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Minerals as a source of novel Li-ion battery electrode materials

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Figure

Fig. 1. The structure of spinel AB 2 O 4  (magnetite,  hausmannite) shown for the Li-insertion material LiMn 2 O 4 ,  with Mn octahedral coordination (green) and Li-ions (yellow)
Fig. 2. A comparison of the LiFePO 4  (olivine) and Li 2 FeSiO 4  (orthosilicate) structures; the latter clearly exhibits a significantly  higher concentration of lithium ions and more available ion-diffusion pathways
Fig. 4. A schematic illustration of the effect on the charging  curve for Li 2 FeSiO 4  (green line) of 50% substitution of Fe

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