1,4-Butanedicarboxylic acid; 1,6-Hexanedioic acid; Hexanedioic Acid Nylon 66, Polyurethane, etc. No Data Available C6H10O4

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Chemical Name Chemical Formula Chemical Family Other Names Product Name Uses

Adipic Acid

Nylon 66, Polyurethane, etc.

Product Description

No Data Available C6H10O4 Adipic Acid No Data Available

1,4-Butanedicarboxylic acid; 1,6-Hexanedioic acid; Hexanedioic Acid

1. IDENTIFICATION

Organisation Location Telephone

Redox Pty Ltd 2 Swettenham Road

Minto NSW 2566 Australia

+61-2-97333000

Redox Pty Ltd 11 Mayo Road

Wiri Auckland 2104 New Zealand

+64-9-2506222

Redox Inc. 2132A E. Dominguez Street

Carson CA 90810 USA

+1-424-675-3200

Redox Chemicals Sdn Bhd No. 8, Block G, Ground Floor, Taipan 2 Jalan PJU 1A/3

Ara Damansara

47301, Petaling Jaya, Selangor, Malaysia

+60-3-7843-6833

Organisation Location Telephone

Poisons Information Centre Westmead NSW 1800-251525

131126 Chemcall Australia 1800-127406 +64-4-9179888 Chemcall Malaysia +64-4-9179888

Chemcall New Zealand 0800-243622

+64-4-9179888

National Poisons Centre New Zealand 0800-764766

CHEMTREC USA & Canada 1-800-424-9300 CN723420

+1-703-527-3887

Contact Details of the Supplier of this Safety Data Sheet

Emergency Contact Details

For emergencies only; DO NOT contact these companies for general product advice.

No Data Available Poisons Schedule (Aust)

2. HAZARD IDENTIFICATION

Safe Work Australia

Approved Criteria for Classifying Hazardous Substances (NOHSC:1008(2004))

Hazard Classification Hazardous according to the criteria of Safe Work Australia [NOHSC:1008(2004)]

Adipic Acid

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Hazard Categories Xi Irritant

Safe Work Australia

National Code of Practice for the Labelling or Workplace Substances (NOHSC:2012(1994))

Risk Phrases R36 Irritating to eyes.

R52 Harmful to aquatic organisms.

Safety Phrases S25 Avoid contact with eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S61 Avoid release to the environment. Refer to special instructions/Material Safety Data Sheets.

National Transport Commission (Australia)

Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code)

Dangerous Goods Classification NOT Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code)

Environmental Protection Authority (New Zealand)

Hazardous Substances and New Organisms Act 1996

HSNO Classifications Health Hazards

6.1D Substances that are acutely toxic - Harmful

6.4A Substances that are irritating to the eye Environmental

Hazards

9.1D Substances that are slightly harmful to the aquatic environment or are otherwise designed for biocidal action

9.2D Substances that are slightly harmful in the soil environment 9.3C Substances that are harmful to terrestrial vertebrates

Chemical Entity Formula CAS Number Proportion

Adipic Acid No Data Available 124-04-9 >=99.8 %

Ingredients

3. COMPOSITION/INFORMATION ON INGREDIENTS

Description of necessary measures according to routes of exposure

4. FIRST AID MEASURES

Swallowed PROTECTION TO FIRST-AIDERS, wear appropriate dust mask.

IF SWALLOWED, immediate first aid is not likely to be required. A physician or poison control centre can be contacted for advice. Induce vomiting by giving large amount of water under medical attention.

Advice to Doctor Treat symptomatically based on judgement of doctor and individual reactions of patient.

Inhaled IF INHALED, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult.give oxygen. Eye IF IN EYES, immediately flush with plenty of water.if easy to do, remove any contact lenses. Get medical attention if

irritation persists. Remove material from eyes, skin and clothing. Wash heavily contaminated clothing before reuse. Skin IN ON SKIN, immediate first aid is not likely to be required. However, this material can be removed with soap and

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Medical Conditions Aggravated by Exposure

No information available on medical conditions which are aggravated from exposure to this product.

5. FIRE FIGHTING MEASURES

General Measures Perform fire fighting from the windward side of fire,to avoid inhaling gases generated by incomplete combustion. Clear fire area of all non-emergency personnel. Stay upwind. Keep out of low areas. Eliminate ignition sources. Move fire exposed containers from fire area if it can be done without risk.

Flammability Conditions Combustible solid.

Extinguishing Media In case of fire, use water spray (fog), foam, dry chemical, or carbon dioxide.

Fire and Explosion Hazard Combustible. May form explosive dust mixture in air. This material as normally packaged and handled can contain sufficient fines to form an explosive mixture if dispersed in a sufficient quantity of air.

Hazardous Products of Combustion

As with any organic material, carbon dioxide, carbon monoxide, smoke and soot can be produced.

Special Fire Fighting Instructions Do NOT allow fire fighting water to reach waterways, drains or sewers. Store fire fighting water for treatment. Personal Protective Equipment Fire fighters should wear a positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting

clothing (includes fire fighting helmet, coat, trousers, boots and gloves).

Flash Point $$MFWFMBOEPQFODVQ

Lower Explosion Limit 35 g/m3 % Upper Explosion Limit No Data Available Auto Ignition Temperature $

Hazchem Code No Data Available

6. ACCIDENTAL RELEASE MEASURES

General Response Procedure Avoid accidents, clean up immediately. Slippery when spilt. Eliminate all sources of ignition. Increase ventilation. Avoid generating dust. Stop leak if safe to do so. Isolate the danger area. Use clean, non-sparking tools and equipment.

Clean Up Procedures Contain and sweep/shovel up spills with dust binding material or use an industrial vacuum cleaner. Transfer to a suitable, labelled container and dispose of promptly as hazardous waste. Use vacuum equipment designed specifically for handling combustible dusts.

Containment Stop leak if safe to do so. Isolate the danger area. Environmental Precautionary

Measures

Do NOT let product reach drains or waterways. If product does enter a waterway, advise the Environmental Protection Authority or your local Waste Management.

Evacuation Criteria Evacuate all unnecessary personnel.

Personal Precautionary Measures Personnel involved in the clean up should wear full protective clothing as listed in section 8.

7. HANDLING AND STORAGE

Handling Avoid contact with eyes. Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep away from heat, sparks and flame. Avoid creating a dust cloud in handling,transfer and clean up.

Storage Store in a cool, dry, well-ventilated area. Keep containers tightly closed when not in use. Inspect regularly for deficiencies such as damage or leaks. Protect against physical damage. Store away from incompatible materials as listed in section 10. Keep the surroundings clean and particularly free from water to avoid storing this material, whether in paper bags or flexible containers, in a moist environment. Any spill due to bag rupture, etc. must be cleaned up, as the scattered powder makes the floor slippery. For storage in stacked flexible containers, the maximum number of tiers should be 3. This product is not classified dangerous for transport according to The Australian Code for the Transport of Dangerous Goods By Road and Rail.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION

General No exposure standard has been established for this product by the Australian Safety and Compensation Council (ASCC). However, the exposure standard for dust not otherwise specified is 10mg/m3 (for inspirable dust) and 3mg/m3 (for respirable dust).

NOTE: The exposure value at the TWA is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week.

These exposure standards are guides to be used in the control of occupational health hazards. All atmospheric contamination should be kept to as low a level as is workable. These exposure standards should not be used as fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity.

Exposure Limits No Data Available

Biological Limits No information available on biological limit values for this product.

Engineering Measures A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Provide shower, hand wash, and eyewash facilities and display signs clearly indicating their locations, near the area where this material is handled.

Personal Protection Equipment RESPIRATOR: In case of Insufficient ventilation wear suitable respiratory equipment (AS1715/1716). EYES: Tightly fitting safety goggles (AS1336/1337).

HANDS: Wear rubber gloves (AS2161).

CLOTHING: Long-sleeved protective clothing, apron and safety footwear as appropriate (AS3765/2210). Work Hygienic Practices No Data Available

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Solid

Odour Odourless

Colour White

pH 2.5 20 g/L

Vapour Pressure 1B !$

Relative Vapour Density 5.04 Air = 1

Boiling Point $

Freezing Point No Data Available

Solubility H-$

Specific Gravity 1.36

Flash Point $$MFWFMBOEPQFODVQ

Auto Ignition Temp $

Evaporation Rate No Data Available

Bulk Density No Data Available

Corrosion Rate No Data Available

Decomposition Temperature No Data Available

Density No Data Available

No Data Available Specific Heat

Molecular Weight No Data Available Net Propellant Weight No Data Available Octanol Water Coefficient log pow 0.08

Particle Size No Data Available

Partition Coefficient No Data Available Saturated Vapour Concentration No Data Available Vapour Temperature No Data Available

Viscosity No Data Available

Melting Point $

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Volatile Percent No Data Available

VOC Volume No Data Available

Additional Characteristics Fire point: 232 deg C

Potential for Dust Explosion Combustible: Potential dust explosion hazard. Fast or Intensely Burning

Characteristics

No Data Available

Flame Propagation or Burning Rate of Solid Materials

No Data Available

Non-Flammables That Could Contribute Unusual Hazards to a Fire

No Data Available

Properties That May Initiate or Contribute to Fire Intensity

No Data Available

Reactions That Release Gases or Vapours

No Data Available

Release of Invisible Flammable Vapours and Gases

No Data Available

10. STABILITY AND REACTIVITY

General Information Combustible Solid.

Chemical Stability Product is stable under normal conditions of use, storage and temperature. Conditions to Avoid All sources of ignition

Materials to Avoid Base, oxidizing regent, reducing agent Hazardous Decomposition

Products

None under normal use. Slowly decomposes above boiling point.

Hazardous Polymerisation No Data Available

EyeIrritant Irritating to eyes. This material may cause pain,redness,and tearing based on human experience.

Inhalation Excessive concentrations of dusts of this material have been noted to cause respiratory tract irritation including coughing,sneezing,and blood-tinged mucous based on human experience.

SkinIrritant This material is practically non-irritating and non-toxic based on toxicity studies.

11. TOXICOLOGICAL INFORMATION

General Information Likely routes of exposure: Skin contact and inhalation Single dose (acute) studies indicate:

Oral-Practically Non-toxic (Rat LD50-5,050 mg/kg) Dermal-Practically Non-toixc (Rabbit LD50->7,940 mg/kg) Eye Irritation-Moderately Irritating (Rabbit,18.2/110.0) Skin Irritation-Non-irritating (Rabbit,4-hr.exposure,0.0/8.0) Sensitization: not a skin sensitizer in cavy

Mutagenicity: does not have mutagenic in rat

No adverse effects were reported in rats exposed to adipic acid by repeated inhalation. Rats given adipic acid in their diets for two years showed no in crease in tumors.

No birth defects were reported in mice, rats and hamsters given adipic acid orally during pregnancy.

Not adverse genetic changes were reported in standard tests using bacterial, animal and human cells, and animals.

Carcinogen Category No Data Available

12. ECOLOGICAL INFORMATION

Ecotoxicity Warm water fish:96-hr LC50 in Fathead minnow:97 mg/L(Harmful)

Cold water fish: 48-hr LC50 in Rainbow trout:>100 mg/L;Practically non- toxic No definitive invertebrate or algal toxicity data were available for this material.

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Biodegradation studies indicate that this material would meet the OECD guidelines for classification as "readily biodegradable"

Essentially biodegradable Persistence/Degradability

Mobility No Data Available

Environmental Fate Do NOT let product reach waterways, drains and sewers. Bioaccumulation Potential No Data Available

Environmental Impact No Data Available

13. DISPOSAL CONSIDERATIONS

General Information Dispose of in accordance with all local, state and federal regulations. All empty packaging should be disposed of in accordance with Local, State, and Federal Regulations or recycled/reconditioned at an approved facility.

Contact a specialist disposal company or the local waste regulator for advice. Pack in paper bags or the like by dividing into as small portions as practical,then burn in an incinertator. Do not dump this product into sewers,on the ground or into any body of water.

Special Precautions for Land Fill

Land Transport (Australia)

ADG

Proper Shipping Name ADIPIC ACID

Class No Data Available

Subsidiary Risk(s) No Data Available

No Data Available

UN Number No Data Available

Hazchem No Data Available

Pack Group No Data Available

Special Provision No Data Available

Land Transport (New Zealand)

NZS5433

No Data Available

Land Transport (United States of America)

US DOT

No Data Available

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Sea Transport

IMDG

EMS No Data Available

Marine Pollutant No

Air Transport

IATA

National Transport Commission (Australia)

Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code)

Dangerous Goods Classification NOT Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code)

15. REGULATORY INFORMATION

Environmental Protection Authority (New Zealand)

Hazardous Substances and New Organisms Act 1996

Approval Code HSR002761

National/Regional Inventories

Australia (AICS) Listed

Canada (DSL) Not Determined

General Information No Data Available Poisons Schedule (Aust) No Data Available

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Canada (NDSL) Not Determined

China (IECSC) Not Determined

Europe (EINECS) Not Determined

Europe (REACh) Not Determined

Japan (ENCS/METI) Not Determined

Korea (KECI) Not Determined

Malaysia (EHS Register) Not Determined

New Zealand (NZIoC) Not Determined

Phillipines (PICCS) Not Determined

Switzerland (Giftliste 1) Not Determined

Switzerland (Inventory of Notified Substances)

Not Determined

Taiwan (NCSR) Not Determined

USA (TSCA) Not Determined

16. OTHER INFORMATION

< Less Than > Greater Than

AICS Australian Inventory of Chemical Substances atm Atmosphere

CAS Chemical Abstracts Service (Registry Number) cmðSquare Centimetres

CO2 Carbon Dioxide

COD Chemical Oxygen Demand GHJ&&Degrees Celcius

EPA (New Zealand) Environmental Protection Authority of New Zealand GHJ))Degrees Farenheit

g Grams

g/cmñGrams per Cubic Centimetre g/l Grams per Litre

HSNO Hazardous Substance and New Organism IDLH Immediately Dangerous to Life and Health immiscible Liquids are insoluable in each other. inHg Inch of Mercury

inH2O Inch of Water K Kelvin

kg Kilogram

kg/mñKilograms per Cubic Metre lb Pound

LC50 LC stands for lethal concentration. LC50 is the concentration of a material in air which causes the death of Key/Legend

Related Product Codes ADACID1000, ADACID1001, ADACID1002, ADACID1003, ADACID1004, ADACID1005, ADACID1006, ADACID1007, ADACID1008, ADACID1009, ADACID1010, ADACID1011, ADACID1012, ADACID1013, ADACID1014, ADACID1015, ADACID1016, ADACID1017, ADACID1018, ADACID1019, ADACID1020, ADACID1021, ADACID1022, ADACID1023, ADACID1024, ADACID1025, ADACID1026, ADACID1027, ADACID1028, ADACID1029, ADACID1030, ADACID1031, ADACID1032, ADACID1033, ADACID1034, ADACID1035, ADACID1036, ADACID1037, ADACID1038, ADACID1039, ADACID1500, ADACID1501, ADACID1502, ADACID1600, ADACID1601, ADACID1800, ADACID2000, ADACID2500, ADACID3000, ADACID3001, ADACID3002, ADACID3100, ADACID3200, ADACID3300, ADACID3500, ADACID3600, ADACID3700, ADACID4000, ADACID4001, ADACID4200, ADACID4500, ADACID4600, ADACID4700, ADACID5000, ADACID5500, ADACID5600, ADACID6000, ADACID6500, ADACID7000, ADACID7100, ADACID8000, ADACID8100, ADACID8200, ADACID8300, ADACID8400, ADACID9000, ADACID9100, ADACID3900, ADACID4800, ADACID4900, ADACID2100, ADACID2200, ADACID2300, ADACID3502, ADACID1050

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50% (one half) of a group of test animals. The material is inhaled over a set period of time, usually 1 or 4 hours. LD50 LD stands for Lethal Dose. LD50 is the amount of a material, given all at once, which causes the death of 50% (one half) of a group of test animals.

ltr or L Litre mñCubic Metre mbar Millibar mg Milligram

mg/24H Milligrams per 24 Hours mg/kg Milligrams per Kilogram mg/mñMilligrams per Cubic Metre

Misc or Miscible Liquids form one homogeneous liquid phase regardless of the amount of either component present. mm Millimetre

mmH2O Millimetres of Water mPa.s Millipascals per Second N/A Not Applicable

NIOSH National Institute for Occupational Safety and Health NOHSC National Occupational Heath and Safety Commission OECD Organisation for Economic Co-operation and Development Oz Ounce

PEL Permissible Exposure Limit Pa Pascal

ppb Parts per Billion ppm Parts per Million

ppm/2h Parts per Million per 2 Hours ppm/6h Parts per Million per 6 Hours psi Pounds per Square Inch R Rankine

RCP Reciprocal Calculation Procedure STEL Short Term Exposure Limit TLV Threshold Limit Value tne Tonne

TWA Time Weighted Average ug/24H Micrograms per 24 Hours UN United Nations