ZINUS INC.
461-469#, HUANZHU ROAD, JIMEI DISTRICT, XIAMEN, FUJIAN, CHINA
The following sample(s) was / were submitted and identified on behalf of the client as: Sample Description : 100% COTTON FIBER BARRIER
SGS Ref No. : CAN12-178308 & GZSL1212132419TX & GZSL1212130190TX
Buyer : KEETSA INC.
Manufacturer : ZINUS
Supplier : ZINUS
Country of Destination : USA
Testing Request : As requested by applicant, selected test(s) with reference to OEKO-TEX Standard 100 edition 04/2012
Sample Receiving Date : Dec.20, 2012
Test Performing Date : Dec.20, 2012 to Jan.05, 2013
Test Result(s) : For further details, please refer to the following page(s)
Signed for and on behalf of SGS-CSTC Co., Ltd.
Jack Yao
Test Summary Result
Part A
To determine the pH Value in the submitted sample(s) with reference to Client’s
requirement. PASS
Determination of Free Formaldehyde content in the submitted sample(s) with
reference to Client’s requirement. PASS
To determine the Extractable Heavy Metals contents in the submitted sample(s)
with reference to Client’s requirement. PASS
Determination of Organostannic compounds contents in the submitted sample(s)
with reference to Client’s requirement. PASS
Determination of O-phenylphenol (OPP) content(s) in the submitted sample(s)
with reference to Client’s requirement. PASS
To determine Content(s) of PBBs&PBDEs in the selected parts on the submitted
sample(s) with reference to Client’s requirement. PASS To determine the Tris(2,3-Dibromopropyl) phosphate(TRIS) content in the
submitted sample(s) with reference to Client’s requirement. PASS To determine the Tris (aziridinyl) phosphineoxide (TEPA) content in the submitted
sample(s) with reference to Client’s requirement. PASS To determine the Chlorinated Organic Carriers content in the submitted sample(s)
with reference to Client’s requirement. PASS
Determination of Chlorinated Phenols ( TeCP, PCP) content(s) in the submitted
sample(s) with reference to Client’s requirement. PASS To determine the Tris(2 chloroethyl)phosphate (TCEP) content in the submitted
sample(s) with reference to Client’s requirement. PASS To determine Polynuclear Aromatic Hydrocarbons (PAHs) in the submitted
sample(s) with reference to Client’s requirement. PASS To determine the Short Chained Chlorinated Paraffins (SCCP) contents in the
submitted sample(s) with reference to Client’s requirement. PASS To determine the Nonylphenol (NP), Octylphenol (OP), Nonylphenol Ethoxylates
(NPEOs) and Octylphenol Ethoxylates (OPEOs) content(s) in the submitted sample(s) with reference to Client’s requirement.
PASS
To determine the Hexabromocyclododecane (HBCDD) content in the submitted
sample(s) with reference to Client’s requirement. PASS
Part B Determination of Smell Development (SNV 195651: 1968) PASS Part C Colour Fastness To Water (ISO 105 E01:2010) Colour Fastness To Perspiration (ISO 105 E04:2008) PASS PASS
Part A (SGS Ref No.: CAN12-178308)
Test Results :
Test Part Description :
Specimen No. SGS Sample ID Description
1 CAN12-178308.001 Beige fabric sheet
Remarks :
(1) 1 mg/kg = 0.0001%
(2) MDL = Method Detection Limit (3) ND = Not Detected ( < MDL ) (4) "-" = Not Regulated
pH Value
Test Method : With reference to ISO 3071, test performed by pH meter
Test Item(s) Limit 001
pH value 4.0-9.0 5.3
Notes:
(1) The limit is quoted from client’s requirement
Formaldehyde
Test Method : With reference to JIS L 1041:2000 Section 6.3.1 (b) Method B, analysis was preformed by UV-Vis.
Test Item(s) Limit Unit MDL 001
Free Formaldehyde Content 300 mg/kg 20 ND
Notes:
Extractable Heavy metal
Test Method : With reference to ISO 105-E04:2008, analysis was performed by ICP-MS and UV-VIS.
Test Item(s) Limit Unit MDL 001
Arsenic (As) 1 mg/kg 0.1 ND Antimony (Sb) 30 mg/kg 1.0 ND Cadmium (Cd) 0.1 mg/kg 0.05 ND Chromium (Cr) 2 mg/kg 0.5 ND Lead (Pb) 1.0 mg/kg 0.1 ND Mercury (Hg) 0.02 mg/kg 0.01 ND Copper (Cu) 50.0 mg/kg 5.0 ND Nickel (Ni) 4 mg/kg 0.5 ND Cobalt (Co) 4 mg/kg 0.5 ND Chromium VI (Cr VI) ND mg/kg 0.5 ND Notes:
(1) The limit is quoted from client’s requirement
Organic-tin compounds
Test Method : With reference to ISO 17353: 2004 with carbamate, analysis was performed by GC-MS.
Test Item(s) Limit Unit MDL 001
Dibutyl tin (DBT) 2 mg/kg 0.02 ND
Tributyl tin (TBT) 1 mg/kg 0.02 ND
Dioctyl tin (DOT) 2 mg/kg 0.02 ND
Triphenyl tin (TPhT) 1 mg/kg 0.02 ND
Notes:
(1) The limit is quoted from client’s requirement
OPP
Test Method : SGS in house method (GZTC CHEM-TOP-055-01), analysis was performed by GC-MS.
Test Item(s) CAS_NO Limit Unit MDL 001
O-phenylphenol (OPP) 90-43-7 100 mg/kg 0.5 ND
Notes:
(1) The limit is quoted from client’s requirement
PBBs/PBDEs
Test Method : With reference to US EPA 3550C:2007 for PBBs / PBDEs content, analysis was performed by GC-MS.
Test Item(s) Limit Unit MDL 001
Monobromobiphenyl ND mg/kg 5 ND Dibromobiphenyl ND mg/kg 5 ND Tribromobiphenyl ND mg/kg 5 ND Tetrabromobiphenyl ND mg/kg 5 ND Pentabromobiphenyl ND mg/kg 5 ND Hexabromobiphenyl ND mg/kg 5 ND Heptabromobiphenyl ND mg/kg 5 ND Octabromobiphenyl ND mg/kg 5 ND Nonabromobiphenyl ND mg/kg 5 ND Decabromobiphenyl ND mg/kg 5 ND Pentabromodiphenyl ether ND mg/kg 5 ND Octabromodiphenyl ether ND mg/kg 5 ND Decabromodiphenyl ether ND mg/kg 5 ND Notes:
(1) The limit is quoted from client’s requirement
TRIS(Tris(2,3-Dibromopropyl)-phosphate)
Test Method : With reference to EPA 3550C:2007 . Analysis was performed by LC-MS.
Test Item(s) CAS_NO Limit Unit MDL 001
Tris(2,3-Dibromopropyl) 126-72-7 ND mg/kg 5 ND -phosphate
Notes:
Tris-(aziridinyl) phosphineoxide (TEPA)
Test Method : With reference to US EPA 3550C:2007, Analysis was performed by GC-NPD or GC-MS.
Test Item(s) Limit Unit MDL 001
Tris-(aziridinyl) phosphineoxide (TEPA) ND mg/kg 5 ND
Notes:
(1) The limit is quoted from client’s requirement
Chlorinated Organic Carriers
Test Method : With reference to DIN 54232:2007, analysis was conducted with GC-MS.
Test Item(s) Limit Unit MDL 001
Sum of chlorinated organic carriers 1 mg/kg 0.1 ND
2-Chlorotoluene - mg/kg 0.1 ND 3-Chlorotoluene - mg/kg 0.1 ND 4-Chlorotoluene - mg/kg 0.1 ND 1,3-Dichlorobenzene - mg/kg 0.1 ND 1,4-Dichlorobenzene - mg/kg 0.1 ND 1,2-Dichlorobenzene - mg/kg 0.1 ND 2,4-Dichlorotoluene - mg/kg 0.1 ND 2,5-Dichlorotoluene - mg/kg 0.1 ND 2,6-Dichlorotoluene - mg/kg 0.1 ND 1,3,5-Trichlorobenzene - mg/kg 0.1 ND 1,2,4-Trichlorobenzene - mg/kg 0.1 ND 1,2,3-Trichlorobenzene - mg/kg 0.1 ND 2,4,5-Trichlorotoluene - mg/kg 0.1 ND 2,3,6-Trichlorotoluene - mg/kg 0.1 ND 1,2,3,5-Tetrachlorobenzene - mg/kg 0.1 ND 1,2,4,5-Tetrachlorobenzene - mg/kg 0.1 ND 1,2,3,4-Tetrachlorobenzene - mg/kg 0.1 ND α,α,α,4-Tetrachlorotoluene - mg/kg 0.1 ND Pentachlorobenzene - mg/kg 0.1 ND Pentachlorotoluene - mg/kg 0.1 ND Hexachlorobenzene - mg/kg 0.1 ND Notes:
(1) The limit is quoted from client’s requirement
Chlorinated Phenols
Test Method : With reference to LFGB § 64 BVL B 82.02.08:2001, analysis was performed by GC-ECD or GC-MS .
Test Item(s) Limit Unit MDL 001
2,3,4,5-Tetrachlorophenol (2,3,4,5-TeCP) - mg/kg 0.05 ND 2,3,5,6-Tetrachlorophenol (2,3,5,6-TeCP) - mg/kg 0.05 ND 2,3,4,6-Tetrachlorophenol (2,3,4,6-TeCP) - mg/kg 0.05 ND Tetrachlorophenol (TeCP) 0.5 mg/kg - ND Pentachlorophenol (PCP) 0.5 mg/kg 0.05 ND Notes:
(1) The limit is quoted from client’s requirement
Tris(2-chloroethyl)phosphate (TCEP)
Test Method : With reference to EPA 3550C :2007.Analysis was performed by HPLC-MS.
Test Item(s) CAS_NO Limit Unit MDL 001
Tris(2-chloroethyl) phosphate 115-96-8 ND mg/kg 5 ND (TCEP)
Notes:
(1) The limit is quoted from client’s requirement
PAHs
Test Method : With reference to ZEK 01.4-08 of German ZLS and its amendments, analysis was performed by GC-MS.
Test Item(s) Limit Unit MDL 001
Naphthalene(NAP) - mg/kg 0.2 ND Acenaphthylene(ANY) - mg/kg 0.2 ND Acenaphthene(ANA) - mg/kg 0.2 ND Fluorene(FLU) - mg/kg 0.2 ND Phenanthrene(PHE) - mg/kg 0.2 ND Anthracene(ANT) - mg/kg 0.2 ND Fluoranthene(FLT) - mg/kg 0.2 ND Pyrene(PYR) - mg/kg 0.2 ND Benzo(a)anthracene(BaA) - mg/kg 0.2 ND Chrysene(CHR) - mg/kg 0.2 ND Benzo(b)fluoranthene(BbF) + - mg/kg 0.4 ND Benzo(j)fluoranthene(BjF) Benzo(k)fluoranthene(BkF) - mg/kg 0.2 ND Benzo(e)pyrene(BeP) - mg/kg 0.2 ND Benzo(a)pyrene(BaP) 1 mg/kg 0.2 ND Indeno(1,2,3-c,d)pyrene(IPY) - mg/kg 0.2 ND Dibenzo(a,h)anthracene(DBA) - mg/kg 0.2 ND Benzo(g,h,i)perylene(BPE) - mg/kg 0.2 ND Sum of 18 PAHs 10 mg/kg - ND To be continued…
Notes:
(1) The limit is quoted from client’s requirement
Short Chained Chlorinated Paraffin (SCCP)
Test Method : With reference to US EPA 3550C: 2007, analysis was performed by GC-ECD.
Test Item(s) Limit Unit MDL 001
Short Chained Chlorinated Paraffin (SCCP) ND mg/kg 50 ND
Notes:
(1) The limit is quoted from client’s requirement
Nonylphenol (NP), Octylphenol (OP), Nonylphenol Ethoxylates (NPEOs) and Octylphenol Ethoxylates (OPEOs)
Test Method : With reference to US EPA Method 3550C:2007, analysis was performed by LC-MS.
Test Item(s) Limit Unit MDL 001
Nonylphenol ethoxylates (NPEOs) 1000 mg/kg 10 ND Octylphenol ethoxylates (OPEOs) 1000 mg/kg 10 ND
Nonylphenol(NP) 100 mg/kg 10 ND
Octyphenol(OP) 100 mg/kg 10 ND
Notes:
(1) The limit is quoted from client’s requirement
Hexabromocyclododecane (HBCDD)
Test Method : With reference to US EPA 3550C: 2007, analysis was performed by GC-MS.
Test Item(s) Limit Unit MDL 001
Hexabromocyclododecane (HBCDD) ND mg/kg 5 ND
Notes:
Photo Appendix
Part B (SGS Ref No.: GZSL1212132419TX) Test Result:
Determination of Smell Development Of Shoes (SNV 195651: 1968)
Test Procedure: The samples was kept in a hermetically closed space with 37°C±1°C for a duration of 15 hours, in this status the smell independently judge by at least 3 persons and described by possibility of its type.
The judgement 1
End Result Weak odour
Sample blank
End Result Odourless
Photo Appendix
Part C (SGS Ref No.: GZSL1212130190TX) Test Result:
Requirement
Colour Fastness To Water (ISO 105 E01:2010)
Change in shade 4-5 Min 3
Staining on multi-fiber stripe Min 3 Acetate 4-5 Cotton 4-5 Nylon 4-5 Polyester 4-5 Acrylic 4-5 Wool 4-5
Colour Fastness To Perspiration (ISO 105 E04:2008)
Acidic
Change in shade 4-5 Min 3-4
Staining on multi-fiber stripe Min 3-4 Acetate 4-5 Cotton 4-5 Nylon 4-5 Polyester 4-5 Acrylic 4-5 Wool 4-5 Alkaline
Change in shade 4-5 Min 3-4
Staining on multi-fiber stripe Min 3-4 Acetate 4-5 Cotton 4-5 Nylon 4-5 Polyester 4-5 Acrylic 4-5 Wool 4-5
Photo Appendix
Remark: This test was conducted at 198 Kezhu Road, Scientech Park Guangzhou Economic & Technology Development District, Guangdong Province, China.