Crystal structure of {bis­­[(1H benzimid­azol 2 yl κN3)meth­yl]sulfane}di­chloridomercury(II)

In the crystal, pairs of N—H O hydrogen bonds link the molecules into inversion dimers which are further linked into supra- molecular chains by N—H O hydrogen bonds and

Keywords : crystal structure; silver(I) complex; distorted square-planar geometry; benzimida- zole; N—H O hydrogen bonds.. CCDC reference

The crystal packing can be described as a linear arrangement of complex units along c formed by bifurcated O—H Cl hydrogen bonds between two water molecules from one complex

planes of the hydrazide group and the benzene and pyridinium rings, respectively. In the crystal, N—H O, N—H Cl, C— H O, C—H Cl, O—H O, O—H N and O—H Cl hydrogen

Packing diagram of the title compound with C—H···N hydrogen bonds and short Cl···Cl contacts shown as dashed lines. H atoms bonded to C atoms have been omitted for clarity, except

solvent water molecules and carboxylate O atoms, carboxyl groups and benzimidazole N atoms, and benzimidazole units. and solvent water molecules, consolidate the crystal packing

dashed lines. All hydrogen atoms not involved in the intermolecular N—H···Cl hydrogen bonds were omitted for clarity.. in the dihedral angle between two l.s. planes) are estimated

The amino groups participate in intra- and intermolecular NÐH Cl hydrogen bonds, with N Cl distances in the range 3.202 (6)± 3.316 (6)