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A New Approach to Understanding Biological Control of Quinone Electrochemistry

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Figure

Figure 1.2. Natural quinone cofactors. PQQ, pyrroloquinoline quinone; TPQ, topaquinone; LTQ, lysine tyrosylquinone; TTQ, tryptophan tryptophylquinone; CTQ, cysteine tryptophylquinone
Figure 1.3. 
   The nine redox states of quinones shown with 2-methyl-1,4-naphthoquinone’s redox couples.2 Values in parentheses are educated guesses or calculated from educated guesses
Figure 2.1. Naturally occurring quinone cofactors derived from amino acids. PQQ, pyrroloquinoline quinone; TPQ, topaquinone; LTQ, lysine tyrosylquinone; TTQ, tryptophan tryptophylquinone; CTQ, cysteine tryptophylquinone
Figure 2.3. 
   Possible backbone connectivity regiomers of the naphthoquinone amino acid (A-C) and the final design (D); see text for details
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