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4-TERT-BUTYL-2

4 tert Butyl 2 [2 (1,3,3 tri­methyl­indolin 2 yl­­idene)ethyl­­idene]cyclo­hexa­none

4 tert Butyl 2 [2 (1,3,3 tri­methyl­indolin 2 yl­­idene)ethyl­­idene]cyclo­hexa­none

... of 4-tert-butyl-2-hy- droxymethylenecyclohexanone 1 with Fisher's base 2 ...from 4-tert-butylcyclohexanone using the general procedure reported by Ainsworth ...

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(4 tert Butyl 2 methyl­thio­semicarb­azido)(O methyl­di­thio­phosphato)­palladium(II)

(4 tert Butyl 2 methyl­thio­semicarb­azido)(O methyl­di­thio­phosphato)­palladium(II)

... is tert-butyl), in acetonitrile in the absence of any HCl-acceptor, to yield a new compound, (1), with a ®ve- membered heterocycle (JancÏa et ...and ...

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(E) 4 tert Butyl 2 (2,6 diiso­propyl­phenyl­imino­meth­yl) 6 (morpholinometh­yl)phenol

(E) 4 tert Butyl 2 (2,6 diiso­propyl­phenyl­imino­meth­yl) 6 (morpholinometh­yl)phenol

... butyl group is disordered over two positions; site-occupation factors were kept fixed at 0.5. The morpholine ring has a chair conformation. Intramolecular O—H N hydrogen bonding results in the formation of a ...

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Di­ethyl (4 tert butyl 1,3 thia­zol 2 yl­amino­methyl­ene)­malonate

Di­ethyl (4 tert butyl 1,3 thia­zol 2 yl­amino­methyl­ene)­malonate

... a 2-aminothiazole moiety. Only two of these structures have a 4-tert-butyl group, namely 4-tert-butyl-2-(N- methyl-N-phenylamino)thiazole-5-carbaldehyde (Gillon et ...

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Dieth­yl 2 amino­thia­zole 4,5 di­carboxyl­ate hemihydrate

Dieth­yl 2 amino­thia­zole 4,5 di­carboxyl­ate hemihydrate

... substituted 2-amino N atoms, two have tertiary amino groups, viz. ethyl 2-(5- ethoxycarbonyl-2-(pyrrol-1yl)thiazol-4yl-2-iminoethanoate (Brickute et ...ethyl ...

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2 tert Butyl 4,6 di­nitro­phenol

2 tert Butyl 4,6 di­nitro­phenol

... The title compound, (I), was ®rst prepared in 1938 (Ipatieff et al., 1938) by the nitration of 2,4-di-tert-butylphenol, with cleavage of the 4-tert-butyl group. It was later found that (I) ...

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2 tert Butyl 4 methyl 6 (1 piperidinio­methyl)­phenol bromide

2 tert Butyl 4 methyl 6 (1 piperidinio­methyl)­phenol bromide

... 2-tert-Butyl-4-methyl-6-(piperidyl-N-methyl)phenol was prepared as in previous work (Deng et al., 2001). Colorless single crystals of the title compound, (III), suitable for X-ray diffraction ...

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2 tert Butyl 4 methyl 6 (1 piperidinio­methyl)­phenol chloride

2 tert Butyl 4 methyl 6 (1 piperidinio­methyl)­phenol chloride

... Cl1 0.0646 (4) 0.0410 (3) 0.0800 (5) −0.0074 (3) −0.0032 (4) −0.0008 (3) N1 0.0351 (11) 0.0367 (10) 0.0564 (13) 0.0030 (9) 0.0010 (10) −0.0057 (10) O1 0.0510 (11) 0.0573 (11) 0.0599 (11) −0.0117 (10) ...

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4 tert Butyl 1 iso­propyl 1H imidazole 2(3H) thione

4 tert Butyl 1 iso­propyl 1H imidazole 2(3H) thione

... The title compound, (I), was formed by accident, instead of the sulfenamide which was expected. A search in the Cambridge Structural Database (Version 5.25; Allen, 2002) for the imidazoline-2-thione fragment ...

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(R) N {2 tert Butyl 2 [(R) tert butyl­sulfonamido]ethyl­idene} tert butane­sulfonamide

(R) N {2 tert Butyl 2 [(R) tert butyl­sulfonamido]ethyl­idene} tert butane­sulfonamide

... S1 0.0687 (5) 0.0399 (4) 0.0566 (5) 0.0111 (4) 0.0316 (4) 0.0094 (3) S3 0.0751 (6) 0.0619 (5) 0.0430 (4) −0.0116 (5) 0.0207 (4) −0.0050 (4) O1 0.1006 (17) 0.0986 (17) 0.0521 (12) ...

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O,O Bis(2 tert butyl 4 meth­oxy­phen­yl) chloro­thio­phospho­nate  Corrigendum

O,O Bis(2 tert butyl 4 meth­oxy­phen­yl) chloro­thio­phospho­nate Corrigendum

... An ORTEP-3 (Farrugia, 1997) view of (I) and a packing diagram are shown in Figs. 1 and 2, respectively. The P atom lies on a twofold rotation axis, eading to disorder of the Cl and S atoms. Compound (I) has no ...

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3,5 Di tert butyl 2 hy­droxy­benz­aldehyde

3,5 Di tert butyl 2 hy­droxy­benz­aldehyde

... O3 0.0435 (7) 0.0401 (7) 0.0436 (7) −0.0028 (6) 0.0246 (6) −0.0161 (6) O4 0.0399 (7) 0.0202 (6) 0.0405 (7) −0.0015 (5) 0.0209 (6) −0.0074 (5) C16 0.0277 (9) 0.0375 (9) 0.0299 (9) −0.0026 (7) 0.0130 (7) −0.0054 (7) C17 ...

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2 tert Butyl 4 methyl 6 (1 piperidinio­methyl)­phenol perchlorate

2 tert Butyl 4 methyl 6 (1 piperidinio­methyl)­phenol perchlorate

... derivative, 2- tert-butyl-4-methyl-6-(piperidyl±N-methyl)phenol, (I) (Deng et ...viz. 2-tert-butyl-4-methyl-6-(1- piperidiniomethyl)phenol perchlorate, ...

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1 tert Butyl 2 (4 ethyl­benzoyl) 1 (2 mercapto 3,5 di­methyl­benzoyl)­hydrazine

1 tert Butyl 2 (4 ethyl­benzoyl) 1 (2 mercapto 3,5 di­methyl­benzoyl)­hydrazine

... dichloromethane (5 ml) dropwise at 263 K. A solution of 1-tert-butyl- 1-(3,5-dimethylbenzoyl)-2-(4-ethylbenzoyl)hydrazine (0.007 mol) in dichloromethane (5 ml) was then added at 263 K. The ...

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3,5 Di tert butyl 2 hy­droxy­benz­aldehyde

3,5 Di tert butyl 2 hy­droxy­benz­aldehyde

... C9′ 0.149 (8) 0.047 (4) 0.091 (5) 0.020 (5) 0.012 (5) 0.000 (4) C10′ 0.112 (6) 0.056 (5) 0.122 (6) −0.008 (4) 0.014 (5) 0.022 (4) C11′ 0.101 (6) 0.052 (4) 0.118 (6) −0.003 (4) ...

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Synthesis of biologically active compounds and development of new methodologies

Synthesis of biologically active compounds and development of new methodologies

... (entry 2, table 2) was treated under similar reaction conditions to isolate 4-methyl benzyl tert- butyl ether in 85% ...table 2), naphthaldehyde tosylhydrazone (entry 6, table ...

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(E) N [2 (3,5 Di tert butyl 2 hy­droxy­benzyl­­idene­amino)cyclo­hexyl] 4 methyl­benzene­sulfonamide

(E) N [2 (3,5 Di tert butyl 2 hy­droxy­benzyl­­idene­amino)cyclo­hexyl] 4 methyl­benzene­sulfonamide

... As shown in Fig. 1, the asymmetric unit contains two molecules. In each of these molecules the cyclohexyl rings adopt chair conformations. The dihedral angles between the benzene rings are 16.89 (9)° and 34.11 (9)°. The ...

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tert Butyl 4 [2 (meth­oxy­carbonyl)­ethyl] 3,5 di­methyl 1H pyrrole 2 carboxyl­ate

tert Butyl 4 [2 (meth­oxy­carbonyl)­ethyl] 3,5 di­methyl 1H pyrrole 2 carboxyl­ate

... N 0.0523 (8) 0.0466 (7) 0.0401 (7) 0.0050 (6) −0.0003 (5) 0.0197 (6) O2 0.0556 (7) 0.0452 (6) 0.0624 (7) −0.0002 (5) −0.0110 (5) 0.0265 (5) C7 0.0480 (9) 0.0439 (8) 0.0605 (10) 0.0009 (7) 0.0014 (7) 0.0250 (8) C3 0.0497 ...

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tert Butyl N benzyl N [4 (4 fluoro­benzoyl­meth­yl) 2 pyrid­yl]carbamate

tert Butyl N benzyl N [4 (4 fluoro­benzoyl­meth­yl) 2 pyrid­yl]carbamate

... the 4-fluorophenyl ring (C18–C23), ...the 4-fluorophenyl ring (C18–C23), respectively. The 4-fluorophenyl ring (C18–C23) is perpendicular to the carbamate acid plane, the dihedral angle between them ...

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tert Butyl N benzyl N (4 methyl 2 pyrid­yl)carbamate

tert Butyl N benzyl N (4 methyl 2 pyrid­yl)carbamate

... To a solution of tert -butyl 4-methylpyridin-2-ylcarbamate (0.75 g, 3.6 mmol) in dry DMF (11 ml) was added under an argon-atmosphere sodium hydride (0.18 g, 4.5 mmol, 60% oil dispersion) at ...

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