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EC safety data sheet. SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification

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EC safety data sheet

Trade name:

Flottec X2909 Solvent

Current version :, issued: 31.07.2014 Replaced version: issued:

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1

Product identifier

Trade name

Flottec X2909 Solvent

Identification numbers

CAS no. 9003-29-6

1.2

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses of the substance or mixture

Base material and intermediates, Lube Blendstock, Mineral Oil, Diluent

1.3 Details of the supplier of the safety data sheet

Address

Flottec, LLC

338 West Main Street Boonton, NJ 07005

Telephone no. +1.973.588.4717 Fax no. +1 973.588.4719

Information provided by / telephone

+1 713-861-7070

Advice on Safety Data Sheet [email protected]

1.4

Emergency telephone number

For medical advice (in English): +1 713 861 7070

SECTION 2: Hazards identification

2.1

Classification of the substance or mixture

Classification in accordance with Regulation (EC) No 1272/2008 (CLP)

Asp. Tox. 1; H304

Classification in accordance with Directive 67/548/EEC or 1999/45/EC

Xn; R65

2.2

Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP Regulation)

Product identifier 9003-29-6 Hazard pictograms GHS08 Signal word Danger Hazard statements

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EC safety data sheet

Trade name: Flottec X2909 Solvent

Current version : issued: 31.07.2014 Replaced version:

Precautionary statements

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331 Do NOT induce vomiting.

2.3

Other hazards

Vapours can form an explosive mixture with air. PBT assessment

The product is not considered to be a PBT. vPvB assessment

The product is not considered to be a vPvB.

SECTION 3: Composition/information on ingredients

3.1

Substances

Chemical characterization

Substance name C16 - C20 hydrocarbons, mixture of isomers

Identification numbers

CAS no. 9003-29-6

3.2

Mixtures

Not applicable. The product is not a mixture.

SECTION 4: First aid measures

4.1

Description of first aid measures

General information

In case of persisting adverse effects, consult a physician. Remove contaminated clothing and shoes immediately, and launder thoroughly before reusing.

After inhalation

Remove affected person from the immediate area. Ensure supply of fresh air. Summon a doctor immediately.

After skin contact

Wash off immediately with soap and water. Consult a doctor if skin irritation persists.

After eye contact

Separate eyelids, wash the eyes thoroughly with water (15 min.). Seek medical assistance.

After ingestion

Do not induce vomiting - aspiration hazard. Summon a doctor immediately. Never give anything by mouth to an unconscious person. In case of vomiting keep head of person in face-down position to prevent penetration of vomitus into the trachea.

4.2

Most important symptoms and effects, both acute and delayed

No data available.

4.3

Indication of any immediate medical attention and special treatment needed

Treat symptomatically

In the case of swallowing with subsequent vomiting, aspiration of the lungs can occur which can lead to chemical pneumonia or asphyxiation.

SECTION 5: Firefighting measures

5.1

Extinguishing media

Suitable extinguishing media

Water spray jet; Foam; extinguishing powder; Carbon dioxide

Unsuitable extinguishing media

Full water jet

5.2

Special hazards arising from the substance or mixture

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EC safety data sheet

Trade name:

Flottec X2909 Solvent

Current version : issued: 31.07.2014 Replaced version:

5.3

Advice for firefighters

Cool endangered containers with water spray jet. Use self-contained breathing apparatus. Wear protective clothing. Pressure increase, bursting and explosion hazard during heating.

SECTION 6: Accidental release measures

6.1

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Refer to protective measures listed in sections 7 and 8. Keep away sources of ignition. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Do not inhale vapours.

For emergency responders

No data available. Personal protective equipment (PPE) - see Section 8.

6.2

Environmental precautions

Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil.

6.3

Methods and material for containment and cleaning up

Take up with absorbent material (e.g., sand, kieselguhr, universal binder). Send in suitable containers for recovery or disposal.

6.4

Reference to other sections

No data available.

SECTION 7: Handling and storage

7.1

Precautions for safe handling

Advice on safe handling

Provide good ventilation of working area (local exhaust ventilation, if necessary). If workplace exposure limits are exceeded, respiratory protection approved for this particular job must be worn. Product inherent handling risks must be minimised taking the appropriate measures for protection and preventive actions. The working process should be designed to rule out the release of hazardous substances or skin contact as far it is possible by the state of the art.

General protective and hygiene measures

Do not eat, drink or smoke during work time. Keep away from foodstuffs and beverages. Avoid contact with eyes and skin. Remove soiled or soaked clothing immediately. Do not inhale vapours. Wash hands before breaks and after work. Provide eye wash fountain in work area. Have emergency shower available.

Advice on protection against fire and explosion

Keep away from sources of heat and ignition. Take precautionary measures against static charges. Vapours can form an explosive mixture with air.

7.2

Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions

Keep container tightly closed and dry in a cool, well-ventilated place. Keep under inert gas.

Requirements for storage rooms and vessels

Containers which are opened must be carefully resealed and kept upright to prevent leakage. Always keep in containers of same material as the original one.

Appropriate Material steel

Advice on storage assembly

Do not store together with: Oxidizing agents

7.3

Specific end use(s)

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EC safety data sheet

Trade name: Flottec X2909 Solvent

Current version: issued: 31.0572014 Replaced version:

SECTION 8: Exposure controls/personal protection

8.1

Control parameters

No parameters available for monitoring.

8.2

Exposure controls

Appropriate engineering controls

No data available.

Personal protective equipment

Respiratory protection

If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.

Respirator AX

Eye / face protection

Safety glasses with side protection shield (EN 166)

Hand protection

Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work- station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the

manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.

Appropriate Material nitrile rubber

Other

Normal chemical work clothing.

Environmental exposure controls

No data available.

SECTION 9: Physical and chemical properties

9.1

Information on basic physical and chemical properties

Form/Colour liquid colourless Odour almost odourless Odour threshold No data available pH value Not applicable

Boiling point / boiling range

Value

Reference pressure

249 - 338 °C 1013 hPa

Remarks At standard pressure, not distillable without decomposition.

Melting point / melting range

Value < -70 °C

Decomposition point / decomposition range

No data available

Flash point

Value 120 °C

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EC safety data sheet

Trade name:

Flottec X2909 Solvent

Current version: issued: 31.07.2014 Replaced version:

Ignition temperature Value 205 °C Method DIN 51794 Auto-ignition temperature No data available Oxidising properties No data available Explosive properties not explosive

Method: 92/69/EEC, A.14

Flammability (solid, gas)

Not applicable

Lower flammability or explosive limits

No data available

Upper flammability or explosive limits

No data available Vapour pressure Value Reference temperature 2 hPa 20 °C Method OECD 104 Vapour density No data available Evaporation rate No data available Relative density Value Reference temperature 0,8101 20 °C Method OECD 109 Density Value Reference temperature 0,815 g/cm³ 20 °C Solubility in water Value Reference temperature < 0,010 20 g/l H2O °C Solubility(ies) No data available

Partition coefficient: n-octanol/water

log Pow > 3

Viscosity

Value appr. 6,2 mPa*s

Reference temperature 20 °C Type dynamic Value 6,84 mm²/s Reference temperature 20 °C Type Method kinematic OECD 114 Value 3,96 mm²/s Reference temperature 40 °C Type Method kinematic OECD 114

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EC safety data sheet

Trade name:

Flottec X2909 Solvent

Current version: 31.07.2014 Replaced version:

Corrosive to metals

Not to be expected in view of the structure.

9.2 Other information

Other information

No data available.

SECTION 10: Stability and reactivity

10.1 Reactivity

No data available.

10.2 Chemical stability

No data available.

10.3 Possibility of hazardous reactions

No data available.

10.4 Conditions to avoid

Heat, naked flames and other ignition sources.

10.5 Incompatible materials

strong oxidizing agents; Violent reaction under influence of oxidising agents.

10.6 Hazardous decomposition products

None, if handled according to order

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute oral toxicity

LD50 > 10000 mg/kg

Species Method

rat OECD 401

Acute dermal toxicity

LD50 > 2000 mg/kg Species Method Remarks rat OECD 402

Analogous to product with a similar composition.

Acute inhalational toxicity

LC50 Duration of exposure > 19,171 mg/l 4 h State of aggregation Species Source Remarks Vapour rat EPA

Test conducted with a similar formulation.

Skin corrosion/irritation Species Method Evaluation rabbit OECD 404 slightly irritant

Serious eye damage/irritation

Species Method Evaluation rabbit OECD 405 non-irritant

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EC safety data sheet

Trade name: Flottec X2909 Solvent

Current version: issued: 31.07.2014 Replaced version:

Respiratory or skin sensitisation

Route of exposure Skin

Method Remarks Evaluation

OECD 429

Test conducted with a similar formulation. non-sensitizing

Germ cell mutagenicity

Species Method Evaluation

Escherichia coli WP2 uvr A OECD 471

No experimental information on genotoxicity in vitro available.

Reproduction toxicity

Route of exposure

oral

NOEL

1000 mg/kg Method OECD 421 Carcinogenicity No data available STOT-single exposure No data available STOT-repeated exposure

Route of exposure

oral

NOAEL Duration of exposure

300 mg/kg 4 week/s Species Target organ Method rat kidney OECD 407 Aspiration hazard

In the case of swallowing with subsequent vomiting, aspiration of the lungs can occur which can lead to chemical pneumonia or asphyxiation.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Repeated and prolonged skin contact may cause removal of natural fat from the skin and irritation of the skin.

SECTION 12: Ecological information

12.1 Toxicity

Fish toxicity LC50 Duration of exposure >= 1,55 96 mg/l h Species Method Cyprinus carpio 92/69/EEC, C.1 Daphnia toxicity EC50 Duration of exposure > 100 mg/l 48 h Species Method Remarks Daphnia magna OECD 202

Water Accomodated Fraction (WAF)

Algae toxicity ErC50 Duration of exposure > 19,2 mg/l 72 h Species Method Desmodesmus subspicatus OECD 201 Bacteria toxicity NOEC Duration of exposure 1000 mg/kg 14 d

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EC safety data sheet

Trade name:

Flottec X2909 Solvent

Current version: issued: 31.07.2014 Replaced version:

12.2 Persistence and degradability

Biodegradability

Type

Anaerobic biodegradability

Value

Duration

15 %

28 d

Method modified Sturm test

12.3 Bioaccumulative potential

Bioconcentration factor (BCF)

BCF 314 - 1882

Partition coefficient: n-octanol/water

log Pow > 3

12.4 Mobility in soil

No data available.

12.5 Results of PBT and vPvB assessment

Results of PBT and vPvB assessment

PBT assessment vPvB assessment

The product is not considered to be a PBT. The product is not considered to be a vPvB.

12.6 Other adverse effects

No data available.

12.7 Other information

Other information

Do not discharge product unmonitored into the environment.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product

Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.

Packaging

Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.

SECTION 14: Transport information

14.1 Transport ADR/RID/ADN

The product is not subject to ADR/RID/ADN regulations.

14.2 Transport IMDG

The product is not subject to IMDG regulations.

14.3 Transport ICAO-TI / IATA

The product is not subject to ICAO-TI / IATA regulations.

14.4 Other information

No data available.

14.6 Special precautions for user

No data available.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not relevant

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EC safety data sheet

Trade name:

Flottec X2909 Solvent

Current version: issued: 31.07.2014 Replaced version:

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulations

Restriction of occupation

Adhere to the national sanitary and occupational safety regulations when using this product.

Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances

Remarks Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter 10.

15.2 Chemical safety assessment

No data available.

SECTION 16: Other information

Sources of key data used to compile the data sheet:

EC Directive 67/548/EC resp. 99/45/EC as amended in each case.

Regulation (EC) No 1907/2006 (REACH), 1272/2008 (CLP) as amended in each case. EC Directives 2000/39/EC, 2006/15/EC, 2009/161/EC

National Threshold Limit Values of the corresponding countries as amended in each case. Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.

The data sources used to determine physical, toxic and ecotoxic data, are indicated directly in the corresponding chapter.

Full text of the R-, H- and EUH- phrases drawn up in sections 2 and 3 (provided not already drawn up in these sections)

R65 Harmful: may cause lung damage if swallowed.

This information is based on our present state of knowledge. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship.

Alterations/supplements:

Alterations to the previous edition are marked in the left-hand margin.

"IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR

APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY ACME HEREUNDER ARE GIVEN GRATIS AND ACME ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK". ACME WILL NOT MAKE ITS PRODUCTS AVAILABLE TO CUSTOMERS FOR USE IN THE MANUFACTURE OF MEDICAL DEVICES WHICH ARE INTENDED FOR PERMANENT IMPLANTATION IN THE HUMAN BODY OR IN PERMANENT CONTACT WITH INTERNAL BODILY TISSUES OR FLUIDS. THE POSSIBILITY OF BEING REQUIRED TO RESPOND TO UNFOUNDED LITIGATION AND/OR CLAIMS ARISING OUT OF CONCERNS RELATING TO SUCH USE PRESENTS AN UNACCEPTABLE RISK TO THE COMPANY”.

References

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