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Reactions of cationic (allyl)Ni(II) complexes with 1,3-dienes and olefins : polymerization and mechanistic studies

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Figure

Figure 1.1.  Polymer microstructures for polybutadiene and 2-substituted poly-1,3-dienes
Figure 1.2. Syn and anti allyls control the stereochemistry of the polymer chain.
Figure 2.1.   1 H NMR spectrum of complex 10 (500 MHz) in CD 2 Cl 2  at -30 ºC. 17
Figure 2.3.   1 H NMR overlay displaying insertion of butadiene into complex 10 at -30 ºC  generating the catalyst resting state, 12
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