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Ames Laboratory Accepted Manuscripts Ames Laboratory 2017

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Figure

Fig. 1 K6k√√√√mixed with 500 mM K2CO3 induced 2D superlattices of PEG-AuNPs at the vapor-liquid interface
Fig. 2 In-plane structure evolution of 2D superlattices from aqueous solutions of 5 nM PEG6kGISAXS patterns as functions ofrange (0.02–0.07Ådisplayed on logarithmic scales
Fig. 3 Surface-normal structure evolution of 2D superlattices fromaqueous solutions of PEG-AuNPs mixed with different KKPEGfit electron density (ED) profiles that regenerate thecentrations.2CO3 con-Representative R/RF data for (a) PEG6k-AuNPs and (c)800-AuNPs with same nanoparticle concentration (5 nM) at various2CO3 concentrations as indicated.(b) and (d) are one of the best- R/RF in (a) and (c)(solid lines), respectively.
Fig. 4 A schematic of 2D self-assembly and crystallization of PEG-AuNPs at liquid-vapor interface induced by K2CO3 (a) side view and (b) top view.
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