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Delignification of Kraft-AQ Southern Pine Pulp with Hydrogen Peroxide Catalyzed by Mn(IV)2-Me4DTNE

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Figure 0.2. Chemical structure of commonly used mediators, 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonicacid) diammonium salt (ABTS) (2), and 3-hydroxy-
Figure 0.3. Chemical structure of [LMn(IV)(µ-O)3Mn(IV)](ClO4)2 (4), and [LMn(III)(µ-O))(µ-OAc)Mn(IV)](ClO) (5), where L=1,2-bis(4,7-dimethyl-1,4,7-triazacy-
Figure 1.1. The disappearance of the 1-(3,4-dimethoxyphenyl)ethanol (8) upon theoxidation with hydrogen peroxide catalyzed by [LMn(IV)(µ-O)Mn(VI)](ClO) (4) at
Figure 1.2. The disappearance of the 1-(3,4-dimethoxyphenyl)-1-propene (10hydrogen peroxide without catalyst at 60)upon the oxidation with hydrogen peroxide catalyzed by [LMn(IV)(µ-O)3Mn(VI)](ClO4)2 (4) at I 30oC, N 40oC, X 50oC, L 60oC
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Comparison of Catalyzed and Uncatalyzed Delignification H and 13 C Correlation NMR Spectroscopy Process Simulation of Hydrogen Peroxide Delignification Catalyzed by Mn(IV) 2 Me 4 DTNE Using WinGEMS4

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