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Inorganic sulfur nitrogen compounds : from gunpowder chemistry to the forefront of biological signaling

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Figure

Fig. 1StructuresofS-nitroso-N-acetylpenicillamine(SNAP)andS-nitroso-t-dodecanethiol (t-DodecSNO).
Fig. 2Reactivity of HSNO formed by the reaction of RSNO and HS−:isomerization, homolysis, nucleophilic attack and transnitrosation.

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