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Pyrazolidinones as templates in asymmetric catalysis

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Figure

Figure 1.1: Simplified organocatalytic cycles.
Figure 1.6: Hajos-Parrish-Eder-Sauer-Wiechert reactionIn one of the first examples of ‘modern’ organocatalysis, the intermolecular variant of this reaction, between acetone again used as the catalyst (Table 1.1)
Table 1.1: Aldol reaction catalysed by (S)-proline 14
Table 1.2: Organocatalytic conjugate addition of malonates to �,�-unsaturated aldehydes (Ar = 3,5-(CF3)2-C6H4)
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