Click Chemistry in Polymers
Synthesis and application of some novel functional polymers via controlled radical polymerization and click chemistry
... thermoresponsive polymers with LCSTs ranging from 16 to 95 o ...pure polymers with a very low amount of residual catalyst ...‘‘click’’ chemistry has opened new avenues for the design and ...
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Surface modification with polymers using living radical polymerisation and click chemistry
... synthetic polymers, which are mechanically and chemically stable, have been developed to meet the demand for packing materials that are able to withstand high pressures and high flow ...synthetic polymers ...
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Chemical functionalization of emulsion templated porous polymers by thiol–ene “click” chemistry
... porous polymers (polyHIPEs) have been prepared by the photopolymerization of high internal phase emulsions (HIPEs) with varying ratios of thiol and acrylate ...resulting polymers have a nominal porosity of ...
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Synthetic Nitrogen-containing Polymers and their Application as Copper Supports in Click Chemistry
... The activity of the polymers was measured by titration with standard hydrochloric acid solution to compare the ability of each polymer to complex with copper. The imidazole polymer, PVI-DVB showed more activity ...
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Synthesis of multi walled carbon nanotube/polyhedral oligomeric silsesquioxane nanohybrid by utilizing click chemistry
... i.e., polymers, metals, or inorganic nanoparticles, on the surface of the CNTs ...“ click chemis- try, ” has received a great deal of attention from researchers in fields ranging from organic synthesis to ...
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Hyperbranched polymers with high degrees of branching and low dispersity values : pushing the limits of thiol–yne chemistry
... orthogonal click chemistry have greatly improved applications of dendrimers and increased their availability to the scientific community, by reducing number of reaction steps and need for demanding ...
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Applications of Click Chemistry in the Development of Electrochemical Sensors
... synthesis, click chemistry has emerged as one of the most highlighted techniques for engineering the architecture and functions of different types of ...to polymers or other substrates such as carbon ...
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Biological Chemistry A Metal-free Click Chemistry Approach for the Assembly and Probing of Biomolecules
... The probing experiments were performed multiple times at different tip locations on the substrate. In each experiment, rupture forces for both events and the distances between them were measured. The data are assembled ...
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Chemical modification of Bombyx mori silk fibers with vinyl groups for thiol-ene click chemistry
... thiol-ene click reaction involves the addition of a thiyl radical across a carbon–carbon double bond in a regio- and enantio-selective manner ...Thiol-ene click reac- tions are appealing for material ...
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Exploring the Chemistry of η5-Cyclopentadienyl-Cobalt-η4-Cyclobutadiene Containing Polymers; Synthesis, Properties, and Self-Assembly
... Over the last decade, research to incorporate transition metals into polymers has continually expanded. 1-6 Metallopolymers have shown properties distinct from their organic (conventional polymer) and inorganic ...
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Exploring the Chemistry of Cyclopentadienyl-Cobalt- Cyclobutadiene (CpCoCb) Complexes and Synthesis of Side- Chain CpCoCb Polymers
... containing polymers have been recognized as important synthetic targets based on their isoelectronic nature with ferrocene and enhanced metal-metal interactions have also been suggested in ...cobaltoarene ...
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Synthesis of novel coumarin and L-ascorbic acid derivatives using click chemistry
... Funkcionalne grupe su odabrane prema određenim kriterijima pa sintetizirane molekule sadrže sljedeće strukturne karakteristike: 7-metoksi-8-supstituirani kumarin koji je odabran[r] ...
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Monovalent maleimide functionalization of gold nanoparticles via copper-free click chemistry
... Analysis of the products of the reaction of MPBH 15 mg/mL and dp12 1 mg in formamide using anion-exchange chromatography 230 nm using a HiTrap Q column 1 mL equilibrated with HPLC grade [r] ...
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Synthesis, Molecular Modeling and Anticancer Activity of Novel 1,2,3 Triazole Hybrids a Click Chemistry Approach
... A novel series of 1,4-disubstituted 1,2,3-triazole derivatives (3a-3m) were one pot synthesized via cupper nanoparticles azide-alkyne click chemistry, and evaluated for their lung cancer (A549), prostate ...
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Article Synthesis of nitrogen-rich polymers by click polymerization reaction and gas sorption property
... microporous polymers with N,N,N’,N’-tetraphenyl-1,4-phenylenediamine, 1,3,5-tris(diphenylamino)benzene and 1,3,5-tris[(3- methylphenyl)-phenylamino]benzene as the core for high iodine capture and fluorescence ...
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Detecting N-myristoylation and S-acylation of host and pathogen proteins in plants using click chemistry
... a click chemistry-based method using metabolic labeling with ω-alkynyl fatty acid analogs to study the fatty acylation, especially myris- toylation, of both host and pathogen proteins in the plant ...
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Antibiotic spider silk: site specific functionalisation of recombinant spider silk using ‘click’ chemistry
... The use of functionalised recombinant spider silk as a sustainable advanced biomaterial is currently an area of intense interest owing to spider silk’s intrinsic strength, toughness, biocompatibility and ...
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Novel rGO T C(n) Nanosheets developed via click chemistry as a lubricant anti wear additive
... In summary, an industrial scalable route used to functionalize reduced graphene oxide for anti-wear additive via click chemistry. This additive nanostructure is effective when formulated with group III ...
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Copper(I) complexes bearing carbenes beyond classical N heterocyclic carbenes : synthesis and catalytic activity in “click chemistry”
... The isolation of a N-heterocyclic carbene (NHC, I) by Arduengo and co-workers in the early 1990’s led to major breakthroughs in organometallic chemistry. [1] In the course of developing more efficient transition ...
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Synthesis of maleimide derivatives via CuAAC click chemistry and biological evaluation of their antitumor activity against cancer cell lines
... Many compounds containing 1,2,3-triazole moiety have good biological activities such as anti-inflammatory[11], anticancer[12,13], and antimicrobial activity[14]. The Cu(I)-catalysed azide-alkyne cycloaddition (CuAAC) ...
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