MATERIAL SAFETY DATA SHEET

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MATERIAL SAFETY DATA SHEET

According to US Regulation ANSI Z400.1-2004

1. PRODUCT AND COMPANY IDENTIFICATION

MSDS Number D0238071

Commercial Product Name

_{Finish Powder - all scents}

Formula Number: #0237266

NA formula #1402-168

UPC Code(s) and Size: US:

Lemon Fresh, 50 oz 51700 79348 8 Lemon Fresh, 75 oz 51700 78234 5 Orange Fresh, 75 oz 51700 79347 1

Canada:

Fresh Scent, 3 kg 51700 31300 6

Recommended / Intended Use: Detergent for use in domestic automatic dishwashers

Manufacturer Reckitt Benckiser (United States), 815 North College Street,

30942 Brandon, MS

Distributor: Reckitt Benckiser Inc.

Morris Corporate Center IV

399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 Telephone: +1 973 404 2600

Emergency Telephone Number: 1-800-228-4722 (U.S.)

Transportation Emergencies: 1-800-424-9300 (U.S. & Canada) CHEMTREC

Outside U.S. and Canada (North America), call Chemtrec:703-527-3887

D0238071 Version No.:2

Print date:

Page 1 of 10 16-Dec-2009

MSDS Num ber

0237266 (1402-168) 21-Jan-2010

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2. HAZARDS IDEN TIFICATION

KEEP OUT OF REACH OF CHILDREN

3. COMPOSITION / IN FORMATION ON IN GREDIEN TS

Chem ical Nam e Proportion (% w /w )

ACGIH - Occupational Exposure Lim its - TWAs

OSHA PEL

Sodium carbonate 497-19-8

30 - 60 % -

-Sodium Silicate, molar ratio >1.6 - </= 2.6 1344-09-8

1 - 5 % -

-Sodium percarbonate 15630-89-4

< 2.5 % -

-Subtilisin 9014-01-1

< 0.01 % 0.00006 mg/m³ Ceiling 0.00006 mg/m³ STEL

4. FIRST AID MEASURES

Inhalation Move to fresh air

Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes

Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Consult a physician.

Ingestion If swallowed, promptly drink a large quantity of water. DO NOT induce vomiting! Contact a Physician or Poison Control Center immediately.

Notes to Physician Treat symptomatically

Protection of First-aiders Use personal protective equipment

Aggravated Medical Conditions: No information available.

Validation/Revision Date

16-Dec-2009

Emergency Overview

MSDS Num ber

D0238071

Version No.:

2

Com m ercial Product Nam e

Finish Pow der - all scents

HARMFUL IF SWALLOWED EYE IRRITANT! DO NOT get in eyes.

DO NOT ingest.

Page 2 of 10 CAUTION!

Validation/Revision Date 21-Jan-2010

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5. FIRE-FIGHTIN G MEASURES

Flash point: Not applicable.

Suitable Extinguishing Media: As suitable for surrounding fire.

Extinguishing media which must not be used for safety reasons:

No information available

Unusual hazards: None known.

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus, pressure-demand, MSHA / NIOSH (approved or equivalent) and full protective gear.

Precautions for fire-fighting Standard procedure for chemical fires.

Key: B = Eye protection + Gloves

6. ACCIDEN TAL RELEASE MEASURES

Personal Precautions: Ensure adequate ventilation.

Environmental Precautions: Do not allow material to contaminate ground water system.

Methods for Cleaning Up: Small spills: Wearing appropriate protective equipment, soak up with an inert absorbent material and dispose of in an appropriate waste container. Rinse surface residue and flush to sink or sanitary sewer.

Methods for Containment: Prevent further leakage or spillage if safe to do so

7. HANDLING AND STORAGE

Handling: Ensure adequate ventilation Avoid contact with eyes Do not ingest

Storage: Keep out of the reach of children.

Keep container tightly closed in a dry and well-ventilated place Keep in properly labeled containers.

Keep at temperatures below 40 °C / 104 °F.

8. EXPOSURE CON TROLS/ PERSON AL PROTECTION

Chem ical Nam e ACGIH TLV OSHA PEL

Sodium carbonate 497-19-8

-Sodium Silicate, molar ratio >1.6 - </= 2.6 1344-09-8

-

-Health Hazard:2

HMIS: Health Hazard:2 Flammability: 0

Flammability: 0

Physical Hazard:0

16-Dec-2009

Personal Protection:B

MSDS Num ber

D0238071

Version No.:

2

Page 3 of 10 Physical Hazard:0

NFPA:

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Sodium percarbonate 15630-89-4

-

-Subtilisin 9014-01-1

Ceiling: 0.00006 mg/m3 _{0.00006 mg/m³ STEL}

Engineering Controls: For occupational exposures, ensure adequate ventilation.

Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained Personal Protective Equipment

Respiratory Protection: None required under normal usage.

Eye/Face Protection: Safety glasses with side-shields

Hand Protection: Impervious gloves.

Skin and Body Protection: Usual safety precautions while handling the product will provide adequate protection against injury or irritation. Follow product label instructions.

Hygiene Measures: Avoid contact with eyes, skin, and clothing.

Version No.:

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16-Dec-2009

Page 4 of 10 MSDS Num ber

D0238071 Validation/Revision Date

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9. PHYSICAL AN D CHEMICAL PROPERTIES

Physical State: Solid.

Appearance: Powder

Colour: White Blue

Odour: perfumed, typical to meet the Tradename descriptor

pH 10.8 ± 0.2 (10 %)

Flammability Limits in Air: No information available

Autoignition Temperature: No information available.

Specific Gravity / Density [g/mL]: 1.2

Vapour Pressure: Not determined.

Solubility: No information available.

10. STABILITY AN D REACTIVITY

Stability: Stable under recommended storage conditions.

Conditions to Avoid: Strong sunlight for prolonged periods. Avoid temperatures above 40 °C / 104 °F

Materials to Avoid: Do not mix with bleach or other household chemicals.

Hazardous Decomposition Products: Oxides of carbon and unknown organic compounds.

Polymerization: Hazardous polymerization does not occur.

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11. TOXICOLOGICAL IN FORMATION

PRODUCT TOXICITY DATA

LD50Oral: >2000 mg/kg (rat) estimated

LD50Dermal: >2000 mg/kg (rat) estimated

LC50Inhalation (Dust): >5 mg/m3(dust) estimated

LC50Inhalation (Vapor): No information available

ACUTE EFFECTS::

Eye Irritation Irritating to eyes.

Skin Irritation None expected during normal conditions of use.

Inhalation May cause mild nasal irritation upon prolonged or repeated contact to the dust in occupational or emergency response situation.

Ingestion Harmful if swallowed.

Ingestion could cause irritation of the mouth and throat.

Will cause burning in mouth and throat. Difficulty swallowing, excessive salivating in infants. Reddening and swelling of muscous membranes of mouth and throat.

Sensitization Not expected to be a skin sensitiser. Specific Effects

Carcinogenic Effects: Not listed as carcinogenic by OSHA, NTP or IARC.

Mutagenic Effects No information available.

Reproductive Toxicity: No information available.

Additional Toxicity Information: Information is based on available component data and toxicity result of similar products. COMPONENT TOXICITY DATA

Chem ical Nam e CAS-No LD50 Oral - w ith units - Rat - m g/kg

LD50 Derm al - With Units Rat/Rabbit

-m g/kg

LC50 Inhalation With units

-Rat/Rabbit

Sodium carbonate 497-19-8 4090 mg/kg ( Rat )

Sodium Silicate, molar ratio >1.6 - </= 2.6 1344-09-8 1153 mg/kg ( Rat ) 4640 mg/kg ( Rabbit ) Sodium percarbonate 15630-89-4 1034 mg/kg ( Rat )

Subtilisin 9014-01-1 3700 mg/kg ( Rat )

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12. ECOLOGICAL IN FORMATION

PRODUCT TOXICITY DATA Ecotoxicity effects

Aquatic toxicity: No information available COMPONENT TOXICITY DATA

Other Information

Ozone depletion potential; ODP; (R-11 = 1)

No information available.

Global Warming Potential (GWP): No information available.

Additional Ecological Information: Information given is based on data on the components and the ecotoxicology of similar products.

13. DISPOSAL CON SIDERATION S

Waste from residues / unused products:

Dispose of in accordance with local regulations.

Contaminated Packaging: Dispose of as unused product.

Waste Disposal: Dispose of according to Local, State, Provincial and / or Federal regulations. Sodium carb onate

497-19-8 (30 - 60 %)

Sodium Silicate, molar ratio >1.6 - </= 2.6 1344-09-8 (1 - 5 %)

Freshwater Fish

Water Flea h EC50 96 216 mg/L

LC50 = 300 mg/L Lepomis macrochirus 96 h

Sodium percarb onate 15630-89-4 (< 2.5 %)

Freshwater Algae EC50 = 242 mg/L 120 h

Freshwater Algae h EC50 240 70 mg/L

16-Dec-2009

Water Flea EC50 = 265 mg/L 48 h

MSDS Num ber

D0238071

Version No.:

2

Water Flea

Page 7 of 10 h EC50 48 4.9 mg/L

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14. TRAN SPORT IN FORMATION

General remarks Not classified as dangerous in the meaning of transport regulations. For long distance transport of bulk material or shrunk pallet take into consideration sections 7 and 10.

DOT Not regulated

TDG Not regulated

MEX Not applicable.

ICAO Not regulated

IATA Not regulated

IMDG/IMO Not regulated

RID Not applicable.

ADR Not applicable.

ADN Not applicable.

15. REGULATORY IN FORMATION

Chem ical Nam e PICCS TSCA DSL NDSL ENCS CHINA AICS EINECS/ ELINCS

South Africa STELs

Sodium carbonate Present Present X X X X 207-838-8 Sodium Silicate, molar ratio >1.6

-</= 2.6

Present X _X _X _X _215-687-4

Sodium percarbonate Present Present X _X _X _X _239-707-6

Subtilisin Present XU IUB#3.4.21.6 2

X X 232-752-2

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According to US Regulation ANSI Z400.1-2004 U.S. Regulations:

WHMIS (Canada)

WHMIS Hazard Class D2B Toxic materials Not Listed

Sodium carbonate - 497-19-8

SARA313 None

California Prop. 65 Not Listed

Sodium Silicate, molar ratio >1.6 - </= 2.6 - 1344-09-8

Subtilisin - 9014-01-1

Appearance Grayish-w hite pow der or lumps

NJRTK Not Listed.

Appearance None.

SARA313 None

California Prop. 65 Not Listed

Appearance None.

NJRTK

SARA313 None

California Prop. 65 Not Listed Not Listed.

Sodium percarbonate - 15630-89-4

16-Dec-2009

MSDS Num ber

D0238071

California Prop. 65

Version No.:

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Page 9 of 10

NJRTK Not Listed.

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16. OTHER IN FORMATION

Reason for revision: Inclusion of UPC codes

Additional advice: Consult your supplier if the material is to be used for special applications such as in the food industry or for hyhiene, medical or surgical end-use.

Prepared by: Regulatory, Safety and Environmental Services RSE Dishwashing

Reckitt Benckiser Produktions GmbH Benckiserplatz 1

D-67059 Ludwigshafen am Rhein Germany

Phone: +49 (0) 621 59146-0 Fax: +49 (0) 621 59146-398 eMail: [email protected]

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

National Fire

Protection Association (U.S.A.):

16-Dec-2009

HMIS (U.S.A.):

MSDS Num ber

D0238071

Version No.:

2

Page 10 of 10

Health Hazard

Physical hazards 0 2 Flammability:

PERSONAL PROTECTION B 0