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Lithium-Ion Batteries

R. V. Bugga

Jet Propulsion Laboratory

California Institute of Technology

Pasadena, California, USA

M. C. Smart

Jet Propulsion Laboratory

California Institute of Technology

Pasadena, California, USA

A. Manthiram

The University of Texas at Austin

Austin, Texas, USA

Editors:

Sponsoring Division:

Published by

The Electrochemical Society

65 South Main Street, Building D

Pennington, NJ 08534-2839, USA

tel 609

737

1902

fax 609 737 2743

www.electrochem.org

TM

Vol. 58, No. 48

Battery

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Copyright 2014 by The Electrochemical Society.

All rights reserved.

This book has been registered with Copyright Clearance Center.

For further information, please contact the Copyright Clearance Center,

Salem, Massachusetts.

Published by:

The Electrochemical Society

65 South Main Street

Pennington, New Jersey 08534-2839, USA

Telephone 609.737.1902

Fax 609.737.2743

e-mail: [email protected]

Web: www.electrochem.org

ISSN 1938-6737 (online)

ISSN 1938-5862 (print)

ISSN 2151-2051 (cd-rom)

ISBN 978-1-62332-180-2 (Softcover)

ISBN 978-1-60768-536-4 (PDF)

Printed in the United States of America.

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iii

Preface

The papers included in this issue of ECS Transactions were originally presented in the

symposium “Lithium-Ion Batteries”, held during the 224

th

meeting of The

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v

ECS Transactions, Volume 58, Issue 48

Lithium-Ion Batteries

Table of Contents

Preface

iii

Chapter 1

Cathodes - Li-Rich NMC Oxides

The Hierarchical Functional Layers on High-Capacity Lithium-Excess Cathodes for

Superior Lithium Ion Batteries

J. Zhao, S. Aziz, Y. Wang

3

Chapter 2

Anodes - Si and Sn Systems

Optimizing the Composition of the Cu/Si Thin Film Anodes Produced via Magnetron

Sputtering

D. B. Polat, L.

Eryilmaz, Keleş

15

Improving the Electrochemical Performance of the Tin Based Anodes formed via

Oblique Angle Deposition Method

D. B. Polat, N.

Sezgin, Keleş

23

Chapter 3

Anodes - Miscellaneous Systems

Electrochemical Quartz Crystal Microbalance Measurements of Lithium-Aluminum

Alloy in a Glyme-Lithium Salt Molten Complex

N. Serizawa, T. Kobayashi, S. Seki, K. Takei, H. Miyashiro, Y. Katayama,

M. Watanabe, T. Miura

37

A Nanoarchitectured Porous Electrode Assembly of NiSi Thin Film for Lithium Ion

Batteries

D. B. Polat, O. Keles

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vi

Chapter 4

Battery/Joint General Session

Novel Lithium Titanate for High Power Applications

H. Jin, G. Pan, S. J. Xue, F. P. Wang

63

Simulation of Li-ion Cells by Dualfoil Model under Constant-Resistance Load

J. Mao, W. Tiedemann, J. Newman

71

Electrospun TiO

2

Nanofiber Electrode with Optimized Diameters for Lithium Ion

Battery

Y. Cui, K. Sun, Q. Sun, Y. Deng, H. Lu, Y. Zhou, Z. W. Fu

83

Chapter 5

Electrolytes - Non-Aqueous Systems

The Use of Methyl Butyrate-Based Electrolytes with Additives to Enable the

Operation of Li-Ion Cells with High Voltage Cathodes over a Wide Temperature

Range

F. C. Krause, C. Hwang, B. V. Ratnakumar, M. C. Smart, D. W. McOwen,

W. A. Henderson

97

Chapter 6

Electrolytes - Liquid and Polymer Electrolytes

Investigation of Electrolyte Additives with LiNi

0.5

Mn

1.5

O

4

/Graphite Cells at High

Temperature

S. A. Delp, J. L. Allen, T. R. Jow

111

Chapter 7

Cells - General

Bottlenecks to Fast Charging of Lithium-Ion-Insertion Cells for Electric Vehicles

R. Chandrasekaran

121

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vii

Thermal Conductivity, Heat Sources and Temperature Profiles of Li-Ion Batteries

O. S. Burheim, M. A. Onsrud, J. G. Pharoah, F. Vullum-Bruer, P. J. S. Vie

145

Lithium Recovery from Seawater by Electrodialysis Using Ionic Liquid-based

Membrane Technology

T. Hoshino

173

Investigation of Particle Size and Coating Thickness for Pulse Performance of

Automotive Lithium Ion Batteries

B. C. Sisk, Z. Zhang

179

Diagnostics of Li-Ion Commercial Cells – Experimental Case Studies

A. Devie, M. Dubarry, B. Y. Liaw

193

Evaluation of High C Rate Cycle Induced Aging on Low Impedance Lithium-Ion

Batteries Using In-Situ Electrochemical Impedance Spectroscopy (EIS) Analysis

B. Shrestha, P. Novak, D. Wetz Jr., A. Matasso

207

Chapter 8

Cells - Thin Film Cells and Advanced Chemistries

Preparation and Characterization of the Sulfur-Carbon Nano-Composite Material for

Li/S Battery

Y. Yuan, H. Lu, B. Chen

225

Chapter 9

Modeling

Sensitivity Analysis of Material Parameters on Performance of Lithium Ion Battery

Using Electrochemical Modeling

Z. Zhang, B. C. Sisk

235

Construction of a General POD Basis for Faster Li-Ion Cell Simulations

J. Rubeša, B. Suhr

253

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Facts about ECS

The Electrochemical Society (ECS) is an international, nonprofi t, scientifi c, educational organization founded for the advancement of the theory and practice of electrochemistry, electronics, and allied subjects. The Society was founded in Philadelphia in 1902 and incorporated in 1930. There are currently over 7,000 scientists and engineers from more than 70 countries who hold individual membership; the Society is also supported by more than 100 corporations through Corporate Memberships.

The technical activities of the Society are carried on by Divisions. Sections of the Society have been organized in a number of cities and regions. Major international meetings of the Society are held in the spring and fall of each year. At these meetings, the Divisions and Groups hold general sessions and sponsor symposia on specialized subjects.

The Society has an active publication program that includes the following:

Journal of The Electrochemical Society — (JES) is the leader in the fi eld of electrochemical science and technology. This peer-reviewed

journal publishes an average of 550 pages of 85 articles each month. Articles are published online as soon as possible after undergoing the peer-review process. The online version is considered the fi nal version and is fully citable with articles assigned specifi c page numbers within specifi c issues. The date of online publication is the offi cial publication date of record.

Journal of Solid State Science and Technology — (JSS) is one of the newest peer-reviewed journals from ECS launched in 2012. JSS

covers fundamental and applied areas of solid state science and technology including experimental and theoretical aspects of the chemistry and physics of materials and devices. Articles are published online as soon as possible after undergoing the peer-review process. The online version is considered the fi nal version and is fully citable with articles assigned specifi c page numbers within specifi c issues. The date of online publication is the offi cial publication date of record.

Electrochemistry Letters — (EEL) is one of the newest journals from ECS launched in 2012. It is dedicated to the rapid dissemination

of peer-reviewed and concise research reports in fundamental and applied areas of electrochemical science and technology. Articles are published online as soon as possible after undergoing the peer-review process. The online version is considered the fi nal version and is fully citable with articles assigned specifi c page numbers within specifi c issues. The date of online publication is the offi cial publication date of record.

Solid State Letters — (SSL) is one of the newest journals from ECS launched in 2012. It is dedicated to the rapid dissemination of

peer-reviewed and concise research reports in fundamental and applied areas of solid state science and technology. Articles are published online as soon as possible after undergoing the peer-review process. The online version is considered the fi nal version and is fully citable with articles assigned specifi c page numbers within specifi c issues. The date of online publication is the offi cial publication date of record.

Electrochemical and Solid-State Letters — (ESL) was the fi rst rapid-publication electronic journal dedicated to covering the leading edge

of research and development in the fi eld of solid-state and electrochemical science and technology. ESL was a joint publication of ECS and IEEE Electron Devices Society. Volume 1 began July 1998 and contained six issues, thereafter new volumes began with the January issue and contained 12 issues. The fi nal issue of ESL was Volume 16, Number 6, 2012. Preserved as an archive, ESL has since been replaced by SSL and EEL.

Interface— Interface is an authoritative yet accessible publication for those in the fi eld of solid-state and electrochemical science and

technology. Published quarterly, this four-color magazine contains technical articles about the latest developments in the fi eld, and presents news and information about and for members of ECS.

ECS Meeting Abstracts— ECS Meeting Abstracts contain extended abstracts of the technical papers presented at the ECS biannual

meetings and ECS-sponsored meetings. This publication offers a fi rst look into the current research in the fi eld. ECS Meeting Abstracts are freely available to all visitors to the ECS Digital Library.

ECS Transactions— (ECST) is the online database containing full-text content of proceedings from ECS meetings and ECS-sponsored

meetings. ECST is a high-quality venue for authors and an excellent resource for researchers. The papers appearing in ECST are reviewed to ensure that submissions meet generally-accepted scientifi c standards. Each meeting is represented by a volume and each symposium by an issue.

Monograph Volumes — The Society sponsors the publication of hardbound monograph volumes, which provide authoritative accounts of specifi c topics in electrochemistry, solid-state science, and related disciplines.

For more information on these and other Society activities, visit the ECS website:

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