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Conformationally Strained trans-Cyclooctene (sTCO) Enables the Rapid Construction of 18F-PET Probes via Tetrazine Ligation

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Figure

Table 1. Illustration of the practical importance of fast, bimolecular reactivity for radiolabeling at 1 M
Figure 2. (A) Synthesis of syn-sTCO 5, labeling precursor 8, cold standard 19F-9, and radiotracer 18F-9
Figure 3. Rapid reactions of s-TCO derivatives with tetrazines. (A) Rate constants of anti-sTCO and tetrazine analogs in water
Figure 5. Radio-HPLC analyses. (A) Purified 18F-9 after incubation in PBS for 2 h at 37 °C
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