SAFETY DATA SHEET Bupi Spraywash
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Product name Bupi Spraywash
Special User Instructions
1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Cleaner for metals.
1.3. Details of the supplier of the safety data sheet
Supplier Trimite Technologies Ltd
1 Dover Street Hockley Birmingham West Midlands B18 5HW
Tel: 0121 554 7000 Mon-Thur: 8:00-16:30 Fri: 8:00-13:00 [email protected]
1.4. Emergency telephone number
Emergency telephone +44 (0) 121 554 7000 Mon-Thur: 8:00-16:30 Fri: 8:00-13:00 SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Classification (EC 1272/2008)
Physical hazards Not Classified
Health hazards Acute Tox. 2 - H300 Skin Corr. 1B - H314 Eye Irrit. 2 - H319 STOT SE 3 - H335 Environmental hazards Not Classified
2.2. Label elements Hazard pictograms
Signal word Danger
Hazard statements H300 Fatal if swallowed.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTRE/doctor if you feel unwell.
Contains Sodium metasilicate penta, Sodium nitrite, Butyl oxitol Supplementary precautionary
statements
P260 Do not breathe vapour/ spray.
P261 Avoid breathing vapour/ spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P321 Specific treatment (see medical advice on this label).
P363 Wash contaminated clothing before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.
2.3. Other hazards
This product does not contain any substances classified as PBT or vPvB.
SECTION 3: Composition/information on ingredients 3.2. Mixtures
Sodium Carbonate (light) 25-50%
CAS number: 497-19-8 EC number: 207-838-8 REACH registration number: 01-
2119485498-19-XXXX Classification
Eye Irrit. 2 - H319
Sodium metasilicate penta 25-50%
CAS number: 10-21-3 EC number: 229-912-9 REACH registration number: 01-
2119449811-37-XXXX Classification
Met. Corr. 1 - H290 Skin Corr. 1B - H314 STOT SE 3 - H335
Sodium nitrite 5-25%
CAS number: 7632-00-0 EC number: 231-555-9 M factor (Acute) = 1
Classification Ox. Sol. 3 - H272 Acute Tox. 3 - H301 Eye Irrit. 2 - H319 Aquatic Acute 1 - H400
Butyl oxitol 1-10%
CAS number: 111-76-2 EC number: 203-905-0 Classification
Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319
The full text for all hazard statements is displayed in Section 16.
SECTION 4: First aid measures 4.1. Description of first aid measures
General information Remove affected person from source of contamination. Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical personnel.
Inhalation Remove person to fresh air and keep comfortable for breathing. Get medical attention if symptoms are severe or persist.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Get medical attention immediately.
Skin contact Remove contaminated clothing and rinse skin thoroughly with water. Continue to rinse for at least 15 minutes. Get medical attention if symptoms are severe or persist after washing.
Eye contact Remove any contact lenses and open eyelids wide apart. Wash with plenty of water. Continue to rinse for at least 15 minutes and get medical attention.
Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure.
Inhalation Irritation of nose, throat and airway.
Ingestion May cause chemical burns in mouth, oesophagus and stomach. May cause stomach pain or vomiting.
Skin contact Burns can occur.
Eye contact Contact with concentrated chemical may very rapidly cause severe eye damage, possibly loss of sight.
4.3. Indication of any immediate medical attention and special treatment needed Specific treatments Show this safety data sheet to the doctor in attendance.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture Hazardous combustion
products
In combustion, harmful or even toxic fumes may be produced
5.3. Advice for firefighters Protective actions during firefighting
If risk of water pollution occurs, notify appropriate authorities.
Special protective equipment for firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Environmental precautions Do not allow to enter drains or watercourses. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Avoid generation and spreading of dust. Avoid spreading dust or contaminated materials.
Absorb spillage with sand or other inert absorbent.
6.4. Reference to other sections
Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.
SECTION 7: Handling and storage 7.1. Precautions for safe handling
Usage precautions Do not handle until all safety precautions have been read and understood. Read label before use.
Advice on general occupational hygiene
Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Provide eyewash station and safety shower.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Store at temperatures between 5°C and 25°C.
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls/Personal protection 8.1. Control parameters
Occupational exposure limits Sodium metasilicate penta
Long-term exposure limit (8-hour TWA): 2 mg/m³ dust Sodium nitrite
Long-term exposure limit (8-hour TWA): 10 mg/m³ respirable dust Short-term exposure limit (15-minute): 4 mg/m³ respirable dust Butyl oxitol
Long-term exposure limit (8-hour TWA): 25 ppm 123 mg/m³ vapour Short-term exposure limit (15-minute): 50 ppm 246 mg/m³ vapour
Sodium Carbonate (light) (CAS: 497-19-8) DNEL Workers - Inhalation; Long term local effects: 10 mg/m³ 8.2. Exposure controls
Protective equipment
Appropriate engineering controls
Provide adequate ventilation.
Eye/face protection Wear chemical splash goggles.
Hand protection Wear protective gloves. It is recommended that chemical-resistant, impervious gloves are worn. To protect hands from chemicals, gloves should comply with European Standard EN374. The most suitable glove should be chosen in consultation with the glove
supplier/manufacturer, who can provide information about the breakthrough time of the glove material. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected.
Other skin and body protection
Wear suitable protective clothing as protection against splashing or contamination. Provide eyewash station and safety shower.
Hygiene measures Good personal hygiene procedures should be implemented. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Promptly remove any clothing that becomes contaminated.
Respiratory protection Respiratory protection must be used if the airborne contamination exceeds the recommended occupational exposure limit. If ventilation is inadequate, suitable respiratory protection must be worn.
Thermal hazards Contact with hot product can cause serious thermal burns.
Environmental exposure controls
Keep container tightly sealed when not in use. Residues and empty containers should be taken care of as hazardous waste according to local and national provisions.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance Powder.
Colour Off-white.
pH pH (concentrated solution): >12
Solubility(ies) Completely soluble in water.
9.2. Other information
Other information No data available.
SECTION 10: Stability and reactivity 10.1. Reactivity
Reactivity Stable at normal ambient temperatures and when used as recommended.
10.2. Chemical stability
Stability Stable at normal ambient temperatures and when used as recommended.
10.3. Possibility of hazardous reactions Possibility of hazardous
reactions
Under normal conditions of storage and use, no hazardous reactions will occur.
10.4. Conditions to avoid
Conditions to avoid Avoid exposure to high temperatures or direct sunlight. Protect from moisture.
10.5. Incompatible materials
Materials to avoid Acids. May be corrosive to metals.
10.6. Hazardous decomposition products Hazardous decomposition
products
In combustion, harmful or even toxic fumes may be produced
SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity - oral
ATE oral (mg/kg) 5.0
Serious eye damage/irritation
Serious eye damage/irritation Corrosivity to eyes is assumed.
Inhalation Burns can occur.
Ingestion May cause chemical burns in mouth, oesophagus and stomach. May cause chemical burns in mouth and throat. Swallowing concentrated chemical may cause severe internal injury.
Skin contact Burns can occur.
Eye contact Contact with concentrated chemical may very rapidly cause severe eye damage, possibly loss of sight.
Route of exposure Inhalation Ingestion Skin and/or eye contact Combined SECTION 12: Ecological information
12.1. Toxicity
Toxicity No data available.
12.2. Persistence and degradability
Persistence and degradability There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential No data available on bioaccumulation.
12.4. Mobility in soil
Mobility The product is water-soluble and may spread in water systems.
12.5. Results of PBT and vPvB assessment Results of PBT and vPvB
assessment
This product does not contain any substances classified as PBT or vPvB.
12.6. Other adverse effects
Other adverse effects Fatal to fish and other aquatic life due to high pH.
SECTION 13: Disposal considerations 13.1. Waste treatment methods
General information This material and its container must be disposed of as hazardous waste.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.
SECTION 14: Transport information 14.1. UN number
UN No. (ADR/RID) 2923
UN No. (IMDG) 2923
UN No. (ICAO) 2923
UN No. (ADN) 2923
14.2. UN proper shipping name Proper shipping name
(ADR/RID)
CORROSIVE SOLID, TOXIC, N.O.S. (SODIUM METASILICATE PENTA, SODIUM NITRITE)
Proper shipping name (IMDG) CORROSIVE SOLID, TOXIC, N.O.S.
Proper shipping name (ICAO) CORROSIVE SOLID, TOXIC, N.O.S.
Proper shipping name (ADN) CORROSIVE SOLID, TOXIC, N.O.S.
14.3. Transport hazard class(es)
ADR/RID class 8
ADR/RID subsidiary risk 6.1 ADR/RID classification code CT2
ADR/RID label 8
IMDG class 8
IMDG subsidiary risk 6.1 ICAO class/division 8 ICAO subsidiary risk 6.1
ADN class 8
ADN subsidiary risk 6.1 Transport labels
ADR/RID packing group II IMDG packing group II ICAO packing group II
ADN packing group II
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant No.
14.6. Special precautions for user
EmS F-A, S-B
ADR transport category 2 Emergency Action Code 2X Hazard Identification Number (ADR/RID)
86
Tunnel restriction code (E)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
SECTION 16: Other information
Revision date 13/07/2020
Revision 2
SDS number 6079
Hazard statements in full H272 May intensify fire; oxidiser.
H290 May be corrosive to metals.
H300 Fatal if swallowed.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
