MATERIAL SAFETY DATA SHEET
Identity:
ACRALOCK® SA1-05 A & SA1-15 A (Adhesive Component A)
Included in following stock codes: AA3001, AA3003, AA3010, AA3011, CA6005, CA6010 SECTION I: PRODUCT AND COMPANY IDENTIFICATION Trade Name: ACRALOCK® SA1-05 A & SA1-15 A (Component “A” Adhesive)
General use: Adhesive
Chemical Family: Acrylate
Manufacturer Phone Number for
Information
Address Date Prepared
Engineered Bonding Solutions, LLC 321-747-0160 801 Marina Road Titusville, FL 32796 11/1/2011 Transportation Emergency Phone
CHEMTREC: 800-424-9300 Transportation Emergency Phone Outside USA
CHEMTREC: 703-527-3887
SECTION II: HAZARDS IDENTIFICATION
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects
Inhalation: Vapors may cause headaches, nausea, dizziness and respiratory tract irritation. May be harmful Inhaled.
Skin contact: Causes skin irritation. May cause allergic skin reaction. May be harmful if absorbed through skin.
Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation.
Ingestion: May cause gastrointestinal tract irritation if swallowed. May be harmful if swallowed. Existing conditions aggravated by exposure: Eye, skin and respiratory disorders.
This material is considered hazardous by the OSHA Hazard Communications Standard (29 CFR 1910.1200) See Section 11 for additional toxicological information
SECTION III: COMPOSITION/IDENTITY INFORMATION ON INGREDIENTS Emergency Overview
PHYSICAL STATE: Liquid HEALTH: *2
COLOR: White, Opaque FLAMMABILITY: 3
ODOR: SHARP PHYSICAL HAZARD: 1
PERSONAL PROTECTION: MSDS SECTION VIII
WARNIING: FLAMMABLE LIQUID AND VAPOR. CAUSES EYE AND RESPIRATORY TRACT IRRITATION.
Constituent CAS No. Approx %
Elastomeric Polymers NON-HAZ 5.0 -30.0
Methyl Methacrylate 80-62-6 50.0 - 60.0
Methacrylic Acid 79-41-4 < 5.0
Malelic Acid 110-1-67 <2.0
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances, see section XV. SECTION IV: FIRST AID MEASURES
GENERAL INFORMATION:
General first aid, rest, warmth and fresh air. Take off all contaminated clothing immediately. Do not give victim anything to drink if they are unconscious. Get medical attention if any discomfort continues. Show this safety data sheet to the doctor in attendance. INHALATION:
Place unconscious person on the side in the recovery position and ensure breathing. If respiratory problems arise, get artificial respiration/oxygen. Get medical attention if any discomfort continues.
INGESTION:
Immediately rinse mouth and drink plenty of water or milk. Keep person under observation. Do not induce vomiting. If vomiting occurs, keep head low. Transport immediately to hospital and show this safety data sheet to the doctor in attendance.
SKIN CONTACT:
Immediately remove contaminated clothing. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. Consult a physician if necessary.
EYE CONTACT:
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention promptly if symptoms occur after washing.
SECTION V: FIRE FIGHTING MEASURES
Flash Point °F: 52.7 °F (11.5°C) Method: TCC
Autoignition temperature: Not available
Explosive limits in air (percent) : – Lower: 1.7 Upper: 12.5 EXTINGUISHING MEDIA:
Water spray, fog or mist, foam, carbon dioxide or dry powder, dry chemicals, sand, dolomite, etc. DO NOT USE WATER JET as extinguisher as this will spread the fire.
SPECIAL FIRE FIGHTING PROCEDURES:
If large amounts of material are involved, evacuate the area and fight fire from safe distance. Do not enter confined space without full bunker gear. Firefighters should wear self-contained breathing apparatus and protective clothing. Cool fire exposed containers with water spray. Keep run-off water out of sewers and water sources. Dike for water control.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Fire causes formation of toxic gases. Sealed containers at elevated temperatures may rupture explosively due to polymerization. Vapors are heavier than air and may travel to the source and flash back. Burning liquid may float on water. Personnel in vicinity and downwind should be evacuated.
HAZARDOUS PRODUCTS OF COMBUSTION:
SECTION VI: ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Wear protective clothing as described in Section VIII of this safety data sheet. ENVIRONMENTAL PRECAUTIONS:
Do not let product enter drains. Avoid subsoil penetration. Spillage or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.
CONTAINMENT AND CLEAN UP:
Keep combustibles away from spilled material. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb in vermiculite, dry, sand or other suitable material and then place into containers. Wash thoroughly after dealing with a spillage.
SECTION VII: HANDLING AND STORAGE USAGE PRECAUTIONS:
Do not taste or swallow. Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Wash thoroughly with soap and water after using and particularly before eating, drinking, smoking, applying cosmetics, or using toilet facilities. Launder contaminated clothing and protective gear before reuse. Discard contaminated leather articles. Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Vapors are heavier than air and may spread near ground to sources of ignition.
STORAGE PRECAUTIONS:
Flammable / combustible – keep away from oxidizers, heat and flames. Keep in a cool ventilated place at or below 80oF (27oC) in accordance with shelf life policy, without direct exposure to sunlight. Keep container closed and follow NFPA regulations. Maintain air space in storage containers, inhibitor requires oxygen contact to function. Vapors are uninhibited and may form polymers in vents or flame arrestors, resulting in blockage of vents. Check inhibitor levels after 6 months and return to original level. STORAGE CLASS:
Flammable liquid storage.
SECTION VIII: EXPOSURE CONTROL / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed.
Constituent ACGIH TLV OSHA PEL AIHA WEEL Other Limits
Elastomeric Polymers None None None None
Methyl Methacrylate 50 ppm 100 PPM STEL (Sensitizer) 100 ppm (410mg/m3) TWA None 50 ppm
Methacrylic acid 20 ppm None None None
Maleic acid None None None None
EYE AND FACE PROTECTION:
Safety glasses with side shields. Wear coverall chemical splash goggles and face shield when eye and face contact is possible. SKIN PROTECTION:
For prolonged or repeated skin contact, use suitable protective gloves. Use protective gloves made of: Neoprene, Nitrile, Rubber (natural or latex).
RESPIRATORY PROTECTION:
confined space, for poorly ventilated areas and for large spill clean-up sites. Consult with an industrial hygienist to determine the appropriate respiratory protection for your specific use of this material.
OTHER PROTECTION:
Chemical resistant apron, protective suit, safety shoes / boots. PROCESS CONDITIONS:
Provide eyewash station. ENGINEERING MEASURES:
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined workplace exposure limit is not exceeded. All handling to take place in well-ventilated area.
HYGIENE MEASURES:
DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using this material, do not eat, drink or smoke. Handle in accordance with good industrial hygiene and safety practices.
SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Viscous liquid
COLOR: White
ODOR: Solvent, Sharp
Physical State: Paste
pH: Not available
Vapor Pressure: Not available
Vapor Density: Heavier than air
Evaporation Rate: Faster than either
SOLUBILITY: Insoluble in water
BOILING POINT (C°): 50-150
SPECIFIC GRAVITY: .95 – 1.10 @ 25°C
FLASH POINT (C°) 11.5°C (52.7°F) TCC
based on monomer composition
SECTION X: STABILITY AND REACTIVITY STABILITY:
Stable under normal temperature conditions. CONDITIONS TO AVOID:
Avoid exposure to high temperatures and direct sunlight. Avoid heat, sparks and open flames or other sources of ignitions. Areas of low oxygen supply. Avoid mixing A and B components in large masses >100g unless you intend to use immediately.
HAZARDOUS POLYMERIZATION:
May polymerize as a result of heat or upon depletion of inhibitor. INCOMPATIBLE MATERIALS:
Incompatible with strong oxidizing agents, reducing agents, acids, bases, azo-compounds, catalytic metals (such as; copper, iron) halogens and peroxides.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition or combustion may liberate Irritating organic vapors such as; carbon oxides and other toxic gases or vapors.
GENERAL INFORMATION:
Prolonged and repeated contact with solvents over a long period may lead to permanent health problems. INHALATION:
In high concentrations, MMA vapors may irritate throat and respiratory system and cause coughing. In higher concentrations 5-100 times the TLC, vapors are narcotic and may cause headache, fatigue, dizziness and nausea.
INGESTION:
Gastrointestinal symptoms, including upset stomach. SKIN CONTACT:
Dermatitis. May cause sensitization by skin contact. Maleic acid is a skin and mucous membrane irritant EYE CONTACT:
Irritation of eyes and mucous membranes. Maleic acid is a severe eye irritant.
Acute inhalation effects: LC50 (rat): No data available. Toxicity of MMA at 5-100 times TLV from respiratory and gastrointestinal irritation, lung damage and nervous system.
Subchronic effects: Repeated inhalation exposure of 5-100 times the TLV include lung damage, pulmonary irritation, liver changes, eye irritation, nasal tissue changes, upper respiratory irritation.
Carcinogenicity, teratogenicity, and mutagenicity: Possible reproductive hazard based on animal data.
Hazardous Component Health Effects/Target Organs
Elastomeric Polymers n/d
Methyl Methacrylate Allergen, Irritant, Kidney, Liver, Mutagen, Nervous System, Respiratory
Methacrylic acid Corrosive, Irritant, Allergen
Maleic acid Corrosive, Irritant
n/d- Not determined
SECTION XII: ECOLOGICAL INFORMATION
Ecotoxicity: Not available
SECTION XIII: DISPOSAL CONSIDERATIONS Waste management recommendations:
Waste to be treated as controlled wastes. Dispose of as special waste in compliance with local and national regulations. Disposal methods:
Dispose of waste and residues in accordance with local authority requirements. Make sure containers are empty before discarding (explosion risk). Absorb in vermiculite or dry sand, dispose in licensed special wastes. Incineration is preferred method of disposal.
SECTION XIV: TRANSPORT INFORMATION U.S. Department of Transportation Ground (49CFR):
Proper shipping name: Adhesives*
Hazard Class: 3
UN Number: 1133
Packing group: II
Other: Containers < 30 liters are PG III
International Air Transportation (ICAO/IATA):
Proper shipping name: Adhesives*
Hazard Class: 3
Identification number: UN 1133
Packing group: II
Exceptions: May qualify as Consumer Commodity or Limited Quantity”, ID8000, (Not more than
500ml) Water Transportation (IMO/IMDG):
Proper shipping name: Adhesives*
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
*Depending on the size and type of container, this material may be reclassified as “consumer commodity, ORM-D” for shipments within the United States, or “Limited Quantity” elsewhere. Refer to the appropriate regulation.
SECTION XV: REGULATORY INFORMATION U.S. Federal Regulations
TSCA 8 (b) Inventory status: All components are listed or are exempt from listing on the Toxic Substance Control Act Inventory.
TSCA 12(b) Export Notification: None above reporting de minimus
CERCLA/SARA Section 302 EHS: None above reporting de minimus
CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Fire
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting
requirements of section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40 CFR 372).
CERCLA Reportable quantity: Methyl methacrylate (CAS# 80-62-6) 1,000lbs (454kg) Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substance List.
WHMIS hazard class: B.2, D.2.B
SECTION XVI: OTHER INFORMATION Hazardous Materials Identification System (HMIS) ratings:
Health = 2 Flammability = 3 Reactivity = 2
The information and recommendations in this document are based on the best information available to us at the time of
