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UNIT 0:

UNIT 0:

Chapter 1

Chapter 1

: Introduction

: Introduction

to Matter and Change

to Matter and Change

Scientific Method

Scientific Method

Physical vs. Chem Changes

Physical vs. Chem Changes

Units, Measurements and Sig Figs

Units, Measurements and Sig Figs

Matter and Nomenclature

Matter and Nomenclature

(2)

Scientific Method

Scientific Method

A systematic/organized way for scientists 

to solve a problem or answer a question.

There are about 5 steps to the scientific 

method

What are they?

(3)

Sci Method

(4)

Variables:

Variables:

Independent Variable

Independent Variable

– something that 

– something that 

is changed by the scientist

is changed by the scientist

Dependent Variable

Dependent Variable

– something that 

– something that 

might be affected by the change in the 

might be affected by the change in the 

independent variable

independent variable

Controlled Variable

Controlled Variable

– a variable that is 

– a variable that is 

not changed

(5)

Claim – Evidence - Reasoning

Claim – Evidence - Reasoning

Claim

 – a statement that answers a question

Evidence

 – observations, data tables, 

graphs, pictures that support the claim

Reasoning

 – scientific principles, readings, 

(6)
(7)

Chemical vs. Physical Properties

Chemical vs. Physical Properties

Physical:

Physical:

 Can be 

 Can be 

measured without 

measured without 

change

change

MP

MP

BP

BP

Color

Color

Texture

Texture

Density…

Density…

Chemical:

Chemical:

 How a 

 How a 

substance reacts to 

substance reacts to 

form others (new)

form others (new)

Changes used to ID:

Changes used to ID:

1.

1.

Bubbles 

Bubbles 

2.

2.

Ppt

Ppt

3.

3.

Light

Light

4.

4.

Heat

Heat

5.

(8)

Properties of Matter Classified as:

Properties of Matter Classified as:

Extensive properties

Extensive properties

Intensive properties

Intensive properties

Volume Mass

Energy Content (think Calories!)

depend on the amount

of matter that is present.

do not depend on the

amount of matter present (think physical

prop)

Melting point
(9)

Separation of a Mixture: 3

Separation of a Mixture: 3

main

main

ways to separate

ways to separate

1.

1.

Filtration

Filtration

2.

2.

Distillation

Distillation

3.

3.

Chromatography

Chromatography

How would you separate iron fillings from 

How would you separate iron fillings from 

sand?  

sand?  

(

(

hint

hint

: it is not one of the common 3 

: it is not one of the common 3 

methods of separation listed above)

(10)

The constituents of the mixture retain their

The constituents of the mixture retain their

identity and may be separated by physical

identity and may be separated by physical

means.

means.

Answer:

(11)

Separation of a Mixture

Separation of a Mixture

(12)

Separation of a Mixture

Separation of a Mixture

(13)

Separation of a Mixture

Separation of a Mixture

(14)

Separation of a Compound

Separation of a Compound

The Electrolysis of water

Water  Hydrogen + Oxygen

H2O H2 + O2

Reactant Products

Compounds must be

separated by chemical

means.

With the application of electricity, water can be separated into its elements

(15)

Phase

Phase

Differences

Differences

Solid

Solid – definite volume and shape; particles packed in fixed positions.

Liquid

Liquid – definite volume but indefinite shape;

particles close together but not in fixed positions

Gas

Gas – neither definite volume nor definite shape; particles are at great distances from one another

Plasma – high temperature, ionized phase of matter as found on the sun. (not really emphasized in

(16)

The Fundamental SI Units

The Fundamental SI Units (le Système International, SI)(le Système International, SI)

Physical Quantity

Name

Abbreviation

Mass

kilogram

kg

Length

meter

m

Time

second

s

(17)

SI Prefixes Common to Chemistry

SI Prefixes Common to Chemistry

Prefix

Unit Abbr. Exponent

Mega

M

10

6

Kilo

k

10

3

Deci

d

10

-1

Centi

c

10

-2

Milli

m

10

-3

Micro

10

-6

Nano

n

10

-9
(18)

Measurements

Measurements

Use the correct instrument to make your

Use the correct instrument to make your

measurement

measurement

A digit that must be

A digit that must be

estimated

estimated

is called

is called

uncertain

uncertain

. A

. A

measurement

measurement

always has some

always has some

degree of uncertainty.

degree of uncertainty.

Measurements are performed with

instruments

No instrument can read to an infinite

(19)

Uses for laboratory Glassware

(20)

Volume:

(21)

Precision and Accuracy

Precision and Accuracy

Accuracy

Accuracy refers to the agreement of a particular refers to the agreement of a particular value with the

value with the truetrue value.value. Precision

Precision refers to the degree of agreement among refers to the degree of agreement among several measurements made in the same manner.

several measurements made in the same manner.

Neither accurate nor

precise

Precise but not

(22)

To measure accuracy

% error can be used

% error =         experimental results - accepted value

(23)

Rules for Counting Significant Figures

Rules for Counting Significant Figures

- Details

- Details

1.

Nonzero integers

Nonzero integers

always count as

always count as

significant figures.

significant figures.

3456

3456

4

(24)

Rules for Counting Significant Figures

Rules for Counting Significant Figures

- Details

- Details

2.

2.

Zeros

Zeros

Leading zeros

Leading zeros

do not count as

do not count as

significant figures.

significant figures.

0.0486

0.0486

3

(25)

Rules for Counting Significant Figures

Rules for Counting Significant Figures

- Details

- Details

3.

3.

Zeros

Zeros

Captive

Captive

zeros

zeros

always count as

always count as

significant figures.

significant figures.

16.07

16.07

4

(26)

Rules for Counting Significant Figures

Rules for Counting Significant Figures

- Details

- Details

4. Zeros

4. Zeros

Trailing zeros

Trailing zeros

are significant

are significant

only

only

if the

if the

number contains a decimal point.

number contains a decimal point.

9.300

9.300

4

(27)

Sig Fig Practice #1

Sig Fig Practice #1

How many significant figures in each of the following?

1.0070 m

5 sig figs

17.10 kg

4 sig figs

100,890 L

5 sig figs

3.29 x 10

3

s

3 sig figs

0.0054 cm

2 sig figs

3,200,000 m/s

2 sig figs

(28)

Rules for Significant Figures in

Rules for Significant Figures in

Mathematical Operations

Mathematical Operations

Multiplication and Division

Multiplication and Division

:

:

# sig

# sig

figs in the result equals the number in

figs in the result equals the number in

the least precise measurement used in

the least precise measurement used in

the calculation.

the calculation.

6.38 x 2.0 =

6.38 x 2.0 =

12.76

(29)

Sig Fig Practice #2

Sig Fig Practice #2

3.24 m x 7.0 m

Calculation

Calculator says:

Answer

22.68 m

2

23 m

2

100.0 g ÷ 23.7 cm

3

4.219409283 g/cm

3

4.22 g/cm

3

0.02 cm x 2.371 cm

0.04742 cm

2

0.05 cm

2

710 m ÷ 3.0 s

236.6666667 m/s

240 m/s

(30)

Rules for Significant Figures in

Rules for Significant Figures in

Mathematical Operations

Mathematical Operations

Addition and Subtraction

Addition and Subtraction

: The

: The

number of decimal places in the result

number of decimal places in the result

equals the number of decimal places in

equals the number of decimal places in

the least precise measurement.

the least precise measurement.

6.8 + 11.934 =

6.8 + 11.934 =

18.734

(31)

Sig Fig Practice #3

Sig Fig Practice #3

3.24 m + 7.0 m

Calculation

Calculator says:

Answer

10.24 m

10.2 m

100.0 g - 23.73 g

76.27 g

76.3 g

0.02 cm + 2.371 cm

2.391 cm

2.39 cm

713.1 L - 3.872 L

709.228 L

709.2 L

1818.2 lb + 3.37 lb

1821.57 lb

1821.6 lb

(32)

Dimensional Analysis

Dimensional Analysis

Use conversion factors to change the units

Use conversion factors to change the units

Conversion factors = 1

Conversion factors = 1

1 foot = 12 inches (equivalence statement)

1 foot = 12 inches (equivalence statement)

12 in

12 in

=

=

11

= =

1 ft.

1 ft.

1 ft.

1 ft.

12 in

12 in

2 conversion factors

2 conversion factors

multiply by the one that will give you the correct

multiply by the one that will give you the correct

units

units

in your answer.

in your answer.

(33)

Convert 223 mL to L

223 mL 1 L

1000 mL

(34)

Dimensional Analysis Method of Solving Problems

Conversion Unit 1 L = 1000 mL

1L

1000 mL

1.63 L x = 1630 mL

1L

1000 mL

1.63 L x = 0.001630 L2

mL

(35)

The speed of sound in air is about 343 m/s. What is this speed in miles per hour?

1 mi = 1609 m 1 min = 60 s 1 hour = 60 min

343 ms x 1609 m1 mi x 1 min 60 s 60 min 1 hour

x = 767 mi

hour meters to miles

seconds to hours

(36)

Density: D=m/V

Density: D=m/V

 Ratio of mass to volumeRatio of mass to volume

 Useful for identifying a Useful for identifying a compound

compound

 Useful for predicting Useful for predicting weight

weight

 An intrinsic propertyAn intrinsic property

(37)

Density

– SI derived unit for density is kg/m

3

1 g/cm

3

= 1 g/mL = 1000 kg/m

3

density = mass

volume

d =

V

m

A piece of platinum metal with a density of 21.5

g/cm

3

has a volume of 4.49 cm

3

. What is its

mass?

d =

V

m

21.5 g

cm

3
(38)

What about percentages? How can they be

used to measure amount?

Ex. A 2.0 gram, 14 K gold ring contains 58.3% gold by  mass.  How many grams of  pure gold does the ring  contain?

58.3 100

x 2.0

x = 1.2 g gold

Percent by mass is a common way to express 

quantity.

(39)

Figure

figs in the result equals the number in

References

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