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TiAIN based nanoscale multilayer coatings designed to

adapt their tribological properties at elevated temperatures

HOVSEPIAN, Papken <http://orcid.org/0000-0002-1047-0407>, LEWIS, D. B., LUO, Q. <http://orcid.org/0000-0003-4102-2129> and MUNZ, W. D.

Available from Sheffield Hallam University Research Archive (SHURA) at:

http://shura.shu.ac.uk/585/

This document is the author deposited version. You are advised to consult the publisher's version if you wish to cite from it.

Published version

HOVSEPIAN, Papken, LEWIS, D. B., LUO, Q. and MUNZ, W. D. (2005). TiAIN

based nanoscale multilayer coatings designed to adapt their tribological properties at elevated temperatures. Thin solid films, 1-2.

Copyright and re-use policy

See http://shura.shu.ac.uk/information.html

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TiAlN based nanoscale multilayer coatings designed to adapt their

tribological properties at elevated temperatures

P. Eh. Hovsepian1, D. B. Lewis1, Q. Luo1, W. -D. Münz1, P. H. Mayrhofer2, C. Mitterer2, Z. Zhou3, W. M. Rainforth3

1

Materials and Engineering Research Institute, Sheffield Hallam University, Howard Street, Sheffield, S1 1WB, UK,

2

Department of Physical Metallurgy and Materials Testing, University of Leoben, Franz-Josef- Strasse 18, A-8700, Leoben, Austria,

3

Department of Engineering Materials, University of Sheffield, Sheffield, S1 3JD, UK

Abstract

The addition of properly selected elements, coupled in nanoscale multilayer structures can further enhance the properties of TiAlN coatings and bring new high performance. The incorporation of Y in the nanoscale pseudo-superlattice TiAlCrN/TiAlYN with typical period of 1.7 nm not only improves the oxidation resistance but also effectively reduces the

coefficient of friction of the coating from 0.9 to 0.65 at temperatures in the range of 850 - 950

0

C. The adaptation of the tribological properties occurs as a result of the preferential

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1 Introduction

The demand for high performance physical vapor deposition (PVD) coatings to resist

degradation in severe environments, endurance of extremely high thermo-mechanical loads in particular is ever increasing. Additionally, in recent years, a demand for a new generation of coatings capable to adapt their surface or bulk properties to these severe conditions has emerged. In an attempt to combat wear in an environment with a variable humidity a super-tough wear resistant WC/diamond-like-carbon/WS2 coating with “chameleon” surface

adaptation has been developed [1]. The adaptation effect lies in the synergy of smart material and structure selection processes and has been proved for low temperatures. The combination of nanocrystalline grains and amorphous matrix initially developed for super-hardness and improved toughness [2 – 4] has shown also potential for self-adaptation in specific conditions. In the medium temperature range up to 500 0C, yttrium-stabilized -zirconia/Au utilising composite (nanocrystalline / amorphous) structures have shown consistently low friction coefficient due to the microstructure adaptive changes and formation of lubricating Au transfer films [5]. Recent research on the effect of the age hardening, in Ti1-xAlxN has

considered the effect as self adaptation mechanism contributing towards maintaining high wear resistance at elevated temperatures (up to 1000 0C). It has been demonstrated that in this temperature range, Ti1-xAlxN coatings undergo spinodal decomposition into coherent

face-centre-cubic (fcc) structured AlN and fcc-TiN nanometer-size domains. This transformation generates an increase in hardness due to coherency stresses and therefore enhances the wear resistance at elevated temperatures [6, 7].

The requirement for high temperature stability involves several key applications, which gain increasing importance in modern technology, such as dry high speed machining [8],

machining of “sticky” alloys used in aerospace and automotive industries [9] as well as

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family has been recognised as successful alternative, due to their excellent resistance to micro-abrasive wear and to high temperature oxidation up to 750 0C. The remarkable high temperature stability of these coatings has been attributed to the formation of highly protective double layer oxide scale including a very dense Al2O3 top layer [11]. Further

enhancement of the functional properties of these coatings has been achieved by incorporating of active elements to Ti1-xAlxN, such as Cr and Y [12]. Several mechanisms have been

proposed to explain the improved protective nature of the scale, due to the incorporation of Y, such as improvement of the mechanical adherence of the Al2O3 scale, reduction of the scale growth rate, grain refinement, and “plugging” diffusion paths via segregation at the grain

boundaries [13, 14].

To address specific applications however, the properties of the Ti1-xAlxN based coatings can

also be tailored successfully by structural design. Utilising the nanoscale multilayer, superlattice structures and combining selected coating materials allows extremely high hardness, > 40 GPa to be achieved [15, 16]. Together with the structure, the compressive stress will also play an important role in hardness enhancement. This factor can be easily controlled by the applied bias voltage during the coating deposition process [16]. Layering with VN in TiAlN/VN superlattice structures in addition to the super-hardness however, brings a unique tribological behaviour, due to the formation of a low melting point highly lubricious V2O5, during sliding [16 – 18]. The exceptionally low coefficient of friction and

wear rates, achieved by this approach bring into consideration another adaptation mechanism, which can be described as a compositionally regulated tribo-oxidation process, taking place under the conditions of the tribological contact.

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segregation mechanisms triggered by the exposure to high temperatures as well as by the formation of friction reducing liquefied tribofilms of V2O5 will be described.

2 Technological aspects in deposition of nanoscale multilayer, superlattice structured

TiAlCrN/TiAlYN and TiAlN/VN coatings.

TiAlCrN/TiAlYN and TiAlN/VN nanoscale multilayer coatings have been produced in a computer- controlled Hauzer HTC 1000-4 coater, utilising the combined cathodic

arc/unbalanced sputtering technique, known also as Arc-Bond-Sputtering (ABS) technique [19, 20]. The coater comprises four linear dual- purpose cathodes, which can be operated either in steered arc or unbalanced magnetron sputtering mode. Fig. 1a schematically outlines the cross-section of the system, with a typical target arrangement used for deposition of TiAlCrN/TiAlYN. The key advantage of the ABS approach is the utilization of a metal ion pre-treatment (metal ion etching) of the substrate material prior to the coating deposition step, which results in excellent coating adhesion. During the surface pre-treatment step, typically 20 min long, metal ions generated from an arc discharge sustained on one of the targets are accelerated towards the substrate due to the applied high bias voltage (Ub = -1200 V). In the

case of Cr+ ion etching, high substrate current densities of 20 Am-2 have been measured by

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proportional to the critical load values in scratch testing [20]. Furthermore, depending on the deposition conditions both nanoscale multilayer coatings exhibit relatively high compressive residual stress, up to -7 GPa, which can only be maintained by strong adhesion. This problem is further addressed by deposition of stress reduced 0.2 – 0.3 µm thick base layer of TiAlCrN or VN prior to the deposition of the TiAlCrN/TiAlYN or TiAlN/VN coating, respectively. The HTC 1000-4 system is equipped with a threefold planetary rotating table, which in combination with the multi target arrangement utilising linear sources allows straightforward deposition of nanoscale multilayer coatings. High deposition rates (typically of 1 µm per hour) are achieved by avoiding complicated installations, such as shielding and shuttering. The coatings are deposited by reactive unbalanced magnetron sputtering in a common Ar + N2 atmosphere at temperature of 450 0C. The deposition of TiAlCrN/TiAlYN coatings

requires one Cr (99.8 at.%), two Ti0.5Al0.5 and one Ti0.48Al0.48Y0.04 targets. The incorporation

of the Y in one target only is deliberate, to achieve layered distribution of Y in the coating. This target will usually be installed between the two TiAl targets as shown in Fig. 1a. The individual layer thickness in the nanoscale multilayer coatings is controlled precisely by the power dissipated on the targets, sample rotation speed, applied bias voltage and the

composition of the reactive atmosphere, controlled in total pressure controlled mode (pAr +

pN2 = constant). To deposit TiAlN/VN superlattice structured coatings, schematically shown

in Fig. 1b, two pairs of adjacent Ti0.5Al0.5 and V targets (99.8% pure) have been used. All the

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3 Thermal behaviour of the nanoscale (pseudo-superlattice) structured

TiAlCrN/TiAlYN coating

Compared to previous generation of TiAlN coatings, TiAlCrN/TiAlYN exhibit significantly higher resistance to oxidation and to abrasive wear. It has been reported that the onset of rapid oxidation of TiAlN in thermo-gravimetric tests has been increased from 750 0C to 850 0C and further to 950 0C by the incorporation in the coating of 3 at.% Cr and 2 at.% Y respectively [25, 26]. It has been shown in [25] that the incorporation of a large and therefore relatively immobile Y atom (atomic radius 0.18 nm) leads to repeated re-nucleation in the growing film, resulting in a much finer grain size (typically in the range of 5 – 10) compared to that of the TiAlN and a near equi-axed grain morphology. The incorporation of Y in TiAlCrN in a layered manner has been found to be from a key importance for its efficiency to enhance both the oxidation resistance as well as the high temperature tribological behavior of the coating. The Y containing layers are separated at a distance of  = 1.7 nm to form a pseudo

superlattice TiAlCrN/TiAlYN coating. The term “pseudo superlattice” is used here mainly to

emphasise the layered incorporation of the Y and the single phase structure of the coating. Due to the small bilayer thickness however, the typical for the “true” superlattices, ( = 3 – 5

nm) hardness enhancement (the superlattice effect, [27] ) can not be realised. The typical hardness values for this coating are in the range of HK0.025 = 27 GPa. The incorporation of Y

leads to accumulation of high residual stress, typically of -7 GPa. Therefore, in addition to the Cr+ metal ion etching, a 300 nm thick Y free TiAlCrN base layer of low stress (-3.2 GPa) is deposited with a main role to provide a smooth transition in stress and hardness from the substrate material to the coating to achieve superior adhesion. This strategy proved to be efficient as critical load values of Lc = 60 N have been measured in scratch adhesion test when the coating is deposited on hardened high speed steel substrate [26].

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in which TiAlYN and CrN were selected as a second partner material. It has been anticipated that the thermal stability of the nanoscale multilayer structures will be additionally enhanced due to the higher activation energies for diffusion and oxidation compared to the

monolithically grown structures [28]. Thermo-gravimetric analysis carried out in long duration (up to 1000 h) iso-thermal tests in air at 750 oC showed that both TiAlCrN/TiAlYN and TiAlN/CrN coatings are highly oxidation resistant. In this test however, the Y free coating exhibited accelerated mass gain with increasing exposure time reaching mass gain in the end of the test of 1.2  10-3 gcm-2 compared to 8  10-4 gcm-2 measured for the

TiAlCrN/TiAlYN coating. It has been found through detailed cross-sectional microstructure examination that, the accelerated oxidation in the TiAlN/CrN coating was attributed to internal oxidation of the sub-dense columnar structure. After the long term iso-thermal process, no multilayer fringes could be seen in the TiAlN/CrN indicative of homogization of the as-deposited TiAlN/CrN multilayer. Additionally, the coating exhibited numerous places of inter-column porosity, Fig. 2a. The openings in the structure between the columns can be attributed to reduction of the coating volume and development of tensile stress due to

annealing-out of voids or vacancies (Schottky defects) during the high temperature treatment [29]. The cross-sectional transmission electron microscopy (TEM) analysis also revealed a multitude of sites of internal oxidation in the bulk of the TiAlN/CrN coating associated mainly with the inter-column porosity as the porous inter-column areas worked as tunnels for the inward oxygen diffusion. In the monolithically grown TiAlCrN base layer as expected, the internal oxidation and the structural porosity were even more pronounced and severe, Figure 2b.

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layer regions. On the surface of the TiAlCrN/TiAlYN coating a 1.6 m thick continuous oxide scale had been formed followed by a transition region. The top part of the oxide scale appeared dense, fully crystallised and rich in aluminium, which provided a barrier to the inward diffusion of oxygen thus contributing to slower oxidation rate. In the nitride-oxide transition region, the TiAlCrN/TiAlYN coating was decomposed by progressive release of nitrogen followed by the formation of amorphous-like multicomponent oxide.

The higher density in aluminium- rich top oxide layer undoubtedly provides better protection against the environmental attack. However this can not explain the high density of the bulk of the coating retained after the long term exposure to high temperatures. This special behaviour can be attributed to the segregation of the Y into the grain boundaries [25]. Fig. 4 shows a scanning TEM (STEM) energy dispersive X-ray analysis (EDX) elemental map

demonstrating this unique behaviour [30]. The preferential diffusion of Y to potentially sub-dense regions, such as grain boundaries is predetermined by the large size of the Y atom and the kinetics of the recovery process of thermodynamically unstable phases, taking place during annealing. It has been reported that the thermal stability of defects in the PVD coatings strongly depends on the biaxial stress in the as deposited state [31]. The introduction of 2% Y in the TiAlN leads to a large lattice distortion, increasing the lattice parameter ao from 0.418

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this sub- dense structure has allowed significant outward diffusion of substrate elements into the base layer, which has been demonstrated by quantitative TEM-EDX analysis and scanning TEM-EDX elemental mapping [10, 30]. In contrast no sign of inward and outward diffusion of oxygen or substrate material elements has been found in the densified bulk of the coating.

Further evidence on the adaptation and self-healing effect can be found in investigating the high temperature wear properties of TiAlCrN/TiAlYN. High-temperature wear test was conducted on the TiAlCrN/TiAlYN and TiAlCrN coatings using a reciprocating sliding ball-on-disk configuration, [32]. The test conditions were as follows: counterpart, 10 mm

diameter hard metal (tungsten carbide) ball, normal load 15 N (initial Hertzian contact pressure 2.1 GPa), reciprocating stroke 2 mm, frequency 15 Hz, test duration 60 minutes, the samples were heated to temperatures of 400, 600, 800and 900 0C . In this test the two

coatings showed very different wear behaviour. For TiAlCrN, increasing the test temperature from 400 0C to 900 0C led to consistent increase of the depth of the wear crater from 0.076 µm to 0.97 µm, whereas the Y-stabilised coating after an initial increase in the wear depth to 1.82 µm at 600 0C showed consistent decrease of the wear depth at higher temperatures, reaching the lowest value of 0.82 µm at 900 0C. Further more the friction coefficient showed similar behaviour, reducing its values from 0.9 at 600 0C to 0.65 at temperatures in the range of 850 – 950 0C. In contrast the TiAlCrN showed consistently high coefficient of friction increasing from 1.1 to 1.6 when the test temperature increased from 600 0C to 900 0C. This peculiar behaviour of the TiAlCrN/TiAlYN can be related to the progressing coating densification (self-healing) with the temperature increase due to the operation of the Y segregation mechanism.

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Depending on the hardness of the work piece and the cutting speed, the measured cutting temperatures ranged from below 700 0C in cutting EN24 steel (HRC 38, cutting speed Vc = 385 mmin-1) to 950 0C in cutting hardened A2 steel (HRC 58, Vc = 500 mmin-1). The cutting lifetime data of the TiAlCrN/TiAlYN and TiAlCrN coated end mills are presented in Figs. 5a and 5b. In cutting the relatively soft steels EN24 where the cutting temperatures were below 700 0C, the TiAlCrN/TiAlYN had no advantage as compared to the Y-free coating TiAlCrN, Fig. 5a. However, the TiAlCrN/TiAlYN coating had indeed superior performance to the TiAlCrN in cutting harder steels and at higher cutting speeds where the cutting temperatures were above 800 0C. In the extreme case of cutting the A2 steel at cutting speed Vc = 500 mmin-1, Fig. 5 b, the TiAlCrN/TiAlYN doubled the lifetime of the TiAlCrN.

4. Nanoscale multilayer/superlattice structured TiAlN/VN coatings.

The excellent wear behaviour of TiAlN/VN in dry sliding conditions has been widely reported elsewhere in [16, 33]. However, the exceptionally low wear rate of 2.1  10-17 m3N

-1

m-1 is difficult to be explained by the superhardness (42 GPa, [16]) alone or by the distinctive wear mechanism of the superlattice structured coatings, which suggests material removal in 6 – 8 nm thick nano layers as opposed to monolithically grown coatings, where due to severe plastic deformation, bending and cracking of the columns, release of large 50 – 75 nm particles is observed [34]. In the special case, when V is incorporated in the coating

constitution, the effect of tribo-oxidation wear mechanism in dry sliding has to be carefully considered. Vanadium is known to form Magnéli-phases with oxygen, with „easy‟

crystallographic shear planes [35] that can act as solid lubricants in dry sliding conditions. Additionally the low melting point of the V2O5 (Tm = 685 0C), which lies in the range of the

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microscopy (SEM) observations of the wear track after 1 million laps in room temperature pin-on-disk test showed smooth worn surface and almost no transfer of material from the alumina ball used as a counter part [16]. The low friction coefficient of 0.4 measured in this test can be related to the behaviour of the tribo-oxide film containing V2O5. It is believed that

the small amount of V2O5, whichforms predominantly at the asperity contacts, reduces the

coefficient of friction due to melting. The sliding wear mechanism in such conditions

resembles very much boundary lubrication, where the surfaces are separated and the junction formation mechanism is suppressed by adsorbed molecular films (in this case molten phase) although appreciable asperity contact may still occur. Thus the synergy between the fine delamination wear mechanism characteristic of superlattice structures and the low melting point of the tribo- film controls the low friction coefficient at room temperature. In the view of potential high temperature applications the oxidation and the tribological behaviour of TiAlN/VN at elevated temperatures have been studied extensively [17, 18, 37]. A

combination of differential scanning calorimetry investigations and high temperature (up to 700 0C) tribometry revealed a unique self- adapting behaviour of TiAlN/VN to combined thermal mechanical and chemical wear, [17]. It has been shown that at 700 0C in steady state conditions, low friction coefficient in the range of 0.5 was achieved, Fig. 7, which in effect is similar to the friction coefficient measured at room temperature. To explain this effect an operation of a specific controlling mechanism has been suggested that involves sliding against liquefied oxide scale and conversion of V2O5 to lower oxidised Magnéli-phases [17]. The

very low value for the coefficient of friction of 0.18 (Fig. 7), measured for the initial stages of the sliding process was related to a sliding over liquefied V2O5 phase. A SEM cross section,

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TiAlN/VN coating remains intact at these temperatures. The second part of the friction curve in Fig. 7 represents the friction behaviour in steady state conditions. The exceptionally low friction coefficient of 0.55 for hard coatings at this temperature range is believed to result from sliding against low shear strength Magnéli-phases of V6O13 and VO2 produced by a

reduction process of V2O5 [38]. The operation of the above- described mechanism however,

requires availability of significant amount of V2O5 phase, the largest portion of which at 700 0

C is produced by thermal oxidation process. Thermo-gravimetric oxidation experiments and isothermal oxidation tests at 550 0C for 30 min showed, that the surface of the TiAlN/VN was almost free of V2O5 [18, 37]. Fig. 9a shows an SEM image of the surface after isothermal

oxidation at 550 0C. After 30 min exposure, only very thin oxide layer with a needle like morphology has been formed, which did not produce intensive enough signal to be detected by X-ray diffraction. In the temperature range of 500 0C indeed significant increase of the friction coefficient was recorded [17], which implies for the existence of a transition regime in the control mechanisms operating at room and elevated temperatures. At higher temperatures, above 600 0C however, formation of V2O5 mixed predominantly with AlVO4 is detected in

sufficient amount to trigger the control mechanism for low friction in steady state conditions. An SEM image of the surface after exposure for 30 min to 638 0C shows that the coating surface was uniformly oxidised, Fig. 9b. A large area of the surface was covered by fine needles/plates, which form with a certain preferred orientation (arrowed). EDX selected area analysis showed that these fine needles/plates were highly V-rich. Further X-ray diffraction analysis confirmed the presence of the V2O5 phase. Fig. 10 shows a bright field

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This observation demonstrates that the bulk of the coating retains the enhanced mechanical properties of the superlattice coatings and the material responds to the environment by adapting its surface properties only. The consistently low and almost identical coefficient of friction recorded for room and 700 0C determine the major application fields for TiAlN/VN, such as protection of wear parts and cutting tools used for machining of softer but much “stickier” materials e.g. Ni based alloys. TiAlN/VN coated 8 mm two flute ball nosed end

mills were tested in dry cutting of Inconel 718, HRC43, cutting speed 90 mmin-1, axial depth of cut 0.5 mm, feed 0.2 mm. The superlattice coated tools showed the longest length of cut of 380 m, out-performing various PVD coatings: TiAlN, TiAlN+WC/C, TiAlN+MoS2,

TiAlN+graphite, thus demonstrating the importance of maintaining the low coefficient of friction at elevated temperatures.

5. Conclussions

The experince gained so far in the design, large scale manufacturing and application of nanoscale multilayer/superlattice structured PVD coatings allows us to identify two TiAlN based coatings adapting their tribological proparties at high temperatures. In the TiAlCrN/TiAlYN system, high wear resistance and low friction coefficient are achieved due to a segregation mechanism taking place in the bulk of the coating, which results in coating structural densification at high (800 – 950 0C) temperatures. In the TiAlN/VN system, exceptionally low coefficient of friction and wear rates are acieved by the adaptation of the surface properties, due to a compositionally regulated tribo-oxidation process taking place during sliding.

Acknowledgements

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Surface Engineering Programme GK/K76351 MULTICOAT and UK Engineering and Physical Science Research Counsil (EPSRC) Programme, grant No. GR/N23998/01.

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List of Figure Captions:

Figure 1 Schematic cross sections of (a) the four cathode HTC 1000-4 PVD coating system, and (b) schematic of a typical superlattice structured coating design.

Figure 2 Cross-sectional TEM micrographs of (a) bulk of the TiAlN/CrN superlattice coating. and (b) the base layer region after iso-thermal treatment (T = 750 0C, for 1000 h).

Figure 3 Cross-sectional TEM micrograph of TiAlCrN/TiAlYN coating, iso-thermally treated at T = 750 0C, for 1000 h.

Figure 4 STEM-EDX maps (a) L-Y and (b) K-Y of TiAlCrN/TiAlYN coating, showing segregation of Y at the grain boundaries.

Figure 5 Life-time of 8 mm in diameter two flute ball nosed end mills coated with various coatings (a) in cutting soft EN24 steel (HRC 38) and (b) in cutting hard A2 steel (HRC 58).

Figure 6 Cross-sectional TEM micrograph of TiAlN/VN superlattice coating from the wear track region after pin-on-disk test showing the tribo-film formation.

Figure 7 Friction coefficient curve of TiAlN/VN superlattice coating tested at high temperature of 700 0C in air atmosphere.

Figure 8 (a) Cross-sectional SEM overview of the wear track on a TiAlN/VN superlattice coating after a tribo-test at 700 0C, (b) Detailed image of the oxidised coating surface from the indicated area in Fig. 8 a of the wear track.

Figure 9 (a) SEM image from the surface of TiAlN/VN superlattice coating iso-thermally treated at T = 550 0C, for 30 minutes; (b) after oxidation in air at 638 0C for 30 min.

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