Material Safety Data Sheet

Issuing Date 27-Jun-2011 Revision Date 13-Jun-2011 Revision Number 1

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name MITSUBISHI Li-Mn Button Cell CR2025 Recommended Use Lithium Primary/Metal Batteries.

Supplier Name GUANGZHOU TIANQIU ENTERPRISE CO., LTD.

Supplier Address 9/F TianQiu Building No.16-30, He Yi Rd., San Yuan Li Ave., GuangZhou China GUANGZHOU

GUANDONG 510410 CN

Supplier Phone Number Phone:8620-13825131170 Fax:8620-36323339

Contact Phone8615989631997 Supplier Email [email protected] Supplier Contact Name WEI SHAOFENG Company Emergency Phone

Number

8620-13825131170

2. HAZARDS IDENTIFICATION

Potential Health Effects

Principle Routes of Exposure Eye contact. Skin contact. Acute Toxicity

Eyes May cause irritation

Skin No known effect based on information supplied.

Inhalation No known effect based on information supplied May be harmful if inhaled Ingestion No hazard from product as supplied

Chronic Effects No known effect based on information supplied May cause adverse effects on the bone marrow and blood-forming system

Aggravated Medical Conditions

None known Central nervous system. Blood disorders. Kidney disorders. Respiratory disorders. Central Vascular System (CVS).

Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects

Environmental Hazard See Section 12 for additional Ecological information. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

.

Chemical Name CAS No Weight-%

Iron 7439-89-6 30-60

Manganese dioxide 1313-13-9 10-30

Propylene carbonate 108-32-7 3-7

CAUTION

Emergency Overview

This product is an article. No exposure to hazardous chemicals is expected to occur during intended product use. Misuse of the product may result in exposure to hazardous chemicals.

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Polypropylene 9003-07-0 1 - 5

Ethylene glycol dimethyl ether 110-71-4 1 - 5

Graphite 7782-42-5 1 - 5

Lithium 7439-93-2 1 - 5

Perchloric acid, lithium salt 7791-03-9 1 - 5

Polytetrafluoroethylene 9002-84-0 0.1 - 1

5. FIRE-FIGHTING MEASURES

Flammable Properties May re-ignite after fire is extinguished.

Flash Point Not determined.

Suitable Extinguishing Media Dry chemical, soda ash, lime or sand. DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire burn. Move containers from fire area if you can do it without risk.

This product contains a Class 1 Oxidizer as defined by the Uniform Fire Code

Unsuitable extinguishing media DO NOT USE WATER OR FOAM.

Hazardous Combustion Products Carbon oxides.

Explosion Data

Sensitivity to Mechanical Impact No.

Sensitivity to Static Discharge No.

Specific Hazards Arising from the Chemical Produce flammable gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or

explosively on contact with water. May be ignited by heat, sparks or flames. Some are transported in highly flammable liquid. Runoff may create fire or explosion hazard.

Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

4. FIRST AID MEASURES

General Advice In case of rupture. Remove and isolate contaminated clothing and shoes.

Eye Contact In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.

Inhalation Move victim to fresh air. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.

Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Drink plenty of water.

Notes to Physician Keep victim warm and quiet.

_____________________________________________________________________________________________ Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to

protect themselves and prevent spread of contamination.

NFPA Health Hazards 1 Flammability 0 Stability 0 Physical and Chemical Hazards

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7. HANDLING AND STORAGE

Handling In case of rupture. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing.

Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch or walk through spilled material. Stop leak if you can do it without risk. DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. Environmental Precautions Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material.

Methods for Containment Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Dike for later disposal; do not apply water unless directed to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry.

Methods for cleaning up Use personal protective equipment as required. Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. Take up mechanically, placing in appropriate containers for disposal. Avoid generation of dust. Clean contaminated surface thoroughly. Other Information DO NOT GET WATER on spilled substance or inside containers.

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9. PHYSICAL AND CHEMICAL PROPERTIES

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Manganese dioxide 1313-13-9 TWA: 0.02 mg/m3 _Mn TWA: 0.1 mg/m3 _Mn (vacated) Ceiling: 5 mg/m3 Ceiling: 5 mg/m3 _Mn IDLH: 500 mg/m3 _Mn TWA: 1 mg/m3 _Mn STEL: 3 mg/m3 _Mn Graphite 7782-42-5

TWA: 2 mg/m3 _{respirable fraction all} forms except graphite fibers

TWA: 15 mg/m3 _{total dust synthetic} TWA: 5 mg/m3 _{respirable fraction}

synthetic

(vacated) TWA: 2.5 mg/m3 _respirable dust natural

(vacated) TWA: 10 mg/m3 _{total dust} synthetic

(vacated) TWA: 5 mg/m3 _respirable fraction synthetic TWA: 15 mppcf natural

IDLH: 1250 mg/m3 TWA: 2.5 mg/m3 _{respirable dust}

ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health

Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).

Engineering Measures Showers

Eyewash stations Ventilation systems Personal Protective Equipment

Eye/Face Protection Tight sealing safety goggles

Skin and Body Protection No special protective equipment required

Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required Hygiene Measures When using do not eat, drink or smoke. Regular cleaning of equipment, work area and

clothing is recommended. Avoid contact with skin, eyes or clothing. Wash hands before breaks and immediately after handling the product. Keep away from food, drink and animal feeding stuffs.

Appearance Silver. Odor No data available.

Odor Threshold No information available Physical State Solid

pH No information available

Flash Point No information available Autoignition Temperature No information available Decomposition temperature No information available Boiling point / boiling range No information available Melting Point/Range No information available

Water Solubility Insoluble in water Solubility No information available. Evaporation Rate No information available Vapor pressure

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No data available Vapor density No data available

Flammability Limits in Air No information available Explosion Limits No information available

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11. TOXICOLOGICAL INFORMATION

Product Information Product does not present an acute toxicity hazard based on known or supplied information. LD50 Oral VALUE mg/kg (rat) Estimated

Chronic Toxicity

Chronic Toxicity No known effect based on information supplied. May cause adverse effects on the bone marrow and blood-forming system.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical Name ACGIH IARC NTP OSHA

Polypropylene Group 3

Polytetrafluoroethylene Group 3

IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans

Target Organ Effects Blood. Central Nervous System (CNS). Central Vascular System (CVS). Kidney. Respiratory system.

13. DISPOSAL CONSIDERATIONS

Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.

10. STABILITY AND REACTIVITY

Conditions to Avoid None known. Hazardous Decomposition Products Carbon oxides.

Hazardous Polymerization Hazardous polymerization does not occur.

12. ECOLOGICAL INFORMATION

The environmental impact of this product has not been fully investigated. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to

Microorganisms

Daphnia Magna (Water Flea)

Iron 96h LC50: = 13.6 mg/L

(Morone saxatilis) Propylene carbonate 72h EC50: > 500 mg/L

(Desmodesmus subspicatus) 96h LC50: > 1000 mg/L (Cyprinus carpio) 96h LC50: = 5300 mg/L (Leuciscus idus) EC50 > 10000 mg/L 17 h 48h EC50: > 500 mg/L

Chemical Name Log Pow

Manganese dioxide <0

_____________________________________________________________________________________________ Contaminated Packaging Dispose of contents/containers in accordance with local regulations

California Hazardous Waste Codes 181

Chemical Name California EHW California Carc California Hazardous

Waste

California Waste - Part 2

Lithium Corrosive Ignitable Reactive Corrosive Ignitable Reactive

14. TRANSPORT INFORMATION

Note: The transportation of primary lithium cells and batteries is regulated by the International Civil Aviation Organization, International Air Transport Association, International Maritime Dangerous Goods Code and the US Department of Transportation. The batteries must meet the following criteria for shipment: 1. Air shipments must meet the requirements listed in Special Provision A45 of the International Air Transport Association Dangerous Goods Regulations. 2. Meet the requirements for the US Department of Transportation listed in 49 CFR 173.185. 3. The transport of primary lithium batteries is prohibited aboard passenger aircraft. Refer to the Federal Register December 15, 2004 (Hazardous Materials; Prohibited on the Transportation of Primary Lithium Batteries and Cells Aboard Passenger Aircraft; Final Rule)

Lithium batteries shipped as "Lithium batteries", "Lithium batteries packed with equipment", or "Lithium batteries contained in equipment" may not be classified as "Dangerous Goods" when shipped in accordance with "special provision A45 of IATA-DGR" or "special provision 188 of IMO-IMDG Code"

Emergency Response Guide Number

138

DOT NOT REGULATED

TDG Not regulated

MEX Not regulated

ICAO Not regulated

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IATA Not regulated

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15. REGULATORY INFORMATION

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name CAS No Weight-% SARA 313 - Threshold

Values %

Manganese dioxide 1313-13-9 10-30 1.0

Ethylene glycol dimethyl ether 110-71-4 1 - 5 1.0

SARA 311/312 Hazard Categories

Acute Health Hazard No

Chronic Health Hazard Yes

Fire Hazard No

Sudden release of pressure hazard No

Reactive Hazard No

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)

This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act:

Chemical Name CAS No Weight-% HAPS data VOC Chemicals Class 1 Ozone

Depletors

Class 2 Ozone Depletors

Manganese dioxide 1313-13-9 10-30

Propylene carbonate 108-32-7 3-7 Group V

Ethylene glycol dimethyl ether

110-71-4 1 - 5 Group I

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

US State Regulations California Proposition 65

This product contains the following Proposition 65 chemicals

Chemical Name CAS No California Proposition 65

Lead 7439-92-1 Carcinogen

Developmental Female Reproductive

Male Reproductive

Cadmium and compounds (as Cd) 7440-43-9 Carcinogen

Developmental Male Reproductive

Mercury 7439-97-6 Developmental

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16. OTHER INFORMATION

Issuing Date 27-Jun-2011

Revision Date 13-Jun-2011

Revision Note No information available. Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material

designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet

Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Manganese dioxide X X X

Ethylene glycol dimethyl ether

X X X X X

Graphite X X X

Lithium X X X

International Regulations

Mexico - Grade Minimum risk, Grade 0

Chemical Name Carcinogen Status Exposure Limits

Manganese dioxide Mexico: TWA= 0.2 mg/m3

Graphite Mexico: TWA= 2 mg/m3

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS Hazard Class D2B - Toxic materials

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Chemical Name NPRI

Manganese dioxide X

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