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SUBJECT INDEX

TO

VOLUME 46

a = abstract

Acetates, methyl, from MeOH, a I39

Acetylenes, phenyl-, oligomerisation, a I90

polymensation, a 140. 190

Acid Chlorides, hydrogenation 73

Acrylic Acids, asymmetric hydrogenation I80

ACTm‘, Pt, Pt-Rh coatings, for the glass industry 181

Activation, CHJ. a 87

Alcohols, allylic, arylation, a 41 I40

aromatic. transfer dehydrogenation. a 40

2-arylcyclohexenols, to 2-arylcyclohexenes, a 139

methyl. conversion. to methyl acetate, a 139

decomposition, a 190

electrooxidation I06

DMFCs 88, 146

oxidation, a 42, 84

oxidation, (I 42,84. 191

aerobic 26

selective 24

from alcohols 26, 191

14 C-C bond formation, with enoxysilane, a

Aldehydes, from acid chlorides 73

Alfa Aesar, Fuel Cell Catalysts Brochure

Alkali Metals. iodides. effects on Pd. Pt cathodes. in superdry conditions

Alkenes, dihydroxylation

Alkoxycarbonylation, chloropyridines, a

Alkylacrylates, copolymerisation with ethene, a Alkynes, hydroalkenylation, a

from alkynes

oxidation, a

hydroarylation, a hydrogenation hydrosilylation. a

Alloys, dental, a

jewellery

Aluminium, Al-Mg-Pd, melt oxidation, a Al-Pd-Co. U-, V-phase, structures, a

Amination, aryl halides with an ammonia analogue Hartwig-Buchwald

Amines, in fast living radical polymerisation. a Amino Acids, L-DOPA synthesis

Ammonia, oxidation, over Pt

Aquation, cis-, trans-Pt(Ypy),(NO,),, a Arenecarboxvlic Acids. svnthesis. a Arenes, hydrogenation,

h

iodo-. homocoupling, u

Aroyl Halides, microwave-assisted phenylation,

Aryl Halides? arylation, of allylic alcohols, a

cross-coupling reactions dehalogenation, a Heck reactions

Suzuki couplings. a

Arylation, allylic alcohols. a

a-amino acid esters, ( I

N-Arylation, aryl indolea

Arylboronic Acids, coupling reactions

Autocatalysts, technologies adopted by EU

94 24 73 39 87 139 I39 139 73 138 88 66 38 38

so

so

140

82 24 I88 41 42. 138

I39

a 87

41 50 41 50, 139 190. 191 41 87 50 41.50 27

Biomimetic Assemblies, in photosynthesis, a

Book Reviews, “Catalysis of Organic Reactions” 85 23

Catalysrs Q Cutalysed Reactions 65

“Handbook of Heterogeneous Catalytic Hydrogenation

“Modern Electrochemistry” 15

37

Buchwald-Hartwig Couplings 50

Bushveld Complex, PGE geology, conference I77

Cancer, drugs 88, 165. 166

Capacitors, container, with Pt films, for memory cells 107

MJPLZT/Pt. Pt/PLZT/Pt, H-damage. u 42

for Organic Synthesis” 73

“Progress in Hydrogen Treatment of Materials”

Page Page

88

MlM. Pt thin film electrodes, a I89

Pt/SrBiz zTa20u/Pt. annealing effects, a 88

Ru, a 87. 140

86

reforming of propane, a 41

supercritical, solvent 139, 165, 176

I06

copolymerisation, with ethene, a I39

effects in fuel cells 106, 117. 146

electrooxidation 84. 106. 191

poisoning, in PEMFC 118

reaction with Oz, a 40

41

41

in ketone synthesis, a 41

a$-, P.y-unsaturated, hydrogenation 82

23, 65. 73

conferences 23.24, 165. 167

heterogeneous, LI 4041.86, 138-139. 189-190

homogeneous, (I 4142,87, 139-140, 19&191

in ionic liquids, a 191

low temperature fuel cells 3.64, 117, 146

in sc-COz 139, 165, 176

Catalysts, dendrimers 167. 180

in fat hardening 23

144

high purity gas production 144

homogeneous, supported 23

pgm/C, paste, powder, preferences 48

recycling 24.41. 176, 180. 190, 191

three-way, see Three-Way Catalysts

Catalysts, Iridium, Ir black, NOx reduction 24.41

Ru02/lrOz, to sustain H 2 0 electrolysis, in PEMFCs 132 Catalysts, Iridium Complexes, [ ( ~ o d ) I r C l ] ~ , a 140

[Ir(cod)(PPh3)JX, for C< bond formation, a I40

Ir(I), for hetero-Heck type reaction, a 139 88

OsO,

+

cinchona alkaloid, dihydroxylation 82, 191

OsO,/FibreCatTM, dihydroxylation 24

hydrogenation of arenes, a 138

LaFeCoPdO. for automotive emissions control. CI 190

Lindlar 73

Pd nanopanicleslAIZOJNiAl, MeOH decomposition, a 190

Pd-Bi/C. glucose selective oxidation, a I38

Pd-perovskite. automotive emissions control, (I I90

Pd-Pt/AIMCM-41, n-decane isomerisation, a I89

Pd/AI,O?, aromatic alcohol dehydrogenation, a 40

hydrodechlorination of chlorinated olefins, a 138

Pd/A1203

+

Mg mesh, phenol hydrogenation, a I90

Pd/y-Al~O~,4-chloro-2-nitrophenol hydrogenation, a 86

PdAIMCM-41, n-decane isomerisation, a 189

73

Pd/bulk MgO single crystal, particle morphology 24

P d C . paste, commercial 48.92

liquid phase hatch hydrogenation 92

+

soluble Bi, glucose selective oxidation, (I 138

Suzuki coupling, a I90

Pd/CeOz/AI2O3, thiophene, VOC, oxidation, a I38

PdlFe, Pd/Mg, phenol hydrogenation, a 190

73

Pdsupport, aromatic alcohol dehydrogenation, a 40

PdC12-CuC12. myrcene oxidation, (I 190

transfer of oxide ions, to a catalyst substrate 165

Capacitors, (cont.)

memory, Pt-PtO, thin film electrodes, a

Carbenes, Pd. N-heterocyclic nucleophilic

so

poisoning, in PEMFC 122

Carbon Oxides, C 0 2 , methanation, a

CO, chemisorbed, on Pt, PtRu nanoparticles

Carbonylation, with aryltin compounds, a Carboxylic Acids, arene-, synthesis, (I

Catalysis, hook reviews

fixed bed reactors, design aspects

Catalysts, Osmium, Os,(CO),,Nulcan C. in PEMFCs. a Catalysts, Osmium Complexes,

Catalysts, Palladium, KsPPdWI,03.. 1 2H20/y-AII03. /C,

PdlBaSO,, hydrogenation of acid chlorides

selective poisoning, with thioquinanthrenr 73

powder, commercial 48

PdPb-doped CaCO,, hydrogenation of alkynes

modified with pyridine, quinoline 73

(2)

Page

Catalysts, Palladium Complexes, n-allyl-Pd,

(-)-mesembrane, (-)-mesembrine. asymmetric synthesis of (-)-haemanthidine,

(+)-crinamine, (+)-pretazettine. a I39

(q'-aIlyl)Pd intermediate. allylsilanes cyclisation. a 41

for cross-coupling reactions SO. 165

(dippf)PdCI>, (dippf)PdCI(CH,), polymerisation. a 190

(dppe)PdCI?. (dppe)PdCI(CH>), oligomerisation, LI 190

(dppf)PdC12, (dppf)PdCl(CH,), polymerisation, (I 190

FibreCatM, Suzuki coupling. a I90

N-heterocyclic nucleophilic carbenes. for C X . C-N 5 0

Pd, for poly@ara-phenylene) polymer. synthesis 187

Pd(0) tricyclohexylphosphine. coupling reaction. a 4 1

Pd-phosphino-oxazoline allyl, 'meta-dialkyl effect' 1 67

Pd-polymer-bound phosphine, Suzuki coupling. a 19 1

PdClz(Ph3P)>/dpph, alkoxycarhonylation. u 87

Pd(dba)?

+

phosphinobenzene sulfonic acid, a I39

Pd(dba)~/(trimethylphenyl)dihydroimidazolium salt, a 4 1

Pd>(dba)dphosphine, a-amino acid ester arylation. a 87

Pd(l1) acetate-pyridine/hydrotalcite, aerobic oxidation 26

Pd(I1) salt. carbonylation of aryltin compounds, a 41

41

Pd(OAc)?

+

phosphinohenzene sulfonic acid, a I39

Pd(OAc)?

+

PPh,, synthesis of isoxazolidines, (I 190

Pd(OAc)?

+

P(o-tolyl),, for coupling reactions, a 139

Pd(OCOCF1)1/P(2-furyl)l, iodoarene homocoupling. a 139

Pd(PPh&C12. microwave promoted phenylation, a 87

Pd(PPh& unsaturated N-chloroamine cyclisation. a I39

24

electrocatalysts, anodes, for fuel cells 117. 146

3, 146 88

NHI oxidation 24

Pd-WAIMCM-41, n-decane isomerisation. a I89

Pt black. electrocatalysts, cathodes, for DMFCs I46

Pt-Rh/AI2O1, TWC, CO

+

Or reaction, a 40

Pt-Sn/AI20,. for cyclohexane dehydrogenation,

40

WA1201. Ce addition, phenol wet oxidation, a 138

for cyclohexane dehydrogenation, ri-octane

hydrocarbon oxidation. a 86

I38

+

Rh/Alr03, hydrocarbon oxidation. a 86

Pt/AI?OJAI monoliths, VOC oxidation. a I89

Pt/AIMCM-41, rr-decane isomerisation, CI 189

PtlC, 4-chloro-2-nitrophenol hydrogenation. (I 86

hydrosilylation of alkynes, a 138

MeOH oxidation, a 42

NO decomposition, a 86

O? reduction reaction, a 42

PtlCeOr-ZrO?, in high throughput screening, (I 190

Pt/graphite, cinchona-modified, for hydrogenation. ( I 86

m i , Pt/Ru, Pt/Ru/Ni, nanoparticles, for DMFC. (I 88

WSPE membrane, preparation. a 40

Wwide-pore S O 2 , polystyrene hydrogenation, a 86

PtCr. PtFe, PtMn, PtNi, PtTi, PtZr, electrocatalysts,

cathodes. for PEMFCs 3

PtMo. electrocatalysts. anodes, for PEMFCs 117

PtRu, fuel cell electrocatalysts 14, 88, 106. 117, 146. 191

CO tolerance in fuel cells 106, 122

PtRu/C, fuel cell electrocatalysts 14, 117. 140, 146, 19 I

Pt,Sn/Mg(Al)O, propane dehydrogenation, a 40

Catalysts, Platinum Complexes, Pt(hpym )CI2,

87

Catalysts, Rhodium, Pt-Rh/AI2O3. TWC. CO

+

O?, a 40

Rh aluminosilicate, laminar, zeolitic structures, a 138

anchoring [Rh(Me2C0),(2.5-norbornadiene)]C104, a 138

Rh/A1201, film, model catalyst 24

hydrocarbon oxidation. a 86

+

Pt/ALO3. hydrocarbon oxidation. a 86

Pd(OAc)?, arylation of allylic alcohols. a

Pd(0Ac):. for cross-coupling reactions 50

Pd(OAch/dppf, alkoxycarbonylation, n 87

Catalysts, Platinum, CH, partial oxidation

cathodes, for fuel cells nanoparticles. Pt, for DMFC, a

Pt/y-Al?03, preparation I 15

ti-octane reforming, n-pentane isomerisation. cr

reforming, n-pentane isomerisation. a 40

impregnated using H2PtClh, Pt(NH3)KI,, a

Pt(NH&CI>, for CH, activation, a

Pase

Catalysts, Rhodium Complexes, alknyl-Rh. aryl-Rh. a 87

with fluoroorganic groups. solubility in sc-COr I65

in fluorous phases 165

Rhz(OAc)r. for 1 ,3-dipolar cycloaddition. ( I 191

Rh-polymer. sc-CO? soluble 176

[Rh(A)CO]*/SiO2. hydrofortnylation-hydrogenation, a 4 1

[Rh-(-)-BINAP(COD)IClO,. in L-menthol process 82

[Rh(cod)(MeCN):]BF,, conjugate additions, a 87

[Rh((R.R)-DiPAMP)COD]BF,. L-DOPA synthesis 82

Rh(1). for hetero-Heck type reaction, a I39

Rh(1II) salt, carbonylation of aryltin compounds. a 41

[Rh(OH)(cod)],, for internal alkynes

+

silanediols. a 139

Rh(TAN,,DPPA)CI, cyclohexene hydrogenation 176

88

14, 88, 106. 117, 146. 191

106, 122

14. 117. 140, 146. 191

I39

methyl acetate formation. ( I 139

41 86

in PEMFCs 132

groups, solubility in sc-CO: 165

in fluorous phases 16.5

["Pr,N][RuO,]

+

NMO or O?. alcohol oxidation, (I 191

permthenate</. ruthenateslFibreCat

' ~',

alcohol oxidation 24

[( RrP(CH2),,PR?-ffJXRu=CHR']+. olefin metathesis, ( I 87

Ru-BINAP. dendritic. asymmetric hydrogenation 180

sing enyne metathesis, CI 140

87

RCM of diolefins. (I 87

(PPh,),, fast living radical polymerisation. (I 140

(xylylbinap)(diamine). ally1 alcohol synthesis 82

42 167

82

RuO,. with NaOCI, oxidation oferhers. o 87

IRU(OAC)~((S)-BINAP)]. (S)-(+)-naproxen synthesis 82

[RuX2(BINAP)]. for ketone hydrogenation 82

[RuX(arene)BINAP]X. for ketone hydrogenation 82

18 107. 189

precursors for 38, 107, 189

Chemiluminescence, see Luminescence

Chirdl, catalysis. in hydrogenation. oxidation 82

Cisplatin 88, 165. 166

Clusters, Rh-Pt. a 38

Coatings, ACT'", Power Coatings'". for glass industry 18 I

see also Deposition and Electrodeposition

Cobalt, Al-Pd-Co, U-. V-phase. structures. N 38

Pt-Co. jewellery alloy 66

Colloids, Ag. Pd. for Ag:Pd powder. ( I 84

Pt 105. 136

Combinatorial Chemistry, in catalysis 24

Composites, ceramic matrix. with Al-Mg-Pd. a 38

Pd-ceramic membrane. a 86

see also Nanocomposites

Conferences, 8th Int. Conf. Cheni. of the PGMs,

Southampton, 2002 81. 165, 166. 167

177

SC. U.S.A., 2000 23

24

EuropaCat-VI, 2003 24

Fuel Cells for Automotive Applications, London. 2002 64

Fuel Cells - Science and Technology 2002.

Amsterdam, 2002 64

Thc Dynamic Electrode Surface, Berlin, 2002 I Oh

Catalysts, Ruthenium,

Pt/Ru, Pt/Ru/Ni. nanoparticles, for DMFC, (I

PtRu, fuel cell electrocatalysts

CO tolerance in fuel cells

PtRu/C. fuel cell electrocatalysts

Ru-Sn/Y zeolite. MeOH conversion. ( I

Ru/AI?O1, COr reforming of propane. (1

Rdsepiolite,

+

Mn, Mo, Zr. for CO? methanation. a

RuO?, RuOJIrO?, /TiO?, to sustain H1O electrolysis.

Catalysts, Ruthenium Complexes, with fluoroorganic

Ru Schiff base, Kharasch addition. CCI,

+

olefins. a

RuCI?, chlorination. aromatic compounds. olefins. (7

RuC11.3H20

+

trioctylamine, lignin hydrogenation

[RuH?(H?),(PCy,)?l. arene hydrogenation, a 42

Ru(l1) BINAP. chiral propdnediol production

CerOx"' Process, to treat hazardous organic wastes

Chemical Vapour Deposition, Pt, films

nanoparticles, ri 38

9th Int. Platinum Symp.. Billings, MT, U.S.A.. 2002

18th Conf. on Catal. of Org. React.. Charleston,

EuropaCat-V. Limerick, Ireland. 200 I

RhRiO?, with propene, NOx reduction 24 Copper,-Pt-Cu, jewellery alloy 66

(3)

Page PLI@

Electrodes, ( m i ? . )

TiRuO?, anodes, preparation, a I37

Ti/Ru,Mn, ~ ,01 anodes. CI2

+

O2 evolution, a 188

Electroflotation, of wastewater. n I37

Electroless Plating, Ag-Pd thin films, for membranes, a 86

40

Emission Control, motor vehicles 27, 190

Erbium, Pd-Er-H. H effects on 169

Etching, Pt, by ICP, using BClKI?, a 140

Ethene, copolymerisation with alkylacrylates. a 139

non-alternating copolymerisation with CO, a 139

Ethers, cyclic enol, by ring-closing enyne metathesis, a 140

oxidation, a 87

Ethyl Pyruvate, hydrogenation, a 86

Europe, EU adopted emission control, legislation 27

Eutectic Reactions, Pd-rare earths 108

Films, Co-Pt, sputtered on (001)-oriented Si wafer, a 140

Ir, by MOCVD, a 39

107

2, 48, 92, 144 74 42,88, 140, 191

automotive use 24, 64

catalysts, Pt/C, for MeOH oxidation. a 42

42

PtRu. CO tolerance 106, 122

conferences 24, 64

DMFC, anodes 14. 146

cathodes 146

MEAs 146

miniaturisation 161

portable applications 161

191 191 14 14, 146 3.64, 117. 146 3, 117. 140. 146

Pt. on SPE membranes, a

Pt, by CVD, for memory capacitors see also Thin Films

'Final Analysis'

Fuel Cells, a

Fracture, in Ir-based refractory superalloys

for 0 2 reduction reaction. in presence of C1-, a

electrocatalysts, Pt-RdC, by sulfito method, a

electrodes. Pt-Ru, nanostructured, CO oxidation. a

Fuel Cell Catalysts Brochure. Alfa Aesar HiSPECT" fuel cell catalysts

low temperature, catalysis membrane electrode assemblies

Coupling Reactions, (arylboronic

+

carboxylic) acids, a 41

cross-. for C-C. C-N bonds 50

homo-, iodoarenes, a I39

Pd catalysts SO, 165

see also Heck Reactions and Suzuki Couplings 74

Crystallisation, P&Cu3,,PzoNi,o, a I36

Pd.IINil,Eu?IP211 melts, a 38

Cyclisation, allylsilanes, a 41

unsaturated N-chloroamines, to piperidines, a 139

Cycloadditions, 1.3-dipolar. a 190, 191

Cyclohexenes, 2-aryL. from 2-arylcyclohexenols, N 139

hydrogenation 176

Decomposition, CH,, a 189

MeOH. a I90

NO, (I 86

Dehalogenation, aryl halides, a 41

Dehydrogenation, propane, a 40

transfer, aromatic alcohols, a 40

Dendrimers, as catalysts 167, 180

Os(ll), Ru(l1) polypyridines, photoproperties. a 85

synthesis 165

Dental, alloys, a 88

85

DHPS@, for the glass industry 181

Diesel, oxidation catalysts, Pt 27

particulate filters 27

selective catalytic reduction 27

Dihydroxylation, by OsO, 24, 82, I9 I

P-Diketones, Pt(11) with AI(CH1),, for Pt networks 105

Pt(I1) P-diketonates, photoreactions with olefins, a 39

Dimerisation, of [M(L-L)?(eilatin)]'+, M = 0 s. Ru, a 136

94 74

Electrical Conductivity, in (C,H1,NH)[Pd(dmit)2]2, a 39

Electrical Contacts, ohmic, Pd/n'-GaAs, a 88

Pt, with Si interlayers. o n p-type Sic, a 191

Electrochemical Cells, CerOxTM waste process 18

Electrochemistry, a 84-85, 137. 188

book review 15

94

18

85

189

organosilanes, as coupling agents 50

Creep, in Ir-based refractory superalloys

Deposition, Pd, at C paste electrodes, a

see also Coatings and Electrodeposition

2,4-Dinitrotoluene, electron transfer reduction of Ductility, in Ir-based refractory superalloys

cathode reactivity of Pd, Pt, in dry DMF destruction of hazardous organic wastes doping, of Pt phthalocyanine microcrystals, a

Pt, fine particles. a 39

in fuel cells, see Fuel Cells

Electrodeposition, 0s. 0 s alloys, a

see also Coatings and Deposition

Electrodeposition and Surface Coatings, a 39,85, 189

Electrodes, Au, anchoring of Pt(l1) complex. a 137

Au-Pt black. for glucose sensor, a 86

C paste, Pd deposition and dissolution, a 85

conference 106

in fuel cells, see Fuel Cells

94 Pt( 1 1 I). for CO electrochemical oxidation 106 94

for CO electrooxidation 106

in hydrocarbon sensor, a 40

microdisk, in NO sensor, a 40

nanoparticles.

+

nano-honeycomb diamond films, a 84

189

wire. for in vivo biolo ical sensors 72

18

Pt-PtO, thin films. for memory capacitors, a 88

PtRu, for CO electrooxidation 106

Ru(001). electrooxidation I06

R u O K , in supercapacitors, a 88

39

TiflrOz-TaOs, anode ageing, in HzSOd, a 188

Ti/lr0,-Sb~O5-SnO1. wastewater electroflotation, a 137

Pd. cathode reactivity in dry DMF

Pt, cathode reactivity in dry DMF

thin films, for MIM capacitors, a

Pt-plated Ti, in CerOx"e1ectrochemical cell

n-Si. with fine Pt particles, CI

Ti2FeRu02, Ti,Fe,Ru,O,,, in supercapacitors I05

nanoparticles 3, 88, 117. 146

PEFC, Pt-Ru/C electrocatalysts, XANES. a I40

MEAs, ( I

anodes cathodes

CO,, CO. poisoning comparison with DMFC

electrocatalysts, anode, PtMo, PtRu

cathode, Os,(CO),JVulcan C, a

PEMFC, air bleed technique

I40 129 117

117 I46 117 88 3, 88

Pt. Pt alloys 3

MEAs 3, 117

water electrolysis. effects 132

191

SOFC, LaSrCrRuO, anode material, a

see also Catalysts, Iridium, Platinum, Ruthenium

Gases, high purity HI, Oz 144

Geology, book 17

conference I77

Glass, production technology 181

Glucose, oxidation 106, 138

sensors, CI 40, 86

Halogenation, of aromatic compounds, olefins, a 42

Heck Reactions 50, 139. 165

High Temperature, Ir-based refractory superalloys 74

High Throughput Screening Techniques 24, 87, 190

Hydroalkenylation, alkynes, with silanediols, a I39

Hydroarylation, alkynes, with silanediols, a I39

Hydrocarbons, emission control in EU 27

oxidation. a 86

sensor, a 40

Hydrocracking, n-decane, a I89

Hydrodechlorination, chlorinated olefins, a 138

Hydroformylation-Hydrogenation, 1 -octene, a 41

(4)

P q r

37, 169. 188

P q r

165 85

Hydrogen, absorption, Pd

book review 37

damage of capacitors. a 42

electrooxidation 117 interaction with Pd. Pd alloys 37, 169

sensors, a 189

separation. using Pd-Ag membrane reactor. 189

solid solutions, in Pd

structural changes in Pd, Pd-Er. Pd-W treatment of materials

a-(acy1amino)acrylic acids, esters alkynes

arenes. a

asymmetric, acrylic acids book review

carboxylic acids, a$-. P.y-unsaturated

chiral-catalysed cyclohexene

ethyl pyruvate, a

ketones lignin

in liquid phase batch reactors

1 -octene

phenols, (1

polystyrenes, a

using Pd-ceramic membranes, a 86

Hydrogenation, acid chlorides

Hydrolysis, cis-, rram-Pt( Ypy),(NOi),, a Hydrosilylation, alkynes. a

Hydrotalcites, catalyst suppon

169 169 37 73 82 73 42. 138 180 73 82 82 I76 86 82, 138 I67 48.92 I76 86. 190 86 I88 138 26

Insulators, single-molecule, tram-Pt(I1) complex. u 137

Ion Source, high temperature, of Pd. a I36

Ion Transfer, IrCL-. across liquid interface, u I37

Ionic Liquids, solvents, a 191 39

Ir( 1 I I ) , surface, for electrolyte hydration I06

thin films, hy DC sputtering, a 42

74

Ir-Nb, Ir-Zr, Ir-Nb-Ni, Ir-Nb-Ni-Al 74

Pt-lr, jewellery alloy 66

superalloys. refractory: creep. ductility. fracture 74

137

IIr(DPF)ll. electrophosphorescence, a 137

luminescence 137. 165

137. 188

Ir02, thin films, by DC sputtering, ( I 42

Isomerisation, n-decane, (i 189 Isoxazolidines, synthesis. a I90

Jewellery, Pt, Pr alloys. welding by laser 66

18 1

3. 64. 117, 146 24, 190

Iridium, films, by MOCVD. a

Iridium Alloys, (Ir. Rh)75Nb15Ni10, specific strength

Iridium Complexes, IrClh?-, ion transfer. a

Iridium Compounds, electrodes. (I

IrOJPLZT/Pt, capacitors. a 42

Johnson Matthey, ACTn', Power CoatingsrM catalysis for fuel cells, research

Fi breCat

' ''

PGM Conference competition winners "Platinum 2002"

Rhodium Bicentenary Competition, winner

Ketones, synthesis hydrogenation

Kumada-Tamao-Corriu Couplings

Lasers, to drill cavities in Pt wire electrodes

Lignin, hydrogenation

Liquid Crystals, Rh carboxylate polymers, ci

Luminescence, electrochemi-, Ir(ppy),. c/

Ru(bpy)<'*. a

welding of Pt jewellery

Ir terpyridyls

Os(I1) polypridines. dendrimers. (1

photo-. Ir(ppy),, a

Pt(I1) quaterpyridine, a

Ru(bpy)<". a

Pt octaethylporphyrin, C I

166, 167 116 2

26.41. 191

82. 138 50

72 66 I67 I88 137 39, 137 165

85

137 39 137 137

Luminescence, ( c m i . )

Ru terpyridyls

Ru(1I) polypridines. dendrimers. n

Macrocycles, Pd(ll). Pt(I1). N 39

Magnesium, AI-Mg-Pd. melt oxidation, a Magnetism, in CoCrPt perpendicular media, a

38

191

in CoCrPtB layers. on TiZr underlayers. (I 140

in SrCuRhO, SrNiRhO. a 136

Mass Spectrometry, differential electrochemical, a 42

laser-activated membrane introduction. LAMIMS, a I90

Medical Uses, (1 88

PGM Conference 165. 166

Melting Points, Pt, Pt alloys 66. 181 MEAs, in fuel cells 3. 117. 140. 146

Membranes, Pd-Ag, for CHI decomposition. a I89

Pd-ceramic, a 86

SPE, with Pt particles. a 40

Memory, capacitors for 88. 107

1.-Menthol, commercial synthesis 82

Metathesis, of olefins. RCM. ROMP. (I 87

ring-closing enyne. a 140

Methanation, CO.. a 86

Methane, activation, ( I 87

decomposition. ( I I89

partial oxidation 2 1

steam reforming. a 191

Microwaves, in phenylation of aroryl chlorides. a 87

in synthesis of [RuCp(dppm)SR]. a I36

MOCVD, Ir films, a 39

Myrcene, oxidation. ( I I90

Nanocomposites, Pd:Ag, physical properties, a 84

Pt-RdGCNF. for DMFC anodes 14

R u O K . supercapacitors, a 88

see also Composites

Nanocrystalline Powders, Pd:Ag. a 84

Ti,Fe,Ru~O,,. in supercapacitors 105

Nanocrystals, Pt-Ru. on GCNF 14

Nanoparticles, Pd, on AI201NAI. model catalyst, a 190

embedded in Zr02. H? absorption. a 188

in HOin-oil microemulsions. n 38

stahilised by polyfluorinated chains, ( I 84

Pt. 3D networks. Al-organic-stabilised 10s

on y-Al,O,. catalysts I 15

on C nanospheres. a 38

with nano diamond films. as electrodes, a 84

preparation. ( I I36

in Pt. Pt alloys. fuel cell electrocatalysts 3, 88. 117. 146

Pt. PURL surface diffusion of cheniisorbed CO 106

Nanostructures, PGM Conference I65

Pt-Ru electrodes. for fuel cells. ( I 191

Nanowires, Pt, u I36

(S)-(+I-Naproxen, synthesis 82

Nitrogen Oxides, NO, decomposition, ( I 86

sensor. ci 40

NOx, adsorbera 27

reduction 24.41

selective catalytic reduction of diesel emissions 27

188 188

DeNOx, catalysts 27

Nitroxides, reactions with Rh porphyrin alkyls, (I

NMR, multi-. aqueous products of Pt(Ypy).(NO,),, a

Nobel Prize, Chcmistry, chiral-catalysed reactions.

Noril'sk, PGE geology. conference I77

I-Octene, reactions 41, 176

Ohmic Contacts, see Electrical Contacts

OLEDs, Ilr(DPF)31 in PVUPBD. ( I I37

Olefins, dihydroxylation. asymmetric. N 191

as H acceptors. (I 40

Kharasch addition, of CCI,. a 87

metathesis: RCM, ROMP, ci 87

with Pt(I1) P-diketonates. photoreactions, (1 39

Oligomerisation, phenylacetylene. ( I I90

pgm catalysts 82

(5)

Puge

Osmium, electrodeposition. a 189

Osmium Alloys, electrodeposition, a I89

Osmium Complexes, in glucose sensors. a 40

ground and excited states 106

luminescence, a 85

OS~(CO)P. pyrolysis, a 88

0s.bipy-modified DNA, voltammetric analysis. a 138

IOs(L-L),(eilatin)]'+. dimerisation, a I36

Osmium Compounds, osma-aromatics, osmabenzenes 165

OsO,, in DNA voltammetric analysis, a 138

Os(V111), oxidation state 165

24. 26.42, 84. 191

alkenes. ( I 39

chiral-catalysed 82

electro-. C O 84, 106, 191

formaldehyde. formic acid I06

H: 117

MeOH 88, 106, 146

ethers, a 87

glucose 106, 138

hydrocarbons, a 86

McOH, a 42.84

myrcene, (1 190

NH, 24

partial. CHI 24

[Pt"CL(Hzenda)]. a 84

thiophene, a 138

v o c s , a 138, 189

wet, phenol, a 138

40

reduction reaction, ORR, for Os,(CO),Nulcan C, a 88

42

sensors, a 137

Oxidation, alcohols

liquid organic waste 18

melt. Al-Mg-Pd, a 38

Oxygen, reaction with CO. u

on Pt/C, for fuel cells. a

Page

Phase Diagrams, Ag-Pd-Gd-Ru, a 38

Ir-Nb-Ni, Ir-Nb-Ni- Al 74

Pd-rare earth systems I08

Phase Transformation Kinetics, Pd-H, Pd-Er-H,

Pd-W-H 169

Phenols, hydrogenation. N 86, 190

wet oxidation, a I38

Phenylation, aroyl chlorides, a 87

Phosphorescence, from Ir-based OLEDs. a I37

from Pd-poly@ara-phe@ylene) I87

Photocatalysis, in Pt(I1) quaterpyridine complex, a 39

Photoconversion, a 39.85, 137, 189

PGM Conference 165

Photoluminescence, see Luminescence Photoproperties, Pt-phenylene ethynylene

monomers, polymers. a I89

R~(phen)~(3-carbethoxy,4-hydro~y-phen)'+(PF~)~, a 1 89 85

Ru(I1) bipyridyls. dendrimeric oligomers 165

I37

[(PEt,)2HPt(~-Hz)Pt(PEt,)?][BPkll, Pt-Pt homolysis, a 85

[(PEt,),HPt(~-H)hH(PEtl)'][BPh,], Pt-h homolysis, a 85

[(PEt&PtH,]. [(PEt,),PtH(S)I[BP~], formation, a 85

39 39

Photosynthesis, Ru polypyridines, as models, a 85

Piperidines, from unsaturated N-chloroamines. a 139

"Platinum 2002" I I6

addition to, (NdEuGd)BaCuO, effects, a 42

capacitors 42.88, 107. 189

94

colloids 105, 136

drilling. by laser 72

electrodes, see Electrodes

etching, using BCIJCI? gas plasma, a I40

films 107

laser welding, iewellery 66

Ru polypyridines, biomimetic assemblies, a

ra~-[Ru(bpy)~(PhP(OMe)~(CI)]Cl. a 85

Photoreactions, Pd(I1) to Pd, by UV irradiation, a

Pt(I1) P-diketonates. with olefins. u

R m i O z , COz reduction, by HI. a

Platinum, ACTTM, Power CoatingsTM 181

cathodic reactivity, in superdry conditions

in glass making 181

Palladium, AlMgPd ceramic composites, formation. a 38 9 4

circuit patterns, on polyimide, a I37

interaction with H2 37, 169

cathodic reactivity, in superdry conditions

ion source, a I36

nanoparticles, a 38, 84, 188, 190

Pd in poly@arcr-phenylene), phosphorescence 187

PdAg. nanocomposite, a 84

Pd-H. structural changes 169

Pd-rare earth systems. phase diagrams 108

Pd/n'-GaAs ohmic contacts,

+

Ge, Sn layers, a 88

[Pd,,;,

M

'

,

MX], [Pd,-, M', ,(MX)I, ekctrogenerdted 9 4

solid solutions of H I69

thin films, a 85, 189

Palladium Alloys, Ag-Pd-Gd-Ru, a 38

Al-Mg-I'd, melt oxidaton, a 38

Al-Pd-Co. U-. V-phase, structures, a 38

dental, Ag-Au-I'd-Cu, a 88

interaction with HI 37, 169

membranes. a 86, 189

P&I,Cu3UPz,,Nilll, crystallisation, a I36

Pd41Ni,,Cu27Pzu melts, crystallisation, a 38

Pd-Er-H, Pd-W-H, structural changes 169

Pd-Pt, interaction with HI 3 1

Pd-rare earths 108

Pt-Pd. jewellery alloy 66

Ti(PdNi). shape memory, a 188

38

(C7H1 jNH)I[Pd(dmit),l. air-oxidation of, a 39

(C,HltNH)lPd(dmit),l, electrical conductivity, a 39

Pd(l1) N& macrocycles, synthesis, a 39

Pd(1I) with pincer-like amido ligand, (I 38

in poly@ara-phenylene), synthesis 187

[Pd"CI,J, formation, at C paste electrode, a 85

Palladium Compounds, Pd(NH3)dX. reduction, a 38

Na2(Pd2Cln), reduction. a 84

Patents 4347.89-91. 141-143, 192-194

pH, sensors, a 189

Palladium Complexes, (BQA)PdCI, preparation. a

melting point 66. 181

nanoparticles 38, 84, 88. 105. 106, 1

IS,

136

nanowires. a 136

ohmic contacts, WSi interlayerslp-type Sic, a 191

in 0 sensors, a 137

particles, electroless plated, on SPE membranes. a 40

39

[Pt2-, Na', Nal], reduction of 2.4-dinitrotoluene 94

Pt( I 1 I ), surface, for electrolyte hydration 106

[Pt,,-, M'. MXI, [Pt. , M+, ?(MX)!, electrogenerated 94

single crystals, for CO electrooxidation, a 84

thermal diffusivity 66

thin films, a 85, 88, 189

welding, laser 66

for solar cell electrodes, a

Platinum Alloys, CoCrPt film, perpendicular media.

magnetic properties. a 191

CoCrPtB perpendicular media on TiZr,

magnetic properties, a I40

electrodes, see Electrodes and Fuel Cells

films, a I40

jewellery, Pt alloys 66

laser welding. jewellery 66

melting points 66. 181

nanoparticles 88, 106

Pt-Pd. interaction with Hz 37

thermal diffusivities 66

welding. laser 66

137

(~-C~H1)(Cl)Pt(~-CI),Ru(CI)(11':.rl'-2.7-dimethyl-

octadienyl), nanocrystal precursor 14

(COD)PtCI,

+

dimethylphenyl(quinolinyl)amine, a 38

luminescence, a 39. 137

in glass making 181

Pt-Rh, coatings. ACTrM 181

Platinum Complexes, rrans-Pt(II), insulator, a

(BQA)PtCI, preparation. a 38

(6)

Page PAGE

Ruthenium Alloys, (corn.)

Ruthenium Complexes, his(~'-2.4-diincthyl-

PI-Ru. jewellery alloy 66

Ta/Ru bufter layer, for CoCrPt perpendicular media, n 191

pentadienyl)Ru(II), for vapour-phase epitaxy, (I 42

Platinum Complexes, (cont. )

DhotODrODertieS. ( I 1 8 9

~hoto;ea~tions. LI 39.85

precursors for CVD, n 38. 107.189

LP~,CI~{N(H)C(BU')O)~], Pt(III)-Pt(llI) distance. ( I 136

lPt24(N(H)C(B~')o),l, o I36

Pt phthalocyanine, electrochemical doping of, a

Pt(I1) acetylacetonate, reaction with AI(CHI)J Pt(I1) N& macrocycles. synthesis. n Pt octaethylporphyrin, in 0 sensor, a

[PtIvCl2(enda)l, by oxidation of [Pt"C1dH2enda)], a

[Pt(en)iHzO)z]2', reaction with oL-penicillamine. a

I37 85 84 84

10s

39

Pt(I1) with pincer-like amido ligand, (I 38

Pt(II1) 'lantern-shaped'. u 136

PtR,(cod), ligand displacement reactions, n 136

PtR2L:. H20-soluble diorgano-, synthesis, (I 136

cis-. trcr,is-PtiYpy)2(NOl)l. aquation, hydrolysis, ci 188

88. 165. 166

[Rh,Pt,(CO)lb(dppm)~l, LRhxPt:(C0)21(dppm)?1, n 38

Platinum Compounds, antitumour agents

electrodes, a

K2[Pt(C,0,),], K2PtCIJ. K2PtC16. reduction, n thin films, u

geology conference

wastewater, electroflotation, (1

see also Emission Control

Polymerisation, co-, a

fast living radical, N

of phenylacetylene. (1

ROMP. a

matrix, for Pt complex thin film 0 sensor. ( I

polyimide, with Pd circuit patterns, n

poly(/,aru-phenylene)

+

Pd. phosphorescence

polystyrenes, hydrogenation. n

Pt-phenylene ethynylenes, photoproperties, (I

PVKPBD, with [Ir(DPF)& for OLEDs. n

Platinum Group Elements, geology book

Pollution Control, organic wastes, destruction

Polymers, coordination, Rh carboxylates, o

Power Coatings'", for the glass industry

Propane, CO, reforming of. CI

Propene, for reduction of NOx

Pyridines, chloro-, alkoxycarbonylation, n

dehydrogenation, a

Rare Earths, Pd-rare earths, eutectic phases

RCM, n

Reactors, fixed bed catalyst, design aspects solid solublities in Pd. strengthening effects

hydrogen-permeating membrane, a

for liquid phase hatch hydrogenations

electron transfer. of 2,4-dinitrotoluene 0,. 0

Reduction, C 0 2 . by HI, CI

88 I36 88 17 I77

18

I37

139 I40

140, 190

87

188

I37 137 187

86

I89 I37

181

41 40 24.41 87

108

108 87. I40

144

189

48,92 39 94 42

Reforming, (I 41, 191

Rhodium Alloys, (Ir, Rh)7,Nbl,Nii,,. specific strength 74

Pr-Rh. coatings. ACT"' 181

Rhodium, Rhodium Bicentenary Competition 2

jewellery alloy 66

Rhodium Complexes, [ RhoPt(CO)lo(dppm)i].

[RhxPt,(CO),I(dppm)21. 38

Rh porphyrin alkyls. reactions with nitroxides, n 188

tetra(alkoxybenzoato)dirhodium(ll), liquid crystals, a I88

188

TpmsRh(LL) (LL = (CO)?, cod, nbd). Rh(I) chemistry, CI 84

Rhodium Compounds, SrCuRhOh, Sr,NiRhOh, LI 136

ROMP, n 87

Rosenmund Reduction, acid chlorides 73

effect of HIO 48

Russia, PGE geology. conference 177

Ruthenium, electrodes I06

Ru-doped InP. resistivities. a 42

Ru(001), surface, for electrolyte hydration 106

Ruthenium Alloys, Ag-Pd-Gd-Ru, a 38

electrodes, see Electrodes and Fuel Cells

nanoparticles 88. 106

pyrazine adducts, liquid crystals, a

cance; drugs 165, 166

(~-C2HI)(CI)Pt(~-CI),Ru(Cl)(~':~'-2.7-dimethyl-

octadienyl ), nanocrystal precursor 14

luminescence 39. 85, 137. 165

(2-MelmH )?[ RuC11(2-Mclm

):I.

(2-MelniH).[RuC1~(2-Melm)]. synthesis. a 84

photoproperties 8 5 , 165, 189

[RuCp(dppin)SR

1,

micrnwave- ted synthesis, o 136

[RuH(arene)(Binap)lCF~SO!, piano-stool inverted. (I I88

[R~(L-L)~(cilatin)]~+, dimerisation. n I36

88. 105, 137. I88

LaSrCrRuO. SOFC anode material, ( I 191

RuO? powders, from RuCIl thermal decomposition, n 137

Selective Catalytic Reduction,

+

diesel particulate filter 27

NOx 27

Sensors, glucose. ( I 40. 86

H?, CI 189

hydrocarbons. CI 40

i n v i w biological 72

NO, (r 40

0 2 , (I 137

pH, a 189

I88

41. 50, 138, 139. 140

84 85

RuOz. RuO?/Ti anodes, LI I37

39 50 I77 140 42 88

thin films. Pd-Ag. for Pd-ceramic membranes. (I 86

50

Sulfuric Acid, Ti/lr02-TaOi anodes, degradation. o I88

Supercapacitors, RuO-/C, nanoconiposite. ( I 88

Superconductors, Pt

+

CeO? additions, a 42

Suzuki Couplings, FibreCatT". Pd/C. n I90

Pd-polymer-bound phosphine. a 191

Ruthenium Compounds, electrodes

Shape Memory Effect, in Ti(PdNi). LI

Single Crystals, PI. CO electrooxidation, (I Sol-Gel, Pt-doped Sn02 t h i n films. a

Solar Cells, with Pt particles on wSi electrodes, a

Sonogashira Couplings, of terminal alkynea

Silanes

South Africa, PGE geology, conference

Sputtering, DC. films. Co-Pt. CI

thin films, Ir, IrO,. CI

reactive r.f. magnetron. thin films. PI-PtO,. n

Stille Couplings, aryl halides

+

organostannanes

Superalloys, Ir-based refractory 74

Ti2FeRu02. Ti,Fe,Ru-0,,, nanocrystalline I05

Suzuki-Miyaura Couplings 50

in superdry conditions 94

Tetraalkylammonium Salts, effects on Pd. Pt cathodes.

Tetralins, amino-, synthesis. n 191

Thermal Diffusivities, PI, PI alloys 66

Thin Films, Ir, IrO:. by DC sputtering. u 42

NilPd, XRD, LI 85

137

189 86

I89 I37 85 88

188

Pd, circuit patterns on polyimide. (1

Pd. for poly-Si wires. as H? sensors. n

Pd-Ag. for ceramic composite membranes. n

PI. by chemical vapour deposition, n Pt octaethylporphyrin. for 0 sensors. o

Pt-doped SnO?. sol-gel preparation. ( I

Pt-PtO,. for memory capacitor electrodes. a

Ti(PdNi), bhape memory hehaviour. ti

see also Films

Thinpenes, oxidation, n I38

Three-Way Catalysts 27.40

Tungsten, Pd-W-H. H effects on I69

Pt-W. jewellery alloy 66

VOCs, oxidation. ( I 138, 189

Voltammetry, (DNA-0s.bipy ). microanalysis. n 138

Water, waste, electrode system for electrollotation. u 137

Welding, laser. of PI jewellery 66

References

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