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Triplet State Photophysics of Perylenemonoimide Revealed in a Pt(II) Charge Transfer Complex.

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Figure

Figure 1: Molecular architecture consisting of Pt(II)terpyridyl ensemble connected to the 9-position of the PMI by an acetylide linker
Figure 8. Figure 2:Frontier molecular orbitals of PTCAI (INDOIS).  Molecular orbitals of PDI reproduced from Adachi, et al(A€, J, .
Figure 3: General Jablonski diagram of absorption to S1, Fluorescence, ISC to T1, and phosphorescence
Figure 6.absorption transient at 610 nm along with its corresponding single exponential ( Transient absorption spectra of compound 1 in MTHF at several delay times following a 100 fs, 480 nm excitation pulse (a); the model complex, indicative of ultrafast energy migration in thisτ ) 240 fs) solid fit line superimposed (b).
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