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Determining molecular orientation via single molecule SERS in a plasmonic nano gap

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Figure

Fig. 1: Schematic representation of the SERS plasmonic nano-gap investigated in this work
Fig. 2: (a) Calculated extinction spectra as a function of wavelength for a gap of width 5 nm for a silver particle of diameter
Fig. 3:  (a) Calculated near field enhancement factor 〈
Fig. 5: (a) Spectra 1-3 show three typical single molecule Rhodamine 6G  SERS spectra recorded from three different 5 nm nano-gaps formed between a 118nm silver particle and a 100 nm extended silver film

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