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Synthesis and properties of scandium carboxylate metal organic frameworks

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Figure 1.2: Images of the structure of HKUST-1 27. Blue polyhedra represent the square pyramidal
Figure 1.3: Coordination of structural units of MOF-5 framework and IRMOFs. ZnO4 tetrahedra (purple and blue polyhedral in MOF-5 and IRMOFs, respectively) (C and O atoms are represented for red and black spheres), yellow sphere represents the largest sphere that can occupy the pores (diameter of 12 Å in MOF-5) into the framework.11, 30, 31
Figure 1.4: MIL-100 and MIL-101 super-tetrahedral units. Each unit is assembling in supertetrahedra
Table 1. 2: Summary of isoreticular MIL-88 materials prepared with Fe3+. 36
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Applications of MOFs in catalysis Background: Origin of X-rays Nuclear Magnetic Resonance (NMR) Spectroscopy Gas adsorption Thermogravimetric Analysis (TGA)

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