Ami
Ami
d
de
e
By
By
Mint, Fahsai, Yuyu, Ice, Aom
Mint, Fahsai, Yuyu, Ice, Aom
1107
1107
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Ami
Amin
n
e
e
●
●
derives from ammonia
derives from ammonia
●
●
H in ammonia is replaced by Hydrocarbon group
H in ammonia is replaced by Hydrocarbon group
one at a time
one at a time
Structure of Amine:
Structure of Amine:
Examples:
Examples:
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Classes
Classes
Primary
Primary
Only one H is
Only one H is
replaced by R
replaced by R
Secondary
Secondary
Two H are
Two H are
replaced by R
replaced by R
Tertiary
Tertiary
Three H are
Three H are
replaced by R
replaced by R
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Physical
Physical
Properties:
Properties:
➔➔
Normal state : liquid or gas
Normal state : liquid or gas
➔
➔
pH : mostly base
pH : mostly base
➔
➔
Melting points : higher than alkane
Melting points : higher than alkane
➔
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Reaction and Utilization or
Reaction and Utilization or
Application:
Application:
●
●
Reaction of amine with copper(II)
Reaction of amine with copper(II)
ions : give off
ions : give off
tetraamminediaquacop
tetraamminediaquacop
per(II)
per(II)
ions
ions
●
●
Reaction of amine with nitrous acid
Reaction of amine with nitrous acid
:
:
○
○
If react with primary, the
If react with primary, the
Reaction:
Reaction:
●
●
Conversion from amine to amide
Conversion from amine to amide
with carboxylic acid
with carboxylic acid
●
●
Reaction of amines and water :
Reaction of amines and water :
ammonia produce ammonium
ammonia produce ammonium
ions and hydroxide ions from
ions and hydroxide ions from
hydrogen ion
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Reaction and Utilization or
Reaction and Utilization or
Application:
Application:
●
●
Methylamine
Methylamine
○
○
Solvent similar to
Solvent similar to
ammonia
ammonia
○ ○Refining
Refining
● ● ● ●Chloramine
Chloramine
○ ○disinfectant
disinfectant
Utilization and Application:
Utilization and Application:
●
●
Ethanolamine
Ethanolamine
○
○
Production of detergents,
Production of detergents,
emulsifiers, polishes,
emulsifiers, polishes,
chemical immediates, etc.
chemical immediates, etc.
○
○
Alkalinization of water in
Alkalinization of water in
stream cycles of power
stream cycles of power
plant
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Ami
Amid
d
e
e
●
●
derives from carboxylic acids.
derives from carboxylic acids.
OH of -COOH group is replaced with -NH2
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Physical
Physical
Properties:
Properties:
➔➔
Normal state : solid except
Normal state : solid except
methanamide, which is liquid
methanamide, which is liquid
➔
➔
pH : neutral
pH : neutral
➔
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Reaction and Utilization or
Reaction and Utilization or
Application:
Application:
●
●
Dehydration : Removing water
Dehydration : Removing water
from mixture of amide and
from mixture of amide and
Reaction:
Reaction:
●
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Reaction and Utilization or
Reaction and Utilization or
Application:
Application:
●
●
Dimethylformamide
Dimethylformamide
○
○
Solvent and Catalyst
Solvent and Catalyst
Utilization and Application:
Utilization and Application:
●
●
Sodamide
Sodamide
○
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Naming : Amine
Naming : Amine
●
●
End with -mine
End with -mine
●
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