SUBJECT INDEX
TO
VOLUME 46
a = abstract
Acetates, methyl, from MeOH, a I39
Acetylenes, phenyl-, oligomerisation, a I90
polymensation, a 140. 190
Acid Chlorides, hydrogenation 73
Acrylic Acids, asymmetric hydrogenation I80
ACTm‘, Pt, Pt-Rh coatings, for the glass industry 181
Activation, CHJ. a 87
Alcohols, allylic, arylation, a 41 I40
aromatic. transfer dehydrogenation. a 40
2-arylcyclohexenols, to 2-arylcyclohexenes, a 139
methyl. conversion. to methyl acetate, a 139
decomposition, a 190
electrooxidation I06
DMFCs 88, 146
oxidation, a 42, 84
oxidation, (I 42,84. 191
aerobic 26
selective 24
from alcohols 26, 191
14 C-C bond formation, with enoxysilane, a
Aldehydes, from acid chlorides 73
Alfa Aesar, Fuel Cell Catalysts Brochure
Alkali Metals. iodides. effects on Pd. Pt cathodes. in superdry conditions
Alkenes, dihydroxylation
Alkoxycarbonylation, chloropyridines, a
Alkylacrylates, copolymerisation with ethene, a Alkynes, hydroalkenylation, a
from alkynes
oxidation, a
hydroarylation, a hydrogenation hydrosilylation. a
Alloys, dental, a
jewellery
Aluminium, Al-Mg-Pd, melt oxidation, a Al-Pd-Co. U-, V-phase, structures, a
Amination, aryl halides with an ammonia analogue Hartwig-Buchwald
Amines, in fast living radical polymerisation. a Amino Acids, L-DOPA synthesis
Ammonia, oxidation, over Pt
Aquation, cis-, trans-Pt(Ypy),(NO,),, a Arenecarboxvlic Acids. svnthesis. a Arenes, hydrogenation,
h
iodo-. homocoupling, u
Aroyl Halides, microwave-assisted phenylation,
Aryl Halides? arylation, of allylic alcohols, a
cross-coupling reactions dehalogenation, a Heck reactions
Suzuki couplings. a
Arylation, allylic alcohols. a
a-amino acid esters, ( I
N-Arylation, aryl indolea
Arylboronic Acids, coupling reactions
Autocatalysts, technologies adopted by EU
94 24 73 39 87 139 I39 139 73 138 88 66 38 38
so
so
14082 24 I88 41 42. 138
I39
a 87
41 50 41 50, 139 190. 191 41 87 50 41.50 27
Biomimetic Assemblies, in photosynthesis, a
Book Reviews, “Catalysis of Organic Reactions” 85 23
Catalysrs Q Cutalysed Reactions 65
“Handbook of Heterogeneous Catalytic Hydrogenation
“Modern Electrochemistry” 15
37
Buchwald-Hartwig Couplings 50
Bushveld Complex, PGE geology, conference I77
Cancer, drugs 88, 165. 166
Capacitors, container, with Pt films, for memory cells 107
MJPLZT/Pt. Pt/PLZT/Pt, H-damage. u 42
for Organic Synthesis” 73
“Progress in Hydrogen Treatment of Materials”
Page Page
88
MlM. Pt thin film electrodes, a I89
Pt/SrBiz zTa20u/Pt. annealing effects, a 88
Ru, a 87. 140
86
reforming of propane, a 41
supercritical, solvent 139, 165, 176
I06
copolymerisation, with ethene, a I39
effects in fuel cells 106, 117. 146
electrooxidation 84. 106. 191
poisoning, in PEMFC 118
reaction with Oz, a 40
41
41
in ketone synthesis, a 41
a$-, P.y-unsaturated, hydrogenation 82
23, 65. 73
conferences 23.24, 165. 167
heterogeneous, LI 4041.86, 138-139. 189-190
homogeneous, (I 4142,87, 139-140, 19&191
in ionic liquids, a 191
low temperature fuel cells 3.64, 117, 146
in sc-COz 139, 165, 176
Catalysts, dendrimers 167. 180
in fat hardening 23
144
high purity gas production 144
homogeneous, supported 23
pgm/C, paste, powder, preferences 48
recycling 24.41. 176, 180. 190, 191
three-way, see Three-Way Catalysts
Catalysts, Iridium, Ir black, NOx reduction 24.41
Ru02/lrOz, to sustain H 2 0 electrolysis, in PEMFCs 132 Catalysts, Iridium Complexes, [ ( ~ o d ) I r C l ] ~ , a 140
[Ir(cod)(PPh3)JX, for C< bond formation, a I40
Ir(I), for hetero-Heck type reaction, a 139 88
OsO,
+
cinchona alkaloid, dihydroxylation 82, 191OsO,/FibreCatTM, dihydroxylation 24
hydrogenation of arenes, a 138
LaFeCoPdO. for automotive emissions control. CI 190
Lindlar 73
Pd nanopanicleslAIZOJNiAl, MeOH decomposition, a 190
Pd-Bi/C. glucose selective oxidation, a I38
Pd-perovskite. automotive emissions control, (I I90
Pd-Pt/AIMCM-41, n-decane isomerisation, a I89
Pd/AI,O?, aromatic alcohol dehydrogenation, a 40
hydrodechlorination of chlorinated olefins, a 138
Pd/A1203
+
Mg mesh, phenol hydrogenation, a I90Pd/y-Al~O~,4-chloro-2-nitrophenol hydrogenation, a 86
PdAIMCM-41, n-decane isomerisation, a 189
73
Pd/bulk MgO single crystal, particle morphology 24
P d C . paste, commercial 48.92
liquid phase hatch hydrogenation 92
+
soluble Bi, glucose selective oxidation, (I 138Suzuki coupling, a I90
Pd/CeOz/AI2O3, thiophene, VOC, oxidation, a I38
PdlFe, Pd/Mg, phenol hydrogenation, a 190
73
Pdsupport, aromatic alcohol dehydrogenation, a 40
PdC12-CuC12. myrcene oxidation, (I 190
transfer of oxide ions, to a catalyst substrate 165
Capacitors, (cont.)
memory, Pt-PtO, thin film electrodes, a
Carbenes, Pd. N-heterocyclic nucleophilic
so
poisoning, in PEMFC 122
Carbon Oxides, C 0 2 , methanation, a
CO, chemisorbed, on Pt, PtRu nanoparticles
Carbonylation, with aryltin compounds, a Carboxylic Acids, arene-, synthesis, (I
Catalysis, hook reviews
fixed bed reactors, design aspects
Catalysts, Osmium, Os,(CO),,Nulcan C. in PEMFCs. a Catalysts, Osmium Complexes,
Catalysts, Palladium, KsPPdWI,03.. 1 2H20/y-AII03. /C,
PdlBaSO,, hydrogenation of acid chlorides
selective poisoning, with thioquinanthrenr 73
powder, commercial 48
PdPb-doped CaCO,, hydrogenation of alkynes
modified with pyridine, quinoline 73
Page
Catalysts, Palladium Complexes, n-allyl-Pd,
(-)-mesembrane, (-)-mesembrine. asymmetric synthesis of (-)-haemanthidine,
(+)-crinamine, (+)-pretazettine. a I39
(q'-aIlyl)Pd intermediate. allylsilanes cyclisation. a 41
for cross-coupling reactions SO. 165
(dippf)PdCI>, (dippf)PdCI(CH,), polymerisation. a 190
(dppe)PdCI?. (dppe)PdCI(CH>), oligomerisation, LI 190
(dppf)PdC12, (dppf)PdCl(CH,), polymerisation, (I 190
FibreCatM, Suzuki coupling. a I90
N-heterocyclic nucleophilic carbenes. for C X . C-N 5 0
Pd, for poly@ara-phenylene) polymer. synthesis 187
Pd(0) tricyclohexylphosphine. coupling reaction. a 4 1
Pd-phosphino-oxazoline allyl, 'meta-dialkyl effect' 1 67
Pd-polymer-bound phosphine, Suzuki coupling. a 19 1
PdClz(Ph3P)>/dpph, alkoxycarhonylation. u 87
Pd(dba)?
+
phosphinobenzene sulfonic acid, a I39Pd(dba)~/(trimethylphenyl)dihydroimidazolium salt, a 4 1
Pd>(dba)dphosphine, a-amino acid ester arylation. a 87
Pd(l1) acetate-pyridine/hydrotalcite, aerobic oxidation 26
Pd(I1) salt. carbonylation of aryltin compounds, a 41
41
Pd(OAc)?
+
phosphinohenzene sulfonic acid, a I39Pd(OAc)?
+
PPh,, synthesis of isoxazolidines, (I 190Pd(OAc)?
+
P(o-tolyl),, for coupling reactions, a 139Pd(OCOCF1)1/P(2-furyl)l, iodoarene homocoupling. a 139
Pd(PPh&C12. microwave promoted phenylation, a 87
Pd(PPh& unsaturated N-chloroamine cyclisation. a I39
24
electrocatalysts, anodes, for fuel cells 117. 146
3, 146 88
NHI oxidation 24
Pd-WAIMCM-41, n-decane isomerisation. a I89
Pt black. electrocatalysts, cathodes, for DMFCs I46
Pt-Rh/AI2O1, TWC, CO
+
Or reaction, a 40Pt-Sn/AI20,. for cyclohexane dehydrogenation,
40
WA1201. Ce addition, phenol wet oxidation, a 138
for cyclohexane dehydrogenation, ri-octane
hydrocarbon oxidation. a 86
I38
+
Rh/Alr03, hydrocarbon oxidation. a 86Pt/AI?OJAI monoliths, VOC oxidation. a I89
Pt/AIMCM-41, rr-decane isomerisation, CI 189
PtlC, 4-chloro-2-nitrophenol hydrogenation. (I 86
hydrosilylation of alkynes, a 138
MeOH oxidation, a 42
NO decomposition, a 86
O? reduction reaction, a 42
PtlCeOr-ZrO?, in high throughput screening, (I 190
Pt/graphite, cinchona-modified, for hydrogenation. ( I 86
m i , Pt/Ru, Pt/Ru/Ni, nanoparticles, for DMFC. (I 88
WSPE membrane, preparation. a 40
Wwide-pore S O 2 , polystyrene hydrogenation, a 86
PtCr. PtFe, PtMn, PtNi, PtTi, PtZr, electrocatalysts,
cathodes. for PEMFCs 3
PtMo. electrocatalysts. anodes, for PEMFCs 117
PtRu, fuel cell electrocatalysts 14, 88, 106. 117, 146. 191
CO tolerance in fuel cells 106, 122
PtRu/C, fuel cell electrocatalysts 14, 117. 140, 146, 19 I
Pt,Sn/Mg(Al)O, propane dehydrogenation, a 40
Catalysts, Platinum Complexes, Pt(hpym )CI2,
87
Catalysts, Rhodium, Pt-Rh/AI2O3. TWC. CO
+
O?, a 40Rh aluminosilicate, laminar, zeolitic structures, a 138
anchoring [Rh(Me2C0),(2.5-norbornadiene)]C104, a 138
Rh/A1201, film, model catalyst 24
hydrocarbon oxidation. a 86
+
Pt/ALO3. hydrocarbon oxidation. a 86Pd(OAc)?, arylation of allylic alcohols. a
Pd(0Ac):. for cross-coupling reactions 50
Pd(OAch/dppf, alkoxycarbonylation, n 87
Catalysts, Platinum, CH, partial oxidation
cathodes, for fuel cells nanoparticles. Pt, for DMFC, a
Pt/y-Al?03, preparation I 15
ti-octane reforming, n-pentane isomerisation. cr
reforming, n-pentane isomerisation. a 40
impregnated using H2PtClh, Pt(NH3)KI,, a
Pt(NH&CI>, for CH, activation, a
Pase
Catalysts, Rhodium Complexes, alknyl-Rh. aryl-Rh. a 87
with fluoroorganic groups. solubility in sc-COr I65
in fluorous phases 165
Rhz(OAc)r. for 1 ,3-dipolar cycloaddition. ( I 191
Rh-polymer. sc-CO? soluble 176
[Rh(A)CO]*/SiO2. hydrofortnylation-hydrogenation, a 4 1
[Rh-(-)-BINAP(COD)IClO,. in L-menthol process 82
[Rh(cod)(MeCN):]BF,, conjugate additions, a 87
[Rh((R.R)-DiPAMP)COD]BF,. L-DOPA synthesis 82
Rh(1). for hetero-Heck type reaction, a I39
Rh(1II) salt, carbonylation of aryltin compounds. a 41
[Rh(OH)(cod)],, for internal alkynes
+
silanediols. a 139Rh(TAN,,DPPA)CI, cyclohexene hydrogenation 176
88
14, 88, 106. 117, 146. 191
106, 122
14. 117. 140, 146. 191
I39
methyl acetate formation. ( I 139
41 86
in PEMFCs 132
groups, solubility in sc-CO: 165
in fluorous phases 16.5
["Pr,N][RuO,]
+
NMO or O?. alcohol oxidation, (I 191permthenate</. ruthenateslFibreCat
' ~',
alcohol oxidation 24[( RrP(CH2),,PR?-ffJXRu=CHR']+. olefin metathesis, ( I 87
Ru-BINAP. dendritic. asymmetric hydrogenation 180
sing enyne metathesis, CI 140
87
RCM of diolefins. (I 87
(PPh,),, fast living radical polymerisation. (I 140
(xylylbinap)(diamine). ally1 alcohol synthesis 82
42 167
82
RuO,. with NaOCI, oxidation oferhers. o 87
IRU(OAC)~((S)-BINAP)]. (S)-(+)-naproxen synthesis 82
[RuX2(BINAP)]. for ketone hydrogenation 82
[RuX(arene)BINAP]X. for ketone hydrogenation 82
18 107. 189
precursors for 38, 107, 189
Chemiluminescence, see Luminescence
Chirdl, catalysis. in hydrogenation. oxidation 82
Cisplatin 88, 165. 166
Clusters, Rh-Pt. a 38
Coatings, ACT'", Power Coatings'". for glass industry 18 I
see also Deposition and Electrodeposition
Cobalt, Al-Pd-Co, U-. V-phase. structures. N 38
Pt-Co. jewellery alloy 66
Colloids, Ag. Pd. for Ag:Pd powder. ( I 84
Pt 105. 136
Combinatorial Chemistry, in catalysis 24
Composites, ceramic matrix. with Al-Mg-Pd. a 38
Pd-ceramic membrane. a 86
see also Nanocomposites
Conferences, 8th Int. Conf. Cheni. of the PGMs,
Southampton, 2002 81. 165, 166. 167
177
SC. U.S.A., 2000 23
24
EuropaCat-VI, 2003 24
Fuel Cells for Automotive Applications, London. 2002 64
Fuel Cells - Science and Technology 2002.
Amsterdam, 2002 64
Thc Dynamic Electrode Surface, Berlin, 2002 I Oh
Catalysts, Ruthenium,
Pt/Ru, Pt/Ru/Ni. nanoparticles, for DMFC, (I
PtRu, fuel cell electrocatalysts
CO tolerance in fuel cells
PtRu/C. fuel cell electrocatalysts
Ru-Sn/Y zeolite. MeOH conversion. ( I
Ru/AI?O1, COr reforming of propane. (1
Rdsepiolite,
+
Mn, Mo, Zr. for CO? methanation. aRuO?, RuOJIrO?, /TiO?, to sustain H1O electrolysis.
Catalysts, Ruthenium Complexes, with fluoroorganic
Ru Schiff base, Kharasch addition. CCI,
+
olefins. aRuCI?, chlorination. aromatic compounds. olefins. (7
RuC11.3H20
+
trioctylamine, lignin hydrogenation[RuH?(H?),(PCy,)?l. arene hydrogenation, a 42
Ru(l1) BINAP. chiral propdnediol production
CerOx"' Process, to treat hazardous organic wastes
Chemical Vapour Deposition, Pt, films
nanoparticles, ri 38
9th Int. Platinum Symp.. Billings, MT, U.S.A.. 2002
18th Conf. on Catal. of Org. React.. Charleston,
EuropaCat-V. Limerick, Ireland. 200 I
RhRiO?, with propene, NOx reduction 24 Copper,-Pt-Cu, jewellery alloy 66
Page PLI@
Electrodes, ( m i ? . )
TiRuO?, anodes, preparation, a I37
Ti/Ru,Mn, ~ ,01 anodes. CI2
+
O2 evolution, a 188Electroflotation, of wastewater. n I37
Electroless Plating, Ag-Pd thin films, for membranes, a 86
40
Emission Control, motor vehicles 27, 190
Erbium, Pd-Er-H. H effects on 169
Etching, Pt, by ICP, using BClKI?, a 140
Ethene, copolymerisation with alkylacrylates. a 139
non-alternating copolymerisation with CO, a 139
Ethers, cyclic enol, by ring-closing enyne metathesis, a 140
oxidation, a 87
Ethyl Pyruvate, hydrogenation, a 86
Europe, EU adopted emission control, legislation 27
Eutectic Reactions, Pd-rare earths 108
Films, Co-Pt, sputtered on (001)-oriented Si wafer, a 140
Ir, by MOCVD, a 39
107
2, 48, 92, 144 74 42,88, 140, 191
automotive use 24, 64
catalysts, Pt/C, for MeOH oxidation. a 42
42
PtRu. CO tolerance 106, 122
conferences 24, 64
DMFC, anodes 14. 146
cathodes 146
MEAs 146
miniaturisation 161
portable applications 161
191 191 14 14, 146 3.64, 117. 146 3, 117. 140. 146
Pt. on SPE membranes, a
Pt, by CVD, for memory capacitors see also Thin Films
'Final Analysis'
Fuel Cells, a
Fracture, in Ir-based refractory superalloys
for 0 2 reduction reaction. in presence of C1-, a
electrocatalysts, Pt-RdC, by sulfito method, a
electrodes. Pt-Ru, nanostructured, CO oxidation. a
Fuel Cell Catalysts Brochure. Alfa Aesar HiSPECT" fuel cell catalysts
low temperature, catalysis membrane electrode assemblies
Coupling Reactions, (arylboronic
+
carboxylic) acids, a 41cross-. for C-C. C-N bonds 50
homo-, iodoarenes, a I39
Pd catalysts SO, 165
see also Heck Reactions and Suzuki Couplings 74
Crystallisation, P&Cu3,,PzoNi,o, a I36
Pd.IINil,Eu?IP211 melts, a 38
Cyclisation, allylsilanes, a 41
unsaturated N-chloroamines, to piperidines, a 139
Cycloadditions, 1.3-dipolar. a 190, 191
Cyclohexenes, 2-aryL. from 2-arylcyclohexenols, N 139
hydrogenation 176
Decomposition, CH,, a 189
MeOH. a I90
NO, (I 86
Dehalogenation, aryl halides, a 41
Dehydrogenation, propane, a 40
transfer, aromatic alcohols, a 40
Dendrimers, as catalysts 167, 180
Os(ll), Ru(l1) polypyridines, photoproperties. a 85
synthesis 165
Dental, alloys, a 88
85
DHPS@, for the glass industry 181
Diesel, oxidation catalysts, Pt 27
particulate filters 27
selective catalytic reduction 27
Dihydroxylation, by OsO, 24, 82, I9 I
P-Diketones, Pt(11) with AI(CH1),, for Pt networks 105
Pt(I1) P-diketonates, photoreactions with olefins, a 39
Dimerisation, of [M(L-L)?(eilatin)]'+, M = 0 s. Ru, a 136
94 74
Electrical Conductivity, in (C,H1,NH)[Pd(dmit)2]2, a 39
Electrical Contacts, ohmic, Pd/n'-GaAs, a 88
Pt, with Si interlayers. o n p-type Sic, a 191
Electrochemical Cells, CerOxTM waste process 18
Electrochemistry, a 84-85, 137. 188
book review 15
94
18
85
189
organosilanes, as coupling agents 50
Creep, in Ir-based refractory superalloys
Deposition, Pd, at C paste electrodes, a
see also Coatings and Electrodeposition
2,4-Dinitrotoluene, electron transfer reduction of Ductility, in Ir-based refractory superalloys
cathode reactivity of Pd, Pt, in dry DMF destruction of hazardous organic wastes doping, of Pt phthalocyanine microcrystals, a
Pt, fine particles. a 39
in fuel cells, see Fuel Cells
Electrodeposition, 0s. 0 s alloys, a
see also Coatings and Deposition
Electrodeposition and Surface Coatings, a 39,85, 189
Electrodes, Au, anchoring of Pt(l1) complex. a 137
Au-Pt black. for glucose sensor, a 86
C paste, Pd deposition and dissolution, a 85
conference 106
in fuel cells, see Fuel Cells
94 Pt( 1 1 I). for CO electrochemical oxidation 106 94
for CO electrooxidation 106
in hydrocarbon sensor, a 40
microdisk, in NO sensor, a 40
nanoparticles.
+
nano-honeycomb diamond films, a 84189
wire. for in vivo biolo ical sensors 72
18
Pt-PtO, thin films. for memory capacitors, a 88
PtRu, for CO electrooxidation 106
Ru(001). electrooxidation I06
R u O K , in supercapacitors, a 88
39
TiflrOz-TaOs, anode ageing, in HzSOd, a 188
Ti/lr0,-Sb~O5-SnO1. wastewater electroflotation, a 137
Pd. cathode reactivity in dry DMF
Pt, cathode reactivity in dry DMF
thin films, for MIM capacitors, a
Pt-plated Ti, in CerOx"e1ectrochemical cell
n-Si. with fine Pt particles, CI
Ti2FeRu02, Ti,Fe,Ru,O,,, in supercapacitors I05
nanoparticles 3, 88, 117. 146
PEFC, Pt-Ru/C electrocatalysts, XANES. a I40
MEAs, ( I
anodes cathodes
CO,, CO. poisoning comparison with DMFC
electrocatalysts, anode, PtMo, PtRu
cathode, Os,(CO),JVulcan C, a
PEMFC, air bleed technique
I40 129 117
117 I46 117 88 3, 88
Pt. Pt alloys 3
MEAs 3, 117
water electrolysis. effects 132
191
SOFC, LaSrCrRuO, anode material, a
see also Catalysts, Iridium, Platinum, Ruthenium
Gases, high purity HI, Oz 144
Geology, book 17
conference I77
Glass, production technology 181
Glucose, oxidation 106, 138
sensors, CI 40, 86
Halogenation, of aromatic compounds, olefins, a 42
Heck Reactions 50, 139. 165
High Temperature, Ir-based refractory superalloys 74
High Throughput Screening Techniques 24, 87, 190
Hydroalkenylation, alkynes, with silanediols, a I39
Hydroarylation, alkynes, with silanediols, a I39
Hydrocarbons, emission control in EU 27
oxidation. a 86
sensor, a 40
Hydrocracking, n-decane, a I89
Hydrodechlorination, chlorinated olefins, a 138
Hydroformylation-Hydrogenation, 1 -octene, a 41
P q r
37, 169. 188
P q r
165 85
Hydrogen, absorption, Pd
book review 37
damage of capacitors. a 42
electrooxidation 117 interaction with Pd. Pd alloys 37, 169
sensors, a 189
separation. using Pd-Ag membrane reactor. 189
solid solutions, in Pd
structural changes in Pd, Pd-Er. Pd-W treatment of materials
a-(acy1amino)acrylic acids, esters alkynes
arenes. a
asymmetric, acrylic acids book review
carboxylic acids, a$-. P.y-unsaturated
chiral-catalysed cyclohexene
ethyl pyruvate, a
ketones lignin
in liquid phase batch reactors
1 -octene
phenols, (1
polystyrenes, a
using Pd-ceramic membranes, a 86
Hydrogenation, acid chlorides
Hydrolysis, cis-, rram-Pt( Ypy),(NOi),, a Hydrosilylation, alkynes. a
Hydrotalcites, catalyst suppon
169 169 37 73 82 73 42. 138 180 73 82 82 I76 86 82, 138 I67 48.92 I76 86. 190 86 I88 138 26
Insulators, single-molecule, tram-Pt(I1) complex. u 137
Ion Source, high temperature, of Pd. a I36
Ion Transfer, IrCL-. across liquid interface, u I37
Ionic Liquids, solvents, a 191 39
Ir( 1 I I ) , surface, for electrolyte hydration I06
thin films, hy DC sputtering, a 42
74
Ir-Nb, Ir-Zr, Ir-Nb-Ni, Ir-Nb-Ni-Al 74
Pt-lr, jewellery alloy 66
superalloys. refractory: creep. ductility. fracture 74
137
IIr(DPF)ll. electrophosphorescence, a 137
luminescence 137. 165
137. 188
Ir02, thin films, by DC sputtering, ( I 42
Isomerisation, n-decane, (i 189 Isoxazolidines, synthesis. a I90
Jewellery, Pt, Pr alloys. welding by laser 66
18 1
3. 64. 117, 146 24, 190
Iridium, films, by MOCVD. a
Iridium Alloys, (Ir. Rh)75Nb15Ni10, specific strength
Iridium Complexes, IrClh?-, ion transfer. a
Iridium Compounds, electrodes. (I
IrOJPLZT/Pt, capacitors. a 42
Johnson Matthey, ACTn', Power CoatingsrM catalysis for fuel cells, research
Fi breCat
' ''
PGM Conference competition winners "Platinum 2002"
Rhodium Bicentenary Competition, winner
Ketones, synthesis hydrogenation
Kumada-Tamao-Corriu Couplings
Lasers, to drill cavities in Pt wire electrodes
Lignin, hydrogenation
Liquid Crystals, Rh carboxylate polymers, ci
Luminescence, electrochemi-, Ir(ppy),. c/
Ru(bpy)<'*. a
welding of Pt jewellery
Ir terpyridyls
Os(I1) polypridines. dendrimers. (1
photo-. Ir(ppy),, a
Pt(I1) quaterpyridine, a
Ru(bpy)<". a
Pt octaethylporphyrin, C I
166, 167 116 2
26.41. 191
82. 138 50
72 66 I67 I88 137 39, 137 165
85
137 39 137 137
Luminescence, ( c m i . )
Ru terpyridyls
Ru(1I) polypridines. dendrimers. n
Macrocycles, Pd(ll). Pt(I1). N 39
Magnesium, AI-Mg-Pd. melt oxidation, a Magnetism, in CoCrPt perpendicular media, a
38
191
in CoCrPtB layers. on TiZr underlayers. (I 140
in SrCuRhO, SrNiRhO. a 136
Mass Spectrometry, differential electrochemical, a 42
laser-activated membrane introduction. LAMIMS, a I90
Medical Uses, (1 88
PGM Conference 165. 166
Melting Points, Pt, Pt alloys 66. 181 MEAs, in fuel cells 3. 117. 140. 146
Membranes, Pd-Ag, for CHI decomposition. a I89
Pd-ceramic, a 86
SPE, with Pt particles. a 40
Memory, capacitors for 88. 107
1.-Menthol, commercial synthesis 82
Metathesis, of olefins. RCM. ROMP. (I 87
ring-closing enyne. a 140
Methanation, CO.. a 86
Methane, activation, ( I 87
decomposition. ( I I89
partial oxidation 2 1
steam reforming. a 191
Microwaves, in phenylation of aroryl chlorides. a 87
in synthesis of [RuCp(dppm)SR]. a I36
MOCVD, Ir films, a 39
Myrcene, oxidation. ( I I90
Nanocomposites, Pd:Ag, physical properties, a 84
Pt-RdGCNF. for DMFC anodes 14
R u O K . supercapacitors, a 88
see also Composites
Nanocrystalline Powders, Pd:Ag. a 84
Ti,Fe,Ru~O,,. in supercapacitors 105
Nanocrystals, Pt-Ru. on GCNF 14
Nanoparticles, Pd, on AI201NAI. model catalyst, a 190
embedded in Zr02. H? absorption. a 188
in HOin-oil microemulsions. n 38
stahilised by polyfluorinated chains, ( I 84
Pt. 3D networks. Al-organic-stabilised 10s
on y-Al,O,. catalysts I 15
on C nanospheres. a 38
with nano diamond films. as electrodes, a 84
preparation. ( I I36
in Pt. Pt alloys. fuel cell electrocatalysts 3, 88. 117. 146
Pt. PURL surface diffusion of cheniisorbed CO 106
Nanostructures, PGM Conference I65
Pt-Ru electrodes. for fuel cells. ( I 191
Nanowires, Pt, u I36
(S)-(+I-Naproxen, synthesis 82
Nitrogen Oxides, NO, decomposition, ( I 86
sensor. ci 40
NOx, adsorbera 27
reduction 24.41
selective catalytic reduction of diesel emissions 27
188 188
DeNOx, catalysts 27
Nitroxides, reactions with Rh porphyrin alkyls, (I
NMR, multi-. aqueous products of Pt(Ypy).(NO,),, a
Nobel Prize, Chcmistry, chiral-catalysed reactions.
Noril'sk, PGE geology. conference I77
I-Octene, reactions 41, 176
Ohmic Contacts, see Electrical Contacts
OLEDs, Ilr(DPF)31 in PVUPBD. ( I I37
Olefins, dihydroxylation. asymmetric. N 191
as H acceptors. (I 40
Kharasch addition, of CCI,. a 87
metathesis: RCM, ROMP, ci 87
with Pt(I1) P-diketonates. photoreactions, (1 39
Oligomerisation, phenylacetylene. ( I I90
pgm catalysts 82
Puge
Osmium, electrodeposition. a 189
Osmium Alloys, electrodeposition, a I89
Osmium Complexes, in glucose sensors. a 40
ground and excited states 106
luminescence, a 85
OS~(CO)P. pyrolysis, a 88
0s.bipy-modified DNA, voltammetric analysis. a 138
IOs(L-L),(eilatin)]'+. dimerisation, a I36
Osmium Compounds, osma-aromatics, osmabenzenes 165
OsO,, in DNA voltammetric analysis, a 138
Os(V111), oxidation state 165
24. 26.42, 84. 191
alkenes. ( I 39
chiral-catalysed 82
electro-. C O 84, 106, 191
formaldehyde. formic acid I06
H: 117
MeOH 88, 106, 146
ethers, a 87
glucose 106, 138
hydrocarbons, a 86
McOH, a 42.84
myrcene, (1 190
NH, 24
partial. CHI 24
[Pt"CL(Hzenda)]. a 84
thiophene, a 138
v o c s , a 138, 189
wet, phenol, a 138
40
reduction reaction, ORR, for Os,(CO),Nulcan C, a 88
42
sensors, a 137
Oxidation, alcohols
liquid organic waste 18
melt. Al-Mg-Pd, a 38
Oxygen, reaction with CO. u
on Pt/C, for fuel cells. a
Page
Phase Diagrams, Ag-Pd-Gd-Ru, a 38
Ir-Nb-Ni, Ir-Nb-Ni- Al 74
Pd-rare earth systems I08
Phase Transformation Kinetics, Pd-H, Pd-Er-H,
Pd-W-H 169
Phenols, hydrogenation. N 86, 190
wet oxidation, a I38
Phenylation, aroyl chlorides, a 87
Phosphorescence, from Ir-based OLEDs. a I37
from Pd-poly@ara-phe@ylene) I87
Photocatalysis, in Pt(I1) quaterpyridine complex, a 39
Photoconversion, a 39.85, 137, 189
PGM Conference 165
Photoluminescence, see Luminescence Photoproperties, Pt-phenylene ethynylene
monomers, polymers. a I89
R~(phen)~(3-carbethoxy,4-hydro~y-phen)'+(PF~)~, a 1 89 85
Ru(I1) bipyridyls. dendrimeric oligomers 165
I37
[(PEt,)2HPt(~-Hz)Pt(PEt,)?][BPkll, Pt-Pt homolysis, a 85
[(PEt,),HPt(~-H)hH(PEtl)'][BPh,], Pt-h homolysis, a 85
[(PEt&PtH,]. [(PEt,),PtH(S)I[BP~], formation, a 85
39 39
Photosynthesis, Ru polypyridines, as models, a 85
Piperidines, from unsaturated N-chloroamines. a 139
"Platinum 2002" I I6
addition to, (NdEuGd)BaCuO, effects, a 42
capacitors 42.88, 107. 189
94
colloids 105, 136
drilling. by laser 72
electrodes, see Electrodes
etching, using BCIJCI? gas plasma, a I40
films 107
laser welding, iewellery 66
Ru polypyridines, biomimetic assemblies, a
ra~-[Ru(bpy)~(PhP(OMe)~(CI)]Cl. a 85
Photoreactions, Pd(I1) to Pd, by UV irradiation, a
Pt(I1) P-diketonates. with olefins. u
R m i O z , COz reduction, by HI. a
Platinum, ACTTM, Power CoatingsTM 181
cathodic reactivity, in superdry conditions
in glass making 181
Palladium, AlMgPd ceramic composites, formation. a 38 9 4
circuit patterns, on polyimide, a I37
interaction with H2 37, 169
cathodic reactivity, in superdry conditions
ion source, a I36
nanoparticles, a 38, 84, 188, 190
Pd in poly@arcr-phenylene), phosphorescence 187
PdAg. nanocomposite, a 84
Pd-H. structural changes 169
Pd-rare earth systems. phase diagrams 108
Pd/n'-GaAs ohmic contacts,
+
Ge, Sn layers, a 88[Pd,,;,
M
'
,
MX], [Pd,-, M', ,(MX)I, ekctrogenerdted 9 4solid solutions of H I69
thin films, a 85, 189
Palladium Alloys, Ag-Pd-Gd-Ru, a 38
Al-Mg-I'd, melt oxidaton, a 38
Al-Pd-Co. U-. V-phase, structures, a 38
dental, Ag-Au-I'd-Cu, a 88
interaction with HI 37, 169
membranes. a 86, 189
P&I,Cu3UPz,,Nilll, crystallisation, a I36
Pd41Ni,,Cu27Pzu melts, crystallisation, a 38
Pd-Er-H, Pd-W-H, structural changes 169
Pd-Pt, interaction with HI 3 1
Pd-rare earths 108
Pt-Pd. jewellery alloy 66
Ti(PdNi). shape memory, a 188
38
(C7H1 jNH)I[Pd(dmit),l. air-oxidation of, a 39
(C,HltNH)lPd(dmit),l, electrical conductivity, a 39
Pd(l1) N& macrocycles, synthesis, a 39
Pd(1I) with pincer-like amido ligand, (I 38
in poly@ara-phenylene), synthesis 187
[Pd"CI,J, formation, at C paste electrode, a 85
Palladium Compounds, Pd(NH3)dX. reduction, a 38
Na2(Pd2Cln), reduction. a 84
Patents 4347.89-91. 141-143, 192-194
pH, sensors, a 189
Palladium Complexes, (BQA)PdCI, preparation. a
melting point 66. 181
nanoparticles 38, 84, 88. 105. 106, 1
IS,
136nanowires. a 136
ohmic contacts, WSi interlayerslp-type Sic, a 191
in 0 sensors, a 137
particles, electroless plated, on SPE membranes. a 40
39
[Pt2-, Na', Nal], reduction of 2.4-dinitrotoluene 94
Pt( I 1 I ), surface, for electrolyte hydration 106
[Pt,,-, M'. MXI, [Pt. , M+, ?(MX)!, electrogenerated 94
single crystals, for CO electrooxidation, a 84
thermal diffusivity 66
thin films, a 85, 88, 189
welding, laser 66
for solar cell electrodes, a
Platinum Alloys, CoCrPt film, perpendicular media.
magnetic properties. a 191
CoCrPtB perpendicular media on TiZr,
magnetic properties, a I40
electrodes, see Electrodes and Fuel Cells
films, a I40
jewellery, Pt alloys 66
laser welding. jewellery 66
melting points 66. 181
nanoparticles 88, 106
Pt-Pd. interaction with Hz 37
thermal diffusivities 66
welding. laser 66
137
(~-C~H1)(Cl)Pt(~-CI),Ru(CI)(11':.rl'-2.7-dimethyl-
octadienyl), nanocrystal precursor 14
(COD)PtCI,
+
dimethylphenyl(quinolinyl)amine, a 38luminescence, a 39. 137
in glass making 181
Pt-Rh, coatings. ACTrM 181
Platinum Complexes, rrans-Pt(II), insulator, a
(BQA)PtCI, preparation. a 38
Page PAGE
Ruthenium Alloys, (corn.)
Ruthenium Complexes, his(~'-2.4-diincthyl-
PI-Ru. jewellery alloy 66
Ta/Ru bufter layer, for CoCrPt perpendicular media, n 191
pentadienyl)Ru(II), for vapour-phase epitaxy, (I 42
Platinum Complexes, (cont. )
DhotODrODertieS. ( I 1 8 9
~hoto;ea~tions. LI 39.85
precursors for CVD, n 38. 107.189
LP~,CI~{N(H)C(BU')O)~], Pt(III)-Pt(llI) distance. ( I 136
lPt24(N(H)C(B~')o),l, o I36
Pt phthalocyanine, electrochemical doping of, a
Pt(I1) acetylacetonate, reaction with AI(CHI)J Pt(I1) N& macrocycles. synthesis. n Pt octaethylporphyrin, in 0 sensor, a
[PtIvCl2(enda)l, by oxidation of [Pt"C1dH2enda)], a
[Pt(en)iHzO)z]2', reaction with oL-penicillamine. a
I37 85 84 84
10s
39
Pt(I1) with pincer-like amido ligand, (I 38
Pt(II1) 'lantern-shaped'. u 136
PtR,(cod), ligand displacement reactions, n 136
PtR2L:. H20-soluble diorgano-, synthesis, (I 136
cis-. trcr,is-PtiYpy)2(NOl)l. aquation, hydrolysis, ci 188
88. 165. 166
[Rh,Pt,(CO)lb(dppm)~l, LRhxPt:(C0)21(dppm)?1, n 38
Platinum Compounds, antitumour agents
electrodes, a
K2[Pt(C,0,),], K2PtCIJ. K2PtC16. reduction, n thin films, u
geology conference
wastewater, electroflotation, (1
see also Emission Control
Polymerisation, co-, a
fast living radical, N
of phenylacetylene. (1
ROMP. a
matrix, for Pt complex thin film 0 sensor. ( I
polyimide, with Pd circuit patterns, n
poly(/,aru-phenylene)
+
Pd. phosphorescencepolystyrenes, hydrogenation. n
Pt-phenylene ethynylenes, photoproperties, (I
PVKPBD, with [Ir(DPF)& for OLEDs. n
Platinum Group Elements, geology book
Pollution Control, organic wastes, destruction
Polymers, coordination, Rh carboxylates, o
Power Coatings'", for the glass industry
Propane, CO, reforming of. CI
Propene, for reduction of NOx
Pyridines, chloro-, alkoxycarbonylation, n
dehydrogenation, a
Rare Earths, Pd-rare earths, eutectic phases
RCM, n
Reactors, fixed bed catalyst, design aspects solid solublities in Pd. strengthening effects
hydrogen-permeating membrane, a
for liquid phase hatch hydrogenations
electron transfer. of 2,4-dinitrotoluene 0,. 0
Reduction, C 0 2 . by HI, CI
88 I36 88 17 I77
18
I37
139 I40
140, 190
87
188
I37 137 187
86
I89 I37
181
41 40 24.41 87
108
108 87. I40
144
189
48,92 39 94 42
Reforming, (I 41, 191
Rhodium Alloys, (Ir, Rh)7,Nbl,Nii,,. specific strength 74
Pr-Rh. coatings. ACT"' 181
Rhodium, Rhodium Bicentenary Competition 2
jewellery alloy 66
Rhodium Complexes, [ RhoPt(CO)lo(dppm)i].
[RhxPt,(CO),I(dppm)21. 38
Rh porphyrin alkyls. reactions with nitroxides, n 188
tetra(alkoxybenzoato)dirhodium(ll), liquid crystals, a I88
188
TpmsRh(LL) (LL = (CO)?, cod, nbd). Rh(I) chemistry, CI 84
Rhodium Compounds, SrCuRhOh, Sr,NiRhOh, LI 136
ROMP, n 87
Rosenmund Reduction, acid chlorides 73
effect of HIO 48
Russia, PGE geology. conference 177
Ruthenium, electrodes I06
Ru-doped InP. resistivities. a 42
Ru(001), surface, for electrolyte hydration 106
Ruthenium Alloys, Ag-Pd-Gd-Ru, a 38
electrodes, see Electrodes and Fuel Cells
nanoparticles 88. 106
pyrazine adducts, liquid crystals, a
cance; drugs 165, 166
(~-C2HI)(CI)Pt(~-CI),Ru(Cl)(~':~'-2.7-dimethyl-
octadienyl ), nanocrystal precursor 14
luminescence 39. 85, 137. 165
(2-MelmH )?[ RuC11(2-Mclm
):I.
(2-MelniH).[RuC1~(2-Melm)]. synthesis. a 84
photoproperties 8 5 , 165, 189
[RuCp(dppin)SR
1,
micrnwave- ted synthesis, o 136[RuH(arene)(Binap)lCF~SO!, piano-stool inverted. (I I88
[R~(L-L)~(cilatin)]~+, dimerisation. n I36
88. 105, 137. I88
LaSrCrRuO. SOFC anode material, ( I 191
RuO? powders, from RuCIl thermal decomposition, n 137
Selective Catalytic Reduction,
+
diesel particulate filter 27NOx 27
Sensors, glucose. ( I 40. 86
H?, CI 189
hydrocarbons. CI 40
i n v i w biological 72
NO, (r 40
0 2 , (I 137
pH, a 189
I88
41. 50, 138, 139. 140
84 85
RuOz. RuO?/Ti anodes, LI I37
39 50 I77 140 42 88
thin films. Pd-Ag. for Pd-ceramic membranes. (I 86
50
Sulfuric Acid, Ti/lr02-TaOi anodes, degradation. o I88
Supercapacitors, RuO-/C, nanoconiposite. ( I 88
Superconductors, Pt
+
CeO? additions, a 42Suzuki Couplings, FibreCatT". Pd/C. n I90
Pd-polymer-bound phosphine. a 191
Ruthenium Compounds, electrodes
Shape Memory Effect, in Ti(PdNi). LI
Single Crystals, PI. CO electrooxidation, (I Sol-Gel, Pt-doped Sn02 t h i n films. a
Solar Cells, with Pt particles on wSi electrodes, a
Sonogashira Couplings, of terminal alkynea
Silanes
South Africa, PGE geology, conference
Sputtering, DC. films. Co-Pt. CI
thin films, Ir, IrO,. CI
reactive r.f. magnetron. thin films. PI-PtO,. n
Stille Couplings, aryl halides
+
organostannanesSuperalloys, Ir-based refractory 74
Ti2FeRu02. Ti,Fe,Ru-0,,, nanocrystalline I05
Suzuki-Miyaura Couplings 50
in superdry conditions 94
Tetraalkylammonium Salts, effects on Pd. Pt cathodes.
Tetralins, amino-, synthesis. n 191
Thermal Diffusivities, PI, PI alloys 66
Thin Films, Ir, IrO:. by DC sputtering. u 42
NilPd, XRD, LI 85
137
189 86
I89 I37 85 88
188
Pd, circuit patterns on polyimide. (1
Pd. for poly-Si wires. as H? sensors. n
Pd-Ag. for ceramic composite membranes. n
PI. by chemical vapour deposition, n Pt octaethylporphyrin. for 0 sensors. o
Pt-doped SnO?. sol-gel preparation. ( I
Pt-PtO,. for memory capacitor electrodes. a
Ti(PdNi), bhape memory hehaviour. ti
see also Films
Thinpenes, oxidation, n I38
Three-Way Catalysts 27.40
Tungsten, Pd-W-H. H effects on I69
Pt-W. jewellery alloy 66
VOCs, oxidation. ( I 138, 189
Voltammetry, (DNA-0s.bipy ). microanalysis. n 138
Water, waste, electrode system for electrollotation. u 137
Welding, laser. of PI jewellery 66