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Revealing the Thermodynamic Background of the Memory Effect in Phase Separating Cathode Materials

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Figure

Fig. 1.  Spinodal shaped chemical potential µ dependency on particle state of charge (x in LixFePO4) at charge for the case of high and low overpotential curve
Fig. 4.  A memory effect experiment executed using the same protocol as in Fig. 2, but without first rest in the memory writing cycle
Fig. 5.  Simulation of memory effect calculated for the protocol presented in Fig. 2, with the model described in Section 1.2
Fig. 7.  Simulation of memory effect calculated for the same protocol as in Fig. 5 but with the cut of voltage at the end of the memory writing cycle lowered to 2.8 V
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