Technical Data Sheet Page 1 of 3

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AKEPOX

^®

5010, 5010 Gel Mix, 5010 Single Mix

Technical Data Sheet

Page 1 of 3

TDS 08.20 Properties: AKEPOX^® 5010 is a gel-like, solvent-free, two-component adhesive

based on an epoxy resin containing a cycloaliphatic polyamine hardener. The product is characterized by the following properties:

- very neutral colour

- very low tendency to yellow

- easy dosing and mixing by use of cartridge system - high creeping strength due to gel-like consistency

- very low shrinkage during the hardening process and therefore low tensions in the bonding layer

- very good weather-resistant bondings

- good temperature stability: from -20°C up to 60 - 70°C for bondings exposed to weight, approx. 100 - 110°C for bondings not exposed to weight

- easy colouring with AKEPOX^® Colouring Pastes or Colouring Concentrates

- good dimensional stability of the bonding layer - low tendency to fatigue

- very good alkali-stability, thus the adhesive is very well suited to bond concrete

- excellently suited for bonding gas-impermeable materials as it is a solvent-free product

- good adhesion on slightly humid stones

- suited for bonding materials which are sensitive to solvents (e.g.

expanded polystyrene, ABS)

Application Area: AKEPOX^® 5010 is mainly used in the stone-working industry for the weather-resistant bonding and glueing of natural stone (marble, granite), Techno Ceramics as well as artificial stone or building materials (terrazzo, concrete). By means of the application of high- quality raw materials it was possible to develop a system which hardly yellows. It is thus possible to use it in combination with light-coloured or even white natural stone without the usual intensive yellowing of conventional epoxy-resin systems. Because of its supple, gel-like consistency the product has a high creeping strength on vertical surfaces. It is nevertheless possible to attain thin adhesive joints. Other materials can also be glued with AKEPOX^® 5010, e.g. plastics (hard PVC, polyester, polystyrene, ABS, polycarbonates), paper, wood, glass and many other materials. AKEPOX^® 5010 is not suitable for the gluing of polyolefins (polyethylene, polypropylene), silicones, hydrocarbon fluorides (Teflon), soft PVC, soft polyurethane, butyl rubber and metal.

Instructions for Use: A. Products in cans

1. Thoroughly clean and slightly roughen surfaces to be bonded.

2. Thoroughly mix 2 parts (volume or weight) of component A with 1 part (volume or weight) of component B until a homogeneous shade of colour is achieved.

3. AKEPOX^® Colouring Pastes or Colouring Concentrates can be added up to max. 5%.

4. The mixture remains workable for approx. 20 - 30 minutes (20°C).

After approx. 6 - 8 hours (20°C) the bonded parts may be moved, After 12 - 16 hours (20°C) approx. they may be further processed.

Maximal stability after 7 days (20°C).

5. Tools can be cleaned with AKEMI^® Nitro-Dilution.

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AKEPOX

^®

5010, 5010 Gel Mix, 5010 Single Mix

Technical Data Sheet

Page 2 of 3

TDS 08.20

A

6. The hardening process is accelerated by heat and delayed by cold.

B. Cartridge System

1. Thoroughly clean and slightly roughen surfaces to be bonded.

2. Remove the clasp from the cartridge and put the cartridge in the gun;

work the grip until material emerges from both openings; then eventually screw up the mixing nozzle.

3. AKEPOX^® Colouring Pastes or Colouring Concentrates can be added up to max. 5 %.

4. Both components must be thoroughly mixed when working without mixing nozzle.

5. The mixture remains workable for approx. 20 - 30 minutes (20°C).

After approx. 6 - 8 hours (20°C) the bonded parts may be moved.

After 12 – 16 hours (20°C) approx. they may be further processed.

Maximal stability after 7 days (20°C).

6. Tools can be cleaned with AKEMI^® Nitro-Dilution.

7. The hardening process is accelerated by heat and delayed by cold.

Special Notes: - Suitable for bonding of load-bearing construction parts, however, the relevant standards such as DIN 18516 part 1 and part 3 or DIN 2304 must be observed during application.

- Only if the right mixing ratio is kept, optimal mechanical and chemical properties can be obtained. A surplus of adhesive or hardener has the effect of a softener and can cause discolouration in the marginal zone.

- Single Mix cartridges are not suitable for compressed-air guns or guns with mechanical pistons.

- Two separate spatulas should be used for the adhesive and the hardener.

- An adhesive is no longer to be used if it has already thickened or is jellying.

- The product is not to be used at temperatures below 10°C because it will not sufficiently harden.

- At constant temperatures above 50°C the hardened adhesive tends to yellowing.

- The hardened adhesive can no longer be removed by means of solvents. This can only be achieved mechanically or by applying higher temperatures (> 200°C).

- The A-component slightly tends to crystallize (honey effect). The product can be made workable again by warming it up.

- The stability of the bonding depends on the natural stone to be bonded: silicate-bound stone reacts better than carbonate-bound stone.

Technical Data: 1. Colour (A and B):

2. Density (A and B):

3. Working time:

mixture of 100 g component A + 50 g of component B:

transparent CC 2200

approx. 1.16 g/cm³

at 10°C: 60 – 70 minutes at 20°C: 20 – 30 minutes at 30°C: 10 – 15 minutes at 40°C: 5 – 10 minutes

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AKEPOX

^®

5010, 5010 Gel Mix, 5010 Single Mix

Technical Data Sheet

Page 3 of 3

TDS 08.20 4. Mechanical properties:

Bending strength DIN EN ISO 178:

Tensile strength DIN EN ISO 527:

5. Chemical Resistance:

Water absorption:

Sodium Chloride Solution 10%:

Salt water:

Ammonium 10%:

Soda lye 10%:

Hydrochloric acid 10%:

Acetic acid 10%:

Formic acid 10%:

Petrol:

Diesel oil:

Lubricating oil:

60 - 70 N/mm² 30 - 40 N/mm²

< 0.5 % stable stable stable stable stable

conditionally stable conditionally stable stable

stable stable

6. Hardening process (Shore D hardness)

of a 2 mm layer at 20°C

:

4 h 5 h 6 h 7 h 8 h 24 h 7 d -- 44 67 74 76 82 83

Storage: If stored in dry and cool condition (5-25°C/41-77°F) in its closed original container at least 24 months from production.

Health & Safety: Read Safety Data Sheet before handling or using this product.

Important Notice: The above information is based on the latest stage of development and application technology. Due to a multiplicity of different influencing factors, this information – as well as other oral or written technical advises – must be considered as non-binding hints. The user is obliged in each particular case to conduct performance tests, including but not limited to trails of the product, in an inconspicuous area or fabrication of a sample piece.

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Safety Data Sheet

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9 Section 1 - Identification of Chemical Product and Company TQ Products Pty Ltd

15 Weedon Road Forrestdale

WA 6112

ACN 149-668-342

24hr Emergency Phone: 13 1126 Australia Emergency Services: 000 Phone:

business hours

1 300 075 678

Substance:

Trade Name:

Akepox 1005 Component A

Product Use: Industrial use only Creation Date: July 2021

Revision Date: July 2021 and valid for five years

Section 2 - Hazards Identification

Statement of Hazardous Nature

This product is classified as: HAZARDOUS CHEMICAL; DANGEROUS GOOD according to the WHS Regulations and ADG Code.

Poison Schedule Not applicable

Signal Word: WARNING

Hazard Classification:

Skin Effects Category 2

Eye Effects Category 2

Skin Sensitisation Category 1 Chronic Aquatic Hazard Category 2 Hazard Statements:

H315 Causes skin irritation H319 Causes serious eye irritation.

H317 May cause an allergic skin reaction

H411 Toxic to aquatic life with long lasting effects Precautionary Statement: Prevention

P261 Avoid breathing mist/ vapour/ spray

P280 Wear protective gloves/ protective clothing/ eye protection and face protection P264 Wash all exposed external body parts thoroughly after handling

P272 Contaminated work clothing should not be allowed out of the workplace P273 Avoid release to the environment

Precautionary Statement: Response

P301+P312 IF SWALLOWED: Call a POISON CENTRE or doctor/ physician if you feel

unwell

P330 Rinse mouth

P302+P352 IF ON SKIN: Wash with plenty of soap and water P333+P313 IF skin irritation or rash occurs: Get medical advice P362+P364 Take off contaminated clothing and wash before reuse

P035+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/ attention

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P304+P340 IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing

P391 Collect spillage Precautionary Statement: Storage

P405 Store locked up

Precautionary Statement: Disposal

P501 Dispose of contents/ container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal

Section 3 - Composition/Information on Ingredients

Substances CAS No Conc.%

Bis[4-(2,3-epoxypropoxy)phenyl]propane 1675-54-3 > 50 %

Cyclohexanedimethanol diglycidyl ether 14228-73-0 10 - 30 %

[3-(2,3-epoxypropoxy)propyl]trimethoxysilane 2530-83-8 1 – 5 %

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other nonhazardous ingredients are also possible.

Mixtures

See above for composition of substance

Section 4 - First Aid Measures

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 131126 from anywhere in Australia and is available at all times. Have this SDS or product label with you when you call.

Eye Contact:

Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay;

if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact:

Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Inhalation:

Remove from contaminated area. Other measures are usually unnecessary.

Ingestion:

Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Note to Physician:

Treat symptomatically.

As in all cases of suspected poisoning, follow the ABCDEs of emergency medicine (airway, breathing, circulation, disability, exposure), then the ABCDEs of toxicology (antidotes, basics, change absorption, change distribution, change elimination).

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Safety Data Sheet

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9 Section 5 - Fire Fighting Measures

Extinguishing Media:

Consider: foam. dry chemical powder. carbon dioxide.

Fire Incompatibility:

Avoid contamination with oxidising agents i.e., nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.

Fire Fighting:

Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area. Avoid spraying water onto liquid pools. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.

Fire and Explosion Hazards:

Combustible. Slight fire hazard when exposed to heat or flame. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO). May emit acrid smoke.

Mists containing combustible materials may be explosive.

Fire Decomposition:

Carbon dioxide (CO2) Carbon dioxide (CO2)and other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes.

HAZCHEM 3Z

Section 6 - Accidental Release Measures

Personal precautions, protective equipment and emergency procedures Refer Section 8

Environmental precautions Refer Section 12 Minor Spills:

Environmental hazard - contain spillage. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal.

Major Spills:

Environmental hazard - contain spillage. Moderate hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Absorb remaining product with sand, earth or vermiculite. Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. If contamination of drains or waterways occurs, advise emergency services.

Section 7 - Handling and Storage

Handling:

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well- ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been

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checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions. DO NOT allow clothing wet with material to stay in contact with skin

Storage:

Store in original containers. Keep containers securely sealed. No smoking, naked lights or ignition sources. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storage and handling recommendations contained within this SDS.

Suitable container

Metal can or drum; Packaging as recommended by the manufacturer; Check all containers are clearly labelled and free from leaks

Section 8 - Exposure Controls and Personal Protection

Australia

Exposure limits TWA (mg/m³) STEL (mg/m³)

The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5-day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

Engineering Controls:

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard

"physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure.

General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection.

Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the workplace possess varying

"escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.

Eye Protection:

Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent]

Skin Protection:

Wear chemical protective gloves, e.g. Neoprene or Nitrile or Nitrile+PVC. Wear safety footwear or safety gumboots, e.g. Rubber

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When handling hazardous substances, wear trousers or overalls outside of boots, to avoid spills entering boots. Overalls. P.V.C. apron.

Respirator:

Not normally required. If WES is likely to be exceeded, then a Type A filter of sufficient capacity is recommended

Section 9 - Physical and Chemical Properties:

Physical Description & colour: Colourless pasty Liquid

Odour: Characteristic

Odour threshold: no data

pH: no data

Melting Point: no data

Boiling Point: no data

Flash point: no data

Flammability: no data

Evaporation Rate: > 1 butyl acetate = 1 Lower Explosion Limit: no data

Upper Explosion Limit: no data

Vapour Pressure: 0.2 kPa

Relative Vapour Density: > 1 Specific Gravity: 1.17 g/cm³ Water Solubility: Immiscible Coeff Octanol/water distribution no data Auto ignition temp: no data

Decomposition temp: material is stable under normal conditions

SADT: no data available

Dynamic viscosity: no data

Kinematic viscosity: no data

Volatiles: 7 %

Section 10 - Stability and Reactivity

Reactivity:

Product is considered stable under normal conditions Chemical stability:

Unstable in the presence of incompatible materials. Product is considered stable. Hazardous polymerisation will not occur.

Conditions to Avoid:

Refer Section 7 Incompatibilities:

Refer Section 7 Polymerisation:

This product will not undergo polymerisation reactions.

Hazardous Decomposition Products Refer Section 5

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9 Section 11 - Toxicological Information

Inhaled:

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. Not normally a hazard due to non-volatile nature of product

Ingestion:

The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence.

Skin Contact:

The material may accentuate any pre-existing dermatitis condition Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions. Open cuts, abraded or irritated skin should not be exposed to this material Entry into the blood- stream through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. The material may cause mild but significant inflammation of the skin either following direct contact or after a delay of some time. Repeated exposure can cause contact dermatitis which is characterised by redness, swelling and blistering.

Eye Contact:

Eye contact with reactive diluents may cause slight to severe irritation with the possibility of chemical burns or moderate to severe damage to the cornea. There is evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more after instillation. Severe inflammation may be expected with pain.

Chronic Health Effects:

Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population. Ample evidence exists, from results in experimentation, that developmental disorders are directly caused by human exposure to the material. Glycidyl ethers can cause genetic damage and cancer. For some reactive diluents, prolonged or repeated skin contact may result in absorption of potentially harmful amounts or allergic skin reactions.

There has been concern that this material can cause cancer or mutations, but there is not enough data to make an assessment.

Toxicity refer ingredients

Oral Dermal Inhalation

Product ^LC⁵⁰ 385 mg/L 4h

Bis[4-(2,3-epoxypropoxy)phenyl]

propane

LD50 >2,000 mg/Kg LD50 >2,000 mg/Kg Cyclohexanedimethanol diglycidyl

ether

LD50 >5380 mg/Kg LD50 4248 mg/Kg LC50 5.3 mh/L 4h [3-(2,3-epoxypropoxy)propyl]

trimethoxysilane

LD50 >5350 mg/Kg LD50 4248 mg/Kg LC50 >5.3 mg/L 4h

Section 12 - Ecological Information

Fish Crustacea Algae

Product

Bis[4-(2,3-epoxypropoxy) phenyl]propane

LC50 96hr 1.2 mg/L EC50 48hr 1.1 mg/L

NOEC 504hr 0.3 mg/L EC50 72hr 9.4 mg/L Cyclohexanedimethanol

diglycidyl ether

LC50 96hr 10.2 mg/L

NOEC 96hr 3.4 mg/L EC50 48hr 16.3 mg/L EC50 24hr 9.99 mg/L

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[3-(2,3-epoxypropoxy)propyl]

trimethoxysilane

LC50 96hr 4.9 mg/L

NOEC 96hr 1.5 mg/L EC50 48hr 473 mg/L EC50 24hr 420 mg/L EC50 96hr 250 mg/L

Toxic to aquatic life with long lasting effects. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high-water mark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters. Wastes resulting from use of the product must be disposed of on site or at approved waste sites. DO NOT discharge into sewer or waterways.

Persistence Water/Soil

Persistence Air Bioaccumulation Mobility Bis[4-(2,3-epoxypropoxy)

phenyl]propane HIGH HIGH MEDIUM LOW

Cyclohexanedimethanol

diglycidyl ether HIGH HIGH LOW LOW

[3-(2,3-epoxypropoxy)propyl]

trimethoxysilane HIGH HIGH LOW LOW

Section 13 - Disposal Considerations

Disposal:

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. A Hierarchy of Controls seems to be common - the user should investigate: Reduction Reuse Recycling Disposal (if all else fails) This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf-life considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be appropriate. DO NOT allow wash water from cleaning or process equipment to enter drains.

It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority.

Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.

Dispose of by burial in a landfill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a licensed apparatus (after admixture with suitable combustible material). Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Section 14 - Transport Information

Labels Required

MARINE POLLUTANT YES

HAZCHEM 3Z

Land Transport ADG

UN Number 3082

UN Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains Bis[4- (2,3-epoxypropxy)phenyl]propane and 2,3-epoxypropoxy o-tolyl ether

Class 9

Subrisk not applicable

Packing Group III

Environmental Hazard Environmentally hazardous Special Provisions 274 331 335 375 AU01

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Limited Quantity 5L

Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not subject to this Code when transported by road or rail in;

(a) packaging;

(b) IBCs; or

(c) any other receptacle not exceeding 500 kg(L).

- Australian Special Provisions (SP AU01) - ADG Code 7th Ed.

Air Transport ICAO-IATA/ DGR

UN Number 3082

ICAO/ IATA Class 9

ICAO/ IATA Subrisk not applicable

ERG Code 9L

Environmental Hazard Environmentally hazardous Special Provisions A97 A158 A197 A215 Cargo Only Packing Instructions 964 Cargo only Max Qty/ Pack 450 L Passenger/ Cargo Packing Instruction 964 Passenger/ Cargo Max Qty/ Pack 450 L Passenger/ Cargo LQ Packing Instruction Y964 Passenger/ Cargo LQ Qty/ Pack 30 Kg G Marine Transport IMDG Code /GGVSee

UN Number 3082

IMDG Class 9

IMDG Subrisk not applicable

Environmental Hazard Marine Pollutant

EMS Number F-A S-F

Special Provisions 274 335 969 Limited Quantities 5 L

Section 15 - Regulatory Information

Safety, health and environmental regulations/ legislation specific for the substance or mixture

International Regulations

Montreal Protocol Not applicable Stockholm Convention Not applicable Rotterdam Convention Not applicable

Kyoto Protocol Not applicable

Inventory Status

Australia AICS Yes

Canada DSL Yes

NDSL No

China IECS Yes

EU EINECS Yes

Japan ENCS No

Korea KECI Yes

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New Zealand NZIOC Yes Philippines PICCS Yes

Taiwan CSNN Yes

US TSCA Yes

Taiwan TCSI Yes

Mexico INSQ No

Vietnam NCI Yes

Russia FBEPH No

Section 16 - Other Information

Revision History

July 2021 origination

This SDS contains only safety-related information. For other data see product literature.

Please read all labels carefully before using product.

Acronyms:

CAS number Chemical Abstracts Service Registry Number

Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially fire-fighters.

IARC International Agency for Research on Cancer

NOS Not otherwise specified.

UN Number United Nations Number

The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to

be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material in combination with any other material or in any process, unless specified in the text.

This SDS was prepared by Collievale Enterprises Ltd http://www.collievale.com Phone +64 7 5432428

End of SDS

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Safety Data Sheet

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9 Section 1 - Identification of Chemical Product and Company TQ Products Pty Ltd

15 Weedon Road Forrestdale

WA 6112

ACN 149-668-342

24hr Emergency Phone: 13 1126 Australia Emergency Services: 000 Phone:

business hours

1 300 075 678

Substance:

Trade Name:

Akepox 5010 Component B

Product Use: Industrial use only Creation Date: July 2021

Revision Date: July 2021 and valid for five years

Section 2 - Hazards Identification

Statement of Hazardous Nature

This product is classified as: HAZARDOUS CHEMICAL; DANGEROUS GOOD according to the WHS Regulations and ADG Code.

Poison Schedule Not applicable

Signal Word: DANGER

Hazard Classification:

Acute Oral Toxicity Category 4 Skin Effects Category 1A

Eye Effects Category 1

Skin Sensitisation Category 1 Chronic Aquatic Hazard Category 3 Hazard Statements:

H302 Harmful if swallowed

H314 Causes severe skin burns and serious eye damage.

H317 May cause an allergic skin reaction

H412 Harmful to aquatic life with long lasting effects Precautionary Statement: Prevention

P260 Do not breathe mist/ vapour/ spray

P280 Wear protective gloves/ protective clothing/ eye protection and face protection P264 Wash all exposed external body parts thoroughly after handling

P272 Contaminated work clothing should not be allowed out of the workplace P270 Do not eat, drink or smoke while handling this product

P273 Avoid release to the environment Precautionary Statement: Response

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P302+P361+P352 IF ON SKIN: Take off immediately all contaminated clothing. Wash with plenty of soap and water

P333+P313 IF skin irritation or rash occurs: Get medical advice P362+P364 Take off contaminated clothing and wash before reuse

P035+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/ attention

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P304+P340 IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing

Precautionary Statement: Storage

P405 Store locked up

Precautionary Statement: Disposal

P501 Dispose of contents/ container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal

Section 3 - Composition/Information on Ingredients

Substances CAS No Conc.%

Benzyl alcohol 100-51-6 12.5 – 25 %

1,3-cyclohexanedimethanamine 2579-20-6 < 10 %

2,2,4-trimethylhexan-1,5-diamine 25513-64-8 < 10 %

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other nonhazardous ingredients are also possible.

Mixtures

See above for composition of substance

Section 4 - First Aid Measures

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 131126 from anywhere in Australia and is available at all times. Have this SDS or product label with you when you call.

Eye Contact:

Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.

Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact:

Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. Transport to hospital, or doctor.

Inhalation:

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested.

Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested. Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered. This must definitely be left to a doctor or person authorised by him/her.

Ingestion:

For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed.

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If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.

Note to Physician:

Treat symptomatically.

As in all cases of suspected poisoning, follow the ABCDEs of emergency medicine (airway, breathing, circulation, disability, exposure), then the ABCDEs of toxicology (antidotes, basics, change absorption, change distribution, change elimination).

Section 5 - Fire Fighting Measures

Extinguishing Media:

Consider: foam. dry chemical powder. carbon dioxide.

Fire Incompatibility:

Avoid contamination with oxidising agents i.e., nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.

Fire Fighting:

Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area. Avoid spraying water onto liquid pools. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.

Fire and Explosion Hazards:

Combustible. Slight fire hazard when exposed to heat or flame. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO). May emit acrid smoke.

Mists containing combustible materials may be explosive.

Fire Decomposition:

Carbon dioxide (CO2) Carbon dioxide (CO2), Nitrogen Oxides (NOx)and other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes.

HAZCHEM 2R

Section 6 - Accidental Release Measures

Personal precautions, protective equipment and emergency procedures Refer Section 8

Environmental precautions Refer Section 12 Minor Spills:

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal.

Major Spills:

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. Stop

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leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Neutralise/decontaminate residue (see Section 13 for specific agent). Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. If contamination of drains or waterways occurs, advise emergency services.

Section 7 - Handling and Storage

Handling:

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well- ventilated area. WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained. DO NOT allow clothing wet with material to stay in contact with skin

Storage:

Store in original containers. Keep containers securely sealed. No smoking, naked lights or ignition sources. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storage and handling recommendations contained within this SDS.

Suitable container

Drums and jerricans must be of the non-removable head type. Where a can is to be used as an inner package, the can must have a screwed enclosure.

Section 8 - Exposure Controls and Personal Protection

Australia

Exposure limits TWA (mg/m³) STEL (mg/m³)

The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5-day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

Engineering Controls:

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard

"physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure.

General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection.

Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the workplace possess varying

"escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.

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Eye Protection:

Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent]

Skin Protection:

Wear chemical protective gloves, e.g. Neoprene or Nitrile or Nitrile+PVC. Wear safety footwear or safety gumboots, e.g. Rubber

When handling hazardous substances, wear trousers or overalls outside of boots, to avoid spills entering boots. Overalls. P.V.C. apron.

Respirator:

Not normally required. If WES is likely to be exceeded, then a Type AK-P filter of sufficient capacity is recommended

Section 9 - Physical and Chemical Properties:

Physical Description & colour: Colourless pasty Liquid

Odour: Characteristic

Odour threshold: no data

pH: no data

Melting Point: no data

Boiling Point: 205.4 °C

Flash point: 101 °C

Flammability: no data

Evaporation Rate: > 1 butyl acetate = 1 Lower Explosion Limit: 1.3 %

Upper Explosion Limit: 13 %

Vapour Pressure: 0.01 kPa

Relative Vapour Density: > 1 Specific Gravity: 1.07 g/cm³ Water Solubility: Partially soluble Coeff Octanol/water distribution no data Auto ignition temp: 438 °C

Decomposition temp: material is stable under normal conditions

SADT: no data available

Dynamic viscosity: 8000 mPas

Kinematic viscosity: no data

Volatiles: 23 %

Section 10 - Stability and Reactivity

Reactivity:

Product is considered stable under normal conditions Chemical stability:

Unstable in the presence of incompatible materials. Product is considered stable. Hazardous polymerisation will not occur.

Conditions to Avoid:

Refer Section 7

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Incompatibilities:

Refer Section 7 Polymerisation:

This product will not undergo polymerisation reactions.

Hazardous Decomposition Products Refer Section 5

Section 11 - Toxicological Information

Inhaled:

The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage. Inhaling corrosive bases may irritate the respiratory tract. Symptoms include cough, choking, pain and damage to the mucous membrane. Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack of co-ordination, and vertigo. Inhalation of amine vapours may cause irritation of the mucous membrane of the nose and throat, and lung irritation with respiratory distress and cough.

Swelling and inflammation of the respiratory tract is seen in serious cases; with headache, nausea, faintness and anxiety.

Ingestion:

Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the individual. Ingestion of alkaline corrosives may produce burns around the mouth, ulcerations and swellings of the mucous membranes, profuse saliva production, with an inability to speak or swallow. Both the oesophagus and stomach may experience burning pain; vomiting and diarrhoea may follow. Amines without benzene rings when swallowed are absorbed throughout the gut. Corrosive action may cause damage throughout the gastrointestinal tract.

Skin Contact:

Skin contact with the material may be harmful; systemic effects may result following absorption. The material can produce severe chemical burns following direct contact with the skin. Skin contact with alkaline corrosives may produce severe pain and burns; brownish stains may develop. The corroded area may be soft, gelatinous and necrotic; tissue destruction may be deep. Volatile amine vapours produce irritation and inflammation of the skin. Direct contact can cause burns. Open cuts, abraded or irritated skin should not be exposed to this material Entry into the blood-stream through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Eye Contact:

Direct eye contact with corrosive bases can cause pain and burns. There may be swelling, epithelium destruction, clouding of the cornea and inflammation of the iris. Mild cases often resolve; severe cases can be prolonged with complications such as persistent swelling, scarring, permanent cloudiness, bulging of the eye, cataracts, eyelids glued to the eyeball and blindness. Vapours of volatile amines irritate the eyes, causing excessive secretion of tears, inflammation of the conjunctiva and slight swelling of the cornea, resulting in "halos" around lights. This effect is temporary, lasting only for a few hours. However, this condition can reduce the efficiency of undertaking skilled tasks, such as driving a car. Direct eye contact with liquid volatile amines may produce eye damage, permanent for the lighter species.

Chronic Health Effects:

Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue. Long-term exposure to respiratory irritants may result in airways disease, involving difficulty breathing and related whole-body problems. Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population. Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.

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Oral Dermal Inhalation

Product LD50 2437 mg/Kg LD50 6268 mg/Kg LC50 27.5 mg/L 4h

Benzyl alcohol LD50 1040 mg/Kg LD50 >2000 mg/Kg LC50 >4.178 mg/L 4h 1,3-cyclohexanedimethanmine LD50 200-2000 mg/Kg LD50 1700 mg/Kg

2,2,4-trimethylhexan-1,5-diamine LD50 910 mg/Kg

Section 12 - Ecological Information

Fish Crustacea Algae

Product

Benzyl alcohol LC50 96hr 10 mg/L

NOEC 336hr 5.1 mg/L EC50 48hr 230 mg/L EC50 24hr 500 mg/L EC50 96hr 76.8 mg/L 1,3-cyclohexanedimethanmine ^LC^{50 96hr} ^{130 mg/L} ^EC^{50 48hr} ^{33.1 mg/L} ^EC^{50 72hr} ^{29.7 mg/L} NOEC 72hr 13.7 mg/L 2,2,4-trimethylhexan-1,5-

diamine

EC50 24hr 29.5 mg/L

EC10 72hr 16.3 mg/L

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high-water mark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters. Wastes resulting from use of the product must be disposed of on site or at approved waste sites. DO NOT discharge into sewer or waterways.

Persistence Water/Soil

Persistence Air Bioaccumulation Mobility

Benzyl Alcohol LOW LOW LOW LOW

1,3-cyclohexanedimethanmine LOW LOW LOW LOW

2,2,4-trimethylhexan-1,5-

diamine HIGH HIGH LOW LOW

Section 13 - Disposal Considerations

Disposal:

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. A Hierarchy of Controls seems to be common - the user should investigate: Reduction Reuse Recycling Disposal (if all else fails) This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf-life considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be appropriate. DO NOT allow wash water from cleaning or process equipment to enter drains.

It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority.

Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.

Dispose of by burial in a landfill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a licensed apparatus (after admixture with suitable combustible material). Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

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Labels Required

MARINE POLLUTANT No

HAZCHEM 2R

Land Transport ADG

UN Number 1719

UN Proper Shipping Name CAUSTIC ALKALI, LIQUID, N.O.S. (contains 1,3-cyclohexane dimethanamine and 2,2,4-trimethylhexan-1,5-diamine)

Class 8

Subrisk not applicable

Packing Group II

Environmental Hazard not applicable Special Provisions 274

Limited Quantity 1L Air Transport ICAO-IATA/ DGR

UN Number 1719

Class 8

ICAO/ IATA Subrisk not applicable

ERG Code 8L

Packing Group II

Environmental Hazard not applicable Special Provisions A3 A803

Cargo Only Packing Instructions 855 Cargo only Max Qty/ Pack 30 L Passenger/ Cargo Packing Instruction 851 Passenger/ Cargo Max Qty/ Pack 1 L Passenger/ Cargo LQ Packing Instruction Y840 Passenger/ Cargo LQ Qty/ Pack 0.5L Marine Transport IMDG Code /GGVSee

UN Number 1719

Class 8

IMDG Subrisk not applicable

Packing Group II

Environmental Hazard not applicable

EMS Number F-A S-B

Special Provisions 274 Limited Quantities 1 L

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Safety, health and environmental regulations/ legislation specific for the substance or mixture

International Regulations

Montreal Protocol Not applicable Stockholm Convention Not applicable Rotterdam Convention Not applicable

Kyoto Protocol Not applicable

Inventory Status

Australia AICS Yes

Canada DSL Yes

NDSL No

China IECS Yes

EU EINECS Yes

Japan ENCS Yes

Korea KECI Yes

New Zealand NZIOC Yes Philippines PICCS Yes

Taiwan CSNN Yes

US TSCA Yes

Taiwan TCSI Yes

Mexico INSQ No

Vietnam NCI Yes

Russia FBEPH Yes

Section 16 - Other Information

Revision History

July 2021 origination

This SDS contains only safety-related information. For other data see product literature.

Please read all labels carefully before using product.

Acronyms:

CAS number Chemical Abstracts Service Registry Number

Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially fire-fighters.

IARC International Agency for Research on Cancer

NOS Not otherwise specified.

UN Number United Nations Number

The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to

be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material in combination with any other material or in any process, unless specified in the text.

This SDS was prepared by Collievale Enterprises Ltd http://www.collievale.com Phone +64 7 5432428