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Exploring chemoselective S to N acyl transfer reactions in synthesis and chemical biology

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Figure

Figure 1 | Sa terminal glycine and a lysine residue (-to-N acyl transfer reactions utilized in nature
Figure 2 | Mechanisms of synthetic amide-forming reactions involving S-to-N acyl transfer
Figure 3 | Native Chemical Ligation-Desulfurization. (a) Structures of thiol containing amino acids investigated for NCL-desulfurization (b) Methods fordesulfurization of thiol groups following NCL.
Figure 4 | Auxiliary Mediated Ligation (AML). Structures of common auxiliaries investigated for AML.
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