Information contained in this publication is true and accurate at the time of publication and to the best of our knowledge. The nominal values stated herein are obtained using laboratory test specimens. Before using one of the products mentioned herein, customers and other users should take all care in determining the suitability of such product for the intended use. Unless specifically indicated, the products mentioned herein are not suitable for applications in the pharmaceutical or medical sector. The Companies within Total Petrochemicals do not accept any liability whatsoever arising from the use of this information or the use, application or processing of any product described herein. No information contained in this publication can be considered as a suggestion to infringe patents. The Companies disclaim any liability that may be claimed for infringement or alleged infringement of patents.
Polypropylene PPC 9712
Refining & Chemicals
Polymers
Description
Polypropylene PPC 9712 is heterophasic copolymer with a Melt Flow Index of 25g/10 min combining good fluidity and mechanical properties.
Polypropylene PPC 9712 is characterized by excellent impact resistance and antistatic properties and has been formulated to allow faster cycling through early demoulding.
Polypropylene PPC 9712 has been developed specifically for the injection moulding of crates, pails and other heavy duty applications.
Characteristics
Handling and storage
Please refer to the safety data sheet (SDS) for handling and storage information. It is advisable to convert the product within one year after delivery provided storage conditions are used as given in the SDS of our product. SDS may be obtained from the website: http://www.totalrefiningchemicals.com
An Injection Moulding troubleshooting guide is available upon request.
Method Unit Typical
Value Rheological properties
Melt Flow Index 230°C/2.16 kg ISO 1133 g/10 min 25
Mechanical properties
Tensile Strength at Yield ISO 527-2 MPa 23
Elongation at Yield ISO 527-2 % 6
Tensile modulus ISO 527-2 MPa 1150
Flexural modulus ISO 178 MPa 1050
Izod Impact Strength (notched) ISO 180 kJ/m²
at 23°C >40
at -20°C 5.5
Charpy Impact Strength (notched) ISO 179 kJ/m²
at 23°C >40
at -20°C 6
Hardness Rockwell - R-scale ISO 2039-2 80
Thermal properties
Melting Point ISO 3146 °C 165
Vicat Softening Point ISO 306 °C
50N-50°C per hour 65
10N-50°C per hour 135
Heat Deflection Temperature ISO 752 °C
1.80 MPa - 120°C per hour 48
0.45 MPa - 120°C per hour 90
Other physical properties
Density ISO 1183 g/cm³ 0.905
Bulk Density ISO 1183 g/cm³ 0.525
Technical data sheet Polypropylene – Heterophasic Copolymer
Refining & Chemicals
Total Research & Technology Feluy Regulatory Affairs Tel. : +32 (0)64 51 40 67 [email protected] Page 1/3 CERTIFICATE N° 38545 Feluy, May 15, 2019
POLYPROPYLENE PPC 9712 grade as produced in Europe
Total Research & Technology Feluy
Zone Industrielle Feluy C – B-7181 Seneffe – Belgique. Tel. : +32 (0)64 51 41 11
Fax.: +32 (0)64 54 08 45
E-mail: [email protected]
Statement of compliance for food contact applications in Europe
1- Commission Regulation (EU) N° 10/2011 :
We confirm that the above-mentioned Product fulfills the harmonized requirements on plastic materials and articles intended to come into contact with food as described in the Regulation (EU) 10/2011 amended up to the Regulation (EU) 2019/37 and can therefore be lawfully marketed and used throughout the EU, based on the principle of mutual recognition on the following elements:
- All the monomers, polymer production aids and additives used in the Product are included in the Union list in the Regulation (EU) 10/2011 amended up to the Regulation (EU) 2019/37.
- For other substances (i.e. polymerization aids) used in the Product: they fall outside of the scope of harmonized Regulation (EU) 10/2011. According to article 19 they have been determined to be suitable for their intended use on the basis of the compliance with article 3 of the Framework Regulation (EC) N° 1935/2004 and potentially applicable national Member State Regulation (i.e. Germany – BfR 1) .
Restrictions and/or migration limits:
This Product contains one or more intentionally added substances with a specific migration limit and/or restrictions defined in Annex I of Regulation 10/2011/EU amended up to the Regulation (EU) 2019/37 and in BfR (1).
Experimental tests and/or theoretical calculation for migration carried out on the above mentioned Product (or a specimen representative of this material) covering long term storage at room temperature or below, including heating up to 70 °C for up to 2 hours, or heating up to 100°C for up to 15 minutes with aqueous foodstuffs (i.e. simulants A and B) and fatty foodstuffs (Single use, polymer used at 100% and thickness up to 250 µm) have shown that the overall and if relevant the specific migration limit was not exceeded with aqueous foodstuffs (i.e. simulants A and B) and fatty foodstuffs including metals of annex II.
1 Gesundheitliche Beurteilung von Kunststoffen im Rahmen des Lebensmittel- und
Bedarfsgegenständegesetzes (BfR) : Empfehlung VII: Polypropylen Stand 01.09.2017 – 221 Mitteilung-B. Gesundh.Bl.61(2018) 236
Total Research & Technology Feluy Regulatory Affairs Tel. : +32 (0)64 51 40 67 [email protected] Page 2/3 CERTIFICATE N° 38545 Feluy, May 15, 2019
POLYPROPYLENE PPC 9712 grade as produced in Europe
For other specific conditions of use, not covered above, it pertains to downstream users to check by appropriate overall and/or specific migration tests on the final material or article the suitability for contact with different food-types, various end-use conditions and different thickness . However these are beyond the control of TOTAL RESEARCH & TECHNOLOGY FELUY and are a part of the responsibility of the user of the above-mentioned Product. We shall supply the TOTAL REFINING & CHEMICALS proprietary information needed to perform the migration measurements/analyses upon request.
For obtaining more information, please send directly an e-mail to: [email protected]
Dual use additive:
We inform you that the above-mentioned Product contains one or more substance(s) defined as 'dual use additive(s)'.The downstream user must contact us for additional information and you must inform the downstream user accordingly.
NIAS
Total is well aware of the legal requirements of Regulation 1935/2004/EC and 10/2011/EU, namely materials and articles coming into contact with food shall be manufactured so that they do not transfer their constituents to food in quantities that could endanger human health or bring about unacceptable change to the composition of the food. This does not only include constituents which are intentionally added but also non-intentionally added substances (NIAS).
2- Regulation (EC) N°1935/2004 of the European Parliament & of the Council (Framework Regulation)
We hereby confirm that the above-mentioned Product, when used under normal or foreseeable conditions of use, is expected to meet the relevant requirements laid down in Regulation 1935/2004/EC.
Moreover, we inform you that the organoleptic properties are influenced by the conditions of use i.e. temperature, type of packaged foodstuff, storage conditions. Consequently, the packaging has to be controlled by the downstream user following the specific end-use conditions of use.
3- Commission Regulation (EC) N° 2023/2006 (GMP)
We inform you that the production of the above-mentioned Product is systematically reviewed with regards to good manufacturing practice (GMP) using our ISO 9001 System, and following the Plastics Europe guideline specifically dedicated to GMP.
Therefore we can state that the above-mentioned Product meets the relevant requirements laid down in Commission Regulation (EC) 2023/2006.
Refining & Chemicals
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POLYPROPYLENE PPC 9712 grade as produced in Europe
Total Research & Technology Feluy
Zone Industrielle Feluy C – B-7181 Seneffe – Belgique. Tel. : +32 (0)64 51 41 11
Fax.: +32 (0)64 54 08 45
E-mail: [email protected]
DISCLAIMER:
Our certificate is only valid for as far as above mentioned Product was bought from Total or its distributor and does not cover:
- Any modification of the above-mentioned Product by any addition of any other product or ingredient to it;
- Any prejudicial modification of the above-mentioned Product resulting from a processing of it;
- An inadequate use and/or storage of the above-mentioned Product and/or of the finished articles.
Unless specifically indicated in a regulatory certificate of compliance, the products mentioned herein are not suitable for applications in the pharmaceutical or medical sector. Under no circumstances are any products sold by Total Refining & Chemicals suitable for humans or animals in the following applications: (i) Implantable devices intended for human or animal body (ii) Devices intended to be used in contact with internal body fluids (iii) Devices intended to be used in contact with internal body tissues.
Information contained in this publication is true and accurate at the time of publication and to the best of our knowledge. The nominal values stated herein are obtained using laboratory test specimens. Before using one of the products mentioned herein, customers and other users should take all care in determining the suitability of such product for the intended use. The Companies within Total Refining & Chemicals do not accept any liability whatsoever arising from the use of this information or the use, application or processing of any product described herein. No information contained in this publication can be considered as a suggestion to infringe patents. The Companies disclaim any liability that may be claimed for infringement or alleged infringement of patents.
The present certificate is valid for a period of eighteen months starting from the date first above written and replaces any earlier certificate relating on this subject which should be considered as null and void. Upon the expiration of this certificate, we can issue a new one at your request. In case of change during this period a new certificate will be issued automatically; kindly forward it to any recipient of the present certificate.
TOTAL RESEARCH & TECHNOLOGY FELUY C. RAIMOND F. RADERMACHER Regulatory Affairs Regulatory Affairs, Manager Issued by an electronic system
Refining & Chemicals
Total Research & Technology Feluy Regulatory Affairs Tel. : +32 (0)64 51 40 67 Fax.: +32 (0)64 51 41 49 [email protected] Certificate N° ARP/20L00266 Page 1 of 8 Letter: ARP/20L00266 Feluy, 11/03/2020
PRODUCT STEWARDSHIP CERTIFICATE
ALL POLYPROPYLENE PPC, PPH, PPM, PPR, PPS, ACESO® AND LUMICENE® PRODUCTS (Manufactured in Europe)
A. ABSENCE OF SUBSTANCES
We hereby confirm that we do not intentionally use the following substances as additive* in the manufacturing of the above-mentioned Products:
1
ALLERGEN SUBSTANCES
as listed in Annex II of Regulation (EU) 1169/2011
2 ANTHRAQUINONE CAS 84-65-1
3 ANTIMONY TRIOXIDE CAS 1309-64-4
4
AROMATIC AMINES
as listed in Regulation 1907/2006/EC Annex XVII Appendix 8
5 ASBESTOS as listed in Regulation 1907/2006/EC Annex XVII
6
AZOCOLORANTS
as listed in Regulation 1907/2006 Annex XVII Appendixes 8 and 9
7 BENZENE CAS 71-43-2
8 BENZOPHENONE DERIVATIVES
We mean the following substances by benzophenone derivatives : Benzophenone (CAS 119-61-9), 2-hydroxybenzophenone (CAS 117-99-7), 3-hydroxybenzophenone (CAS 13020-57-0), 4-hydroxybenzophenone (CAS 1137-42-4), 4-methylbenzophenone (CAS 134-84-9),
9 BIOCIDAL PRODUCTS as defined in Article 3(1)(a) of the Regulation (EU) No 528/2012 10 BISPHENOL A, BISPHENOL B,
BISPHENOL F and BISPHENOL S
CAS 80-05-7, CAS 77-40-7, CAS 620-92-8 and CAS 80-09-1
11 BHA (ter-Butyl-4-hydroxyanisole) CAS 25013-16-5 12 BHT (2,6-di-ter-butyl-p-cresol) CAS 128-37-0
Refining & Chemicals
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Issued by an electronic system 2/8
SA TOTAL RESEARCH & TECHNOLOGY FELUY NV Zone Industrielle C – B-7181 Seneffe (Feluy)
Tél. : +32 (0)64 51 41 11 - Fax. : +32 (0)64 54 08 45 - Courriel : [email protected]
RPM Charleroi 0438.021.316 T.V.A. BE 0438.021.316 – BNP Paribas Fortis IBAN BE48 2100 4738 2027 BIC GEBABEBB 13 CHLORINATED ALIPHATIC COMPOUNDS
We mean the following substances by chlorinated aliphatic compounds:
tetrachloromethane (CAS 56-23-5), 1,1,2,2-tetrachloroethane (CAS 79-34-5), 1,1,1,2-tetrachloroethane (CAS 630-20-6), pentachloroethane (CAS 76-01-7),
trichloromethane (chloroform; CAS 67-66-3), 1,1,2-trichloroethane (CAS 79-00-5), 1,1-dichloroethylene (CAS 75-35-4), 1,1,1-trichloroethane (CAS 71-55-6). 14 CHLOROFLUOROCARBONS (CFC), HYDROGENATED CHLOROFLUOROCARBONS (HCFC) AND HALONES
15 CMR SUBSTANCES as listed in Regulation 1272/2008/EC Annex VI
16
CONFLICT MINERALS
(Section 1502 of the Dodd-Frank Wall Street Reform and Consumer Act)
We mean the following substances by conflict minerals: cassiterite, columbite-tantalite, wolframite, tin, tantalum, tungsten and gold
17
COSMETIC prohibited ingredients as listed in Annex II and III of the REGULATION (EC) 1223/2009 on COSMETIC PRODUCTS
18 DIMETHYLFUMARATE CAS 624-49-7
19 DIOXINS AND DIFURANS 20
ENDOCRINE DISRUPTORS category I and II mentioned in Annex 13 of the final report of BKH STUDY 2000
Nevertheless, we inform you that traces of
Dibutylphthalate (DBP) may be present in some of our products as catalyst modifier residues. The maximum residue would not exceed 1 ppm.
21 EPOXIDIZED SOYA BEAN OIL (ESBO) CAS 8013-07-8
22 EPOXY DERIVATIVES Regulation 1895/2005/EC
2,2-bis (4-hydroxyphenyl) propane bis (2,3-epoxypropyl) ether (’BADGE’), bis(hydroxyphenyl) methane bis (2,3-epoxypropyl) ethers (’BFDGE’) and novolac glycidyl ethers (’NOGE’)
23 ETHANOL CAS 64-17-5
24 FLAME RETARDANTS This include Hexabromocyclododecane (HBCD)
25 FORMALDEHYDE CAS 50-00-0
26 HALOGENS
We mean the following substances by Halogens: Fluorine (CAS 7782-41-4), Chlorine (CAS 7782-50-5), Bromine (CAS 7726-95-6), Iodine (CAS 7553-56-2) 27 HEAVY METALS Directive 94/62/EC and Directive
2004/12/EC
The overall concentration of cadmium, mercury, lead and chromium is lower than 100 ppm (w/w). 28 ISOPROPYLTHIOXANTHONE (ITX) CAS 5495-84-1 and CAS 83846-86-0
29 LATEX
We mean the following by latex: "a white, tacky, aqueous suspension of a hydrocarbon polymer occurring naturally in some species of trees, shrubs, or plants, or made synthetically".
Refining & Chemicals
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31 METALS as listed beside Nickel, Barium, Cobalt, Arsenic
32 MOSH (Mineral Oil Saturated Hydrocarbons), MOAH (Mineral Oil Aromatic Hydrocarbons), & Mineral Oil
However, we inform you that some trace amount of Mineral Oil can be present in some of here above mentioned products as a manufacturing process residue. This Mineral Oil is included in the Union List of the authorized substances for the manufacturing of plastic materials intended to come into contact with food
33 N_METHYLPYRROLIDONE (NMP) CAS 872-50-4
34
NONYLPHENOL AND
NONYLPHENOLETHOXYLATES as listed in Regulation 1907/2006/EC Annex XVII
35 ORGANOTIN COMPOUNDS
We mean the following substances by organotin compounds: Monobutyltin compounds (MBT), Dibutyltin compounds (DBT), Dioctyl Tin compounds (DOT), Tributyltin compounds (TBT), Triphenyltin compounds (TPT) and Tributyltin Oxide (TBTO)
36
OZONE-DEPLETING SUBSTANCES - Regulation 1005/2009/EC
- The Montreal Protocol on Substances that deplete the Ozone Layer, as last adjusted and/or amended in Montreal 19-2007 (UNEP-United Nation Environment Program)
- The United States (Clean Air Act, as amended in 1990, title VI, section 602 (a), class I and II.
CFCs, Halons, Other fully halogenated CFCs, Carbon tetrachloride, 1,1,1-Trichloroethane (Methyl
chloroform), Hydrochlorofluorocarbons (HCFC), Hydrobromofluorocarbons (HBFC), Methyl bromide, Bromochloromethane.
37
PARABENS as listed in Annex II and V of the Cosmetic Regulation
1223/2009/EC 38
PENTACHLOROPHENOL and its salts and esters
as listed in Regulation 1907/2006/EC Annex XVII
39
PERFLUOROOCTANE SULFONATE (PFOS) AND PERFLUOROOCTANOIC ACID (PFOA)
40 PESTICIDES, HERBICIDES as defined in Article 2 of the REGULATION (EC) No 1107/2009
41 PHTHALATES
Nevertheless, we inform you that traces of Phthalates may be present in some of our products, as catalyst modifier residues. The maximum residue would not exceed 1ppm.
42
POLYBROMOBIPHENYLS and POLYBROMODIPHENYLETHERS - Regulation 1907/2006/EC Annex XVII - Directive 2011/65/EU
This includes penta-, octa-, decabromobiphenylethers.
43 POLYCHLORINATED BIPHENYLS (PCB) 44 POLYCHLORINATED NAPHTHALENES (PCN) 45 POLYCHLORINATED TERPHENYLS (PCT)
Refining & Chemicals
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Issued by an electronic system 4/8
SA TOTAL RESEARCH & TECHNOLOGY FELUY NV Zone Industrielle C – B-7181 Seneffe (Feluy)
Tél. : +32 (0)64 51 41 11 - Fax. : +32 (0)64 54 08 45 - Courriel : [email protected]
RPM Charleroi 0438.021.316 T.V.A. BE 0438.021.316 – BNP Paribas Fortis IBAN BE48 2100 4738 2027 BIC GEBABEBB 46
POLYCYCLIC AROMATIC HYDROCARBONS (PAH)
as listed in Regulation 1907/2006/EC Annex XVII (1272/2013/EC)
47
POLYVINYLCHLORIDE (PVC), VINYLCHLORIDE MONOMER, POLYVINYLIDENE CHLORIDE (PVDC) VINYLIDENE CHLORIDE MONOMER
48 POP - Persistent Organic Pollutants As listed in Regulation EU 2019/1021
49 PROPOSITION 65, January 3, 2020
Chemicals listed in the Proposition 65, California Safe Drinking Water and Toxic Enforcement Act of 1986, dated January 3, 2020 (chemicals list that you can find at the following web address:
http://www.oehha.org/prop65/prop65_list/Newlist.html). We can hereby confirm that we do not use the chemicals mentioned in this list as additive*. However, some trace amount of Di-isobutyl phthalate (DIBP) and Dibutyl phthalate (DBP), may be present in some of our products, as catalyst modifier residues.
50 RADIOACTIVE SUBSTANCES as defined in Directive 2013/59/EURATOM
Laying down basic safety standards for the protection of the health of workers and the general public against the dangers arising from ionizing radiation.
51
RECYCLED MATERIALS
as defined in Commission Regulation 282/2008/EC
52 SEMICARBAZIDE and AZODICARBONAMIDE
53 SHORT CHAINED CHLORINATED PARAFFINS
Short-Chain Chlorinated Paraffins (SCCPs) include all individual chemicals or mixtures that contain: CxH(2x-y+2)Cly. Where x = 10-13; y = 3-12; and the average chlorine content ranges from approximately 40 to 70 percent with the limiting molecular formulas set at C10H19Cl3 and C13H16Cl12
54 SILICONE CAS 63148-53-8, 63394-02-5, 90337-93-2, 63148-62-9
55 STYRENE CAS 100-42-5
56 TITANIUM ACETYL ACETONATE (TAA) CAS 77927-72-9
57 TRICLOSAN (2,4,4'-Trichloro-2'-hydroxydiphenyl Ether) Decision 2010/169/EU
CAS 3380-34-5
58 TRIS(NONYLPHENYL) PHOSPHITE (TNPP) CAS 26523-78-4
* Additive as defined in Regulation (EU) 10/2011
However, since we do not systematically perform specific test to verify the potential presence of these substances in the above-mentioned Products, we cannot guarantee that there is no trace amount of these substances, as impurity or otherwise, in the above-mentioned Products. Moreover, it cannot be excluded that in specific conditions of processing or incineration certain of the above-mentioned substances might be generated as mentioned in the relevant safety data sheet.
Refining & Chemicals
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B. COMPLIANCE WITH REGULATIONS.
1. CONEG (Coalition of the North-eastern Governors (CONEG, USA)
The above-mentioned Products meet the requirements of less than 100ppm overall concentration of cadmium, mercury, lead and chromium
2. DECRET 2007-1467 (Article 4) and ENVIRONMENTAL CODE (book V-title IV-chapter III-section V)-dated on 10 November 2008.
We inform you that the “Décret” 98-638 is repealed by article 4 of the French “Décret” 2007-1467 (dated 12 October 2007). We hereby certify that the above-mentioned Products meet the requirements of the article R543-44 item 2b and article R543-45 of Environmental Code (book V) imposing to take into account environmental requirements in the conception and in the manufacturing of packaging material as far as the following articles are concerned:
Article R 543-44 - item 2 (b):
- the above mentioned Products are intended for the manufacture of packaging materials; - the above-mentioned Products are recyclable by melting and pelletizing;
- the above-mentioned Products have a heat of combustion sufficient to enable to optimize energy recovery (*).
Article R 543-45:
The total of the concentrations of lead + cadmium + mercury + hexavalent chromium does not exceed 100 ppm.
We kindly remind you that the above-mentioned articles of the Code concern the packaging material as end product, for which we cannot provide any guarantee.
(*) The control of the combustion conditions and the technical measures related thereto cannot be controlled by the manufacturer of the above-mentioned Products and thus do not fall within his responsibility."
3. Directive 76/769/EC and Reach Annex XVII
Directive 76/769/EC relating to restrictions on the marketing and use of certain dangerous substances and preparations, established in its Annex I restrictions for certain dangerous substances and preparations. Regulation 1907/2006/EC (Reach Regulation) repealed and replaced Directive 76/769/EC from 1 June 2009 onwards. Annex XVII, published as Regulation 552/2009/EC amending Regulation 1907/2006/EC, replaces Annex I to Directive 76/769/EC. We herewith confirm that the above-mentioned Products comply with Regulation 552/2009/EC. 4. END OF LIFE VEHICLES Directive 2000/53/EC
We hereby confirm that the above-mentioned Products comply with the Directive 2000/53/EC on end of life of vehicles with respect to the heavy metals content limit defined in the notes of the Decision 2002/525/EC because the overall concentration of lead, chromium and mercury is lower than 0.1% by weight, and the concentration of cadmium is lower than 0.01% by weight.
Refining & Chemicals
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Issued by an electronic system 6/8
SA TOTAL RESEARCH & TECHNOLOGY FELUY NV Zone Industrielle C – B-7181 Seneffe (Feluy)
Tél. : +32 (0)64 51 41 11 - Fax. : +32 (0)64 54 08 45 - Courriel : [email protected]
RPM Charleroi 0438.021.316 T.V.A. BE 0438.021.316 – BNP Paribas Fortis IBAN BE48 2100 4738 2027 BIC GEBABEBB
5. GENETICALLY MODIFIED ORGANISMS
For PPH 8025, PPH 9020, PPH 12020, PPR 7220, PPR 7227, PPR 9220, PPR 10231, PPR 10232, PPR 12232, PPR 19R01, Lumicene® MR30MC2, Lumicene® MR60MC2, Lumicene® MR30MX6:
We hereby confirm that we received below indications form our current additive* suppliers : 1) The majority of additives* used in the here above mentioned products are not GMO derived
2) Whilst the others could derive from Genetically Modified Organism (GMO) For other Polypropylene products mentioned on page 1, we hereby confirm that we received confirmation of our suppliers of additives* mentioning the absence of genetically modified organisms (GMO).
6. HALAL/KOSHER
We inform you that the above-mentioned products have not received Halal/Kosher certification. However, we can hereby confirm that we do not use, Ethanol (CAS No 64-17-5), as additive (as defined in Regulation (EU) 10/2011) in the here above mentioned products.
7. PACKAGING AND PACKAGING WASTE Directive 94/62/EC:
We hereby confirm that the above-mentioned Products comply with Directive 94/62/EC and Directive 2004/12/EC on Packaging Waste with respect to the heavy metals content limit because the overall concentration of cadmium, mercury, lead and chromium is lower than 100 ppm (w/w)(to be checked for other requirements). In addition, the above-mentioned Products have the potential to be recycled according to these requirements.
8. RoHS II and III Directive 2011/65/EC and 2015/863/EU
We hereby inform you that Directive 2011/65/EU (up to amendment (EU) 2020/366) on the restriction of the use of certain hazardous substances in electrical and electronic equipment (RoHS) does not cover our Polymers as “raw materials” but it only applies to the “electrical and electronic equipment” as finished products defined in the Annex I of Directive
2011/65/EU.
Nevertheless, we hereby confirm that neither Polybromo biphenyls (PBB), Polybromo diphenylethers (PBDE), Bis(2-ethylhexyl) phthalate (DEHP), Butyl benzyl phthalate (BBP), Dibutyl phthalate (DBP), Diisobutyl phthalate (DIBP) are intentionally used in the
manufacturing of the above-mentioned Products at a threshold level higher than 0.1%. We confirm that the above-mentioned Products do not contain mercury, lead and hexavalent chromium at a threshold level higher than 0.1% (w/w) each, and of cadmium at a threshold level higher than 0.01% (w/w).
However, since we do not perform specific tests to verify the absence of these substances, we cannot guarantee that there is no trace amount of these substances, as impurity or otherwise, in the above-mentioned product.
9. WASTE ELECTRICAL AND ELECTRONIC EQUIPMENT Directive 2012/19/EU
We hereby inform you that Directive 2012/19/EU (up to amendment (EU) 2018/849) on waste electrical and electronic equipment (WEEE) does not cover our Polymers as “raw materials” but it only applies to the “electrical and electronic equipment” as finished products defined in Article 3 and classified in categories set out in Annex III of Directive 2012/19/EU.
Nevertheless, we hereby confirm that neither Polychlorinated biphenyls (PCB),
Polychlorinated terphenyls (PCT), chlorofluorocarbons (CFC), hydrochlorofluorocarbons (HCFC) or hydrofluorocarbons (HFC), brominated flame retardants, asbestos are
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intentionally used in the manufacturing of the above-mentioned product at a threshold level higher than 0.1%.
We hereby confirm that the above-mentioned product does not contain mercury, lead and hexavalent chromium at a threshold level higher than 0.1% (w/w) each, and of cadmium at a threshold level higher than 0.01% (w/w).
However, since we do not perform specific tests to verify the absence of these substances, we cannot guarantee that there is no trace amount of these substances, as impurity or otherwise, in the above-mentioned product.
10. SAFETY DATA SHEETS (Regulation 1907/2006/EC)
We recommend before using the above-mentioned Products to carefully read the Safety Data Sheets which can be downloaded from the website: http://www.polymers.total.com.Our customers receive automatically a Safety Data Sheet after their first order and when they make a new order after a period that is longer than 12 months. They will also receive automatically a Safety Data Sheet when modifications have been made.
11. TRANSMISSIBLE SPONGIFORM ENCEPHALOPATHY (TSE)
We hereby confirm that we received confirmation of our suppliers of additives* used in the above mentioned products that when substances of animal origin are used, they comply with the requirements stipulated in the Note for guidance on minimising the risk of transmitting
animal spongiform encephalopathy agents via human and veterinary medicinal products
(EMA/410/01 rev.3).
12. VOLATILE ORGANIC COMPOUNDS (VOC)
We hereby inform you that a representative grade of the here above-mentioned product has been analyzed by “Automated Thermal Desorption Gas Chromatography – internal method” for VOC and our results were lower than the threshold concentration pointed out (3% w/w) in Swiss Ordinance on the Incentive Tax on Volatile Organic Compounds (OVOC) of 12 November 1997 (Status as of March 1st, 2013).
* Additive as defined in Regulation (EU) 10/2011 C. NORMS AND STANDARDS
We can hereby confirm that we do not use as additive* any substances listed in these norms and standards above the limit values. The here above mentioned products are plastics and we therefore made reference to the respective parts of these norms and standards. Furthermore, we inform you that we do not test each grade we sell to check the potential presence of trace amounts of each chemicals hereafter listed which could be present in the here above mentioned products as impurities or otherwise.
1. IKEA IOS-MAT-0010 (version AA-10911-15, dated 2019-12-20), IKEA IOS-MAT-0054 (version AA-92520-11, dated 2018-11-14), IKEA IOS-MAT-0195 (version AA-2208470-2, dated 2020-01-20), IKEA IOS-PRG-0021 (version AA-31847-7, dated 2011-10-14). 2. GADSL - GLOBAL AUTOMOTIVE DECLARABLE SUBSTANCE List – 2019 * Additive as defined in Regulation (EU) 10/2011
Refining & Chemicals
Total Research & Technology Feluy Regulatory Affairs Tel. : +32 (0)64 51 40 67 Fax.: +32 (0)64 51 41 49 [email protected] Certificate N° ARP/20L00266 Page 8 of 8
Issued by an electronic system 8/8
SA TOTAL RESEARCH & TECHNOLOGY FELUY NV Zone Industrielle C – B-7181 Seneffe (Feluy)
Tél. : +32 (0)64 51 41 11 - Fax. : +32 (0)64 54 08 45 - Courriel : [email protected]
RPM Charleroi 0438.021.316 T.V.A. BE 0438.021.316 – BNP Paribas Fortis IBAN BE48 2100 4738 2027 BIC GEBABEBB
Our certificate does not cover:
- any modification of The Product by any addition of any other product to it,
- any prejudicial modification of The Product resulting from a processing of The Product, - an inadequate use and/or storage of The Product and of the finished articles.
Information contained in this publication is true and accurate at the time of publication and to the best of our knowledge. The present certificate is based on the status of the legislation at the date written above and is valid until end of August 2021. This certificate cancels and supersedes any prior version thereof. It can be renewed upon request.
We are at your disposal for any further information you may need and remain, Yours faithfully,
Total Research & Technology Feluy
B. KLUYSKENS F. RADERMACHER
TOTAL POLYPROPYLENE HETEROPHASIC
COPOLYMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Date of issue: 7/7/2019 Supersedes: 8/8/2017 Version: 11.3
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Product form : Mixture
Product name : TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER
CAS-No. : 9010-79-1
Type of product : Polymers
Formula : (C3H6)x - (C2H4)y
Chemical structure :
Synonyms : 9010-79-1 ; PPC
Product group : -
Other means of identification : POLYPROPYLENE HETEROPHASIC COPOLYMER - PPC 1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses ---
Main use category : Professional use
Use of the substance/mixture : For more detailled information, see technical data sheet 1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet REFINING & CHEMICALS BRANCH
TOTAL PETROCHEMICALS & REFINING SA/NV
Rue de l'Industrie 52 Nijverheidsstraat - B-1040 BRUSSELS - BELGIUM T +32 (0)2.288.91.11
[email protected] - www.total.com 1.4. Emergency telephone number
Emergency number : Emergency call Carechem 24 International :
• for English speaking countries: +44 (0) 1235 239 670 • for Europe (in local languages): + 33 1 49 00 00 49
• for Africa and Middle East: + 44 (0) 1235 239 671• for China: + 86 512 8090 3042
• for Asia Pacific (Hong-Kong, Singapore, Taiwan, Philippines, India, Vietnam, Sri Lanka, Japan, Korea, Malaysia, Indonesia, Thailand) :
+ 65 3158 1074
Country Organisation/Company Address Emergency number Comment
Ireland National Poisons Information Centre Beaumont Hospital PO Box 1297 Beaumont Road 9 Dublin +353 1 809 2566 (Healthcare professionals-24/7) +353 1 809 2166 (public, 8am - 10pm, 7/7) United Kingdom National Poisons Emergency
number
08 45 46 47
SECTION 2: Hazards identification 2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II)
Not classified
Adverse physicochemical, human health and environmental effects
To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice.
Quick-FDS [19339-34007-27689-019212] - 2020-12-11 - 09:26:48
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/2/2019 EN (English) SDS Reference number: PPRO-A01 2/7
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display No labelling applicable
2.3. Other hazards
Other hazards not contributing to the classification
: Fine dust may cause irritation of respiratory system and mucous. Contact with hot material - prevent serious burns. If heated to more than 160°C, the product may form vapours or fumes which may cause irritation of respiratory tract and cause coughing and sensation of shortness of breath. Handling this product may result in electrostatic accumulation. Use proper grounding procedures. Dust may form explosive mixture in air. Combustible Dust.
SECTION 3: Composition/information on ingredients 3.1. Substances
Not applicable 3.2. Mixtures
Name Product identifier % Classification according to
Regulation (EC) No. 1272/2008 [CLP] Propene, polymer with Ethene. (CAS-No.)9010-79-1 > 98 Not classified
Additive < 2 Not classified
SECTION 4: First aid measures 4.1. Description of first aid measures
First-aid measures after inhalation : Exposure to spray, fumes and vapours produced by heated or burned product: Move to fresh air. Call a doctor.
First-aid measures after skin contact : Exposure to splashing of hot product: Treat the affected part with cold water (by spraying or immersion). Do not remove clothing adhering to the skin. In case of severe burns, seek hospital treatment.
First-aid measures after eye contact : Immediately rinse with water for a prolonged period while holding the eyelids wide open. In case of irritation caused by fine dust: wash with copious volumes of water, until the irritation disappears.
First-aid measures after ingestion : Ingestion during handling is not likely. Do not induce vomiting. Rinse mouth out with water. 4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Refer to § 11 for more details on effects. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable extinguishing media : For small fire: Carbon dioxide. Dry powder. Water. For large fire: Foam. Unsuitable extinguishing media : Do not use a solid water stream as it may scatter and spread fire. 5.2. Special hazards arising from the substance or mixture
Fire hazard : Combustible.
Hazardous decomposition products in case of fire
: Carbon oxides (CO, CO2). Aldehydes. Ketones. Acetone. Acetaldehyde. Formaldehyde. Hydrocarbons. acrolein; prop-2-enal; acrylaldehyde.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
Other information : Notify fire brigade and environmental authorities. Evacuate unnecessary personnel. Use water spray to cool exposed surfaces.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel
Protective equipment : Do not attempt to take action without suitable protective equipment. Gloves. Safety glasses. 6.1.2. For emergency responders
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
For containment : If spilled, may cause the floor to be slippery. Sweep up or vacuum up the product. Keep recovered product for subsequent disposal. Do not allow to enter drains or water courses. On water, recover/skim from surface and pour out in disposal container.
Other information : Dispose of contaminated material at an authorized site. Notify authorities if product enters sewers or public waters.
6.4. Reference to other sections
For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13. SECTION 7: Handling and storage
7.1. Precautions for safe handling
Hygiene measures : Do not eat, drink or smoke when using this product. Keep away from food and drink. 7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations. Provide local exhaust or general room ventilation. Ground/bond container and receiving equipment. Take precautionary measures against static discharge.
Storage conditions : store at ambient temperature and at atmospheric pressure in original packaging (plastic or cardboard boxes) or in silo made of appropriate material (aluminium, stainless steel, ...). Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Proper grounding procedures to avoid static electricity should be followed. Store in dry, cool, well-ventilated area.
Special rules on packaging : three pallets must never be stacked. under normal storage conditions, and following good working practices, two pallets may be stacked on flooring in sound condition. however, when the pictorial "Do not stack" is affixed to the pallet, the pallet must never be placed either on top of or below another pallet.
N.B. :here the term pallet includes both the pallet and its load. when pallets are stored in racks, it should be checked whether the pallet is fit for stacking in the concerned racks.
Packaging materials : Polyethylene. Paper bag. Carton. Stainless steel. 7.3. Specific end use(s)
Recommended to professional users.
SECTION 8: Exposure controls/personal protection 8.1. Control parameters
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER (9010-79-1)
USA - ACGIH ACGIH TWA (mg/m³) 10 mg/m³ inhalable dust particles 3 mg/m³ respirable dust particles
8.2. Exposure controls Appropriate engineering controls:
Ensure good ventilation of the work station. If handling results in dust generation or high temperatures, local exhaust ventilation should be provided to insure that exposure to dust or decomposition products does not exceed the exposure recommended levels. Safety shower. Eye fountain. Personal protective equipment:
Dustproof clothing. Gloves. Safety glasses. Dust formation: dust mask. Hand protection:
Protective gloves. Use insulated gloves when handling this material hot Eye protection:
Safety glasses
Skin and body protection:
Wear suitable protective clothing. Safety foot-wear Respiratory protection:
Dust/aerosol mask with filter type P1 Personal protective equipment symbol(s):
Quick-FDS [19339-34007-27689-019212] - 2020-12-11 - 09:26:48
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/2/2019 EN (English) SDS Reference number: PPRO-A01 4/7
Environmental exposure controls: Avoid release to the environment. Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : Pellet.
Colour : Translucent. White.
Odour : Odourless.
Odour threshold : No data available
pH : Not applicable
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 160 - 165 °C
Freezing point : No data available
Boiling point : No data available
Flash point : ≈ 350 °C
Auto-ignition temperature : > 380 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 905 kg/m³
Solubility : Water: < 1 mg/l Insoluble
Log Pow : No data available
Viscosity, kinematic : Not applicable
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Lower explosive limit (LEL) : 0.02 kg/m³ ( < 63 µm ) 9.2. Other information
VOC content : < 0.3 %
SECTION 10: Stability and reactivity 10.1. Reactivity
Electrostatic charges may be generated during handling. Take precautionary measures against static discharge during blending and transfer operations.
10.2. Chemical stability
The product is stable at normal handling and storage conditions. 10.3. Possibility of hazardous reactions
Dust may form explosive mixture in air. 10.4. Conditions to avoid
No flames, no sparks. Eliminate all sources of ignition. Avoid temperature above 300°C. 10.5. Incompatible materials
Strong acids. Strong bases. Strong oxidizing agents. Halogens. 10.6. Hazardous decomposition products
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Not classified
Skin corrosion/irritation : Not classified (Based on available data, the classification criteria are not met) pH: Not applicable
Additional information : Heated product causes burns
thermal decomposition products are produced at elevated temperatures and these may be irritating
Serious eye damage/irritation : Not classified (Based on available data, the classification criteria are not met) pH: Not applicable
Additional information : Fine dust may cause irritation to ocular mucous
thermal decomposition products are produced at elevated temperatures and these may be irritating
Heated product causes burns Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified STOT-single exposure : Not classified
Additional information : dust may cause irritation of respiratory system.
If heated to more than 160°C, the product may form vapours or fumes which may cause irritation of respiratory tract and cause coughing and sensation of shortness of breath STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
SECTION 12: Ecological information 12.1. Toxicity
Ecology - general : Do not allow product to spread into the environment. This product does not present any particular risk for the environment.
Acute aquatic toxicity : Not classified Chronic aquatic toxicity : Not classified 12.2. Persistence and degradability
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER (9010-79-1)
Persistence and degradability Product persists. Not readily biodegradable. BOD (% of ThOD) Below detection limit
12.3. Bioaccumulative potential
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER (9010-79-1) Bioaccumulative potential Low bioaccumulation potential. 12.4. Mobility in soil
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER (9010-79-1)
Ecology - soil low mobility.
12.5. Results of PBT and vPvB assessment
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER (9010-79-1) Results of PBT assessment Not required
12.6. Other adverse effects No additional information available
SECTION 13: Disposal considerations 13.1. Waste treatment methods
Waste treatment methods : Dispose of in accordance with relevant local regulations. Do not discharge the product into the environment. Recycle the material as far as possible.
Quick-FDS [19339-34007-27689-019212] - 2020-12-11 - 09:26:48
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/2/2019 EN (English) SDS Reference number: PPRO-A01 6/7
SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID
14.1. UN Number
Not applicable Not applicable Not applicable Not applicable Not applicable 14.2. UN proper shipping name
Not applicable Not applicable Not applicable Not applicable Not applicable 14.3. Transport hazard class(es)
Not applicable Not applicable Not applicable Not applicable Not applicable 14.4. Packing Group
Not applicable Not applicable Not applicable Not applicable Not applicable 14.5. Environmental hazards
Dangerous for the
environment : No Dangerous for the environment : No Marine Pollutant : No
Dangerous for the
environment : No Dangerous for the environment : No Dangerous for the environment : No No supplementary information available
14.6. Special precautions for user
- Overland transport
No data available
- Transport by sea (IMDG)
No data available
- Air transport (IATA)
No data available
- Inland waterway transport
No data available
- Rail transport
No data available
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances
VOC content : < 0.3 %
15.1.2. National regulations
These registration entries are for polymers only. For additives, please refer to TOTAL who will provide the necessary certification Not listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Complies the United States TSCA (Toxic Substances Control Act) inventory Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on KECI (Korean Existing Chemicals Inventory)
Listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed on the China Inventory of Existing Chemical Substances (IECSC)
Listed on the Canadian DSL (Domestic Substances List) Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on the Taiwan TCSI (Taiwan Chemical Substaces Inventory) Listed on INSQ (Mexican National Inventory of Chemical Substances)
15.2. Chemical safety assessment
The substance is not classified for human health hazards or for environment effects and it is not PBT or vPvB so that no exposure assessment or risk characterisation is required. For tasks where the intervention of workers is required, the substance must be handled in accordance with good industrial hygiene and safety procedures.
TOTAL POLYPROPYLENE HETEROPHASIC COPOLYMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 SECTION 16: Other information
Other information : Training staff on good practice. Manipulations are to be done only by qualified and authorised persons. Use good personal hygiene practices.
SDS EU (REACH Annex II)
This information applies to the PRODUCT AS SUCH and conforming to specifications of TOTAL. In case of formulations or mixtures, it is necessary to ascertain that a new danger will not appear.
The information contained is based on our knowledge of the product, at the date of publishing and it is given quite sincerely. However the revision of some data is in progress.
Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet shall only be used and reproduced for prevention and security purposes.
The references to legislative, regulatory and codes of practice documents cannot be considered as exhaustive.
It is the responsibility of the person receiving the product to refer to the totality of the official documents concerning the use, the possession and the handling of the product.
It is also the responsibility of the handlers of the product to pass on to any subsequent persons who will come into contact with the product. (usage, storage, cleaning of containers, other processes) the totality of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of environment.