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Rate Constants

The application of the Modified Band Approach for the calculation of on-line photodissociation rate constants in TM5: implications for oxidative capacity

The application of the Modified Band Approach for the calculation of on-line photodissociation rate constants in TM5: implications for oxidative capacity

... Abstract. A flexible and explicit on-line parameteri- zation for the calculation of tropospheric photodissocia- tion rate constants (J -values) has been integrated into the global Chemistry Transport Model ...

21

Evaluation of rate constants and thermodynamic parameters of oxidation of chloramphenicol by cas in mixed solvent media

Evaluation of rate constants and thermodynamic parameters of oxidation of chloramphenicol by cas in mixed solvent media

... Ceric ammonium sulphate (CAS) is well known to oxidize carbon compounds in various acid media via the formation of 1:1 cerium (IV) – substrate complex which undergoes dissociation unimolecularly in the rate ...

6

THYROID FUNCTION ASSAY WITH RADIOIODINE  III  CLINICAL TEST RESULTS AND DIAGNOSTIC LIMITS FOR RATE CONSTANTS

THYROID FUNCTION ASSAY WITH RADIOIODINE III CLINICAL TEST RESULTS AND DIAGNOSTIC LIMITS FOR RATE CONSTANTS

... CHOICE OF PARAMETERS Clearance rates may have slightly more fundamental significance than the rate factors, but in The various parameters that are commonly empractice their measurement i[r] ...

14

The measurement of the rates of hydroxyl radical reactions and the prediction of rate constants in alcohol combustion

The measurement of the rates of hydroxyl radical reactions and the prediction of rate constants in alcohol combustion

... An easily-implemented means is given of calculating recombination rate coefficients using microcanonical variational transition state theory pVTST employing the potential function implic[r] ...

326

Kinetic study of styrene/maleic anhydride copolymers using succine anhydride as the model compound

Kinetic study of styrene/maleic anhydride copolymers using succine anhydride as the model compound

... The rate constants with aniline at Compound determined for the polymers 67 degrees Celsius are as and succinic anhydride follows from Table XV: Rate Constant reacted with aniline Deviati[r] ...

113

Anodic Degradation of Ofloxacin on a Boron-Doped Diamond Electrode

Anodic Degradation of Ofloxacin on a Boron-Doped Diamond Electrode

... Near 100% ofloxacin degradation was accomplished within 90 min electrolysis for all the three tested temperatures (30–70°C). Furthermore, the regressions of ofloxacin degradation data were all linear (R 2 = 0.992−0.996) ...

9

Hydrogen transfer reactions of interstellar Complex Organic Molecules

Hydrogen transfer reactions of interstellar Complex Organic Molecules

... This study focuses on unimolecular rate constants, i.e. on the Langmuir–Hinshelwood mechanism. Both reactants are adsorbed on the surface, approach each other via diffusion and form a PRC on the surface. ...

9

Appel, Roland
  

(2011):


	Phosphorus Ylides, Sulfur Ylides, and Related Carbanions as Reference Nucleophiles for the Quantification of the Electrophilic Reactivities of Aldehydes, Imines, and Enones.


Dissertation, LMU München: Fakultät für Chemie und

Appel, Roland (2011): Phosphorus Ylides, Sulfur Ylides, and Related Carbanions as Reference Nucleophiles for the Quantification of the Electrophilic Reactivities of Aldehydes, Imines, and Enones. Dissertation, LMU München: Fakultät für Chemie und Pharmazie

... In recent years, we have developed the most comprehensive nucleophilicity scale presently available. [16] By defining a series of structurally related benzhydrylium ions and quinone methides (some of them are depicted in ...

375

Microsecond folding dynamics of the F13W G29A mutant of the B domain of staphylococcal protein A by laser-induced temperature jump

Microsecond folding dynamics of the F13W G29A mutant of the B domain of staphylococcal protein A by laser-induced temperature jump

... of rate constants to regions of the folding landscape not directly accessible ...folding rate constant at 0 M guanidinium chloride and 45°C of 249,000 s ⴚ1 ...

7

Horn, Markus
  

(2011):


	Structure-Reactivity Relationships of Substituted Tritylium Ions: A Kinetic Investigation.


Dissertation, LMU München: Fakultät für Chemie und Pharmazie

Horn, Markus (2011): Structure-Reactivity Relationships of Substituted Tritylium Ions: A Kinetic Investigation. Dissertation, LMU München: Fakultät für Chemie und Pharmazie

... ions, covalently bound to nucleosides and peptides, served as mass tags for improving the sensitivity in (MA)LDI-TOF mass spectrometry. [4] Most important in synthetic chemistry, however, is their use as protecting ...

337

Self-inhibition of Rubisco by inhibitory by-products

Self-inhibition of Rubisco by inhibitory by-products

... HPLC high performance liquid chro1natography IPTG isopropyl-~-D-thiogalactopyranoside k1, k2 rate constants for rapid inhibitor binding k1 rate constant for slow tight inhibitor binding [r] ...

250

Rate and equilibrium constants for the addition of N Heterocyclic Carbenes into benzaldehydes : a remarkable 2 substituent effect

Rate and equilibrium constants for the addition of N Heterocyclic Carbenes into benzaldehydes : a remarkable 2 substituent effect

... and rate constants for the reaction of triazolium NHC precatalysts with substituted benzaldehydes to give 3-(hydroxybenzyl)- azolium adducts under both catalytic and stoichiometric conditions have been ...

6

Theoretical investigation into the atmospheric reactions of fluorotelomer alcohols (FTOHs), with OH radicals

Theoretical investigation into the atmospheric reactions of fluorotelomer alcohols (FTOHs), with OH radicals

... Ambient rate constants for FTOHs reactions with and their corresponding atmospheric half-life times: Based on findings of the previous section and the experimental observation of the predominance of ...

5

Synthesis of 1-(isopentyloxy)-4-nitrobenzene under ultrasound assisted liquid-liquid phase-transfer catalysis

Synthesis of 1-(isopentyloxy)-4-nitrobenzene under ultrasound assisted liquid-liquid phase-transfer catalysis

... The rate constants were determined by varying the concentration of the catalyst, stirring speed, the concentration of alcohols, temperature, different solvents, and concentration of sodium hydroxide, ...

9

Derivatives Of Buckminsterfullerene As Efficient Inhibitors In A Model Hydrocarbon Oxidation Environment

Derivatives Of Buckminsterfullerene As Efficient Inhibitors In A Model Hydrocarbon Oxidation Environment

... evaluated rate constants appear to be considerably higher than those of fullerene and given commercials stabilizers, confirming the existence of a synergistic effect promoted by the fullerene component and ...

13

Kinetic studies on the fidelity of DNA replication involving DNA templates containing O6-methylguanine

Kinetic studies on the fidelity of DNA replication involving DNA templates containing O6-methylguanine

... the rate constants for incorporation of thymine and cytosine opposite ...individual rate constant was that the experimental design allowed one to measure elongated DNA, denoted by 10-mer ...internal ...

266

Kempf, Bernhard
  

(2003):


	Construction and Application of Reference Scales for the Characterization of Cationic Electrophiles and Neutral Nucleophiles.


Dissertation, LMU München: Fakultät für Chemie und Pharmazie

Kempf, Bernhard (2003): Construction and Application of Reference Scales for the Characterization of Cationic Electrophiles and Neutral Nucleophiles. Dissertation, LMU München: Fakultät für Chemie und Pharmazie

... the rate-determining ...the rate constants of 327 reactions of carbocations, metal-π-complexes, and diazonium ions with π-, σ-, and n-nucleophiles (Figure ...

302

Electricity is Different

Electricity is Different

... Rate constants chosen at one boundary charge or one potential cannot work for different charges or potentials. Currents in Rate Models[r] ...

71

Theoretical study of the addition and hydrogen abstraction reactions of the methyl radical with formaldehyde and hydroxymethylene

Theoretical study of the addition and hydrogen abstraction reactions of the methyl radical with formaldehyde and hydroxymethylene

... The rate constants of abstraction reactions for hydroxymethylene were much greater than those for ...on rate constants of the addition and hydrogen abstraction reactions of the methyl radical ...

10

Soil Moisture Depletion in the Annual Grass Type.

Soil Moisture Depletion in the Annual Grass Type.

... With the exception of the lightly grazed plot, the percent increase of the rate constants is very close to the percent increase of evapo- transpiration losses as[r] ...

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