28 January 2013
SOx reduction
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28 January 2013
Marpol 73/78 Annex VI
2
MARPOL ANNEX VI applies to
all ships, fixed and floating
drilling rigs and other platforms IAPP Certificate is required for ships of 400 GRT and above engaged in international
voyages involving countries that have ratified the conventions, or ships flying the flag of those countries.
Annex VI Regulation 14 contains requirements to Sulphur Oxide (SOx) emissions from ships
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28 January 2013
GENERAL
Sulphur content of marine fuels (according to MARPOL Annex VI , reg. 14)
The sulphur content of marine fuels must not exceed:
Global: SECA/ECA: 3 3.5% 4.5% 2012 Jan. 2020 Jan. (Possible postponement until 2025) 0.5% 0.5% 1.0% 1.5% 2010 July 2015 Jan. 0.5% 0.1%
THERE is no chance of pushing back the 2015 deadline for ultra-low sulphur fuel, Brussels has warned.
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28 January 2013
Fuel share of daily costs
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28 January 2013
Annex VI Compliant Marine Fuel Use
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28 January 2013
Marine Fuels
Prices ($/ton) in Rotterdam 2013.01.11
LSMGO(0,1%S) - 932 MGO - 932 LS380 (1-1.4%S) - 649 LS180 (1-1,4%S) - 670 IFO380 - 618 IFO180 - 638 LNG price : 570 $/ton - Europe
875 $/ton - Singapore
Energy price equivalent:
MGO - 20,4 $/GJ
LS380 - 14,7 $/GJ
IFO - 13,9 $/GJ
LNG - 10,6-16,3 $/GJ
EC quality types of fuel:
- Quality 1 (MGO) – less than 0,1%S
- Quality 2 (MDO) – less than 1,5%S
- Quality 3 (IFO) - between 1,5 and 4,5%S (max. 3,5%S since Jan. 2012).
IFO - Intermediate Fuel Oil is a blend of gas oil and heavy fuel oil
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World LNG prices
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28 January 2013
MARPOL Annex VI - SOx requirements
The following options for compliance apply:
- Sulphur content of the fuel shall not exceed the set limit
- An exhaust gas cleaning system approved by or on behalf of the national maritime administration in accordance with guidelines developed by IMO – MEPC.184(59). The system shall reduce the total emission of sulphur oxides from vessels including both auxiliary and main propulsion engines
- Any other technological method that is verifiable and enforceable to limit SOx
emissions to a level (described in legislation). These methods shall be approved by the national maritime administration in accordance with IMO guidelines
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28 January 2013
SOx - DNV Services
1) Class and Statutory Approval
Piping Systems, DNV Rules for Classification of Ships, Pt.4 Ch.6
- a new section for Exhaust Gas Cleaning - EGC systems has been added
- Machinery, Control Systems, Electrical Systems, Structure, Stability, Fire Safety
Revised MARPOL Annex VI, Regulation 14
- Guidelines for Exhaust Gas Cleaning System the environmental performance (Resolution MEPC.184(59))
2) Advisory
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28 January 2013
Three options for SO
Xremoval
LNG as fuel
10
…or fleet redeployment,
i.e. give up trading in ECAs…
1
2
3
Scrubbers for exhaust gas cleaning
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28 January 2013
Pros and cons
11
LNG fuel
Scrubber
2013
Low sulphur fuel
2020-2025 Global 2015 ECA
1850-1900
?
Option Pros Cons
Scrubber Can use cheaper, high sulphur fuel.
Fuel available Takes up space. Significant investment cost No significant reduction of NOx Requires additional energy during operation
Discharge of water LNG Currently cheaper fuel, but future
price development is uncertain Reduces NOx and CO2
Retrofit difficult
Requires larger fuel tanks Fuel availability uncertain Infrastructure currently limited Distillate fuel No or little modifications and
investment needed. Well known and tested.
Higher fuel cost.
Prices likely to increase. Fuel availability uncertain. Wear and tear.
1
2
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28 January 2013
LNG: Technically proven, safe in operation
40 years of LNG tanker operation
Used as marine fuel since 2001, now in 34 ships
Class rules in place, IMO regulations in the pipeline (2014)
Relatively high capex, opex highly dependent on the LNG market price
Uncertainties;
- LNG availability and future price? Government incentive schemes?
- Infrastructure development pace? Retrofit? Or newbuilds only?
- Safety record due to higher than normal safety focus?
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28 January 2013
13 13
Technology is approved and available
Many manufactures are offering LNG fuelled engines:
- Wärtsilä
- Rolls-Royce
- MAN Diesel
- Mitsubishi
Main challenges are the loss of cargo space due to cylindrical LNG storage tank, and a slight methane slip from engine when running on low load (continuous improvements)
Development is ongoing to shift from spherical (volume consuming) to hull integrated tanks
Fuel cells on LNG for ship propulsion are under development (FellowShip)
Two engine concepts:
• Lean burn LNG mono fuel • Dual fuel (LNG + Diesel)
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28 January 2013
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Rough estimates for additional CAPEX for LNG tanks, distribution, engine, larger vessel:
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28 January 2013
A typical Baltic Sea Cargo Ship when operating on LNG
547 TEU container vessel (5000 GT) Propulsion power 3960 kWSOx NOx CO2
Particle emissions
With LNG fuel:
0
31
5 500
0
With low-sulphur HFO
(LS380 with 1% sulfur):
50
180
7 250
4
Yearly emissions, tonnes/year© Det Norske Veritas AS. All rights reserved. SOx reduction
28 January 2013
Low sulphur fuel - refinery capacity
Capacity upgrade primarily coking and
cracking units; likely more attractive to produce higher margin products than LS fuels
16
3
Capacity growth in Asia – but LS fuel
demand growth expected primarily in North-America and Europe
Will refineries deliver sufficient volumes
in the right geographies?
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28 January 2013
Class requirements related to the low sulphur fuel system
Class has no specific requirements to the fuels used on board, unless special environmentalclass notation is denoted. The max. sulphur content is 3%S (1%S in ports and SECAs) for CLEAN and CLEAN DESIGN notations.
Class notations ECA(Sox-A) and ECA(Sox-P), when granted assure compliance with
MARPOL Annex VI regulations in ECAs. The fuel shall cover the quality parameters specified in ISO 8217 but S content shall not exceed 0.10% and viscosity shall not be below 2cSt at 40°C.
Where applicable, alterations to systems and components are subject to approval by Class, i.e. drawings need to be submitted and approved prior to commencement of the alterations and after completion these alterations need to be verified and tested during an on board survey.
Though not required by Class or Port State Authorities, ship operators may be asked by e.g. charter parties to provide a statement (witness report) pertaining to the capability of the vessel to operate on LSF, the effectiveness of fuel changeover procedures, or both.
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28 January 2013
Systems and arrangement for meeting regulations in
Emission Control Areas – Class notation ECA(SOx)
Reliable fuel oil systems and machinery components should enable safe operation
on low viscosity (2 cSt) and low sulphur (0.10%) marine distillate fuel oils (marine gas oil) for a minimum of 4 days.
The 4 days rule apply to ships that continuously operate on marine gas oils and also
to ships provided with approved abatement technology capable of cleaning
emissions to a marine distillate fuel equivalent standard.
For example, SCR, Exhaust gas scrubber etc.
Two alternatives:
ECA(Sox-P) - Ships designed to only operate machinery components used in port on marine distillate fuel. i.e. compliance with EU low sulphur directive (Aux.engines and Boilers).
ECA(Sox-A) - Ships designed to operate all machinery components on marine
distillate fuel. i.e. compliance with MARPOL Annex VI for ECA’s after 1st July 2015
(Aux.engines, Boilers and Main engine).
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28 January 2013
GENERAL - SOx Emission Control Areas
19
Day 1
Day 2
200 km
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28 January 2013
Low sulphur fuel
A fuel change-over manual is to be developed.
The machinery components and fuel piping systems are subject to a functional test
using low viscosity marine distillate fuel.
The function test is to include a verification of the feasibility of the ships’ fuel
change-over procedures.
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28 January 2013
SYSTEMS AND ARRANGEMENTS –
Capacity of Storage tank The vessel shall be arranged with minimum one dedicated storage tank for each (e.g. low and/or high sulphur) marine distillate fuel grade carried.
Tanks for storage of marine distillate fuel shall not be located adjacent to heated tanks
unless the calculations required in B101 confirm that viscosity in way of machinery
components (including fuel oil pumps) is not below that specified in Sec.1 A201.
MGO Serv . TK
MGO Storage TK
HFO Bunker TK
22
Not be located adjacent to heated tanks
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28 January 2013
Fuel Oil System Arrangements
Calculations shall be performed to confirm that the viscosity of the marine distillate fuel in way of machinery components (including fuel pumps for marine distillate fuel) is not lower than that specified.
The calculations shall indicate viscosity as well as temperature.
Calculations shall be carried out for the operational loads as well as during change-over from residual oil to marine distillate fuel and vice-versa.
The calculations shall take into account the environmental conditions
Table B2 Ambient reference conditions for machinery
Parameter Value
Total barometric pressure 1 bar Ambient air temperature 45°C Relative humidity of air 60% Sea water temperature 32°C
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28 January 2013
Fuel oil change-over manual
An approved fuel oil change-over manual shall be available onboard and shall
consist of three parts as specified below:
Part I shall cover procedures for safe and efficient change-over from marine
distillate to residual oil and vice versa for all relevant machinery components and associated piping systems.
Part II shall cover calculations of change-over time to ensure that the fuel oil being
consumed by machinery components has a sulphur content not exceeding 0.10%.
This part is only relevant for vessels where the piping system for residual oil and
marine distillate fuel are common.
Part III shall include the following:
- Contingency procedures in case of poor marine distillate fuel quality, or incompatibility between marine distillate fuel and
residual oil
- Contingency procedures are also to be developed for failures due to vapour lock (gasification) in the event of improper
change-over sequence to distillate fuel oil
- Procedures for maintaining machinery readiness for emergency departures with marine distillate fuel - Methods for monitoring cylinder condition and injection pump internal leakage after switching from residual oil to marine
distillate fuel
- Procedures for onboard testing of compatibility between residual oil and marine distillate fuel.
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28 January 2013
MACHINERY COMPONENTS
The manufacturer of machinery components shall declare that the machinery
component (main engine(s), auxiliary engines, boiler(s) and any fuel oil pump) is capable
of continuous operation on marine distillate fuel for the minimum number of operating
days.
The manufacturers’ declarations and required detailed information is subject to approval.
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28 January 2013
Scrubber regulations
Revised Guidelines for Exhaust Gas Cleaning Systems MEPC.184(59) adopted
July 2009, now including changes to requirements for monitoring and discharge of wash water.
The guideline offers two alternative compliance schemes:
- Scheme A - EGCS system approval, survey and certification using parameter and emission checks.
- Each EGCS unit meeting the requirements should be issued with a SOx Emission Compliance
Certificate (SECC)
- Scheme B - EGCS system approval, survey and certification using continuous monitoring of SOX Emissions.
- Scheme B is a single unit approval only and requires continuous monitoring of: pH, PAH, turbidity (suspended particles), nitrates and temperature
All ships should have an SOx Emission Compliance Plan for the ship, approved
by the Administration.
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28 January 2013
Scrubber challenges
Scrubber technology proven on land, but still
early days at sea
Fairly high investment costs
Energy consumption
Capacity & scalability, physical footprint
Sludge production and disposal
Integration challenges: SOx scrubbers + NOx
SCR
Crew issues; training and qualification
How to prove compliance;
- Waste water discharge monitoring
- Performance monitoring & documentation
Manufacturer capacity as 2015 approaches?
28
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28 January 2013
Approval of documentation – class requirements for ships
provided with exhaust gas cleaning systems
Arrangement of exhaust gas system including exhaust gas cleaning units.
Arrangement of exhaust gas treatment fluid systems.
Arrangement of systems for prevention of overheating of exhaust gas cleaning
system components.
Arrangement of sea and fresh water systems for exhaust gas cleaning units.
Arrangement of waste and discharge systems from exhaust gas cleaning units.
Arrangement and details of By-pass valve/dampers.
Pressure drop analysis. Back pressure calculation.
Test procedure for quay and sea trial including tests addressing failure impact on
main functions.
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28 January 2013
Approval of documentation – requirements for ships
provided with exhaust gas cleaning systems contd.
Where DNV is authorized to issue the IAPP certificates:
For Sox
- Operation Manual - SOx Emission Compliance Plan (SECP)
- Operation Manual - Exhaust gas cleaning system technical manual (ETM).Scheme
A or B as applicable
- Operation Manual - Onboard Monitoring Manual (OMM)
- EGC Record book or Electronic Logging System
- Test procedure for sea trial according to the requirements of MEPC 184(59)
- Other Required documentation according to MARPOL Annex VI with amendments
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28 January 2013
Exhaust Gas Cleaning Systems (EGCS)
Limited testing and operational experience with the use of scrubbers
Operational challenges reported
Several types:
- Open loop wet system: MES, Krystallon, Aalborg, Ecospec
- Uses seawater directly followed by filtration. Treated water discharged to sea
- Closed loop wet system : Wartsila scrubber, Clean Marine
- Uses freshwater with alkaline additives (NaOH). More complex system able to
hold water in port
- Dry scrubber. Couple Systems - Utilises lime granulates.
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28 January 2013
Sea water scrubbing
Seawater washing of exhaust gases is a well-known method, which is commonly
used at onshore installations
Seawater washing is a simple and well-proven technology for exhaust gas sulphur
removal. Applications of this technology have been used in inert gas plants for ships for the past 20 years
For marine engines, several types of equipment that can be installed
For sulphur removal, an efficiency of some 90% is achievable
However, in restricted waters with heavy traffic, cleaning the water from the sea
water scrubber may be required to reduce the concentration of sulphur in the seawater.
This is also covered by the regulation of SOx emission in MARPOL Annex VI where
it is state:
- 'Waste streams from the use of such equipment shall not be discharged into enclosed ports or harbours and estuaries unless it can be thoroughly documented that such waste streams have no adverse impact on such ecosystems based upon criteria provided by the Port State authorities.'
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28 January 2013
Open loop, seawater scrubbers
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Scrubber systems
342
Cloud chamber SOX scrubber
Advanced Clean-up Technologies Inc
EcoSilencer® Sea water scrubbing
Marine Exhaust Solutions
Sea water scrubber + hydro cyclone
Hamworthy Krystallon
Advanced Vortex Chamber
Klaveness Group Clean Marine
DryEGCS
Couple Systems GmbH
EGCSCNOx
Ecospec
SOx scrubber + NaOH
Wärtsilä
Exhaust gas scrubber
Aalborg Industries
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28 January 2013
Hamworthy Krystallon – seawater scrubber
Open loop system has been installed on
Holland-America’s ‘Zeendam’ with installed engine power 21 MW.
Able to remove 98% Sox and 85% PM
Investment: 2.5-4 mill $
Linea Messina 45K DWT Ro-Ro (Jan.2011) has 5 scrubbers for each of (4x2MW) engines & boiler. All in funnel. Payback time claimed: 2 years.
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28 January 2013
Tri-Mer Corp. - Cloud Chamber Scrubber
Removal average efficiency: SO2 -99%, PM – 98%
Barge or quey based scrubber used in harbours or at anchorages
36
A. Pre-conditioning chamber – removes particles >10 um B. Positively charged claud generation chamber
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28 January 2013
Alfa Laval Aalborg hybrid system – Pure SOx
SOx removal rate >98%
Traps up to 80% of PM
Operates on SW in open sea and on FW in low alkaline
waters and harbours
Power consumption: approx. 1,5% of engine power
Operational weight: 35 tonnes (20MW), 18 t (8MW)
Dry weight : 25 tonnes (20MW), 15 tonnes (8MW)
Payback time claimed: 1,2 – 10 years on fuel cost saving
More than 1000 hours of operation
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28 January 2013
Aalborg scrubber installation - example
38 Investment: 2-2.5 M$; OPEX ~1.5 – 2% of added fuel cost
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28 January 2013
Wärtsilä SOx scrubber
Closed loop freshwater system with addition of alkalinity (NaOH).
Main stream scrubber – one unit for each engine, not suitable for boilers. Need for holding tanks
Integrated scrubber for several combustion units. Wet sump in the srubber – no process tank, small pump
Prototype installed on the tanker “Suula”.
Sox reduction: 99%
PM reduction: 30-60%
Payback time 2-3 years
Sludge can be conducted to the other
engine room sludge and disposed in
port.
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28 January 2013
Klaveness Invest AS - Clean Marine AS
Exhaust Gas Cleaning System (EGCS) based on what is described as the “Advanced Vortex Chamber
(AVC) principle”. Serves simultaneously several combustion units.
The first ocean going unit entered into service on a Klaveness bulk carrier BARU in June 2009 – 10MW.
Cyclone technology to ensure close turbulent contact and reaction between wash water (sea or fresh water) and the flue gas with possible addition of alkaline agent. A PM trapping mechanism is in place.
A spray of seawater and caustic soda
(NaOH, 50% aqueous solution) into
the exhaust gas flow is regulated
automatically based on the feedback
from the emission monitoring system,
which analyses the SO2/CO2 relation.
Payback time is in the range 1-6 years
depending on trading area. For
continued operation inside ECAs it may
be just a few months.
>98% SOx trapping
Power consumption: abt 2%
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28 January 2013
The Marine Exhaust Solutions -MES EcoSilencer ®
Reduce SO2 exhaust emissions by up to 90 %
Mixes the hot exhaust gas in a turbulent cascade with seawater.
One EcoSilencer® is provided for each diesel engine.
After scrubbing process, the scrubbing water is pumped out from each EcoSilencer® through a water filtration plant where it passes through a series of primary and secondary hydro cyclones.
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28 January 2013
CSNOX system - Ecospec
Open loop system installed onboard 100,000 ton oil tanker
99% SO2, 77% CO2 and 66% NOx removal
The CSNOX uses Ultra Low Frequency (ULF) waves to treat electromagnetically water that reacts with the exhaust gas
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28 January 2013
Couple Systems GmbH - DryEGCS
Reduction of Sulphur (99% SOx), Particles (98% PM)
Dry Scrubber (Chemisorption) with Ca(OH)2 (lime – Calcium Hydroxide Granulate). SOx reacts chemically, producing gypsum disposed ashore
Pilot-Installation on MS Timbus MAK 3,6 MW at 2009
43
Granulate silo
Reactor
Screw conveyor
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28 January 2013
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Cumulated costs for 100% ECA operation
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28 January 2013
Scrubber / fuel change economy
The initial price of the scrubber is assumed to be <170 EUR/kW for retrofit and large
installations. It may go down to 120 EUR/kW for small ships and newbuildings.
Sample costs of scrubbers would be around:
- 3mln EUR for a tanker
- 9mln EUR for a large container ship and
- 0,5ml EUR for a small dry cargo ship
Opex for scrubbers equals to 1-3% Capex. It may reach 0.8 EUR/MWh for a small
ship, 0.5 EUR/MWh for medium and 0.3 EUR/MWh for a large vessel.
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28 January 2013
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