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https://www.journals.elsevier.com/journal-of-materials-research-and-technology Availableonlineatwww.sciencedirect.com

Original

Article

Microstructural

characterisation

and

mechanical

properties

of

dissimilar

AA5083-copper

joints

produced

by

friction

stir

welding

Gihad

Karrar

a,∗

,

Alexander

Galloway

a

,

Athanasios

Toumpis

a

,

Hongjun

Li

b

,

Fadi

Al-Badour

c

aDepartmentofMechanical&AerospaceEngineering,UniversityofStrathclyde,GlasgowG11XJ,UK

bFacultyofMechanicalEngineeringandAutomation,ZhejiangSci-TechUniversity,XiashaHigherEducationZone,Hangzhou310018,

PRChina

cMechanicalEngineeringDepartment,KingFahdUniversityofPetroleumandMinerals,Dhahran,31261,SaudiArabia

a

r

t

i

c

l

e

i

n

f

o

Articlehistory: Received10May2020 Accepted16August2020 Keywords: Intermetalliccompounds

Frictionstirwelding

Mechanicalproperties

Dissimilarjoining

AA5083

Commerciallypurecopper.

a

b

s

t

r

a

c

t

Thisworkaimstostudytheinfluenceofthetoolrotationalspeedandtooltraversespeed

ondissimilarfrictionstirbuttweldson3mmthickAA5083tocommerciallypurecopper

plates.Complexmicrostructureswereformedinthethermo-mechanicallyaffectedzone,

inwhichavortex-likepatternandlamellarstructureswerefound.Severalintermetallic

compoundswereidentifiedinthisregion,suchasAl2Cu,Al4Cu9andthesedevelopedan

inhomogeneoushardnessdistribution.Thehighestultimatetensilestrengthof203MPaand

jointefficiencyof94.8%wereachievedat1400rpmtoolrotationalspeedand120mm/min

traversespeed.Placingthesoftermaterial(aluminium)ontheadvancingsideproducedan

excellentmetallurgicalbondwithnorequirementfortooloffsetting.

©2020TheAuthors.PublishedbyElsevierB.V.Thisisanopenaccessarticleunderthe

CCBY-NC-NDlicense(http://creativecommons.org/licenses/by-nc-nd/4.0/).

1.

Introduction

Dissimilar aluminium/copper joints are commonly used

wherethereareadvantagesinpartiallyreplacingthecopper

withaluminiumforcertainengineeringapplicationssuchas

electricalconnectors,tubesofheatexchangers,transformer’s

foilconductorsandcapacitorfoilwindings[1–4].Thisislargely

drivenbythesimilaritiesintheelectricalpropertiesofeach

metal.Beyondthis,thereducedcostandthelowermassof

alu-miniumrendersitanattractivepartialsubstituteforcopper

Correspondingauthor.

E-mail:[email protected](G.Karrar).

[5–7].Incircumstanceswherethereisaneedtoweldthe

sub-stitutealuminiumparttopurecopper,significantchallenges

emergeasaresultofthedifferencesinchemicalcompositions

and the mismatch inthe physicaland mechanical

proper-ties ofeach metal[8–10]. Basedon therelativeadvantages

againstconventional fusionwelding processes, i.e.absence

ofporosity,solidificationcracking,oxidationandlower

dis-tortion[11–14],thefrictionstirwelding(FSW)techniquecan

replacetheconventionaljoiningmethodsduetoitscapability

toproducedefect-freeweldondissimilarmetalsandalloys

[15–17].

https://doi.org/10.1016/j.jmrt.2020.08.073

2238-7854/©2020 The Authors. Publishedby Elsevier B.V. This is anopen access articleunder the CC BY-NC-ND license (http://

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Ouyanget al. [18] studiedthe microstructuralevolution

duringfrictionstir buttwelding ofAA6061-T6tocopper,in

whichthelatterwasplacedonthe advancingside(AS).As

ageneralnote,theyclaimedthatFSWofaluminiumto

cop-perwasdifficultduetotheformationofbrittleintermetallic

compounds(IMCs)whichledtopoormechanicalproperties.

Intheirstudies[18],thedissimilarmechanicallymixedzone

i.e.stirzoneandthermo-mechanicallyaffectedzone(TMAZ)

exhibitedacomplexmicrostructurewithseveralIMCssuch

asAl2Cu,CuAlandAl4Cu9.Howeverdistinctive

microhard-nesslevelswereobservedatthestir zone,andtherewasa

lackoffurtherinvestigation onthe joint mechanical

prop-erties. Abdollah-Zadehet al. [19]studied the effectof tool

rotationalspeedandtooltraversespeedonthemicrostructure

andmechanicalpropertiesofthejointbyonlyconsideringthe

lapconfiguration.TheexistenceofAl2Cu,CuAland Al4Cu9

IMCswasalsoconfirmedasintheaforementionedstudy[18].

Thestudy[19]concludedthatasuitablerotationaltotraverse

speedratioresultedinmaximisingthejointmechanical

prop-erties.Furthermore,therelationshipbetweenIMCformation

andjointmechanicalstrengthhasbeeninvestigatedbyXue

etal.[20]atdifferenttooloffsets,toolrotationalandtraverse

speedsofdissimilarAA1060aluminiumtopurecopperjoints.

Noticeable improvements in the ultimate tensile strength

(UTS)wereobservedwhentheIMCthicknessincreased,

espe-cially at the interface between the aluminium base metal

andthestirzone.Theirfindings[20]wereinagreementwith

otherstudies [21–24],whereas otherpublishedwork [25,26]

proposedthatthejointmechanicalstrengthdependedonthe

volumefraction,geometryanddistributionoftheIMCs.

Anadditionalkeyfactorthataffectsthejointmechanical

propertiesinFSWofaluminiumtocopperistheplacementof

eachworkpiece[27].Numerousstudiesnotedthatdefect-free

buttjointsbetweenaluminiumtocoppercouldbeproducedby

placingthehardermaterial(copper)ontheAS[28–30].

Accord-ingtothesestudies[28–30],placingthecopperontheASleads

tosuitablemixingbetweenthealuminiumandcoppersinceit

iseasierforthesoftermaterial(aluminium)toflow.However,

tooloffsettingtowardseitherretreatingoradvancingsidewas

usuallyrequiredtoachievedefect-freejoints[31].Thevarious

rangesreportedforthetooloffsetsresultedinthis method

beingimpracticalforindustrialuse.

Incontrast,otherresearchersreportedthatsoundjoints

maybeobtainedbyplacingthesoftermaterial(aluminium)

onthe advancing side [32–35]. For example, Tanet al. [32]

successfullyjoined3mmthick5A02aluminiumtocopperby

placingthealuminiumontheadvancingsideandnegligible

tooloffsettowardstheadvancingside.Toolrotationalspeedof

1100rpmand20mm/mintooltraversespeedwerethe

weld-ingparametersthatresultedinahighUTSof130MPa(75.6%

jointefficiencyrelativetothealuminiumbasemetal).

Accord-ingtotheirfindings[32],thepresenceofathinandcontinuous

layerofIMCswasobservedatthealuminium/copperinterface.

TheformationoftheseIMCswasalsodetectedinsidethestir

zoneandresultedinaninhomogeneoushardness

distribu-tionacrosstheweld.Further,theynotedthatachanneldefect

developedatahighertooltraversespeedof40mm/min.

Despitethe advantageson thejoint mechanical

proper-ties when placing the softer material (aluminium) on the

advancing side, limited research has focusedon this

con-Table1–Chemicalcomposition(inwt.%)ofAA5083.

Si Mg Cu Mn Zn Ti Cr Fe

0.98 4.0 0.10 0.70 0.25 0.15 0.10 0.40

Table2–Chemicalcomposition(inwt.%)of commerciallypurecopper.

Cu Ag Fe Bi Sb As Pb S

Bal 0.035 0.05 0.001 0.002 0.002 0.005 0.005

Table3–Mechanicalpropertiesofbasemetals.

Materials Yield strength (MPa)

UTS(MPa) EL(%) Avg.HV

AA5083 163.97 225.66 67.57 70

Copper 257.26 273.66 114.14 90

Fig.1–Experimentalset-up.

figuration. Additionally, the relationship between the IMCs microstructureand themechanical propertiesrequires fur-ther investigations. In this paper, the influence of tool rotationalandtraverse speedonthejoint qualityhasbeen evaluatedwhenplacingthealuminiumontheadvancingside andwithout introducingthecomplexitiesoftooloffsetting. Using this configuration,threeparametersetsofrotational andtraversespeedwereemployedtoinvestigatethe relation-shipbetweenmicrostructureandmechanicalproperties.

2.

Experimental

programme

2.1. MaterialsandFSWdetails

AfullyinstrumentedHT-JM16×8/2staticgantryFSWmachine wasusedtobuttweld150×50×3mmthickAA5083to com-mercially purecopper plates along their lengths. Asimple highstrengthsteeltooldesignwasusedforwelding.Thetool pindiameter(Dp)andpinlength(plungingdepth,Pd)were 4.5mmand2.7mmrespectively,whiletheshoulder diame-ter (Ds)was 18mm.Thechemicalcompositions, aswellas themechanicalpropertiesofthetwomaterialsarepresented inTables 1,2and 3.A schematicillustrationofthe

exper-imental set-up is shown inFig. 1. After preliminary trials,

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Table4–SummaryoftheFSWprocessparameters.

TestNo. Rotational speed(rpm) Traverse speed (mm/min) ␻/␯ratio (rev/mm) 1 1000 80 12.5 2 1000 100 10 3 1000 120 8.3 4 1200 80 15 5 1200 100 12 6 1200 120 10 7 1400 80 17.5 8 1400 100 14 9 1400 120 11.7

material(AA5083)attheadvancingsidewith0mmtool off-set,therefore,themainpurposeofthisworkistooptimise theprocessparameterswhendifferentrotationalandtraverse speeds(␻/␯ratio)areused(Table4).DuringFSW,thetoolwas

tiltedbyanangleof2.8◦.

2.2. Metallographicexamination

Followingwelding,samplesweremetallographicallyprepared

usingstandardmetallographictechniques.Etchingwas

per-formedusingasolutionof1gofFeCl3,10mLHCl,and100mL

distilledwatertofirstrevealthecopperside,followingwhich

theAA5083sidewasetchedfor60sinasolutionconsistingof

1gNaCland50mLH3PO4dissolvedin125mLofethanol,

fol-lowedbya12sstepusingWecks’stint(4gofKMnO4and1gof

NaOHdissolvedin100mLofdistilledwater).Thereafter,each

etchedsamplewasexaminedwiththeaidofhigh-resolution

opticalmicroscopy.Interms ofcompositionalanalysisand

phaseidentification,energydispersivespectroscopy(EDS)and

X-raydiffraction(XRD)wereperformedatvariouslocationsof

theweldjoint.XRDwasperformedwitha40-mAoperating

current,40-Kvvoltageand1.5406-ÅCuK␣radiation.A

scan-ningrateof0.02deg./stepwithintherangeof20◦<2␪<100◦

wasusedthroughout.

2.3. Mechanicaltesting

Thejointmechanicalstrengthwasinvestigatedinaccordance

withASTM-E8,detailsofwhichareshowninFig.2.The

tech-niqueofhardnessmappingwasalsoemployedtoestablishthe

relationshipbetweenIMCs formationand jointmechanical

strength.

Fig.3–Effectoftoolrotationalandtraversespeedon macrostructure.

3.

Results

and

discussions

3.1. Weldappearanceandmacrostructure

Table5showsthetypicaltopsurfaceweldappearanceand

cross-sectionalmacrostructuresofAA5083tocopper

dissim-ilar metal FSWjoints atdifferent welding conditions. The

symbolsforeachdefecttyperelatetoFig.3.Asexpected,the

weld surfacequalityisindicativeofthe tendencyfor

volu-metric defectstodevelop[26]. For instance,excessiveflash

formation, as well as material discontinuity,will generally

suggestvolumetricdefects[29].Fig.3summarisestheeffect

oftoolrotationalandtraversespeedontheweldappearance

andmacrostructure,inwhichAA5083wasplacedontheAS

without tooloffset.When therotationalspeed variedfrom

1000 to1400rpmand the traverse speed wasin the range

of80–120mm/min,visuallyacceptableweldswithnosurface

defectswereobtainedatthefollowingspecificparametersets:

• Lowrotationalspeedlevelof1000rpmat100mm/minand

120mm/minweldingspeeds(10and8.3␻/␯ratio)i.e.test

no.2and3respectively.

• Intermediaterotationratelevelof1200rpmand80mm/min

(15␻/␯ratio).

• Highrotationratelevelof1400rpmforthetworangesofthe

weldingspeed80,and120mm/min(17.5,and11.7␻/␯ratio),

respectively.

Parameter sets outside the above conditions led to an

unevensurfaceandtheformationofdefectssuchas

macro-crackstowardstheretreatingside(copper,Fig.4(a)),cavities

withacertaindefectareaonthecross-sectionlessthan0.02

mm2(Fig.4(b)),voids(Fig.4(c))andtunneldefectsinwhich

Fig.2–(a)DimensionsofthetensilesampleasperASTME8standards.(b)Exampleofsamplesthroughthewelding directionat1000rpmand100mm/min.

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Table5–Weldappearanceandmacrostructureofdissimilarjoints(marksasinFig.3).

Symbol Defect AppearanceandMacrostructure Microstructure

None –

Crack Fig.4(a)

Cavity Fig.4(b)

Void Fig.4(c)

Tunnel Fig.4(d)

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Table6–EDSresultsatweldstirzoneofTestno.2. Position Al Cu Non equilibrium solidsolution 1 75.14 24.86 – 2 62.76 37.24 – 3 90.35 9.65 Al(Cu) 4 85.84 14.16 Al(Cu) 5 61.98 38.02 – 6 68.08 31.92 – 7 67.18 32.82 – 8 79.26 20.74 – 9 37.72 62.28 – 10 35.22 64.78 –

thedefectareawaslargerthan0.05mm2(Fig.4(d)).Dueto

theinappropriatematerialflow,thesetypesofdefectshave

previouslybeenreported[31], wherethecracksare usually

relatedtotheformationoflargeIMCparticles,cavities,voids

andtunneldefects.

3.2. Microstructuralanalysis

Theweldmechanicalintegrityisdirectlyrelatedtothestir

zonemicrostructure.Aclassical“onionring”structureis

com-monlyfoundinthestirzoneofsimilarmaterialFSWjoints

[23].IndissimilarmaterialFSWhowever,aswirl-likepattern,

bandedorlamellastructure,aswellasvortex-type

microstruc-tures, are formed in the stir zone, TMAZ and also in the

heat-affectedzone(HAZ)[31].Fig.5(a)representsanexample

ofatypicalcross-section ofAA5083(AS) tocopper

dissim-ilar metalFSW jointwelded at1000rpmand 100mm/min.

Towardsthealuminiumside(Fig.5(b&e)),relativelysmall

cop-perparticleswereobservedasregularlydistributedbetween

thealuminiuminterfacezoneand theuppersurfaceofthe

stir zone. Fig.5 (c&f) illustratethat atthe stir zone,larger

copper particles (fragments) were stretched and irregularly

distributedalongthestirzoneandtowardsthebottomofthe

interfacialregionbetweenthestirzoneandthecopperside.

Theirregularcopperparticlescreatedalamellastructureof

copperandaluminiumatthebottomoftheTMAZtowards

thecopperside(Fig.5(d&g)).

EDSanalysiswasperformedtorevealthevariationonthe

aluminiumandcoppercontentat1000rpm,100mm/minand

10␻/v(seeTestno.2ofTable4).ItcanberevealedfromFig.6

(a)andTable6thatgoodintermixingbetweenaluminiumand

copperwasachieved.Table6alsoshowsthepresenceof

dif-ferentaluminiumsolidsolutionsatthislowlevelofrotational

speed.Fig.6(e)presentsanexampleofhowtheEDS

analy-siswasperformedtocapturethevariationonthealuminium

andcoppercontent.Unetchedmicrostructuresforthe

distinc-tiveregionsfromFig.6(a):Al-stirzone(rectangulari),inside

thestirzone(rectangularii)aswellasCu-stirzone

(rectan-gulariii),arepresentedinFig.6(b),(c)and(d),respectively.

Thedarkshadedlayerssurroundingthecopperparticlesand

fragmentsdemonstratetheformationoftheAl/Cuintermixed

regionasshownbythearrows.Thisembeddedlayerwas

pre-viouslyreportedtoaccompanytheformationofAl/CuIMCs

[29]. Moderate stirring actionwas observed on the copper

particlesandfragments,whichindicatestheabsenceofthe

Table7–EDSresultsatweldstirzonecondition7.

Position Al Cu 1 76.5 23.5 2 71.7 28.3 3 55.27 44.73 4 62.62 37.38 5 67.38 32.64 6 33.72 66.28

composite-like structureunderthis condition. Additionally, detachedcopper piecesfailedtoreact withthe aluminium matrixontheadvancingsideresultingintheabsenceofany lamellaorbandedstructuresattheinterfacezone.

Across-sectionofanAA5083tocopperdefect-freejointata higherlevelofrotationalspeedisshowninFig.7(a),as-welded

at1400rpmand80mm/minwithAA5083onASandnotool

offset.Althoughthreedistinctiveregionscanstillbeobserved

acrossthe weldjoint,theseregionswerecompletely

differ-entfromtheexampleoflowerweldingspeed,i.e.1000rpm.

Thecomplexstructurehasformedinthealuminiumsideof

the interface and towardsthe stir zone asshownin Fig.7

(b&e).Copperfragmentswere detachedfromtheretreating

sideandstirredwiththealuminiummatrixtocreatethis

com-plexstructure.Ahigherheatinputisthereasonbehindthis

complexstructure,wherethestirringactionwasinsufficient

tocreatethisstructureatalower levelofrotationalspeed.

Evidenceoftherelationshipbetweentheheatinputandthe

plasticstirringactionwasalsoobservedinsidethestirzonein

Fig.7(c&f)andthisresultedintheswirlandvortex-like

struc-ture.Unlikeothers[33–35],placingthecopperontheretreating

sidewithouttooloffsetproducedawiderTMAZattheAl/Cu

interfaceasillustratedinFig.7(d&g).

Likewise,EDSwasappliedatdifferentpositionsontheweld

zone asillustrated inFig. 8(a),whereTable 7summarises

theelementalcompositionsatthesepoints,Fig.8(e)

demon-stratesanexample oftheseEDSpoints. Table7shows the

variationinAl/Cucontentsasaresultofgoodintermixingand

theabsenceofnon-equilibriumsolidsolutions.Anenlarged

viewofrectangle(i)inFig.8(a)isshowninFig.8(b).Acomplex

structurecanbedetectedfromtheunetchedmicrostructure

ofthisregion,andthechemicalcompositionsofpoints1and

2inTable6showslightvariationinthealuminiumandcopper

contents.Thecompositelikestructureattheupperregionof

theCu-stirzone(rectangle(ii))resultedintwodifferent

con-tentsofAl/CuasillustratedinFig.8(c)andTable7.Thehigher

heatinput(1400rpm)andthetoolstirringactionformed

sim-ilarvariationinAl/CuatthebottomofCu-stirzoneasshown

inFig.8(d)ofrectangle(iii).Thedarkshadedlayersthat

sur-roundedthecopperparticlesandaccompaniedtheformation

ofAl/CuIMCsareshownbythearrows.

3.3. Interfacialelementaldiffusion

ThekeyfactortocriticallyanalysingthejointqualityinFSW

of dissimilar aluminiumtocopper is bycharacterising the

structure of the interfacial region [31]. The elemental

dif-fusion andstructureisable toconfirmareliablejoint [20].

Fig.9(a)representsamagnifiedviewoftheinterfacialregion

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Fig.5–(a)Typicalcross-sectionofjointweldedat1000rpmand100mm/min.(b&e)interfacezonetowardsAA5083side. (c&f)stirzone.(d&g)interfacezonetowardsthecopperside.

1200rpmtoolrotationalspeedand80mm/mintoolwelding

speedasetchedbythealuminiumetchingsolution.

Contin-uouslayersofrefinedaluminiumgrainsareclearlyobserved.

Copperparticleswithdifferentsizesarediffusedalongwith

therefinedlayersofaluminiumasevidenceofgood

metallur-gicalbonding.Theresultantstirzone,asshowninFig.9(b),

elucidatesthatthecontinuousinterfaciallayersubsequently

leadstothelamellastructurethatsignificantlyimprovesthe

jointmechanicalstrength.

Theinterfacialregionformedacompositelikestructureas

aresultofincreasingtheheatinput,asshowninFig.9(c)of

testno.7at1400rpmtoolrotationalspeedand80mm/mintool

weldingspeed.Ithasbeenreportedpreviously[28]thatthe

resultantjointstrengthisgreatlyimprovedbythisstructure.

AsithasbeendemonstratedinFig.9(d),thiscompositelike

structurewasalsodominantinsidethestirzone.

3.4. Intermetallicphases

XRD analysiswas performedthrough the cross-sections to

identifythephasespresentinthestirzone.Fig.10presents

theXRDpatternsofthreetypicaldefect-freejointsoftestno.

2,4and7ofTable4.ThedominantIMCsonthestirzoneof

AA5083andcopperareAl2CuandAl4Cu9,andtheseare

con-firmedfromthethreepatterns,apartfromthefactthatAlCu

wasonlydetectedundertestno.7.Accordingtotheabove

microstructureanalysisoftestno.2and7,itcanbe

estab-lishedthatthenatureandquantityofIMCsareaffectedbythe

weldconditions.Peakintensitychangesbyvaryingthe

weld-ing conditions, where1000rpmand 100mm/min, 1200rpm

and80mm/minand1400rpmand80arethetoolrotational

speedand toolwelding speedoftestno.2,4and 7

respec-tively.Asobserved,thepeakintensityincreasesbyincreasing

thetoolrotationalspeed.Ithasbeenpreviouslyreported[22]

thatthevariationoftheintensitypeaksisattributedtothe

complexmixingbetweenAl-Cuoverall,whererelativelyhigh

intensitypeaksindicateahigherIMCquantity[34].

AccordingtotheAl-Cuphasediagram,theformation

tem-perature Al2Cu phaseis relatively low[18]. Therefore, it is

expectedthatAl2Cu willbepresent inthestir zoneasthe

temperatureduringweldingisknowntoreach0.8−0.9ofthe

aluminiummeltingtemperature[26],i.e.exceedingthe

for-mationtemperatureofAl2Cu.However,theIMCscannotbe

exclusivelypredictedonthebasisofanAl-Cuphasediagram,

wherethechemicalreactionsoccurringduringtheFSWunder

thethermalcyclesarefarfromtheequilibriumcondition[18].

InthecaseofAl4Cu9,thethermomechanicaleffectofFSW

explainsitsformationatthestirzone,wherethemelting

tem-peratureofthisIMCi.e.1030◦C[28]ishigherthanthepeak

temperatureduringFSW.

3.5. Microhardnessdistribution

Fig.11 demonstratestheVickershardnessdistribution

pro-filesofdissimilarjointsmeasuredacrossandatthemiddleof

theweldcross-section.Itisobservedthatthehardnessvalue

increasessignificantlyatthestirzonerelativetothebase

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Fig.6–(a)SEMimageandEDSpointsattheweldzoneofTestno.2.MagnifiedviewofspecificregionsinFig.6(a):(b)region i,(c)regionii,(d)regioniii,(e)regioni.

innature[34],accompaniedwiththeformationofveryfine

recrystallisedgrainsandcopper-richdispersedparticles.

Ontheotherhand,thecombinedeffectofIMCformation

and grainrefinement duetothe recrystallisationincreases

thehardnessattheTMAZ.TheHAZindissimilarFSWof

alu-miniumtocopperismildlyaffectedbytherecrystallisation;

thisreducesthehardnessinbothHAZsides[31].Thehardness

variationsareadirectresultoftheheterogeneousdistribution

ofIMCsalongwiththesoftermaterials(aluminiumorcopper)

withinthestirzone.

3.6. Jointmechanicalstrength

Theperformanceofthedissimilarjointshasbeenevaluated

byassessingthe tensile properties.Fig. 12 showsthe yield

strength,UTSandjointefficiencyattheconditionsthat

devel-opeddefect-freejoints.Unlikeotherpublishedwork[28–30],

placingthe softermaterial(AA5083)onthe advancing side

resultedin higher tensile strength.The increase intensile

propertiescanbedirectlylinkedtothenatureandquantityof

IMCsinadditiontotheevolvedmicrostructure,whereproper

materialmixing isrequiredtoenhance the joint

mechani-cal performance[4].Moreover, significantimprovementsin

thejointtensilepropertieswereachievedcomparedtoother

studiesthatplacedthesoftermaterial(aluminium)ontheAS

[32–35].

ItisrevealedfromFig.12thattheeffectofthetool

rota-tional speed, in general, is higher than the effect of the

welding speed,asthisincreases theheatinputand

subse-quently improves the level of inter-mixing. Increasing the

welding speed for the same level of tool rotational speed

resultsinminorimprovementsinthejointUTS.The

evolu-tion ofthecomposite-likestructurethatwasproducedata

higher leveloftoolrotationalspeed(1400rpm) isthemain

reasonforthisimprovement.Thebenefitsofthisstructure

on the joint strength have also been reported previously

[26].

One ofthe mostimportantcriteria toidentifythe weld

joint performanceis byexpressing the joint efficiency, i.e.

theratiooftheweldtensilestrengthtotheworkpiecetensile

strength,whereajointefficiencylowerthan100%isgenerally

reportedduringFSWofdissimilar aluminium/copperjoints

[31].ThisefficiencyisalwaysrelativetothelowerUTSof

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Fig.7–(a)Typicalcross-sectionofjointweldedat1400rpmand80mm/min.(b&e)interfacezonetowardsAA5083side.(c&f) stirzone.(d&g)interfacezonetowardscopperside.

Fig.8–(a)SEMimageandEDSpointsattheweldzoneofconditionno.7.(b)EnlargeviewofregtanulariinFig.8(a).(c) EnlargeviewofregtanulariiinFig.8(a).(d)EnlargeviewofregtanulariiiinFig.8(a).(e)EnlargeSEMimageofregtanulari inFig.8(a).

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Fig.9–(a)Interfacialmicrostructureofthejointproducedattestno.4.(b)Lamellastructureinsidethestirzoneattestno.4. (c)Interfacialmicrostructureofthejointproducedattestno.7.(d)Compositelikestructureinsidethestirzoneattestno.7.

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Fig.11–Hardnessdistributionundertestsno.2,4and7.

Fig.12–Yieldstrength,UTSandjointefficiencyatdifferent weldingconditions.

wereachievedattheconditionsthatyieldeddefect-freejoints.

Upto94.8%jointefficiencywascalculatedat1400rpmand

120mm/min,whichishigherthanthepreviouslyreported

effi-ciencyof75.6%whenconsideringthesoftermaterialonthe

advancingside[32].

The typical fracture surface for three different welding

conditions isshown inFig. 13.Failure occurred atthe

AS-TMAZattherelativelylowrotationalspeedof1000rpmand

100mm/minweldingspeed(Fig.13(a&d)).Thefailurelocation

graduallyshiftedtotheAS-HAZbyincreasingtherotational

speed asin Fig.13 (b&e)and (c&f) of1200rpm-80mm/min

and1400rpm-80mm/min,respectively.Thischangeinfailure

location,shiftingawayfromtheweldzoneandtowardsthe

AA5083parentmaterialisinfullagreementwiththegradual

increaseinjointefficiency,asdisplayedinFig.12.

4.

Conclusions

FSW of AA5083 to commercially pure copper was

experi-mentally investigated and the conditions that resulted in

successfuljointswere identified.Thefollowingconclusions

aredrawnfromtheresultsofthepresentstudy:

• Asuccessfulweldjointbetweenthetwodissimilar

mate-rialshasbeenachievedatdifferentrotationalandtraverse

speeds,wherethehardermaterial(copper)wasplacedat

theretreatingsidewithoutanytooloffset.

• An inhomogeneous microstructure was observed inside

andontheinterfacialzone,whencopperparticlesdetached

andintermixedwiththealuminiummatrix.

• Acompositelikestructurewasobservedatahigherlevelof

rotationalspeedandlamellaordispersedstructureswere

foundatthelowlevelofrotationalspeed.

• The predominant intermetallic compounds at the

aluminium-copperjointwereAl2CuandAl4Cu9.

• The volume fraction of the IMCs inside the stir zone

increasedbyincreasingthe toolrotationalspeed as

con-firmed by the high XRD peak intensities and higher

hardnessvalues.

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• TheUTSreached203MPa,representingajointefficiencyof

94.8%ofthealuminiumalloyasaresultofthecomposite

likestructureandofanexcellentmetallurgicalbond.

Conflicts

of

interest

Theauthorsdeclarenoconflictsofinterest.

Acknowledgements

Theauthorsacknowledgethatpartofthisworkwascarried

outattheAdvancedMaterialsResearchLaboratory,housed

withintheUniversityofStrathclyde.

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