RHEOLOGY BULLETIN
Publication of the Society of Rheology
Volume 36 No. I
V
t A
January, 1967
FOURTH WINTER MEETING OF
THE SOCIETY OF RHEOLOGY
M I R A M A R H O T E L - M O T E L S A N T A B A R B A R A , C A L I F O R N I A
F E B R U A R Y 6-8, 1967
Accommodations
A t t e n d e e s are u r g e d to pre-register by f i l l i n g out the enclosed f o r m and m a i l i n g it to the Local A r r a n g e -m e n t s C h a i r -m a n . Reservations f o r hotel roo-ms should be m a d e b y sending the reservation f o r m ( a t t a c h e d ) direct-l y to M i r a m a r Hotedirect-l-Motedirect-l. S a n t a B a r b a r a is connected to Los A n g e l e s and S a n Francisco b y U n i t e d a n d P a c i f i c Airlines. R e g u l a r bus ( G r e y h o u n d ) and rail ( S o u t h e r n Pacific) services are also available. Both t h e bus depot a n d r a i l station are located in d o w n t o w n S a n t a B a r b a r a . F o r local t r a n s p o r t a t i o n f r o m t h e airport, t h e r e a r e f r e -q u e n t limousine connections to d o w n t o w n . M i r a m a r Hotel-Motel is located t h r e e miles south of S a n t a B a r b a r a on U . S. h i g h w a y 101 (El C a m i n o Real) a t S a n Ysidro Road.
T h e W e s t Coast Gordon Conference on P o l y m e r s w i l l be held at t h e s a m e hotel the weekdays preceding the W i n t e r M e e t i n g of the Society of Rheology. T h o m a s O'Shaughnessy, Research D e p a r t m e n t , Phillips Pe-t r o l e u m C o m p a n y , BarPe-tlessville, Oklahoma, is Pe-t h e Chair-m a n f o r t h e Gordon Conference.
Facilities
Speakers will be provided with a blackboard and 2 inch by 2 inch and 3 % inch by 4 % inch slide projectors. If o t h e r facilities a r e required for t h e presentation, the Local A r r a n g e m e n t s C h a i r m a n should be contacted as soon as possible.
Publication
A u t h o r s are u r g e d , but n o t r e q u i r e d , to publish t h e i r p a p e r s presented at t h e m e e t i n g in the T r a n s a c -tions of the Society of Rheology. M a n u s c r i p t s should b e submitted to the editor: R. R. M y e r s , C h e m i s t r y D e p a r t
-m e n t , Kent State U n i v e r s i t y , Kent, Ohio. Acceptance f o r publication will be decided b y the editor, in consultation w i t h referees appointed b y h i m for each m a n u s c r i p t .
Program Committee
J. L. W h i t e , ( C h a i r m a n ) , U . S. R u b b e r T i r e Com-p a n y , P r o d u c t D e v e l o Com-p m e n t , 6600 East J e f f e r s o n Ave., Detroit, M i c h i g a n , 48232.
A . Eisenberg, D e p a r t m e n t of C h e m i s t r y , U n i v e r s i t y of California, Los Angeles, C a l i f o r n i a .
D. J. P l a z e k , M e l l o n Institute, 4400 F i f t h Ave., P i t t s b u r g h , P e n n s y l v a n i a , 15213.
N . W . Tschoegl, Division of E n g i n e e r i n g a n d Ap-plied Mechanics, C a l i f o r n i a I n s t i t u t e of T e c h n o l o g y , P a s a d e n a , C a l i f o r n i a .
M . C. Shen, (Local A r r a n g e m e n t s C h a i r m a n ) , N o r t h A m e r i c a n A v i a t i o n Science C e n t e r , T h o u s a n d Oaks, Cali-f o r n i a , 91360.
A MESSAGE FROM THE EDITOR
S t a r t i n g w i t h T r a n s a c t i o n s of T h e Society of Rhe-ology, V o l u m e 11, publication will be on a q u a r t e r l y basis. T h e n e w publication a r r a n g e m e n t w i t h I n t e r science P u b l i s h e r s r e q u i r e s us to s u b m i t w i t h each m a n u -script t h e following i n f o r m a t i o n : authors, address, com-plete title, individual to w h o m proof should be sent. W e do not a l w a y s have unequivocal i n f o r m a t i o n regaxding a u t h o r s ' addresses and the individual to w h o m proof is to be sent; consequently, m a n u s c r i p t accuracy is not alw a y s g u a r a n t e e d . H e n c e f o r t h , t r a n s m i t t a l of a m a n u -script to t h e p u b l i s h e r will be done only a f t e r a given a u t h o r will express i n w r i t i n g t h a t he will assiduously correct proofs.A n o t h e r point of interest to a u t h o r s of p a p e r s con-cerns the f o r m a t of abstracts. You will n o t e f r o m t h e photo offset i n s e r t in this Bulletin t h a t economies will be effected a n d errors will be m i n i m i z e d if abstracts a r e submitted i n accord w i t h these s t a n d a r d r e q u i r e m e n t s : typed on w h i t e 8 y2" x 11" paper, w i t h % " m a r g i n s at top a n d bottom of sheet and m a r g i n s a t l e f t and r i g h t sides, single spaced, w i t h p a p e r title, a u t h o r , and address (avoid use of personal titles and degrees).
RHEOLOGY BULLETIN
Raymond R. Myers, Editor
Department of Chemistry
Kent State University
Kent, Ohio, 44240
PROGRAM
FOURTH WINTER MEETING
SOCIETY OF RHEOLOGY
F e b r u a r y 6-8, 1967 M O N D A Y , F E B R U A R Y 6, 1967 S E S S I O N A — M o n d a y M o r n i n g C h a i r m a n : J. L . W H I T E , U . S . R u b b e r C o m p a n y , D e t r o i t , M i c h i g a n . A - L 8 : 4 5 a.m. I N V I T E D L E C T U R E : " M e c h a n i s m s ofDeforma-tion of Rocks and Minerals at High Temperatures and Pressures," D. T . Griggs, U n i v e r s i t y of
Cali-f o r n i a at Los Angeles, Los Angeles, C a l i Cali-f o r n i a .
T H E R M O D Y N A M I C S I N R H E O L O G Y A - 2
9 : 4 5 a.m. "A Rational Theory of Non-Linear
Visco-elasticity," K. C. V a l a n i s , U n i v e r s i t y of Iowa, Ames,
Iowa.
10:15 a.m. Break
A - 3
10:30 a.m. " T h e r m o e l a s t i c i t y of Natural Rubber at
Small Strains," M . C. S H E N a n d J. D. S t r o n g . N o r t h A m e r i c a n A v i a t i o n Science C e n t e r , T h o u s a n d Oaks, C a l i f o r n i a .
A - 4
11:00 a.m. " D i s s i p a t i o n Function in Thermornechanical
Phenomena of Viscoelastic Solids," N . C. H u a n g .
U n i v e r s i t y of C a l i f o r n i a at S a n Diego, La Jolla, C a l i f o r n i a .
S E S S I O N B — M o n d a y A f t e r n o o n
C h a i r m a n : A. E I S E N B E R G , U n i v e r s i t y of C a l i f o r n i a at Los Angeles, Los Angeles, C a l i f o r n i a .
P O L Y M E R M E L T S A N D C O N C E N T R A T E D S O L U T I O N S
B-l
2 : 0 0 p •m. "Poly Vinyl Chloride Melt Rheology and
Flow Activation Energy," E d w a r d A. Collins, B. F .
Goodrich Chemical C o m p a n y , D e v e l o p m e n t C e n t e r , Avon Lake, Ohio.
B-2
2:30 p.m. "Resin Particles as Flow Units in Polyvinyl
Chloride Melts," A. R. B E R E N S a n d V. L . Folt, B . F .
Goodrich Research C e n t e r , Brecksville, Ohio. B-3
3:00 p . m . "Flow of Polymer Melts in Extruders," H . J. Z a m o d i t s , P o l y m e r C o r p o r a t i o n L i m i t e d , S a r n i a , O n t a r i o , a n d J. R. A. Pearson, C a m b r i d g e U n i v e r s i t y . C a m b r i d g e , E n g l a n d .
3:30 p.m. B r e a k
B - 4
3:45 p.m. "The Steady Flow of Partially Crystalline
Polyethylene," J. F . Johnson, C h e v r o n Research,
R i c h m o n d , C a l i f o r n i a .
B-5
4:15 p.m. "Viscoelastic Properties of Mondisperse
Poly-styrene," J A M E S M . O ' R E I L L Y and W i l l i a m M . Prest, J r . , G e n e r a l Electric, S c h e n e c t a d y , N e w York. B-6
4:45 p . m . "Non-Newtonian Viscosity in Narrow
Dis-tribution Polystyrenes," W I L L I A M W . G R A E S S L E Y ,
Ronald L. H a z e l t o n , and Louis R. L i n d e m a n , N o r t h -w e s t e r n U n i v e r s i t y , E v a n s t o n , Illinois.
T U E S D A Y , F E B R U A R Y 7, 1967 S E S S I O N C — T u e s d a y M o r n i n g
C h a i r m a n : R. F. LANDEL, Jet Propulsion L a b o r a t o r y , C a l i f o r n i a I n s t i t u t e of T e c h n o l o g y , P a s a d e n a , Cali-f o r n i a .
C - l
8 : 4 5 a.m. I N V I T E D L E C T U R E : "Statistical Mechanics and the WLF Equation," J. H . Gibbs, B r o w n U n i
-versity, Providence, Rhode I s l a n d .
R H E O L O G Y O F B U L K P O L Y M E R S C-2
9:45 a.m. " M o l e c u l a r Flow and Lanthanum Catalyzed
Bond Interchange in Sodium Phosphate Polymers,"
A D I E I S E N B E R G a n d Shogo Saito, U n i v e r s i t y of Cali-f o r n i a at I.,os Angeles, Los Angeles, C a l i Cali-f o r n i a . 10:15 a.m. Break
C-3
10:30 a.m. "Chemical Stress Relaxation of Crosslinked
Poly(methylmethacrylate) Polymers at Elevated Temperatures in Vacuum," N . W . T S C H O E G L , J. E. F r e d e r i c k , and T . L. S m i t h , S t a n f o r d Research' Insti-tute, M e n l o P a r k , C a l i f o r n i a .
C-4
11:00 a.m. " S t r e s s - S t r a i n and Ultimate Properties of
Crosslinked Poly(methylmethacrylate) Polymers in the Rubbery State," T . L. SMITH. J. E. F r e d e r i c k ,
and N . W . Tschoegl, S t a n f o r d Research I n s t i t u t e ' M e n l o P a r k , California.
S E S S I O N D — T u e s d a y A f t e r n o o n
C h a i r m a n : N . W . T S C H O E G L , California I n s t i t u t e of
Tech-nology, P a s a d e n a , C a l i f o r n i a . G E N E R A L S E S S I O N
D - l
2 : 0 0 p.m. "Stress Wave Phenomena in a Three
Di-rnensionally Reinforced Plastic," J . J. W u , G. M .
Wassil, and E. M . Lenoe, Avco Space Systems Divis-ion, Avco CorporatDivis-ion, Lowell, Massachusetts.
D - 2
2 : 3 0 p.m. " E f f e c t of Process Variables on the Stress
Relaxation Spectrum of Pure Aluminum," E. M .
L E N O E a n d G . W . Wassil, Avco Space Systems Divis-ion, Avco CorporatDivis-ion, Lowell, Massachusetts. D - 3
3 : 0 0 p.m. " T h e Character of the Stress-Strain Function
for Solid Propellant" R. J . Farris, Aerojet-General
Corporation, S a c r a m e n t o , California. 3 : 3 0 p.m. Break
D - 4
3:45 p.m. "Impedance Matching as an Analog of
Vis-cosity in Pulsating Hydraulic Systems," H a r r y Lobel,
I n d e p e n d e n t School District, Council Bluffs, I o w a . D-5
4:15 p.m. " T h e r m a l Feedback in a Model of a Viscous
Solid Under Cyclic and Random Adiabatic Loading or Straining" S. J . Becker a n d I . J . G R U N T F E S T ,
G e n e r a l Electric C o m p a n y , Space T e c h n o l o g y Center, K i n g of Prussia, P e n n s y l v a n i a .
D-6
4:45 p.m. "Stress Cracking of 0.95 Density
Polyethy-lene Under Constant Load in an Environment as a Function of Load. Temperature and Molecular Weight" G l e n n E. F u l m e r , W . R. G r a c e a n d
Com-pany, Research Division, Clarksville, M a r y l a n d .
T U E S D A Y E V E N I N G 6:00 p.m. Cocktail H o u r
Courtesy of the I n s t r o n C o m p a n y 7:00 p.m. B a n q u e t
L. E. Nielsen, M o n s a n t o C o m p a n y , St. Louis, Mis-souri, will speak on glacier exploration in Alaska.
W E D N E S D A Y , F E B R U A R Y 8, 1967 S E S S I O N E — W e d n e s d a y M o r n i n g
C h a i r m a n : P. J. BLATZ, N o r t h A m e r i c a n A v i a t i o n Sci-ence C e n t e r , T h o u s a n d Oaks, California.
E - l
8:45 a.m. I N V I T E D L E C T U R E : " T h e Continuum Has
Boundaries," W . R. Schowalter, P r i n c e t o n
Universi-ty, N e w Jersey.
C O N T I N U U M M E C H A N I C S O F N O N - N E W T O N I A N F L U I D S E-2
9:45 a.m. " A Modified Functional Expansion for
Vis-coelastic Fluids" J. D. Goddard, T h e U n i v e r s i t y of
M i c h i g a n , A n n Arbor, M i c h i g a n .
10:15 a . m . Break E - 3
10:30 a.m. "A Modified Superposition Principle
Ap-plied to Creep of Non-Linear Viscoelastic Material Under Abrupt Changes in State of Combined Stress,"
W . N . F I N D L E Y a n d J . S. Y. Lai, B r o w n U n i v e r s i t y , Providence, Rhode Island.
E-4
11:00 a.m. " T h e Motion of a Continuous Sheet Through
an Infinite Stagnant Non-Newtonian Fluid," J a m e s
L. W h i t e , U n i v e r s i t y of D e l a w a r e , N e w a r k , N e w Jersey, a n d U . S. R u b b e r T i r e C o m p a n y , Detroit, M i c h i g a n .
S E S S I O N F — W e d n e s d a y A f t e r n o o n
C h a i r m a n : M . C. SHEN, N o r t h A m e r i c a n Aviation Sci-ence C e n t e r , T h o u s a n d Oaks, California.
F L O W O F P O L Y M E R S O L U T I O N S A N D S U S P E N S I O N S
F - l
2:00 p.m. "Prediction of Drag Reduction Using a
Vis-coelastic Model," G. K. P A T T E R S O N and J. L. Z a k i n ,
U n i v e r s i t y of Missouri, Rolla, Missouri. F-2
2 : 3 0 p.m. "Effects of Local Injection of a
Drag-Reduc-ing Fluid Into Turbulent Pipe Flow of a Newtonian Fluid " C. S I N C L A I R W E L L S , J R . and Jack G. Spang-ler, L T V Research C e n t e r , Dallas, T e x a s .
F - 3
3:00 p.m. "Intrinsic Viscosity of Polymer Solutions at
High Shear Rates," A. R a m a n d A. S I E G M A N , Poly-m e r Science a n d E n g i n e e r i n g , Case I n s t i t u t e of Tech-nology, Cleveland, Ohio.
3 : 3 0 p.m. Break F - 4
3:45 p.m. "The Viscosity of Slurries, II: Studies of
Lower Volumetric Loadings," B. G. M o s e r and R. F.
Landel, J e t Propulsion L a b o r a t o r y , California In-stitute of T e c h n o l o g y , P a s a d e n a , California. F-5
4:15 p.m. " P r e d i c t i o n of the Viscosity of Multimodal
Suspensions From Monomodal Viscosity Data," R. J .
Farris, A e r o j e t - G e n e r a l Corporation, S a c r a m e n t o , California.
SYMPOSIUM ON BLOCK COPOLYMERS
A one d a y s y m p o s i u m on Block Copolymers, cover-i n g thecover-ir chemcover-istry, propertcover-ies, and technology, wcover-ill be held at t h e California I n s t i t u t e of T e c h n o l o g y , Pasa-dena, California, on J u n e 5, 1967. Joint sponsors a r e t h e P o l y m e r G r o u p of the S o u t h e r n California Section, A m e r i c a n Chemical Society, and the Institute. P a p e r s are by invitation, a n d w i l l include review lectures as well as discussions of r e c e n t advances in t h e field of block copolymers.Requests for f u r t h e r i n f o r m a t i o n a n d p r e r e g i s t r a t i o n f o r m s should be directed to N. W . Tschoegl, California I n s t i t u t e of T e c h n o l o g y , 1201 E a s t California Street. Pasadena, C a l i f o r n i a 91109 prior to M a y 1, 1967. T h e r e will be n o registration fee.
THE SOCIETY OF RHEOLOGY TREASURER'S REPORT - OCTOBER, 1966
S U M M A R Y O F A C C O U N T Balance in Account J a n u a r y 1, 1966 $8 127.42 Balance on H a n d S e p t e m b e r 30, 1966 9 164.60 Projected Balance J a n u a r y 1, 1967 8 007.42 II. R E V I E W O F COSTS P E R M E M B E R T o t a l Cost P r o p o r t i o n of Cost Year ( P e r M e m b e r ) for T R A N S A C T I O N S 1965(a) $19.50 $9.00 (1000 pages) 1966 13.70 7.30 ( 700 pages) 1967(b) 8.60 3.00 ( 700 pages)
( a ) H i g h cost due to publication of back issue of T R A N S A C T I O N S in addition to two r e g u l a r issues. F u r t h e r m o r e , r e m a i n d e r of bills i n c u r r e d f r o m the 4th I n t e r n a t i o n a l Rheology Congress w e r e paid.
(b) P a g e c h a r g e instituted. III. P R O J E C T E D R E C E I P T S A N D E X P E N S E S , 1966 Balance i n A c c o u n t J a n u a r y 1, 1966 R E C E I P T S D u e s $9,200.00 M e e t i n g I n c o m e ( M o n t e r e r y ) 350.00
Savings Bond Interest 40.00
Total Receipts $9,590.00 T O T A L E X P E N S E S A I P (Dues and A d m i n i s t r a t i o n ) $1,700.00 Secretarial Services ( A I P ) 150.00 W i n t e r Bulletin 600.00 S p r i n g Bulletin 70.00 Fall Bulletin 650.00 T R A N S A C T I O N S (700 pages) 5,500.00 Editorial Expenses 650.00 Brochure 90.00 Miscellaneous 300.00 $9,710.00 $ 8,127.42 $17,717.42 T O T A L E X P E N S E S $ 9 J W Q 0 P R O J E C T E D B A L A N C E I N A C C O U N T J A N U A R Y 1, 1967 $ 8.007.42 ( C o n t i n u e d )
THE SOCIETY OF RHEOLOGY TREASURER'S REPORT - OCTOBER, 1966
(Continued) IV. P R O J E C T E D R E C E I P T S A N D E X P E N S E S , 1967 P r o j e c t e d B a l a n c e in A c c o u n t J a n u a r y 1, 1967 P R O J E C T E D R E C E I P T S D u e s M e e t i n g I n c o m e S a v i n g s Bond I n t e r e s t T o t a l P r o j e c t e d Receipts T O T A L P R O J E C T E D E X P E N S E S T R A N S A C T I O N S C h a r g e (700 p a g e s ) O t h e r P u b l i c a t i o n s A I P E x p e n s e s E d i t o r i a l E x p e n s e s M i s c e l l a n e o u s E x p e n s e s T O T A L P R O J E C T E D E X P E N S E S P R O J E C T E D B A L A N C E I N A C C O U N T J A N U A R Y 1, 1968 $9,200.00 400.00 40.00 $9,640.00 $2,250.00 1,500.00 1,900.00 700.00 100.00 $6,450.00 $ 8,007.42 $17,647.42 $ 6,450.00 $11,197.42 R e s p e c t f u l l y s u b m i t t e d , A r m a n d F . L e w i s T r e a s u r e r , Society of R h e o l o g y
THE SOCIETY OF RHEOLOGY SUPPLEMENTARY TREASURER'S REPORT
PUBLICATION ACCOUNT P R O J E C T E D I N C O M E F R O M P A G E C H A R G E ( A s s u m e 700 p a g e s at $15.00 p e r p a g e w i t h 7 0 % h o n o r i n g c h a r g e ) P R O J E C T E D C O S T O F T R A N S A C T I O N S F O R 1967 " P e r P a g e C h a r g e " ( a ) " S u b s c r i p t i o n C h a r g e " ( b ) $4,140.00 1,575.00 $7,350.00 T O T A L P R O J E C T E D C O S T
( a ) A s s u m e 1900 total subscription and 750 SOR m e m b e r s , t h e r e f o r e 750 X $15.00 = $5.92 p e r p a g e c h a r g e . 1900 ( b ) A s s u m e $0.003 X 700 ( p a g e s ) x 750 ( m e m b e r s ) . P R O J E C T E D I N C O M E F R O M P A G E C H A R G E $5,715.00 $1,635.00 R e s p e c t f u l l y s u b m i t t e d , A r m a n d F . L e w i s T r e a s u r e r , Society of R h e o l o g y
AMERICAN INSTITUTE OF PHYSICS, INCORPORATED FOR
SOCIETY OF RHEOLOGY Statement of Receipts and Disbursements
At September 30, 1966 B a l a n c e in A c c o u n t - J a n u a r y 1, 1966 Receipts ( J a n u a r y 1 - S e p t e m b e r 30, 1966) D u e s Collections: 1965 D u e s 1966 D u e s 1967 D u e s I n t e r e s t o n U . S. G o v e r n m e n t Bond* T r a n s f e r of F u n d s f r o m W e s t Coast C h e c k i n g A c c o u n t T o t a l Receipts $ 8,127.42 100.00 1,658.88 1,180.00 2,938.88 19.37 535.05 $11,620.72 D i s b u r s e m e n t s ( J a n u a r y 1 - S e p t e m b e r 30, 1966) C h a r g e f o r D u e s B i l l i n g a n d Collection $201.47 C h a r g e f o r M a i n t e n a n c e of Society List 394.42 C o n t r i b u t i o n f o r S u p p o r t of A I P f o r 1966 ( N i n e M o n t h s ) 710.49 $ 1,306.38 B u l l e t i n s : W i n t e r B u l l e t i n $109.45 S p r i n g B u l l e t i n 71.53 180.98 M e e t i n g s : W i n t e r M e e t i n g - M o n t e r e y , C a l i f o r n i a $ 65.93 F a l l M e e t i n g - A t l a n t i c C i t y , N . J . 194.81 260.74 S y m p o s i u m o n B i o m e d i c a l F l u i d F l o w 14.78 C o n s t i t u t i o n 18.57 B r o c h u r e 89.91 E d i t o r i a l E x p e n s e s - R. R. M y e r s : S e c r e t a r i a l S e r v i c e s $363.77 O f f i c e E x p e n s e 54.05 417.82 S e c r e t a r i a l D u t i e s - E . W o l f : W e l c o m i n g L e t t e r s $ 36.47 M i s c e l l a n e o u s C o r r e s p o n d e n c e 40.49 76.96 O t h e r : A d d r e s s i n g G a l l e y in A l p h a b e t i c a l O r d e r f o r M i l l e r a n d L e w i s $ 3.68 A d d r e s s i n g List in D u p l i c a t e f o r C o u l e h a n a n d M i l l e r 18.40 F o u r - D r a w e r L e t t e r Size G r a y F i l e 62.50 T e l e p h o n e 5.40 §9.98 T o t a l D i s b u r s e m e n t s 2 4 5 6 1° B a l a n c e in A c c o u n t , S e p t e m b e r 30, 1966 $ g 1 5 4 5 0 • B i n g h a m F u n d : $1.000.00 U . S. G o v e r n m e n t Bond 37/s%— D u e M a y 15, 1968
PRE-REGISTRATION FOR THE 4TH W I N T E R M E E T I N G O F THE S O C I E T Y O F R H E O L O G Y , S A N T A B A R B A R A , C A L I F O R N I A ( F E B R U A R Y 6-8. 1967) Send request and registration fee prior to F e b r u a r y 1, 1967 to M. C. S h e n , N o r t h A m e r i c a n A v i a t i o n Science C e n t e r , T h o u s a n d Oaks, California, 91360.
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R E S E R V A T I O N FOR THE 4TH W I N T E R M E E T I N G O F THE S O C I E T Y O F R H E O L O G Y , S A N T A B A R B A R A , C A L I F O R N I A (FEBRUARY 6-8, 1967) Send request to M i r a m a r Hotel, P. O. Rox " M " , S a n t a B a r b a r a , California DIRECTLY.
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