

162.7 5.4 34 20.0 2 1 2.8 Acetone Acrylonitrile

Antimony, total recoverable Arsenic, total recoverable Banum, total recoverable Benzene

Beryllium, total recoverable Bromochloromethane Bromodichloromethane Bromoform

Bromomethane

Cadmium, total recoverable Carbon disulfide

Carbon tetrachloride Chlorobenzene Chloroethane

Chlomethene (Vinyl chloride) Chloroform

Chloromethane

Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochloromethane I ,2-Dibromo-3-chloroppane 1 ,2-Dibromoethane D i b r m t h a n e 1.2-Dichlorobenzene 1.4-Dichlorobenzene (10 4 0 c5.0 4.1 c2.0 5.2 0.060 c2.0 c2.0 c2.0 <o. 12 4 . 0 c2.0 c2.0 (2.0 c2.0 c2.0 c2.0 4 . 0 c0.82 5.2 c2.0 c2.0 c2.0 c2.0 1 1 I 1 1 1 1 I 1 I I W ~ . l d r n 0 0 0 0 0 0 0 0 0 0 0 V 0 0 0

TOO of Cas inq

213.6 ft msl 4" PVC Screen 7one E levation

116.0-101.0 R msl BE I 1 1 1 1 I 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1

Note: See Appendix B for flagging criteria.

0 = exceeded holding time.

= exceeded standard. 0 0 0 V 0 0 J 0 J 0 V V 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 !ab GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE BmFiScreenZone S Middle Steed Pond

(15)

WELL LFW 74C (cont) P?imm!x trans-I ,dDichloro-2-butene 1,l-Dichloroethane I .BDichlomethane 1 ,I-Dichloroethylene as-l,2-Dichloroethylene transl,2-Dichlorcethylene Dichloromethane 1,2-Diiloropropane cis-I ,tDichloropropene trans-1.3-Dichloropropene Ethylbenzene 2-Hexanone

lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable Selenium, total recoverable Silver, total recoverable Specific conductance

Styrene

I ,l ,1,2-Tetrachlomethane

1,1.2,2-Tetrachloroethane

Tetrachloroethylene Thallium, total recoverable Toluene 1 ,l,l-Trichloroethane 1.1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane 1.2,3-TrichIoropropane Vanadium, total recoverable Vinyl acetate

xylenes

Zinc, total recoverable PH

m

c2.0 c2.0 c2.0 c2.0 e2.0 e1 0 c2.0 e2.0 e2.0 e10 e10 e2.9 ~ 5 . 0 4 0 4 0 5.2 4 . 0 C2.0 35 C2.0 c2.0 c2.0 e2.0 ~ 5 . 0 c2.0 c2.0 c2.0 c2.0 c2.0 c2.0 e1 0 e10 c2.0 11 RE 1 1 1 1 1 1 1 1 1 I 1 I I 1 1 I 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ~ S I k ! ~ 0 0 0 0 0 0 0 0 0 0 0 V 0 0 0 0 J1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 lah GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE WELL LFW 74D SRS Coord. LatlLonaitudp N85828.1 33.289172 'N E45098.0 81.714771 W

Screen 70ne Elevation 167.7-1 52.7 R msl SAMPLE DATE FIELD DATA Parameter Water elevation PH Sp. conductance Water temperature Alkalinity as CaCO, Turbidity Volume purged Sampling code ANALYTICAL DATA Parameter Acetone Acrylonitrile

Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene

Beryllium. total recoverable

01/15/96

lcm

162.6 5.0 16 24.0 1 1 6.8

mJ3

6.4 4 0 c2.3 4 . 5 6.1 c2.0 c1.6

M

1 1 1 1 1 1 1 W s I B r n J 0 0 V 0

v

0 0 0 0

Note: See Appendix B for flagging criteria.

0 = exceeded holding time.

= exceeded standard.

Interim

Sanitary

Landfill

10

Jm of Casiw !ZmQ 213.9 R msl 4" PVC

lab

GE WA GE GE WA GE WA NTU well vol

(16)

WSRGTR-964186

Unclassified

WELL LFW

74D

(cont)

eaameter

Bromochloromethane Bromodichlmmethane B ~ m o f o ~ Bromomethane

Cadmium, total recoverable Carbon disulfide

Carbon tetrachlonde Chlorobenzene Chlmthane

Chloroethene (Vtnyl chlonde) Chloroform

Chloromethane

Chromtum. total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochloromethane 1,2-Dibmmo-3-chlornpmpane I ,2-Dibromoethane Dibromomethane 1 .2-Dichlorobenzene 1 ,4-Dichlorobenzene trans-l.4-Dichloro-2-butene 1,2-Dichloroethane 1 .l-Dichloroethylene CIS-1 .IDichloroethylene trans-l,2-Dichloroethylene Dichloromethane 1.2-D~chloropropane os-l,3-Dichloropropene trans-1 ,3-D1chloropropene Ethylbenzene 2-Hexanone

lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel. total recoverable PH

Selenium. total recoverable Silver. total recoverable Speufic conductance Styrene

1,l ,I ,P-Tetrachloroethane

l11,2.2-Tetrachloroethane

Tetrachloroethylene Thallium. total recoverable Toluene 1.1.1-Tnchloroethane 1,1,2-Tnchloroethane Tnchloroethylene TnchloroRuommethane 1,2,3-Tnchloropropane Vanadium, total recoverable Vinyl acetate

Xylenes

Zinc. total recoverable

1,l-DIchloroetha~ Bas 6 . 0 e2.0 (2.0 e . 0 e0.13 <5.0 e2.0 <2.0 <2.0 e2.0 e . 0 4 . 0 2.0 < O S 4.5 <2.0 e2.0 c2.0 <2.0 4 . 0 4 . 0 e2.0 c2.0 c2.0 G . 0 15.0 c2.0 4 . 8 c2.0 c2.0 c2.0 <IO ~ 5 . 0 8.6 4 . 0 4 0 4.1 5.7 4 . 0 1.1 33 e2.0 e2.0 <2.0 <2.0 4 . 0 c2.0 2.5 <2.0 c2.0 15 c2.0 4 . 9 4 0 <2.0 54 €!E 1 1 1 1 1 1 1 1 1 I 1 I 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 W S I V J V V V J J J J m m H E k J 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 lah WA GE GE GE GE GE GE GE GE GE GE GE WA GE GE GE GE GE GE WA WA GE GE GE GE WA GE GE GE GE GE GE WA GE GE GE WA WA GE WA GE ' GE GE GE GE GE GE WA GE GE WA GE WA GE GE GE

Note: See Appendix B for flagging criteria.

= exceeded holding time.

= exceeded standard.

(17)
(18)

WSRCTR-964186 Unclassified WELL LfW 75C

(cont)

Parameter

m

Styrene 1,1,1.2-Tetrachloroethane I ,1,2,2-Tetrachloroethane Tetrachloroethylene Thallium, total recoverable Toluene 1 .I '1-Trichloroethane 1 ,I ,2-Trichloroethane Trichloroethylene Trichlorofluoromethane I .2,3-Trichloropropane Vanadium, total recoverable Vinyl acetate

Xylenes

Zinc, total recoverable

c2.0 c2.0 4 . 0 (2.0 c2.0 c2.0 c2.0 c2.0 c2.0 c2.0 c0.72 <IO c2.0 32 2.9 LE 1 1 1 I I 1 1 1 1 1 I 1 I 1 1 w s T . t ! E l a a 0 0 0 0 J 2 0 0 0 0 0 0 V 0 0 0 V 8 0 la2

u

GE

wn

GE

w

GE

w

GE Pan GE P W GE Pgll GE P a n GE

w

GE Pan GE

w

GE P s n GE W L GE PglL GE PgR GE PgR WELL LFW 75D SRS Coord. N85868.0 E45355.6 SAMPLE DATE FIELD DATA Parameter Water elevation PH Sp. conductance Water temperature Alkalinity as CaCO, Turbidity Volume purged Sampling code ANALYTICAL DATA Parameter Acetone Acrvlonitrile Cat/LWitUde 33.289681 "N 81.714170 W 03/08/96 I Q96 162.5 5.4 30 20.0 5 1 5.7

m

Screen 70ne Elevation 166.0-1 51 .O R msl

LE

Antimy. total recoverable Arsenic, total recoverable Barium, total recoverable Benzene

Beryllium, total recoverable Bromochloromethane Brornodichloromethane Bromoform

Brornomethane

Cadmium, total recoverable Carbon disulfide

Carbon tetrachloride Chlorobenzene Chlomthane

Chloroethene (vinyl chloride) Chloroform

Chloromethane

Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochloromethane 1,2-Dibromo-3chlorop~ne 1,2-Dibromoethane Dibromomethane 1.2-Dichlorobenzene 1 &Dichlorobenzene transl.4-Dichloro-2-butene <IO 4 0 4 . 0 4 . 0 7.9 c2.0 <O.OIS c2.0 c2.0 c2.0 c2.0 6 . 0 c2.0 c2.0 c2.0 4.0 c2.0 c2.0 4 . 0 -=0.55 4 . 6 4 . 0 c2.0 4 . 0 c2.0 <2.0 1 1 1 1 I 1 I 1 1 1 1 I I 1 1 I 1 1 1 1 I I I 1 1 1 0 0 0 0 V 0 0 JV 0 0 0 0 J 0 0 0 0 0 0 0 0 0 V 0 V 0 0 0 0 0 0

NO@: see Appendix B for flagging criteria.

0 = exceeded holding time.

= exceeded standard. TOO of Ca$& 198.2 R msl

la

GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE sW!u 4- wc

evrrre

-

s

S Upper Steed Pond

(19)

WELL LFW 750 (cont) Parameter 1,l-Dichbmethane 1 ,2-Dichloroethane I ,1-Dichloroethylene a s 1 ,2-Dichbmethylene trans-I ,bDichloroethylene Dichloromethane 1,2-Dichloropropane cis-1.3-Dichloropropene trans-I ,BDichloropropene Ethylberuene 2-hexan one

lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable Selenium, total recoverable Silver, total recoverable Specific conductance Styrene

I ,1,1,2-Tetrachlomethane

1.1.2,2-Tetrachlomethane

Tetrachloroethylene Thallium, total recoverable Toluene

1 .I ,2-Trichloroethane Trichloroethylene Trichlomfluoromethane 1,2,BTrichIoropropane Vanadium, total recoverable Vinyl acetate

Xylenes

Zinc, total recoverable PH 1 .l ,l -Trichl~r~ethane IQB c2.0 c2.0 c2.0 c2.0 4 0 c2.0 c2.0 c2.0 4 0 4 0 4 . 0 4 . 0 < I 0 4 0 4 . 0 c2.0 25 c2.0 c2.0 c2.0 c2.0 ~ 5 . 0 c2.0 c2.0 c2.0 c2.0 c2.0 c2.0 ~0.66 c10 c2.0 43 6.0

E

1 1 1 1 1 1 1 1 I I 1 I 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

Note: See Appendix B for flagging criteria. 0 = exceeded holding time.

= exceeded standard.

Interim Sanitary Landfill

kwSIk!m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 JI 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 V 0 0 0 V . 0

!.a

GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE GE

(20)

WSRC-TR-96-07 86

Unclassified

Appendix A

Standards

(21)

lnterim Sanitary Landfill

WSRGTR-96-0186 Unclassified

THIS PAGE LEFT BLANK INTENTIONALLY.

(22)

WSRCTR-96-07 86 Unclassified

Standards

Analyte Acetone Acrylonitrile Antimony Arsenic Barium Benzene Beryllium Bromochloromethane' Bromodichloromethane Bromoform

2-Butanone (Methyl ethyl ketone) Cadmium Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chromium Cobalt Copper Dibromochloromethane 1,2-Dibromo-3-chloropropane 1 ,e-Dibromoethane 1,2-DichIorobenzene 1 ,4-Dichlorobenzene trans-1 ,4-Dichloro-2-butene 1,l -Dichloroethane 1,2-DichIoroethane 1,l-Dichloroethylene cis-1,2-Di~hloroethylene~ trans-l,2-Dichloroethylene 1,2-DichIoropropane cis-l,3-Dichloropropene trans-l,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Lead

Methyl bromide (Bromomethane) Methyl chloride (Chloromethane) Methylene bromide (Dibromomethane) Methylene chloride (Dichloromethane) 4-Methyl-2-pentanone (Methyl isobutyl ketone)

Level

100 5 30 10 20 5 3

-

5 5 100 40 5 5 5 10 5 70 70 29.8' 5 5 5 10 10 5 5 5 5

-

5 5 5

5

5 50 5 1 8b 10 10 5 10 50

Interim Sanitary Landfill A-3

-

Method EPA 8240 EPA 8240 EPA 7041 EPA 7060 EPA 6010 EPA 8240 EPA 6010

-

EPA 8240 EPA 8240 EPA 8240 EPA 6010 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 6010 EPA 6010 EPA 8240 EPA 8240 EPA 8240 EPA 8270 €PA 8270 EPA 8240 EPA 8240 EPA 8240 EPA 8240

-

EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240

First and Second Quarters 1996

(23)

Analyte Nickel PH Selenium Silver Specific conductance Styrene 1,1,1 ,BTetrachloroethane 1,1,2,2-TetrachIoroethane Tetrachloroethylene Thallium Toluene l,l,l-Trichloroethane 1 ,1,2-TrichIoroethane Trichloroethylene Trichlorof luoromethane 1,2,3-TrichIoropropane Vanadium Vinyl acetate

Vinyl chloride (Chloroethene) Xylene Zinc Level 50 4.11-6.1 5b 20 70 1 0.6-37.0b 5 5 5 5 10 5 5 5 5 5 5 80 5 10 5 29.3’ WSRGTR-96-07 86

Unclassified

Method EPA 601 0 EPA 7740 €PA 601 0 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 7841 EPA 8240 EPA 8240 EPA 8240 EPA 8240 €PA 8240 EPA 8240 EPA 601 0 EPA 8240 EPA 8240 EPA 8240

a No PQL is available for this constituent.

Tolerance limits for Appendix I parameters copper, lead, pH, specific conductance, and zinc are set according to the Interim Sanitary Landfill Groundwater Monitoring Program, Table 2-4.

References Cited

WSRC (Westinghouse Savannah River Company), 1994.

Interim Sanitary Landfill

Groundwater Monitoring Program, WSRC-IM-94-31

,

JuUy 1994, Rev. 0. Savannah River Site, Aiken, SC.

(24)

WSRCTR-964186

Unciassi fied

Appendix B

Flagging Criteria

(25)

Interim Sanitary Landfill

WSRC-TR-96-07 86 Unclassified

THIS PAGE LEFT BLANK INTENTIONALLY.

(26)

WSRC-TR-96-07 86 Unclassified

Flagging Criteria

The Savannah River Site Environmental Protection DepartmentEnvironmental Monitoring Section (EPDEMS) flagging criteria are as follows:

0 Flag 2 criteria for constituents equal the Safe Drinking Water Act (SDWA) final Primary

Drinking Water Standards (PDWS), the SDWA proposed PDWS, or the SDWA Secondary Drinking Water Standards (SDWS).

If

a constituent does not have a drinking water standard, the Flag 2 criterion equals 10 times the method detection limit (MDL) calculated as the 90th percentile detection limit obtained recently by one of the primary analytical laboratories. Flag 1 criteria for constituents equal one half of the final PDWS, one half the proposed PDWS, or one half the SDWS. If a constituent does not have a drinking water standard, the Flag 1 criterion equals 5 times the MDL calculated as the 90th percentile detection limit obtained recently by one of the primary analytical laboratories.

0

0

The following parameters are exceptions to the flagging rules:

0

Flag 0 criteria are assigned to constituent levels below Flag

1

criteria, constituent levels below the sample detection limits, or constituents having no flagging criteria.

EPDEMS sets flagging criteria for pH and specific conductance.

No

flags are set for alkalinity, calcium, carbonate, magnesium, potassium, silica, sodium, total dissolved solids, total phosphates (as P), and total phosphorus. Analyses for these parameters are conducted as part of the biennial comprehensive analyses or by special request.

Aesthetic parameters such as color, corrosivity, Eh, odor, surfactants, and turbidity are not assigned flagging criteria but are analyzed by special request.

Common laboratory contaminants and cleaners such as dichloromethane (methylene

chloride), ketones, phthalates, and toluene are not assigned flagging criteria unless they have PDWS. These constituents are analyzed by special request.

0 0 Analyte Acenaphthene Acenaphthylene Acetone

Acetonitrile (Methyl cyanide) Acetophenone 2-Acetylaminofluorene Acrolein Acrylonitrile Actinium-228 Alachlor Aldicarb’ Aldicarb sulfone’ Aldicarb sulfoxideo Aldrin

Alkalinity

(as

CaC03) Allyl chloride Aluminum

Aluminum, dissolved Aluminum, total recoverable Americium241

Americium-243 4Arninobiphenyi

Interim Sanitary Landfill

Flag

1 50 50 500 500 50 50 100 100 1.64E+03 1 1.5 1 2 0.25 No flag 250 25 25 25 3.1 7E+00 3.1 9E+00 50 8-3 Flag 2 100 100 1000 1000 100 100 200 200 3.27E+03 2 3 2 4 0.5

No

flag 500 50 50 50 6.34E+OO 6.37E+00 100 Sourcea EPA Method 8270 EPA Method 8270 EPA Method 8240 EPA Method 8240 EPA Method 8270 EPA Method 8270 EPA Method 8240 EPA Method 8240 Proposed PDWS (EPA, 1991) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8080 Set by EPDIEMS EPA Method 8240 SDWS (EPA, 1993b) SDWS (EPA, 1993b) SDWS (EPA, 1993b) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) EPA Method 8270

(27)

Analyte Ammonia Ammonia nitrogen Aniline Anthracene Antimony Antimony, dissolved Antimony, total recoverable Antimony-125

Aramite Arsenic

Arsenic, dissolved Arsenic, total recoverable Asbestos

Atrazine Azobenzene Barium

Barium, dissolved Barium, total recoverable Barium-1

40'

Benzene alpha-Benzene hexachloride beta-Benzene hexachloride delta-Benzene hexachloride Benzidine Benzo[a]anthracene Benzo[blfluoranthene Benzo[qf luoranthene Benzoic acid Benzo[g, h, flperylene Benzo[a]pyrene 1 ,CBenzoquinone Benzyl alcohol Beryllium Beryllium, dissolved Beryllium, total recoverable Beryllium-7

Bis(2-chloroethoxy) methane Bis(2-chloroet hyl) et her Bis(2-chloroisopropyI) ether Bis(ch1oromethyl) ether Bis(2-ethylhexyl) phthalate Bismuth-214 Boron Boron, dissolved Boron, total recoverable Bromide

Bromodichloromethane Bromoform

Bromomethane (Methyl bromide)

Interim Sanitary Landfill

Unit

P s n

P s n

P s n

P s n

P s n

P s n

P s n p C i

Psn

P s n

P s n P s n P s n

P s n

P s n

P s n

P s n

p C i P s n P s n P s n P s n

Pa

P s n

P s n

P s n Psn

P s n

PdL

P@-

P@-

P s n P s n PdL p C i

Psn

P s n P s n

P s n

P s n p C i

P s n

P s n P s n

P s n

P s n P s n P s n FibersR Flag 1 500 500 50 50 3 3 3 1.5E+02 50 25 25 25 3,500,000 1.5 50 1,000 1.000 1,000 4.5E+01 2.5 0.25 0.25 0.25 250 0.05 0.1 0.1 250 50 0.1 50 50 2 2 2 3E+03 50 50 50 50 3 9.4E+03 150 150 150 5,000 50 50 5 84 Flag 2 1,000 1 ,OOo 100 100 6 6 6 3E+02 100 50 50 50 7,000,000 3 100 2,000 2,000 2,000 9E+01 5 0.5 0.5 0.5 500 0.1 0.2 0.2 500 100 0.2 100 100 4 4 4 6E+03 100 100 100 100 6 1.89E+04 300 300 300 10,000 100 100 10 WSRGTR-96-07 86

Unclassified

sourcea APHA Method 4178 EPA Method 350.1 EPA Method 8270 EPA Method 8270 Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Interim Final PDWS (EPA, 1977) EPA Method 8270

Final PDWS (EPA, 199%) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 625

Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Interim Final PDWS (EPA, 1977) Final PDWS (EPA, 1993a) EPA Method 8080 EPA Method 8080 EPA Method 8080 EPA Method 8270 Proposed PDWS (EPA, 1990) Proposed PDWS (EPA, 1990) Proposed PDWS (EPA, 1990) EPA Method 8270 EPA Method 8270 Final PDWS (EPA, 1993a) EPA Method 8270 EPA Method 8270 Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Interim Final PDWS (EPA, 1977) EPA Method 8270

EPA Method 8270 EPA Method 8270 EPA Method 8270 Final PDWS (EPA, 1993a) Proposed PDWS (EPA, 1991) EPA Method 6010

EPA Method 6010 EPA Method 6010 EPA Method 300.0 Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8240

(28)

Analyte

CBromophenyl phenyl ether Butylbenzyl phthalate

2-sec-Butyl-4,6-dinitrophenol

Cadmium

Cadmium, dissolved Cadmium, total recoverable Calcium

Calcium, dissolved Calcium, total recoverable Carbofuran Carbon-1 4 Carbonate Carbon disulfide Carbon tetrachloride Cerium-1 41 Cerium-144 Cesium-lNa Cesium-137 Chlordane Chloride CChloroaniline Chlorobenzene Chlorobenzilate CChloro-m-cresol Chloroethane

Chloroethene (Vinyl chloride) Chloroethyl vinyl ether 2-Chloroethyi vinyl ether Chloroform

Chloromethane (Methyl chloride) 2-Chloronaphthalene

2-Chlorophenol

CChlorophenyl phenyl ether Chloroprene

Chromium

Chromium, dissolved Chromium, total recoverable Chromium-51

Chrysene Cobalt

Cobalt, dissolved Cobalt, total recoverable Cobalt-57 Cobalt-58' Cobalt-60 Color Copper Copper, dissolved Copper, total recoverable Corrosivity

P@

p C i Flag 1 50 No flag 3.5 2.5 2.5 2.5

No

flag

No

flag

No

flag 20 1 E+03 No flag 5 2.5 1.5E+02 1.31 E+@ 4.07E+O1 1 E+02 1 125,000 50 50 50 50 5 1 5 5 50 5 50 50 50 1,000 50 50 50 3E+03 0.1 20 20 20 5E+02 4.5E+03 5E+01 No flag 500 500 500 No flag Flag 2 100 No flag 7 5 5 5 No flag No flag

No

flag 40 2E+03 No flag 10 5 3E+02 2.61 E+02 8.13E+01 2E+02 2 250,000 100 100 100 100 10 2 10 10 100 10 100 100 100 2,000 100 100 100 6E+03 0.2 40 40 40 1 E+03 9E+03 1 E+02 No flag 1,000 1.000 1,000

No

flag WSRCTR-96-07 86 Unclassified Source' EPA Method 8270 Set by EPDEMS

Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Set by EPD/EMS

Set by EPDEMS Set by EPD/EMS

Final PDWS (EPA, 1993a) Interim Finai PDWS (EPA, 1977) Set by EPD/EMS

EPA Method 8240 Final PDWS (EPA, 1993a) Interim Final PDWS (EPA, 1977) Proposed PDWS (EPA, 1991)

Proposed PDWS (EPA, 1991)

Interim Final PDWS (EPA, 1977) Final PDWS (EPA, 1993a) SDWS (EPA, 1993b) EPA Method 8270 Final PDWS (EPA, 1993a) EPA Method 8270 EPA Method 8270 EPA Method 8240 Final PDWS (EPA, 199%) EPA Method 8240 EPA Method 8240 Final PDWS (EPA, 1993a) EPA Method 8240 EPA Method 8240 EPA Method 8270 EPA Method 8270 EPA Method 8240 Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Interim Final PDWS (EPA, 1977) Proposed PDWS (EPA, 1990) EPA Method 6010

EPA Method 6010 EPA Method 6010

Interim Final PDWS (EPA, 1977) Interim Final PDWS (EPA, 1977) Interim Final PDWS (EPA, 1977) Set by EPD/EMS

Final PDWS (SCDHEC, 1981) Final PDWS (SCDHEC, 1981) Final PDWS (SCDHEC, 1981) Set by EPDIEMS

(29)

WSRCTR-96-07 86 Unclassified

Source'

EPA Method 8270 EPA Method 8270 EPA Method 8270 Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Final PDWS (EPA. 1993a) Final PDWS (EPA, 199%) EPA Method 8080 EPA Method 8080 EPA Method 8080 EPA Method 8270 Proposed PDWS (EPA, 1990) EPA Method 8270

Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8240 Analyte m-Cresol(3-Methylphenol) 0-Cresol (BMethylphenol) pCresol(4-Methylphenol) Curium-242 Curium-243 curium-243/244e Curium-244 C~rium-245/246~ Curium-246 Cyanide DalaponD p,p'-DDD p,p'-DDE p,p'-DDT Diallate Dibenz[a,h]anthracene Dibenzofuran Di bromochloromet hane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane Di-n-butyl phthalate 1,2-Dichlorobentene 1 ,SDichlorobenzene 1 &Dichlorobenzene 3,3'-Dichlorobenzidine trans-l,4-Dichloro-2-butene Dichlorodifluoromethane 1,l -Dichloroethane 1 ,BDichloroethane 1,l -Dichloroethylene 1,2-DichIoroethylene cis-1 ,2-Dichloroethylene trans-l,2-Dichloroethylene Dichlorornethane (Methylene chloride) 2,4Dichiorop henol 2,6-Dichlorophenol 2,4-Dichlorophenoxyacetic acid 1 ,2-Dichloropropane cis-l,3-Dichloropropene trans-1 ,&Dichloropropene Dieldrin Di(2-ethylhexyl) adipate Diethyl phthalate Dimethoate p-Dimethylarninoazobenzene p-(Dimethylamin0)ethylbenzene 7,12-Dimethylbenz[a]anthracene (Methylene bromide)

Interim Sanitary Landfill

Flag 1 50 50 50 6.65E+01 4.1 5E+00 4.1 5E+00 4.92E+00 3.12E+00 3.1 4E+OO 100 100 0.5 0.5 0.5 50 0.15 50 50 0.1 0.025 5 No flag 300 50 37.5 50 150 5 5 2.5 3.5 25 35 50 2.5 50 50 35 2.5 5 5 2.5 200 No flag 50 50 50 50 6-6 Flag 2 100 100 100 1.33E+02 8.3E+00 8.3E+00 9.84E+OO 6.23E+00 6.27E+OO 200 200 1 1 1 100 0.3 100 100 0.2 0.05 10 No flag 600 100 75 100 300 10 10 5 7 50 70 100 5 100 100 70 5 10 10 5 400 No flag 100 100 100 100 Set by EPDEMS

Final PDWS (EPA, 1993a) EPA Method 8270 Final PDWS (EPA, 1993a) EPA Method 8270 EPA Method 8240 EPA Method 8240 EPA Method 8240 Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8270 EPA Method 8270

Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8240 EPA Method 8240 EPA Method 8080 Final PDWS (EPA, 1993a) Set by EPDEMS

EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270

(30)

WSRC-TU-96-07 86 Unclassified Sourcea EPA Method 8270 EPA Method 8270 EPA Method 8270 Set by EPD/EMS €PA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 Set by EPDEMS EPA Method 8270 EPA Method 8270 EPA Method 8270 Final PDWS (EPA, 1993a) EPA Method 9060 EPA Method 8270 Set by EPDEMS EPA Method 8080 EPA Method 8080 EPA Method 8080 Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8080 Set by EPDEMS

Final PDWS (EPA, 1993a) EPA Method 8270 EPA Method 8270

Interim Final PDWS (EPA, 1977) Interim Final PDWS (EPA, 1977) Interim Final PDWS (EPA, 1977) EPA Method 8270

EPA Method 8270 EPA Method 8270 Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8280

Analyte

3,3’-Dimethylbenzidine a,a-Dimethylphenethylamine 2,4-Dimethyl phenol Dimethyl phthalate 1,3-Dinitrobenzene 2,4Dinitrophenol 2,4-Dinitrotoluene 2,SDinitrotoluene Di-n-octyl phthalate 1 &Dioxane Diphenylamine 1 ,2-Diphenylhydrazine Diquat dibromide’ Dissolved organic carbon Disulfoton Eh Endosulfan I Endosulfan II Endosulfan sulfate Endothalf’ Endrin Endrin aldehyde Endrin ketone Ethylbenzene Ethyl methacrylate Ethyl methanesulfonate Europium-1 52 Europium-154 Europium-155 Famphur Fluoranthene Fluorene Fluoride Glyphosate’ Gross alpha Heptachlor Heptachlor epoxide Heptachlorodibenzo-pdioxin isomers 1,2,3,4,6,7,8-HPCDD Heptachlorodibenzo-p-furan 1,2,3,4,6,7,&HPCDF Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclo pentadiene Hexachlorodibenzo-p-dioxin 1,2,3,4,7,&HXCDD Hexachlorodibenzo-p-f uran isomers isomers isomers

Interim Sanitary Landfill

Flag 1 50 50 50

No

flag 50 250 50 50

No

flag 50

50

50 10 5,000 50

No

flag 0.5 0.5 0.5 50 1 0.5 No flag 350 50 50 3E41 1 E+02 3E+02 50 50 50 2,000 350 7.5E+00 0.2 0.1 0.00325 0.00325 0.00225 0.00225 0.5 50 25 0.00225 0.00225 0.002 8-7 Rag 2 100 100 100

No

flag 100 500 100 100 No flag 100 100 100 20 10,000 100

No

flag 1 1 1 100 2 1 No flag 700 100 100 6E+01 2E+02 6E+02 100 100 100 4,000 700 1.5E+01 0.4 0.2 0.0065 0.0065 0.0045 0.0045 1 100 50 0.0045 0.0045 0.004 EPA Method 8280 €PA Method 8280 EPA Method 8280 Final PDWS (EPA, 1993a) EPA Method 8270 Final PDWS (EPA, 1993a) EPA Method 8280

EPA Method 8280 EPA Method 8280

(31)

Analyte Hexachloroethane Hexachlorophene Hexachloropropene 2-Hexanone Indeno[l,2,3c,d]pyrene Iodine Iodine-1 29 Iodine-131c

lodomethane (Methyl iodide) Iron

Iron, dissolved Iron, total recoverable iron& lr0n-59~ Isobutyl alcohol lsodrin lsophorone lsosafrole Kepone Lanthanum-1 40' Lead Lead, dissolved Lead, total recoverable Lead-21 2

Lindane Lithium

Lithiurn, dissolved Lithium, total recoverable Magnesium

Magnesium, dissolved Magnesium, total recoverable Manganese

Manganese, dissolved Manganese, total recoverable Manganese-%

Mercury

Mercury, dissolved Mercury, total recoverable Methacrylonitrile

Methapyrilene Methoxychlor 3-Methylcholanthrene

2-Methyl-4,6-dinitrophenol

Methyl ethyl ketone Methyl isobutyl ketone Methyl methacrylate Methyl methanesulfonate 2-Methylnaphthalene Molybdenum 1,2,3,4,7,8-HXCDF

Interim Sanitary Landfill

Flag 1 0.002 50 250 50 50 50 250 5E-01 1.5E+00 75 150 150 150 1 E+03 1 E+02 500 50 50 50 50 3E+01 25 25 25 6.2E+01 0.1 25 25 25 No flag No flag No flag 25 25 25 1.5E+02 1 1 1 250 50 20 50 250

No

flag No flag 50 50 50 250 B-8 Flag 2 0.004 100 500 100 100 100 500 1 E+00 3E+00 150 300 300 300 2E+03 2E+02 1,0oo 100 100 100 100 6E+01 50 50

50

1.23E+02 0.2 50 50 50 No flag No flag No flag 50 50 50 3E+02 2 2 2 500 100 40 100 500

No

flag No flag 100 100 100 500 WSRCTR-96-0786 Unclassified Source' EPA Method 8280 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8240 EPA Method 8270 APHA Method 41 5A

Interim Final PDWS (EPA, 1977) Interim Final PDWS (EPA, 1977) EPA Method 8240

SDWS (EPA, 1993b) SDWS (EPA, 1993b) SDWS (EPA, 1993b)

Interim Final PDWS (EPA, 1977) Interim Final PDWS (EPA, 1977) EPA Method 8240

EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270

Interim Final PDWS (EPA, 1977) Final PDWS (SCDHEC, 1981) Final PDWS (SCDHEC, 1981) Final PDWS (SCDHEC, 1981) Proposed PDWS (EPA, 1991) Final PDW S (EPA, 1993a) EPA Method 6010 EPA Method 6010 EPA Method 601 0 Set by EPDlEMS Set by EPD/EMS Set by EPD/EMS SDWS (EPA, 1993b) SDWS (EPA, 1993b) SDWS (EPA, 1993b)

Interim Final PDWS (EPA, 1977) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8240 EPA Method 8270 Final PDWS (EPA, 1993a) EPA Method 8270 EPA Method 8270 Set by EPDIEMS Set by EPD/EMS EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 601 0

(32)

WSRGTR-96-0186 Unclassified

Sourcea

EPA Method 6010 EPA Method 6010 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 Proposed PDWS (EPA, 1991) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Interim Final PDWS (EPA, 1977) Interim Final PDWS (EPA, 1977) Interim Final PDWS (EPA, 1977) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8270 EPA Method 8270 EPA Method 8270 €PA Method 8270 EPA Method 351.2 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270

Interim Final PDWS (EPA, 1977) EPA Method 8280

EPA Method 8280 Set by EPDIEMS EPA Method 413.1 Final PDWS (EPA, 1993a) EPA Method 8080 EPA Method 8080 Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a)

Analyte

Molybdenum, dissolved Molybdenum, total recoverable Naphthalene 1 ,4Naphthoquinone 1 -Naphthylamine 2-Naphthylamine Neptunium-237 Nickel Nickel, dissolved Nickel, total recoverable Nickel-5gc NickeCf33c Niobium-95c Nitrate as nitrogen Nitrate-nitrite as nitrogen Nitrite as nitrogen m-Nitroaniline o-Nitroaniline p- Nitroaniline Nitrobenzene

Nitrogen by Kjeldahl method 2-Nitrophenol 4Nit rophenol 4-Nitroquinoline-1-oxide N-Nitrosodi-n-butylamine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine N-Ntrosodipropylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopipendine N-Nitrosopyrrolidine 5-Nitro-o-toluidine Nonvolatile beta Octachlorodibenzo-p-dioxin isomers Octachlorodibenzo-p-furan isomers Odor Oil & Grease OxamyP Parathion Parathion methyl PCB 1016 PCB 1221 PCB 1232 PCB 1242 PCB 1248 PCB 1254 Flag 1 250 250 50 50 50 50 3.53E+00 50 50 50 1.5E+02 2.5E+01 1.5E+02 5,000 5,000 500 50 50 50 50 500 50 50 50 50 50 50 50 50 50 50 50 50 50 2.5E+01 0.005 0.005 No flag 5,000 100 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Flag 2

500

500 100 100 100 100 7.06E+00 100 100 100 3E+02 5E+01 3E+02 10,000 10,000 1

.m

100 100 100 100 1,000 100 100 100 100 100 100 100 100 100 100 100 100 100 5E+01 0.01 0.01 No flag 10,000 200 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5

(33)

WSRGTR-96-07 86

Unclassified

Analyte PCB 1260 PCB 1262 Pentachlorobenzene Pentachlorodibenzo-p-dioxk isomers 1,2,3,7,8-PCDD Pentach torodibenzo-pfuran isomers 1,2,3,7,8-PCDF Pentachloroethane Pentachioronitrobenzene Pentachlorophenol PH PH Phenacetin Phenanthrene Phenol Phenols pphenylenediamine Phorate Picloramn 2-Picoline Plutonium-238 Plutonium-239 P1utonium-239/240~ Plutonium-240 ~~utonium-241 Plut0nium-242~ Potassium Potassium, dissolved Potassium, total recoverable Potassium40 Promethium-1 44 Promethium-1 46 Promethium-1 47 Pronamid Propionitrile Pyrene Pyridine

Radium (alpha emitting)' Radium-226 Radium-228 Radon-222 Ruthenium-103c Ruthenium-1 06 Safrole Selenium Selenium, dissolved Selenium, total recoverable Silica

Silica, dissolved Silica, total recoverable

Interim Sanitary Landfill

Flag 1 0.25 0.25 50 0.00275 0.00275 0.00275 0.00275 50 50 0.5 8 4 50 50 50 25 50 0.5 250 50 3.51 E+OO 3.11E+01 3.11 E+Ol 3.11 E+01 3.13E+01 3.27E+01 No flag No flag

No

flag 1.5E+02 5E+01 5E+01 2.62E+03 50 1,000 50 50 1 E+01 1 E+01 1 E+01 1.5E+02 1 E+02 1.5E+01 50 25 25 25 No flag No flag No flag 6-70 Rag 2 0.5 0.5 100 0.0055 0.0055 0.0055 0.0055 100 100 1 10 3 100 100 1 00 50 100 1 500 100 7.02E+00 6.21 E+O1 6.21 E+O1 6.22E+01 6.26E+01 6.54E+01 No flag No flag No flag 3E+02 1 E+02 1 E+02 5.24E+03 100 2,000 100 100 2E+01 2E+01 2E+01 3E+02 2E+02 3E+01 100 50 50 50 No flag No flag No flag Source*

Final PDWS (EPA, 1993a) Final PDWS (EPA, 1993a) EPA Method 8270 EPA Method 8280 EPA Method 8280 EPA Method 8280 EPA Method 8280 EPA Method 8270 EPA Method 8270 Final PDWS (EPA, 1993a) Set by EPD/EMS Set by EPD/EMS EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 420.1 EPA Method 8270 EPA Method 8080 Final PDWS (EPA, 1993a) EPA Method 8270 Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Set by EPDIEMS Set by EPD/EMS Set by EPD/EMS Proposed PDWS (EPA, 1986) EPA Method 901.1 EPA Method 901.1 Proposed PDWS (EPA, 1991) EPA Method 8270 EPA Method 8240 EPA Method 8270 EPA Method 8270 Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Proposed PDWS (EPA, 1991) Interim Final PDWS (EPA, 1977) Interim Final PDWS (EPA, 1977) EPA Method 8270

Final PDWS (EPA, 1993a) Final POW S (EPA, 1993a) Final PDWS (EPA, 1993a)

Set by EPDEMS Set by EPDEMS Set by EPDEMS

Figure

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References

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