Poly­[[bis­(1H imidazole κN3)­cadmium(II)] μ3 benzene 1,3 di­oxy­acetato]

Keywords: crystal structure; one-dimensional coordination polymer; cadmium(II); doubly- bridging azide liganda. CCDC reference

Each anion bridges two Cd atoms through the terminal carboxylate group and an imidazole N atom, forming polymeric complex chains running along the b axis. The uncoordinated

In the title complex, the Cd II ion is six-coordinated by three O atoms from a chelating acetate ligand and a methanol.. molecule, one N atom from a bbe ligand and two Cl

Pairs of Cd atoms with two carboxylate bridges form a dimeric unit with twofold rotation symmetry, and these dimeric units are further bridged by m -BDC ligands to form a

Each Cd II atom displays a distorted octahedral coordination defined by three carbox- ylate O atoms from different 3-CPOA 2 groups, two N atoms from two benzimidazole co-ligands

1, the Zn II atom exists in a distorted tetrahedral coordination that is defined by two N atoms from two benzimidazole molecules and two carboxyl O atoms from two different 3-CPOA 2