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Arsenic Contamination in South

Arsenic Contamination in South

-

-

east Asia Region :

east Asia Region :

TECHNOLOGIES FOR ARSENIC MITIGATION

TECHNOLOGIES FOR ARSENIC MITIGATION

M.

M.

Feroze

Feroze

Ahmed

Ahmed

Ph.D., FIE, MASCE

Professor of Civil/Environmental Engineering

Bangladesh Univ. of Eng. & Tech., Dhaka, Bangladesh

Outline of Presentation

Outline of Presentation

O

O

Arsenic Contamination: Global and South

Arsenic Contamination: Global and South

-

-

east Asia Scenario

east Asia Scenario

O

O

Arsenic Mitigation Water Supply Technologies

Arsenic Mitigation Water Supply Technologies

O

O

Arsenic Detection and Measurement Technologies

Arsenic Detection and Measurement Technologies

O

(2)

Worldwide Arsenic Contamination of Groundwater

WAIRAKI. NEW ZEALAND RONPHIBUN DISTRICT. THAILAND

RED RIVER DELTA VIETNAM TAIWAN KYUSHU. JAPAN KAMCHATKA INNER MONGOLIA. CHINA SHANXI PROVINCE. CHINA XINJIANG PROVINCE. CHINA BENGAL DESTA. WEST BENGAL. BANGLADESH GREAT HUNGARIANPLAIN. HUNGARY. ROMANIA LAVRION PENINSULA. GREECE SOUTH-WEST ENGLAND MASSIF CENTRAL. FRANCE ASHANTI REGION. GHANA ZIMBABWE SOUTHAFRICA CHACO-PAMPEAN PLAIN. ARGENTINA NORTH-WEST ARGENTINA ANTOFAGASTA CHILE DOMINICA HALIFAZ. NOVA SCOTIA EL SALVADOR ZIMAPAN VALLEY LAGUNERA DISTRICT. MEXICO WESTERN U.S.A. ALEUTIAN ISLANDS FAIRBANKS. ALASKA BRITISH COLUMBIA YELLOWSTONE PARK NORTH-CENTRAL MEXICO Arsenic-affected aquifers

Arsenic related to mining operations Geothermal waters

(3)

O

O

Treatment of Arsenic Contaminated Water;

Treatment of Arsenic Contaminated Water;

O

O

Alternative water Supply Options

Alternative water Supply Options

O

O

Treatment of surface water

Treatment of surface water

O

O

Deep

Deep

tubewell

tubewell

;

;

O

O

Dug/Ring well;

Dug/Ring well;

O

O

Rainwater harvesting;

Rainwater harvesting;

0

0

Piped Water Supply adopting any of the above

Piped Water Supply adopting any of the above

Technological Option

Technological Option

ARSENIC MITIGATION WS TECHNOLOGIES

(4)

Major Treatment Processes

Major Treatment Processes

O

O

Oxidation and Sedimentation

Oxidation and Sedimentation

O

O

Coagulation and Filtration

Coagulation and Filtration

O

O

Aluminium

Aluminium

Alum

Alum

O

O

Iron salts

Iron salts

O

O

Naturally Occurring Iron

Naturally Occurring Iron

O

O

Sorptive

Sorptive

Filtration

Filtration

O

O

Activated

Activated

Alumina

Alumina

O

O

Granulated Ferric Hydroxide/Oxide

Granulated Ferric Hydroxide/Oxide

O

O

Metallic Iron/ Iron Ore

Metallic Iron/ Iron Ore

O

O

Synthetic Composite Active Materials

Synthetic Composite Active Materials

O

O

Ion Exchange

Ion Exchange

O

O

Membrane Filtration

Membrane Filtration

O

O

Nano

Nano

Filtration

Filtration

O

O

Reverse Osmosis

Reverse Osmosis

TREATMENT OF ARSENIC CONTAMINATED WATER

(5)

Processes Mainly Based on Oxidation

Processes Mainly Based on Oxidation

Passive Sedimentation ( Bashi Pani)

In-situ Oxidation

Solar Oxidation (SORAS)

Advantage

Advantage

No Chemical added

Limitations

Limitations

• Not reliable

• Reduction is variable

• Reduction is dependent on

alkalinity, presence of

adsorbing substances like iron,

aluminum etc.

TREATMENT OF ARSENIC CONTAMINATED WATER

TREATMENT OF ARSENIC CONTAMINATED WATER

Inlet to TW Tray (75 mm slope)

Section X-X

1400 mm 1100 mm 600 mm 35 mm GI pipe 150 mm Wash out 75 mm

(6)

Coagulation, Co

Coagulation, Co

-

-

precipitation And Adsorption Processes

precipitation And Adsorption Processes

--

Household Units

Household Units

Flexible Plastic Pipe Cloth Screen Sand Filter PVC Slotted Screen Top Bucket Bottom Bucket

Bucket Treatment

Unit

Stevens Institute

Technology

Chemicals Mixing stick Main bucket Interior bucket Slits Outlet with cloth filter Plastic pipe to deliver treated water Filte r sand Transfer of chemical mixed water

TREATMENT OF ARSENIC CONTAMINATED WATER

(7)

Tubewell Attached

Unit

Fill and Draw Units

Cover Impeller Tank Sludge withdrawal pipe Handle Filtration unit Gear system Treated water

A - Mixing; B - Flocculation; C - Sedimentation; D - Filtration (Up-flow)

A B

C

D

B

Coagulation, Co

Coagulation, Co

-

-

precipitation And Adsorption Processes

precipitation And Adsorption Processes

--

Community Units

Community Units

TREATMENT OF ARSENIC CONTAMINATED WATER

(8)

y = 0.8718x + 0.4547 R2 = 0.6911 20 30 40 50 60 70 80 90 100 20 30 40 50 60 70 80 90 100 Iron Removal , % Arsenic Removal ,%

Correlation Between

Arsenic and Iron Removal

Pump

Back washing

Water supply

Overhead

water tank

Chlorination

Pump

Aeration

Inlet pipe

Filter bed

As-Fe Removal plant at

For Urban Water Supply

Aeration, Adsorption and Filtration Process

- Small Town Water Supply

TREATMENT OF ARSENIC CONTAMINATED WATER

(9)

Iron Coated Crushed Brick Particles Perforated Plate Covered Cloth Flexible Water Delivery Pipe Treated Water in a Bucket Support Lid

Shapla Filter

Activated Alumina Oxidation Sedimentation Unit Sand Filtratio n Unit

BUET Activated Alumina

Sorptive Filtration-

Household Type

Arsenic

Contaminated

Tubewell Water

Arsenic safe

Water

Adsorbing

Media

SAFI Filter

Raw Water Filter Media 1 Sand, IronFillings & Brick Chips Filter Media 2 Sand, Charcoal & Brick Chips Filtered Water

Sono 3-Kalshi

TREATMENT OF ARSENIC CONTAMINATED WATER

(10)

Tubewell

Outlet (Treated Water) Inlet

( Water from Tubewell)

Aqua-Bind Arsenic Aqua-Bind Filter Media Lift Pump Bucket Containing Treated Water Deliver Hose Pipe Raising Hose

Pipe

Apyron ARU

Alcan Enhanced Activated Alumina

Sorptive Filtration-

Community Type

Contaminated

Water Inflow Treated Water Outflow

Gravel Filter Bed Adsorption Tower

SIDKO(Bangladesh)

Pal Tockner (India) ARU

Chlorine Source

Sieve

Stabilizer

Stone Chips

Stand

Resin Column

(Ion Exchanger)

Column

Head

Tap

Tetrahedron Ion Exchange Unit

TREATMENT OF ARSENIC CONTAMINATED WATER

(11)

Raw Water

Clear

Water

Water from

Pond

Filter

Sand

Coarse

Aggregate

Under Drainage

System

Handpump for water

Supply to Filter

Slow Sand Filter (Pond Sand Filter ( PSF))

Slow Sand Filter (Pond Sand Filter ( PSF))

ALTERNATIVE WATER SUPPLY OPTIONS

ALTERNATIVE WATER SUPPLY OPTIONS

(12)

Multi

Multi

-

-

Stage Roughing and Slow Sand Filters

Stage Roughing and Slow Sand Filters

Raw Water Clear Water

Filter

Sand

Coarse

Aggregate

Under Drainage

System

To Overhead

Reservoir

X

X

X

X

Hydraulic Grade Line

X

ALTERNATIVE WATER SUPPLY OPTIONS

ALTERNATIVE WATER SUPPLY OPTIONS

(13)

ALTERNATIVE WATER SUPPLY OPTIONS

ALTERNATIVE WATER SUPPLY OPTIONS

--

Surface Water Treatment

Surface Water Treatment

Source of Surface Water

Storage/ Sedimentation

Mixing Flocculation

Coagulants

Secondary

Sedimentation

Filtration Disinfection

Chlorine

StorageTank

To Distribution

(14)

Silty clay

Arsenic Contaminated

Shallow Aquifer (Sandy

silt

)

Arsenic-safe

Deep Aquifer

(Fine to medium sand)

Water Table

Clay Seal

Clayey Layer

Strainer

Sand Trap

Relatively Impermeable

Hand Pump

Manually Operated Deep Tubewell

Requirements

O

Availability of deep

aquifers separated from

shallow contaminated

aquifers by relatively

impermeable layers.

O

The annular space of bore

holes of the deep tubewells

is required to be sealed at

the level of impermeable

strata to avoid percolation

of arsenic contaminated

water.

--

DEEP TIBEWELL

DEEP TIBEWELL

ALTERNATIVE WATER SUPPLY OPTIONS

(15)

(a) Conventional Dug Well

(b) Well with Sanitary Protection

--

Dug/Ring Wells

Dug/Ring Wells

ALTERNATIVE WATER SUPPLY OPTIONS

(16)

--

Rainwater Harvesting

Rainwater Harvesting

Basic Requirements

Adequate Rainfall

-Intensity of Rainfall

-Reliability of Rainfall

Distribution of Rainfall

Suitable Catchment area

Storage Tank

Operation and Maintenance

ALTERNATIVE WATER SUPPLY OPTIONS

(17)

Monthly Distribution of

Rainfall of an Average

Year

500

400

300

200

100

00

J

F M A M J J A S O N

D

J

F M A M J J A S O N

D

Rainfall Intensity, mm/Month

Month

Catchment Area

The minimum catchment area,

A (

m

2

)

required for collection of

rainwater for

N

number of person to

be supplied with

q

litre per capita

per day is :

A = 0.365 q N / ( C I )

Rainwater Storage Tank

The minimum volume of storage tank

V

( m

3

) required

V = 0.365 f q N

Where

f

is the fraction of available

rainwater required to be stored

--

Rainwater Harvesting

Rainwater Harvesting

ALTERNATIVE WATER SUPPLY OPTIONS

(18)

COST OF WATER SUPPLY BY ARSENIC REMOVAL TECHNOLOGY

COST OF WATER SUPPLY BY ARSENIC REMOVAL TECHNOLOGY

Technology/Process

Technology/Process

Type

Type

Cost, $/m

Cost, $/m

3

3

Oxidation-Sedimentation Urban WS

0.05

-Filtration

Community

0.10

Coagulation-Sedimentation

Household 1.70

-Filtration

Community

1.21

Sorptive Filtration

O

Iron Fillings

Household

0.24

O

Iron Coated brick Chips

Household

0.73

O

Granulated Ferric Hydroxide

Community

1.37

O

Synthetic Active Materials

Household

1.84

O

Activated Alumina

Household

2.30

Community

3.24

O

Ion Exchange

Community

3.79

(19)

COST OF WATER SUPPLY BY ALTERNATIVE OPTIONS

COST OF WATER SUPPLY BY ALTERNATIVE OPTIONS

* With full development potentials

Technology

Rainwater Harvesting

Manually operated

Deep Tubewell

Pond Sand Filter

Dug/Ring Well

Conventional

Treatment

Ground Water Based

Piped Water Supply

Capital

Recovery

Cost, $/M

3

1.830

0.146

0.143

0.249

0.122

0.358

O and M

Cost,

$/M

3

0.304

0.005

0.018

0.007

0.231

0.049

Total Unit

Cost,

$/M

3

2.134

0.151

0.028*

0.161

0.066*

0.256

0.072*

0.353

0.407

0.091*

(20)

ARSENIC DETECTION AND MEASUREMENT TECHNOLOGY

ARSENIC DETECTION AND MEASUREMENT TECHNOLOGY

Laboratory Analysis Methods

Laboratory Analysis Methods

Techniques MDL ,µ/L System Cost Comments

(1000 US$)

AAS-HG

0.05-2

20- 100

Single Element

AAS-GF

1 - 5

30 - 100

Single Element

ICP-AES

35 - 50

60 - 200

Multi-element

ICP-MS

0.02 - 1

150 - 400

Multi-element

ASV

0.1 - 2

25 - 50

Free Dissolved As

SDDC

1 - 10

2 - 10

Single Element

(21)

ARSENIC DETECTION AND MEASUREMENT TECHNOLOGY

ARSENIC DETECTION AND MEASUREMENT TECHNOLOGY

Field Measurement Methods (Some Common Field Test Kits)

Field Measurement Methods (Some Common Field Test Kits)

Kit Type

Kit Type

Country of Range of Cost/Kit Cos

Country of Range of Cost/Kit Cos

t/Test

t/Test

Origin

Origin

µg/L US $ US $

µg/L US $ US $

E-Mark Kit

Germany

5-500

HACH Kit

USA

10-500

Quick

TM

USA

10-1000

AIID&PH Kit

India

Yes/No

NIPSOM Kit

Bangladesh

10 - 700

GPL Kit

Bangladesh

10-2500

Asenator

Austria/UK

<10-500 1,250/185 1 - 2

40

-100 / Field Test Kit

0.4

(22)

THANK YOU

THANK YOU

For Your Kind Attention

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