MATERIAL SAFETY DATA SHEET
1. Chemical Product and Company IdentificationProduct Name: Zinc Chloride Dry Battery – SUM2 Manufacturer: Chung Pak Battery Works Ltd.
Address: 7/F., Chung Pak Commercial Blog., 2 Cho Yuen St., Yau Tong Bay, Kowloon, Hong Kong Telephone: (00852)27171338
Effective Date: 2011/01/01
Note: Blank space are not pemmited. If any item is not applicable, or no information is available, the space must be marked to indicate that.
2. Composition/Information on Ingredients
Designation SUM2
Hazardous Components CAS No. wt%
Zinc (Zn) 7440-66-6 17.85
Manganese Dioxide (MnO2) 1313-13-9 27.65
Zinc Chloride (ZnCl2) 7646-85-7 6 Carbon (C) 7782-42-5 9.26 Mercury (Hg) 7439-97-6 Љ0.0001 Cadmium (Cd) 7440-43-9 Љ0.0003 Lead (Pb) 7439-92-1 Љ0.0530 3. Hazards Identification
Routes of Entry: Not applicable under normal conditions
Health Hazards: In case of leakage, will be cause itchy and/or chemical burns when direct contact with electrolyte
Hazards to Environment: Not applicable Fire and Explosion Hazards: Not applicable 4. First-aid Measures
Skin Contact: If exposed to a leaking battery, remove contaminated clothing. Wash exposed areas with plenty of water and soap. If irritation occurs, consult a physician.
Eyes Contact: If a battery is leakage and materials contact eyes, flush immediately with running water for at least 15 minutes. Consult an ophthalmologist at once.
Inhalation: If vapor from vented or leaked batteries are inhalation, move to fresh air and get medical attention.
Ingestion: Get immediately medical attention, do not induce vomiting or give a liquid to unconscious person.
5. Fire Fighting Measures
Hazard Characteristic: Not available
Hazards Expose to Combustion Products: In case of fire, carbon dioxide, carbon monoxide and other toxic organic substances will be generated. Do not inhale fumes and smoke.
Zinc Chloride Dry Battery Page 2 of 4 Date Prepared: 2011/01/01
Special Fire Fighting Procedures: Fire fighters should wear self-contained breathing apparatus. 6. Accidental Release Measures
Precautions: Avoid direct contact with the leaking or ruptured batteries. Avoid short circuit.
Methods for clean up: Care for well-ventilated conditions. Recycle or dispose of the materials in an appropriate way.
7. Handling and Storage
Precaution: Handing and transfer the products carefully, make sure the packing always in good condition. Damaged packing may cause batteries contact together, in this case batteries may short circuit or improperly connected, it cause batteries venting, leaking or exploding.
Storage: Store in a dry, cool and well-ventilated area. 8. Exposure Control/Personal Protection
Exposition/Technical Measures: Atmospheric vapor concentrations must be minimized by adequate ventilation.
Protection of Hands, Eyes, and Skin: None required under normal use conditions. When handling leaking batteries, use gloves and wear safety glasses to protect hands, eyes and skin.
General Safety and Hygiene Measures: Use only as directed. 9. Physical and Chemical Properties
Physical State and Appearance: Solid, Cylinder
Odor: Odorless pH: N/A
Melting Point (к): N/A Specific Gravity (H2O=1): N/A
Boiling Point (к): N/A Vapor Density (Air=1): N/A
Vapor Pressure (kPa): N/A Heat of Combustion (kJ/mol): N/A
Critical Temperature (к): N/A Critical Pressure (MPa): N/A
Partition Coefficient: N/A Flash Point (к): N/A
Ignition Temperature (к): N/A Explosion Limit % (V/V): N/A
Solubility in Water: N/A Solubility in Other Solvents: N/A
10. Stability and Reactivity Stability: Stable
Incompatibility: Reactive with acids and alkalis
Condition to Avoid: Avoid shorting, mechanical & thermal abuse Hazardous Polymerization: Will not occur
Hazardous Decomposition: None 11. Toxicological Information
Note: Since the materials in this battery are sealed in the can, the potential for exposure to the components of the battery is negligible, when the battery is used as directed. However technical or electrical abuse of the battery may result in the release of battery contents.
Toxicity to Animals: Not applicable Chronic Effects on Human: Not applicable
12. Ecological Information
This product has not been tested for environmental effects. 13. Disposal Consideration
Dispose in accordance with Federal, States and local regulations 14. Transport Information
Zinc Chloride Dry Battery is unregulated for purpose of transportation by U.S. Department of Transportation (DOT), International Civil Aviation Administration (ICAA), International Air Transport Association (IATA) and the International Maritime Dangerous Goods regulations (IMDG). The only DOT requirement for shipping these batteries is Special Provision 130 which states: “Batteries, dry, are not subject to the requirements of this subchapter only when they are offered for transportation in a manner that prevents the dangerous evolution of heat (for example, by the effective insulation of exposed terminals).” The only requirements for shipping these batteries by ICAO and IATA is Special Provision A123 which states: “An electrical battery or battery powered device having the potential of dangerous evolutions of heat that is not prepared so as to prevent a short-circuit (e.g. in the case of batteries, by the effective insulation of exposed terminals; or in the case of equipment, by disconnection of the battery and protection of exposed terminals) is forbidden from transportation. “The International Maritime Dangerous Goods Code (IMDG) regulate them for ocean transportation under Special Provision 304 which says: “Batteries, dry, containing corrosive electrolyte which will not flow out of the battery if the battery case is cracked are not subject to the provisions of this Code provided the batteries are securely packed and protected against short-circuits. Examples of such batteries are : alkaline-manganese, zinc-carbon, nickel metal hydride and nickel-cadmium batteries”
The requirements for shipping these batteries, in all modes of transportation, are that they be separated from each other to prevent short-circuits and to prevent movement that could lead to short-circuits. Products must also be packed in strong packaging that can withstand the rigors normal to transportation.
15. Regulatory Information
Main Chemical Limitation of EEC, RoHS, TCLP & US Public Law
Chemical EEC (2006_66_EC) wt% RoHS** (2002_95_EC) mg/kg TCLP (Toxic Characteriestics Leaching Procedure) mg/kg US Public Law*** mg/cell Mercury (Hg) <0.0005%* 1000mg/kg 0.2 25 Cadium (Cd) <0.002% 100mg/kg 1 - Lead (Pb) <0.4% 1000mg/kg 5 - Notes:
* Button cells with a mercury content of no more than 2% by wegiht is exempted (Article 4, 2006/66/ec)
Zinc Chloride Dry Battery Page 4 of 4 Date Prepared: 2011/01/01
Commission in May 2005, the battery does not apply to RoHS Directive.
*** According to the US Mercury-Containing Battery Management Act. Public Law No.104- 142 (1996) SEC 204 Zinc-Carbon battery should not contains mercury that was intentionally introduced.
16. Other information
Do not heat or dispose of in fire. Do not recharge or disassemble the battery. Notice to reader:
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Chung Pak, Chung Pak will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product, which may not be covered by this MSDS. The user is responsible for full compliance.
Manganese Dioxide Battery
Mercury and Lead Free Battery
Golden Power Corporation (HK) Ltd.
Ref.No.:GPSDS-Manganese Dioxide Battery
Mercury and Lead Free-2016A
Material Safety Data Sheet
Section 1 - Product and Company Identification
Product Name Sizes: Date of preparation:
Manganese Dioxide Battery Mercury and Lead
Free
All Dec. 20, 2016Company: Telephone Numbers:
Golden Power Corporation (HK) Ltd. (852) 3125 2288
Address (Number, Street, City, State, and ZIP Code): Fax Numbers:
Flat C, 20/F., Block 1, Tai Ping Industrial Centre, 57 Ting Kok Road, Tai Po, N.T., Hong Kong
(852) 3125 2000 / 3125 2001 Section 2 - Hazards Identification
We would like to inform our customers that these batteries are exempt articles and are not subject to the 29 CFR 1910.1200 OSHA requirements, Canadian WHMIS requirements or GHS requirements.
Emergency Overview
OSHA Hazards-not applicable Target Organs-not applicable GHS Classification-not applicable
GHS Label Elements, including precautionary Statement-not applicable Pictogram-not applicable
Signal words-not applicable Hazard statements-not applicable
Precautionary statements-not applicable Section 3 - Composition/Information on Ingredients
Chemical Name Common Name and Synonyms
CAS # Content (Wt %)
Manganese Dioxide MnO2 1313-13-9 20-30 Iron Fe 7539-89-6 45-70 Zinc Zn 7440-66-6 5-10 Potassium Hydroxide KOH 1310-58-3 1-5
Water, paper, other - - Balance *Source: OSHA 29 CFR 1910.1000 Table Z-1, 2 or 3 11-01-2012
The batteries are exempt articles and are not subject to the OSHA Hazard Communication Standard Requirement. This sheet is provided as technical information only. The information and recommendations set forth are made in good faith and are believed to be accurate as of the date of preparation. However, GoldenPower makes no warranty expressed or implied.
Manganese Dioxide Battery
Mercury and Lead Free Battery
NA=Not Applicable
Page 2 / 4
Golden Power Corporation (HK) Ltd.
Ref.No.:GPSDS-Manganese Dioxide Battery
Mercury and Lead Free-2016A
Section 4 - First Aid Measures
THRESHOLD LIMIT VALUE (TLV) AND SOURCE:
C5.0 (Mn, TWA)EFFECTS OF OVEREXPOSURE:
None
(see section 2 and 4 for fire or rupture situations)EMERGENCY FIRST AID PROCEDURES:
Skin and Eyes:In the event that battery ruptures, flush exposed skin with flowing lukewarm water for a minimum of 15 minutes. Get immediate medical attention for eyes. Wash skin with soap and water.
Swallowing:
If you or your doctor suspects that a battery has been ingested-for assistance in the US call the NATIONAL BATTERY INGESTION HOTLINE any time at (202) 625-3333: in Canada call 416-813-5900.
Section 5- Fire Fighting Measures
FLASH POINT: NA
LOWER (LEL): NA
FLAMMABLE LIMITS IN AIR (%): NA
UPPER (UEL): NA
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical or Foam Extinguisher.
AUTO-IGNITION: NA
SPECIAL FIRE FIGHTING PROCEDURES: As with any fire, wear self-contained breathing apparatus to avoid inhalation of hazardous decomposition products (See section 2).
SPECIAL FIRE OR EXPLOSION HAZARDS: Like any sealed container, battery cells
may rupture when exposed to excessive heat; this could result in the release of corrosive materials.
Section 6 - Accidental Release Measures
TO CONTAIN AND CLEAN UP LEAKS OR SPILLS: In the event of a battery rupture, prevent skin contact and collect all released material in a plastic lined metal container. REPORTING PROCEDURE: Report all spills in accordance with Federal, State and Local reporting requirements.
Manganese Dioxide Battery
Mercury and Lead Free Battery
Golden Power Corporation (HK) Ltd.
Ref.No.:GPSDS-Manganese Dioxide Battery
Mercury and Lead Free-2016A
Section 7 - Handling and Storage
Store batteries in a dry place. Storing unpackaged cells together could result in cell shorting and heat build-up. Do not recharge. Do not puncture or abuse.
Section 8 - Exposure Controls, Personal Protection
RESPIRATORY PROTECTION (SPECIFY TYPE): NA
VENTILATION: Local Exhaust: NA
Mechanical (General): NA
Special: NA
Other: NA
PROTECTIVE GLOVES: NA
EYE PROTECTION: NA
OTHER PROTECTIVE CLOTHING: NA
Section 9 - Physical/Chemical Characteristics
Boiling Point @ 760 mm Hg
(°C): NA Percent Volatile by Volume (%): NA Vapor Pressure (mm Hg @
25°C): NA Evaporation Rate (Butyl Acetate = 1): NA Vapor Density (Air =
1): NA
Physical
State: NA
Density (grams/cc): NA Solubility in Water (% by Weight): NA
pH: NA
Appearance and
Odor: NA
Section 10 - Stability and Reactivity
STABLE OR UNSTABLE: Stable
INCOMPATIBILITY (MATERIALS TO AVOID): NA
HAZARDOUS DECOMPOSITION PRODUCTS: When heated, battery may emit hazardous vapor of
KOH/NaOH.
DECOMPOSITION TEMPERATURE (0°F): NA
HAZARDOUS POLYMERIZATION: Will Not Occur
CONDITIONS TO AVOID: Avoid electrical shorting, puncturing or deforming
Section 11 - Toxicological Information
INGREDIENT
NAME
CAS
# % TLV*/**TWA
Manganese Dioxide 1313-13-9 30-40 C5.0 (Mn, TWA)
Zinc 7440-66-6 10-15 5 mg/m3 (as ZnO Fume)
Sodium Hydroxide and
Potassium 1310-73-2, 1310-58-3 10-15 Solution Not Listed
Hydroxide, 30-35% mixture
Metal shell, plastic, other --- 30-40 None Established
Manganese Dioxide Battery
Mercury and Lead Free Battery
NA=Not Applicable
Page 4 / 4
Golden Power Corporation (HK) Ltd.
Ref.No.:GPSDS-Manganese Dioxide Battery
Mercury and Lead Free-2016A
Section 12 - Ecological Information
Consumers should dispose of discharged batteries through waste disposal services or legitimate collection outlets. Those collecting batteries should follow state and federal regulations. Partially discharged damaged batteries can overheat and cause fires in the presence of other combustible materials.
Section 13 - Disposal Considerations
Always comply with Federal, state or local requirements. For additional information on disposal/reclaim options, visit:
http://www.nema.org/Policy/Environmental-Stewardship/Documents/Companies%20Clai
ming%20to%20Recycle.MARCH2005.pdf
Section 14 - Transportation Information
TRANSPORTATION-SHIPPING: These are considered dry-cell batteries and they are non-dangerous goods for transportation. These batteries must be packed in a way to prevent short circuits or generation of a dangerous quantity of heat.
USDOT – See Special Provision 130. IMO/Ocean – Not Listed.
ICAO/IATA – See Special Provision A123. This special provision also states to put the words “not restricted” and “special provision A123” on the air waybill when an air waybill is issued. Section 15 - Regulatory Information
SARA 313: Notification is not required because these products are article(s) that do not release a covered toxic chemical under the normal conditions of storage, use, or handling.
Section 16.Other information
The date of preparation of the SDS or the last change to it
If you want further information, please contact Golden Power sales representative.
NOTICE: The information and recommendations set forth are made in good faith and are believed to be accurate at the date of preparation. (GoldenPower) makes no warranty expressed or implied.