Formic acid 85% Safety Data Sheet according to Regulation (EU) 2015/830 Date of issue: 27/10/2017 Doc No: SDS /1

Doc No: SDS-923.022/1

27/10/2017 EN (English) 1/12

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product form : Mixture

Product name : Formic acid 85%

EC Index-No. : 607-001-00-0

EC-No. : 200-579-1

CAS-No. : 64-18-6

Type of product : Solution,Group

Formula : CH2O2

Chemical structure :

1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses

Use of the substance/mixture : Laboratory chemicals 1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet ISOLAB GmbH

Bahnhofstrasse 10, D-97877 Wertheim - Germany

T +49 93 42 912 355 - F +49 93 42 912 357 [email protected]

1.4. Emergency telephone number

Country Organisation/Company Address Emergency number Comment

Germany Giftnotruf der Charité

CBF, Haus VIII (Wirtschaftgebäude), UG

Hindenburgdamm 30

12203 Berlin +49 30 19240

SECTION 2: Hazards identification

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Skin Corr. 1A Flam. Liq. 3 Acute Tox. 4 (Oral) Acute Tox. 3 (Dermal)

H314 H226 H302 H311

Full text of hazard classes and H-statements : see section 16

Adverse physicochemical, human health and environmental effects No additional information available

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display

Hazard pictograms (CLP) :

GHS02 GHS05 GHS06

Signal word (CLP) : Danger

Hazard statements (CLP) : H226 - Flammable liquid and vapour.

H314 - Causes severe skin burns and eye damage.

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H302 - Harmful if swallowed.

H331 - Toxic if inhaled.

EUH071 - Corrosive to the respiratory tract.

Precautionary statements (CLP) : P210 - Keep away from heat.

P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308 + P310 - IF exposed or concerned: immediately call a POISON CENTER or doctor/

physician.

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

Not applicable

3.2. Mixtures

Name Product identifier %

Formic acid (CAS-No.)64-18-6

(EC-No.)200-579-1 (EC Index-No.)607-001-00-0

>= 70 - < 90 %

Full text of H-statements: see section 16

SECTION 4: First aid measures

First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised.

Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital.

First-aid measures after inhalation : Remove the victim into fresh air. Doctor: administration of corticoid spray. Immediately consult a doctor/medical service.

First-aid measures after skin contact : Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital.

First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take victim to an ophthalmologist.

First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Do not give activated charcoal. Immediately consult a doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Ingestion of large quantities: immediately to hospital. Take the container/vomit to the doctor/hospital. Do not give chemical antidote.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/effects after inhalation : Corrosion of the upper respiratory tract. Dry/sore throat. Coughing. Nausea. Respiratory difficulties. FOLLOWING SYMPTOMS MAY APPEAR LATER: Affection of the nasal septum.

Risk of lung oedema. Respiratory collapse.

Symptoms/effects after skin contact : Caustic burns/corrosion of the skin.

Symptoms/effects after eye contact : Corrosion of the eye tissue.

Symptoms/effects after ingestion : Nausea. Abdominal pain. Risk of aspiration pneumonia. Change in the haemogramme/blood composition. Burns to the gastric/intestinal mucosa. Possible esophageal perforation. Blood in vomit. Bleeding of the gastrointestinal tract. Blood in stool. Shock. Low arterial pressure.

Disturbances of consciousness. Decreased renal function.

Chronic symptoms : No effects known.

4.3. Indication of any immediate medical attention and special treatment needed No additional information available

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SECTION 5: Firefighting measures

Suitable extinguishing media : BC powder. Carbon dioxide. MAJOR FIRE: Water spray. Alcohol-resistant foam.

Unsuitable extinguishing media : No unsuitable extinguishing media known.

5.2. Special hazards arising from the substance or mixture

Fire hazard : DIRECT FIRE HAZARD. Material presenting a fire hazard. INDIRECT FIRE HAZARD.

Temperature above flashpoint: higher fire/explosion hazard. Reactions involving a fire hazard:

see "Reactivity Hazard".

Explosion hazard : INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".

5.3. Advice for firefighters

Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat. Take account of toxic fire-fighting water. Use water moderately and if possible collect or contain it.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel

Protective equipment : Gas-tight suit. Corrosion-proof suit. See "Material-Handling" to select protective clothing.

Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Seal off low-lying areas. Close doors and windows of adjacent premises. No naked flames. Keep containers closed. Wash contaminated clothes.

6.1.2. For emergency responders No additional information available 6.2. Environmental precautions

Prevent soil and water pollution. Prevent spreading in sewers.

6.3. Methods and material for containment and cleaning up

For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to select material of containers. Plug the leak, cut off the supply. Dam up the liquid spill. Try to reduce evaporation. Dilute toxic gases/vapours with water spray. Take account of

toxic/corrosive precipitation water. Hazardous reaction: measure explosive gas-air mixture.

Reaction: dilute combustible gas/vapour with water curtain. Heating: dilute combustible gas/vapour with water curtain.

Methods for cleaning up : Liquid spill: neutralize with powdered limestone or sodium bicarbonate. Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Damaged/cooled tanks must be emptied. See

"Material-handling" for suitable container materials. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.

6.4. Reference to other sections No additional information available

SECTION 7: Handling and storage

Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Keep away from naked flames/heat. At temperature > flashpoint: use spark-/explosionproof appliances. Finely divided: spark- and explosionproof appliances. Finely divided: keep away from ignition sources/sparks. Use earthed equipment. Observe very strict hygiene - avoid contact. Keep container tightly closed. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory protection.

7.2. Conditions for safe storage, including any incompatibilities

Heat and ignition sources : KEEP SUBSTANCE AWAY FROM: heat sources.

Information on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. (strong) acids. (strong) bases. metals.

Storage area : Store in a cool area. Store in a dry area. Ventilation at floor level. Fireproof storeroom. Keep locked up. Protect against frost. Provide for a tub to collect spills. Provide the tank with earthing. Unauthorized persons are not admitted. Store only in a limited quantity. Meet the legal requirements.

Special rules on packaging : SPECIAL REQUIREMENTS: closing. with pressure relief valve. corrosion-proof. dry. clean.

correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers.

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Packaging materials : SUITABLE MATERIAL: stainless steel. carbon steel. glass. MATERIAL TO AVOID: steel. lead.

aluminium. iron. copper. zinc.

7.3. Specific end use(s) No additional information available

SECTION 8: Exposure controls/personal protection

Formic acid, 85%

EU Local name Formic acid

EU IOELV TWA (mg/m³) 9 mg/m³

EU IOELV TWA (ppm) 5 ppm

Austria Local name Ameisensäure

Austria MAK (mg/m³) 9 mg/m³

Austria MAK (ppm) 5 ppm

Austria MAK Short time value (mg/m³) 9 mg/m³

Austria MAK Short time value (ppm) 5 ppm

Belgium Local name Acide formique # Mierenzuur

Belgium Limit value (mg/m³) 9.5 mg/m³

Belgium Limit value (ppm) 5 ppm

Belgium Short time value (mg/m³) 19 mg/m³

Belgium Short time value (ppm) 10 ppm

Bulgaria Local name Мравчена киселина

Bulgaria OEL TWA (mg/m³) 9 mg/m³

Bulgaria OEL TWA (ppm) 5 ppm

Bulgaria Notes • (Химични агенти, за които са определени

гранични стойности във въздуха на работната среда за Европейската общност)

Croatia Local name Mravlja kiselina, > 90%

Croatia GVI (granična vrijednost izloženosti) (mg/m³) 9 mg/m³

Croatia GVI (granična vrijednost izloženosti) (ppm) 5 ppm

Croatia Naznake (HR) EU** (naznaka da se radi o tvarima za koje su

utvrđene indikativne granične vrijednosti izloženosti prema Direktivi 2006/15/ EC (druga lista)); C (nagrizajuće)

Czech Republic Local name Kyselina mraven í

Czech Republic Expoziční limity (PEL) (mg/m³) 9 mg/m³

Czech Republic Expoziční limity (PEL) (ppm) 4.78 ppm

Czech Republic Expoziční limity (NPK-P) (mg/m³) 18 mg/m³

Czech Republic Expoziční limity (NPK-P) (ppm) 9.56 ppm

Denmark Local name Myresyre (Methansyre)

Denmark Grænseværdie (langvarig) (mg/m³) 9 mg/m³

Denmark Grænseværdie (langvarig) (ppm) 5 ppm

Denmark Anmærkninger (DK) E (betyder, at stoffet har en EF-grænseværdi)

Estonia Local name Metaanhape (sipelghape)

Estonia OEL TWA (mg/m³) 9 mg/m³

Estonia OEL TWA (ppm) 5 ppm

Finland Local name Muurahaishappo

Finland HTP-arvo (8h) (mg/m³) 5 mg/m³

Finland HTP-arvo (8h) (ppm) 3 ppm

Finland HTP-arvo (15 min) 19 mg/m³

Finland HTP-arvo (15 min) (ppm) 10 ppm

France Local name Acide formique

France VME (mg/m³) 9 mg/m³

France VME (ppm) 5 ppm

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Formic acid, 85%

France Note (FR) Valeurs règlementaires indicatives

Germany Local name Ameisensäure

Germany TRGS 900 Occupational exposure limit value (mg/m³) 9.5 mg/m³ Germany TRGS 900 Occupational exposure limit value (ppm) 5 ppm

Germany Remark (TRGS 900) DFG;EU;Y

Greece OEL TWA (mg/m³) 9 mg/m³

Greece OEL TWA (ppm) 5 ppm

Hungary Local name HANGYASAV

Hungary AK-érték 9 mg/m³

Hungary Megjegyzések (HU) m; I.

Ireland Local name Formic acid

Ireland OEL (8 hours ref) (mg/m³) 9 mg/m³

Ireland OEL (8 hours ref) (ppm) 5 ppm

Ireland Notes (IE) IOELV

Italy Local name Acido formico

Italy OEL TWA (mg/m³) 9 mg/m³

Italy OEL TWA (ppm) 5 ppm

Latvia Local name Skudrskābe (metānskābe)

Latvia OEL TWA (mg/m³) 9 mg/m³

Latvia OEL TWA (ppm) 5 ppm

Lithuania Local name Skruzdžių rūgštis

Lithuania IPRV (mg/m³) 9 mg/m³

Lithuania IPRV (ppm) 5 ppm

Luxembourg Local name Acide formique

Luxembourg OEL TWA (mg/m³) 9 mg/m³

Luxembourg OEL TWA (ppm) 5 ppm

Malta Local name Formic acid

Malta OEL TWA (mg/m³) 9 mg/m³

Malta OEL TWA (ppm) 5 ppm

Netherlands Local name Mierenzuur

Netherlands Grenswaarde TGG 15MIN (mg/m³) 5 mg/m³

Poland Local name Kwas mrówkowy

Poland NDS (mg/m³) 5 mg/m³

Poland NDSCh (mg/m³) 15 mg/m³

Portugal Local name Ácido fórmico

Portugal OEL TWA (ppm) 5 ppm

Portugal OEL STEL (ppm) 10 ppm

Romania Local name Acid formic

Romania OEL TWA (mg/m³) 9 mg/m³

Romania OEL TWA (ppm) 5 ppm

Slovakia Local name Kyselina mravčia (kyselina metánová)

Slovakia NPHV (priemerná) (mg/m³) 9 mg/m³

Slovakia NPHV (priemerná) (ppm) 5 ppm

Slovenia Local name mravljična kislina

Slovenia OEL TWA (mg/m³) 9 mg/m³

Slovenia OEL TWA (ppm) 5 ppm

Spain Local name Ácido fórmico

Spain VLA-ED (mg/m³) 9 mg/m³

Spain VLA-ED (ppm) 5 ppm

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Formic acid, 85%

Spain Notes VLI (Agente químico para el que la U.E. estableció en

su día un valor límite indicativo), s (Esta sustancia tiene prohibida total o parcialmente su

comercialización y uso como fitosanitario y/o como biocida. Para una información detallada acerca de las prohibiciones consúltese: Base de datos de productos biocidas:

http://www.msssi.gob.es/ciudadanos/productos.do?tip o=plaguicidas Base de datos de productos

fitosanitarios:

http://www.magrama.gob.es/agricultura/pags/fitos/regi stro/fichas/pdf/Lista_sa.pdf)

Sweden Local name Myrsyra

Sweden nivågränsvärde (NVG) (mg/m³) 5 mg/m³

Sweden nivågränsvärde (NVG) (ppm) 3 ppm

Sweden kortidsvärde (KTV) (mg/m³) 9 mg/m³

Sweden kortidsvärde (KTV) (ppm) 5 ppm

Sweden Anmärkning (SE) V (Vägledande korttidsgränsvärde ska användas som

ett rekommenderat högsta värde som inte bör överskridas)

United Kingdom Local name Formic acid

United Kingdom WEL TWA (mg/m³) 9.6 mg/m³

United Kingdom WEL TWA (ppm) 5 ppm

Russian Federation Local name Метановая кислота+

Russian Federation OEL Ceiling (mg/m³) 1 mg/m³

Russian Federation Remark (RU) 2 класс опасности - высокоопасное; п (пары и/или

газы); + (соединения, при работе с которыми требуется специальная защита кожи и глаз; символ проставлен вслед за наименованием вещества)

Norway Local name Maursyre

Norway Grenseverdier (AN) (mg/m³) 9 mg/m³

Norway Grenseverdier (AN) (ppm) 5 ppm

Norway Merknader (NO) E (EU har en veiledende grenseverdi for stoffet)

Switzerland Local name Ameisensäure

Switzerland MAK (mg/m³) 9.5 mg/m³

Switzerland MAK (ppm) 5 ppm

Switzerland KZGW (mg/m³) 19 mg/m³

Switzerland KZGW (ppm) 10 ppm

Switzerland Remark (CH) SSC - Haut & Auge, OAW^{KT AN} - NIOSH, OSHA

Turkey Local name Formik asit

Turkey OEL TWA (mg/m³) 9 mg/m³

Turkey OEL TWA (ppm) 5 ppm

Australia Local name Formic acid

Australia TWA (mg/m³) 9.4 mg/m³

Australia TWA (ppm) 5 ppm

Australia STEL (mg/m³) 19 mg/m³

Australia STEL (ppm) 10 ppm

USA - ACGIH Local name Formic acid

USA - ACGIH ACGIH TWA (ppm) 5 ppm

USA - ACGIH ACGIH STEL (ppm) 10 ppm

USA - ACGIH Remark (ACGIH) URT, eye, & skin irr

USA - OSHA Local name Formic acid

USA - OSHA OSHA PEL (TWA) (mg/m³) 9 mg/m³

USA - OSHA OSHA PEL (TWA) (ppm) 5 ppm

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8.2. Exposure controls Personal protective equipment:

Gloves. Safety glasses.

Materials for protective clothing:

GIVE GOOD RESISTANCE: butyl rubber. natural rubber. neoprene. nitrile rubber. polyurethane. PVC. styrene-butadiene rubber. GIVE LESS RESISTANCE: chlorinated polyethylene. viton. neoprene/SBR. nitrile rubber/PVC. GIVE POOR RESISTANCE: polyethylene

Hand protection:

Gloves Eye protection:

Protective goggles Skin and body protection:

Head/neck protection. Corrosion-proof clothing Respiratory protection:

Wear gas mask with filter type A if conc. in air > exposure limit

Device Filter type Condition Standard

Gas mask Type A - High-boiling (>65 °C) organic compounds

If conc. in air > exposure limit

SECTION 9: Physical and chemical properties

Physical state : Liquid

Appearance : Liquid.

Molecular mass : 46.03 g/mol

Colour : Colourless.

Odour : Irritating/pungent odour.

Odour threshold : No data available

pH : 2.2 (10 g/l, H₂O, 20 °C)

Relative evaporation rate (butylacetate=1) : 2

Melting point : 8.4 °C

Freezing point : No data available

Boiling point : 101 °C (1013 hPa)

Flash point : 48 °C

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : 42 hPa (20 °C)

Relative vapour density at 20 °C : No data available

Density : 1.22 g/cm³ (20 °C)

Solubility : Soluble in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in acetic acid.

Soluble in gasoline. Soluble in glycerol. Soluble in toluene. Soluble in xylene.

Water: Complete

Log Pow : -1.55 - -0.5

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : 12 - 57 %(V)

Oxidising properties : No data available

Explosive limits : 18 - 57 vol %

9.2. Other information

VOC content : >= 90 %

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Other properties : Gas/vapour heavier than air at 20°C. Hygroscopic. Producing fumes/mist. Physical properties depending on the conc

entration. Volatile. Substance has acid reaction.

SECTION 10: Stability and reactivity

On heating: release of highly flammable gases/vapours (hydrogen). Upon combustion: CO and CO2 are formed. Reacts violently with (strong) oxidizers: pressure rise and possible bursting of container. Reacts exothermically with (some) acids/bases. Reacts with (some) metals: release of highly flammable gases/vapours (hydrogen). Prolonged storage: decomposes slowly: release of harmful/irritant gases/vapours (carbon monoxide):

pressure rise and possible bursting of container. This reaction is accelerated on exposure to some compounds and on exposure to temperature rise.

10.2. Chemical stability Hygroscopic.

10.3. Possibility of hazardous reactions No additional information available

10.4. Conditions to avoid No additional information available 10.5. Incompatible materials No additional information available

10.6. Hazardous decomposition products No additional information available

SECTION 11: Toxicological information

Acute toxicity : Not classified

Formic acid 85% (64-18-6)

LD50 oral rat 1100 mg/kg (Rat)

LC50 inhalation rat (mg/l) > 7.4 mg/l/4h (Rat)

Skin corrosion/irritation : Causes severe skin burns and eye damage.

Serious eye damage/irritation : Serious eye damage, category 1, implicit Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

Ecology - general : Classification concerning the environment: not applicable.

Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009).

Ecology - water : Mild water pollutant (surface water). Harmful to fishes. Harmful to invertebrates (Daphnia).

Harmful to algae. Harmful to plankton. pH shift. Not harmful to activated sludge.

Formic acid 85% (64-18-6)

LC50 fish 2 46 mg/l (LC50; 96 h)

EC50 Daphnia 1 34 mg/l (EC50; 48 h)

Threshold limit algae 1 26.9 mg/l (EC50; 72 h)

12.2. Persistence and degradability Formic acid 85% (64-18-6)

Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the components available.

Biochemical oxygen demand (BOD) 0.02 - 0.27 g O₂/g substance

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Formic acid 85% (64-18-6)

ThOD 0.35 g O₂/g substance

BOD (% of ThOD) 0.40 - 0.77

12.3. Bioaccumulative potential Formic acid, 85% (64-18-6)

Log Pow -1.55 - -0.5

Bioaccumulative potential Bioaccumulation: not applicable.

12.4. Mobility in soil No additional information available

12.5. Results of PBT and vPvB assessment No additional information available

12.6. Other adverse effects No additional information available

SECTION 13: Disposal considerations

Product/Packaging disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Treat using the best available techniques before discharge into drains or the aquatic environment.

Additional information : LWCA (the Netherlands): KGA category 03. Hazardous waste according to Directive 2008/98/EC.

SECTION 14: Transport information

ADR IMDG IATA ADN RID

14.1. UN number

1779 1779 1779 1779 1779

14.2. UN proper shipping name

FORMIC ACID FORMIC ACID Formic acid FORMIC ACID FORMIC ACID

Transport document description UN 1779 FORMIC ACID, 3 (8), II, (D/E)

UN 1779 FORMIC ACID, 8 (3), II

UN 1779 Formic acid, 8 (3), II

UN 1779 FORMIC ACID, 8 (3), II

UN 1779 FORMIC ACID, 8 (3), II

14.3. Transport hazard class(es)

3 (8) 8 (3) 8 (3) 8 (3) 8 (3)

14.4. Packing group

II II II II II

14.5. Environmental hazards Dangerous for the

environment : No

Dangerous for the environment : No Marine pollutant : No

Dangerous for the environment : No

Dangerous for the environment : No

Dangerous for the environment : No No supplementary information available

14.6. Special precautions for user

- Overland transport

Classification code (ADR) : CF1

Limited quantities (ADR) : 1l

Excepted quantities (ADR) : E2

Packing instructions (ADR) : P001, IBC02

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Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions

(ADR)

: T7 Portable tank and bulk container special

provisions (ADR)

: TP2

Tank code (ADR) : L4BN

Vehicle for tank carriage : FL

Transport category (ADR) : 2

Special provisions for carriage - Operation (ADR)

: S2 Hazard identification number (Kemler No.) : 83

Orange plates :

Tunnel restriction code (ADR) : D/E

- Transport by sea

Transport regulations (IMDG) : Subject

Limited quantities (IMDG) : 1 L

Excepted quantities (IMDG) : E2

Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02

Tank instructions (IMDG) : T7

Tank special provisions (IMDG) : TP2

EmS-No. (Fire) : F-E

EmS-No. (Spillage) : S-C

Stowage category (IMDG) : A

Stowage and handling (IMDG) : SW2

Properties and observations (IMDG) : Colourless flammable liquid with a pungent odour. Pure FORMIC ACID: flashpoint 42°C c.c.

Corrosive to most metals. Causes burns to skin, eyes and mucous membranes.

MFAG-No : 153

- Air transport

Transport regulations (IATA) : Subject to the provisions PCA Excepted quantities (IATA) : E2

PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851

PCA max net quantity (IATA) : 1L

CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L

ERG code (IATA) : 8F

- Inland waterway transport

Classification code (ADN) : CF1

Limited quantities (ADN) : 1 L

Excepted quantities (ADN) : E2

Carriage permitted (ADN) : T

Equipment required (ADN) : PP, EP, EX, A

Ventilation (ADN) : VE01

Number of blue cones/lights (ADN) : 1

- Rail transport

Transport regulations (RID) : Subject

Classification code (RID) : CF1

Limited quantities (RID) : 1L

Excepted quantities (RID) : E2

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Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions

(RID)

: T7 Portable tank and bulk container special

provisions (RID)

: TP2 Tank codes for RID tanks (RID) : L4BN

Transport category (RID) : 2

Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 83

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations

No REACH Annex XVII restrictions

Formic acid, 85% is not on the REACH Candidate List Formic acid, 85% is not on the REACH Annex XIV List

VOC content : >= 90 %

15.1.2. National regulations

Germany

VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 1 or 2; ID No. 210)

WGK remark : Classification water polluting in compliance with Verwaltungsvorschrift wassergefährdender Stoffe (VwVwS) of 27 July 2005 (Anhang 2)

12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV

: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)

Netherlands

SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting

giftige stoffen – Borstvoeding

: The substance is not listed NIET-limitatieve lijst van voor de voortplanting

giftige stoffen – Vruchtbaarheid

: The substance is not listed NIET-limitatieve lijst van voor de voortplanting

giftige stoffen – Ontwikkeling

: The substance is not listed

Denmark

Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

Pregnant/breastfeeding women working with the product must not be in direct contact with the product

15.2. Chemical safety assessment No additional information available

SECTION 16: Other information

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

ATE Acute Toxicity Estimate BCF Bioconcentration factor

CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 EC50 Median effective concentration

Doc No: SDS-923.022/1

27/10/2017 EN (English) 12/12

IARC International Agency for Research on Cancer IATA International Air Transport Association IMDG International Maritime Dangerous Goods LC50 Median lethal concentration

LD50 Median lethal dose

PBT Persistent Bioaccumulative Toxic

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 RID Regulations concerning the International Carriage of Dangerous Goods by Rail

SDS Safety Data Sheet

vPvB Very Persistent and Very Bioaccumulative

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE

COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.

Full text of H- and EUH-statements:

Skin Corr. 1A Skin corrosion/irritation, Category 1A Flam. Liq. 3 Flammable liquids, Category 3 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3

H226 Flammable liquid and vapour.

H314 Causes severe skin burns and eye damage.

H302 Harmful if swallowed.

H331 Toxic if inhaled.

H314 Causes severe skin burns and eye damage

EUH071 Corrosive to the respiratory tract.

SDS ISOLAB

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product