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CARIBBEAN EXAMINATIONS

COUNCIL

CARIBBEAN SECONDARY EDUCATION

CERTIF'ICATE@

EXAMINATION

CHEMISTRY

Paper

02

_-

General Proficiency

2 hours 30 minutes

DO NOT

TURN THIS

PAGE

UNTILYOU

ARE TOLD

TO DO SO.

1 2. 3 4. 5 6.

READ THE

FOLLOWING

INSTRUCTIONS CAREFULLY.

This paper consists of SIX questions in TWO sections.

AnswerALL

questions. Write your answers in the spaces provided in this booklet.

Do NOT write in the margins.

Where appropriate,ALLWORKING MUST BE SHOWN in this booklet. You may use a silent, non-programmable calculator to answer questions.

If

you need to rewrite any answer and there is not enough space to do so on the

original page, you must use the extra lined page(s) provided at the back of this

booklet. Remember to

draw

a line

through

your

original

answer.

If

you use the extra page(s) you MUST

write

the question number clearly

in

the box provided at the top of the extra page(s) and, where relevant, include

the question

part

beside the answer.

7

Copyright @ 2015 Caribbean Examinations Council

All

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-5-SECTION

A

AnswerALL

questions

in

this section.

Write your

responses

in

the spaces provided

in

this booklet. DO

NOT

spend more than 30 minutes on Question 1.

Hydrogen peroxide (HrOr) decomposes to produce oxygen and water. The rate of reaction can be

increased by the use

ofiatalysts.

The effect of the mass of a catalyst on the rate of decomposition

of

hydrogen peroxide was investigated.

For EACH experiment, a different mass of the catalyst, manganese(IV) oxide gvtnOr) was combined

with 50 cm3 of 0.8 mol dm3 hydrogen peroxide solution and the volume of oxygen produced was

measured. The masses used are shown on the balances displayed in Figure 1.

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E,xpt#2 Expt #3 Expt #4

Expt #5 Expt #6

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Figure L. Masses of manganese(IV) oxide

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-6-(a) The rate of the reaction for EACH quantity of catalyst used was calculated and recorded in

Table

l.

Use the balances shown in Figure 1 on page 5 to complete Table r.

TABLE

I

: RATE OF REACTION BY MASS OF MANGANESE(IV) OXrDE

Experiment Mass of Manganese(IV) Oxide

(g) Rate of Reaction (mLs{) I 0.0 0.0 2 _0.6 J _1.8 4 2.7 5 4.5 6 5.0 (5 marks)

(b)

Define the term 'rate of reaction'

(1mark)

Write a balanced chemical equation to show the decomposition of hydrogen peroxide.

(2 marks)

Using the axes

in

Figure

2

on page

7,

plot a graph

of

rate

of

reaction versus mass

of

manganese(IV) oxide from the information in Table

1.

One point has already been plotted.

Circle the plotted points on the graph

8,

and draw the line of best

fit.

(5 marks)

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(c)

(d)

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Mass of manganese(IV) oxide

Figure 2. Rate of reaction versus mass of manganese(IV) oxide

5.0 4.5 4.0

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-8-(e) Using your graph,

(i)

describe the relationship between the rate of reaction and the mass of the catalyst

(2 marks)

(iD

determine the rate of reaction using 3.0 g of the catalyst

(1mark)

(iii)

determine the volume of oxygen produced after 10 s using the value obtained from

(e) (ii).

(1 mark)

(0

Complete and label the energy profile diagram in Figure 3 to show how a catalyst affects the

rate ofreaction.

Energy level

Reactants---Products Time

tr'igure 3. Energy profile diagram

(2 marks)

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-9-Draw a labelled diagram of the apparatus (including reagents) that was used to conduct the

experiment and collect the gas.

(4 marks)

(h)

List TWO other factors which can affect the rate of reaction.

(2 marks) Totat 25 marks

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(a) Lesley was asked to weigh 0.20 moles of aspirin to be used in a supervised experiment during

her chemistry laboratory class. Before doing so, she read the label, at the back of the bottle,

shown in Figure 4.

Aspirin

Drug

Aspirin

is

used as an analgesic to relieve minor aches and pains,

reduce fever, and as an anti-inflammatory medication.

Formula: CeH8O4

Molar mass: 180 g mol-r

Melting point: 136 _"C

Boiling point: 140 _"C

Density: 1.40 g

cmi

Figure 4. Aspirin label

The information in Figure 4 may be used to answer the following questions

(i)

Define EACH of the following terms:

Mole:

Molar mass

(2 marks)

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(b)

Ethanoic acid is one of the products of the hydrolysis of aspirin as shown in Figure 5.

COOH COOH

ococH3

OH

+ HrO

+

cH3cooH

Ethanoic acid

Aspirin

Figure 5. The hydrolysis of

aspirin

Calculate the mass of ethanoic acid formed when Jared's 18.0 g of aspirin is hydrolysed.

[Molar mass of ethanoic acid = 60.0 g

moft]

(3 marks)

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(iD

Calculate the mass Lesley would have to weigh to obtain 0.20 moles of aspirin.

(1mark)

(iiD

Jared, another student

in

Lesley's class, weighed 18.0 g

of

aspirin. Calculate the

number of moles of aspirin he weighed.

(1 mark)

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-12-Ethanoic acid is known to be an electrolyte.

(i)

Define the term'electrolSrte'.

(ii)

Identiff the ions that are produced from ethanoic acid during electrolysis

(iii)

Define the term'cathode'

(iv)

Predict which ion from (c) (ii)

will

migrate to the cathode.

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(c)

(l

mark) (2 marks)

(1mark)

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(1mark)

(v)

Is ethanoic acid a strong or weak electrolyte? Explain your answer.

(3 marks)

Total 15 marks

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-13-Compound P has the condensed molecular formula C[CH2CH2CH2CH3.

(i)

State the name and the general formula ofthe homologous series to which Compound

P belongs.

Name of homologous

series:

ii;il;

General formula: ...

(l

mark)

(iD

State ONE use of ComPound P.

(1 mark)

(iiD

Define the term 'structural isomerism'.

(2 marks)

(iv)

Draw the FULLYDISPLAYED structure of ONE isomer of Compound P

Isomer of Compound P

(2 marks)

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3.

(a)

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Compound _Q has the condensed molecular formula CH3CH2COOH.

(i)

Explain why Compound _Q is soluble in water.

(2 marks)

(ii)

Is the solution of Compound _{Q acidic} or basic? State a reason for your answer.

(2 marks)

Compound R, CHrCH:CHCH3, reacts with bromine to form Compound S

(i)

State the expected colour change for the reaction.

(2 marks)

(ii)

Draw the _{FULLY DISPLAYED structural formula of Compound S.}

Compound S

(2 marks)

Total 15 marks

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_15_

SECTION B

AnswerALL

questions in this section.

Write

your responses

in

the spaces provided

in

this booklet.

4. Calcium carbonate, CaCO, and sodium nitrate, NaNO, are two salts that are used in the

manufactur-ing industry

(a)

Deflne the term 'salt'. Identit/ ONE product that EACH of the salts mentioned above is used

to manufacture.

(4 marks) (b) Outline the laboratory preparation of a pure, dry sample of CaCOr. Include in your response

a balanced chemical equation.

(6 marks)

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-t6-Write a balanced chemical equation

with

state symbols

to

illustrate how NaNO, can be

prepared in the laboratory. Explain why NaNO, cannot be prepared utilizing the same method

used for the preparation of CaCOr.

(5 marks) Total 15 marks

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(c)

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-El Dorado, White Oak, Appleton and Cockspur are a few of the famous rum brands of the Caribbean.

The main processes of rum making are fermentation and distillation.

(a)

Describe the process of fermentation. Include in your description

the starting material

the role of yeast

the reaction conditions

a balanced chemical equation for the reaction.

(7 marks)

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-18-After fermentation, the product is usually filtered and

distilled.

Suggest why distillation is

necessary and draw a simple labelled diagram ofthe apparatus which can be used for distilling

the fermented product in a school's laboratory.

(6 marks) In some countries, the Breathalyzer test is used to determine the level of alcohol on the breath

of suspected drunk drivers. Identifu the main reagent used in the Breathalyzer test and hence state the type ofreaction that occurs during the test.

(2 marks) Total 15 marks

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(b)

(c)

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-t9-In solution, two metals A and B formA* and 82* ions respectively. MetalA displaces Fe from

a solution containing Fe2* ions but metal B does NOT.

(D

Arrange the metalsA, B and Fe in order of reactivity from LEAST reactive to MOST

reactive. Write a balanced chemical equation to show the reaction between metal

A

and Fe2* ions.

(4 marks)

(ii)

Metal A is placed in a solution of copper(Il) sulfate, CuSOo (aq). Write an equation

for the reaction. State ONE observable change that

will

occur and explain why this

reaction takes place.

(5 marks)

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6.

(a)

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-(iii)

For EACH metal, A and B, state ONE method that can be used to extract

it

from its

respective oxide. Give a reason for EACH answer.

(4 marks) Metal alloys are often used for making objects found in our daily lives. Name an alloy of iron

and state ONE of its uses.

(2 marks) Total 15 marks (b)

END OF'TEST

IF YOU F'INISH BEFORE

TIME

IS CALLED, CHECK YOUR WORK ON THIS TEST.

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