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Chapter 25
Nuclear Chemistry
25.1 Nuclear Radiation
25.2 Nuclear Transformations
25.3 Fission and Fusion
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Where does the sun’s energy come from?
CHEMISTRY & YOU CHEMISTRY & YOU
The sun is about
halfway through its life cycle. It has been
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Nuclear Fission
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
When the nuclei of certain isotopes are
bombarded with neutrons, the nuclei
split into smaller fragments.
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
The figure below shows how uranium-235 breaks into two smaller fragments of roughly the same size when struck by a slow-moving neutron.
U
Uranium-235 (fissionable)
235
92 U
Uranium-236 (very unstable) 236 92 Ba Barium-142 142 56 Kr Krypton-91 91 36
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
In a chain reaction, some of the emitted
neutrons react with other fissionable
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Nuclear fission can release enormous
amounts of energy.
• The fission of 1 kg of uranium-235 yields an amount of energy equal to that
produced when 20,000 tons of dynamite explode.
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Nuclear reactors use controlled fission
to produce useful energy.
• The reaction takes place within uranium-235 or plutonium-239 fuel rods.
• A coolant absorbs heat produced by the controlled fission reaction and transfers the heat to water, which changes to
steam.
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Neutron Moderation
Nuclear moderation
is a process that
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Neutron Moderation
Nuclear moderation
is a process that
slows down neutrons so the reactor fuel can
capture them to continue the chain reaction.
• Moderation is necessary because most of the neutrons produced move so fast that they
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Neutron Moderation
Nuclear moderation
is a process that
slows down neutrons so the reactor fuel can
capture them to continue the chain reaction.
• Moderation is necessary because most of the neutrons produced move so fast that they
would pass right through a nucleus without being captured.
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Neutron Absorption
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Neutron Absorption
To prevent the chain reaction from going too
fast, some of the slowed neutrons must be
trapped before they hit fissionable atoms.
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Neutron Absorption
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Neutron Absorption
Control rods, made of materials such as
cadmium, are used to absorb neutrons.
• When control rods extend almost all the way into the reactor core, they absorb many
neutrons and fission occurs slowly.
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Neutron Absorption
Control rods, made of materials such as
cadmium, are used to absorb neutrons.
• If the chain reaction were to go too fast, heat might be produced faster than the coolant
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Nuclear Waste
Fuel rods from nuclear power plants are one
major source of nuclear waste.
• The fuel rods are made from a fissionable
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Nuclear Waste
Fuel rods from nuclear power plants are one
major source of nuclear waste.
• The fuel rods are made from a fissionable
isotope, either uranium-235 or plutonium-239. • During fission, the amount of fissionable
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Nuclear Waste
Spent fuel rods are classified as high-level
nuclear waste.
• All nuclear power plants have holding tanks, or “swimming pools,” for spent fuel rods.
• Water cools the spent rods and also acts as a radiation shield to
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Nuclear Waste
Spent fuel rods are classified as high-level
nuclear waste.
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25.3 Fission and Fusion > Nuclear FissionNuclear Fission
Nuclear Waste
Spent fuel rods are classified as high-level
nuclear waste.
• At some nuclear power plants, the storage pool has no space left.
• Finding appropriate storage sites is difficult because high-level waste may need to be stored for a long time.
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How does the fission of a uranium-235
nucleus cause a chain reaction?
When slow-moving neutrons bombard uranium-235, the atom splits and releases more
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25.3 Fission and Fusion > Nuclear FusionNuclear Fusion
Nuclear Fusion
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25.3 Fission and Fusion > Nuclear FusionNuclear Fusion
The energy emitted by the sun results
from nuclear fusion.
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25.3 Fission and Fusion > Nuclear FusionNuclear Fusion
The energy emitted by the sun results
from nuclear fusion.
• Fusion occurs when nuclei combine to produce a nucleus of greater mass.
25.3 Fission and Fusion >
25.3 Fission and Fusion > Nuclear FusionNuclear Fusion
The energy emitted by the sun results
from nuclear fusion.
• Fusion occurs when nuclei combine to produce a nucleus of greater mass.
• In solar fusion, hydrogen nuclei (protons) fuse to make helium nuclei.
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25.3 Fission and Fusion > Nuclear FusionNuclear Fusion
Fusion reactions, in which small nuclei
combine, release much more energy
than fission reactions, in which large
nuclei split apart and form smaller
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25.3 Fission and Fusion > Nuclear FusionNuclear Fusion
Fusion reactions, in which small nuclei
combine, release much more energy
than fission reactions, in which large
nuclei split apart and form smaller
nuclei.
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25.3 Fission and Fusion > Nuclear FusionNuclear Fusion
The use of controlled nuclear fusion as
an energy source on Earth is appealing.
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25.3 Fission and Fusion > Nuclear FusionNuclear Fusion
The use of controlled nuclear fusion as
an energy source on Earth is appealing.
• The potential fuels are inexpensive and readily available.
• The problems with fusion lie in achieving the high temperatures needed to start the reaction and in containing the reaction
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25.3 Fission and Fusion > Nuclear FusionNuclear Fusion
The high temperatures required to start
fusion reactions have been achieved by
using a fission bomb.
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The high temperatures needed to
support fusion exist within the sun’s
core. Late in the sun’s life cycle, other
fusion reactions will occur. What
element would form when two helium
nuclei fuse?
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The high temperatures needed to
support fusion exist within the sun’s
core. Late in the sun’s life cycle, other
fusion reactions will occur. What
element would form when two helium
nuclei fuse?
CHEMISTRY & YOU CHEMISTRY & YOU
Be
8
He + He
4 4
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Choose the correct words for the
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Choose the correct words for the
spaces. In solar fusion, _______ nuclei
fuse to form _______ nuclei.
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25.3 Fission and Fusion > Key ConceptsKey Concepts
In a chain reaction, some of the emitted neutrons react with other fissionable
atoms, which emit neutrons that react with still more fissionable atoms.
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25.3 Fission and Fusion > Glossary TermsGlossary Terms
• fission: the splitting of a nucleus into smaller fragments, accompanied by the release of
neutrons and a large amount of energy
• neutron moderation: a process used in
nuclear reactors to slow down neutrons so the reactor fuel captures them to continue the
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25.3 Fission and Fusion > Glossary TermsGlossary Terms
• neutron absorption: a process that decreases the number of slow-moving neutrons in a nuclear reactor; this is
accomplished by using control rods made of a material such as cadmium, which absorbs
neutrons
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Electrons and the Structure of Atoms
• During fission and fusion, atoms change their chemical identity as the number of protons in their nuclei change.
• In fission, large nuclei split into two or more smaller nuclei.
• In fusion, smaller nuclei combine to form larger
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