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Novel Topologies in Vanadium-bis-β-Diketone Chemistry: A [V 4 ] and a [V 6 ] Metallacyclophane

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Figure

Figure 1. Molecular structure of [(VO) 4 (H 2 L) 4 (py) 4 ] (1) with crystallographically-independent  heteroatoms labeled
Figure 2. Molecular structure of [(V V O) 4 (V IV O) 2 (O) 4 (L2) 2 (py) 6 ] (2) with  crystallographically-independent heteroatoms labeled
Figure 3.  χ M T vs. T plots per mole of compounds 1 (green squares) and 2 (red circles)
Figure 5. Variable temperature X-band EPR spectra on solid powdered samples of complexes  1 (a) and 2 (b)

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