[PDF] Top 20 Crystal structure of poly[[{μ2 1,4 bis[(1H imidazol 1 yl)methyl]benzene}[μ6 5 (4 carboxylatophenoxy)isophthalato] μ3 hydroxido dicobalt(II)] 0 25 hydrate]
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Crystal structure of poly[[{μ2 1,4 bis[(1H imidazol 1 yl)methyl]benzene}[μ6 5 (4 carboxylatophenoxy)isophthalato] μ3 hydroxido dicobalt(II)] 0 25 hydrate]
... For general background to the properties and applications of compounds with metal-organic framework structures (MOFs), see: Batten & Robson (1998); Farrusseng et al. (2009); Iremonger et al. (2013); Kreno et al. ... See full document
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catena Poly[[[(1,10 phenanthroline)nickel(II)] μ 4,4′ oxydibenzoato] 0 25 hydrate]
... Geometry . All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of ... See full document
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Crystal structure of a one dimensional looped chain silver(I) coordination polymer: catena poly[[silver(I) bis{μ 4 [1 (5′ isopropyl [1,1′:3′,1′′ terphenyl] 2′ yl) 1H imidazol 2 yl]pyridine κ2N:N′}] nitrate methanol monosolvate monohydrate]
... Group-9 metal complexes bearing phenylimidazole-based ligands are considered to be suitable triplet emitters for use in phosphorescent organic light-emitting diodes (PHOLEDs) because of their high efficiency and ... See full document
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Crystal structure of poly[tetra μ2 cyanido 1:2κ8N:C bis(dimethyl sulfoxide 1κO)diargentate(I)iron(II)]
... polymeric structure extending parallel to (102). In the crystal, the nearest Ag Ag distance between polymeric sheets is ...The crystal studied was a twin with a contribution of ... See full document
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Crystal structure of catena poly[[[triaquastrontium] di μ2 glycinato] dibromide]
... The asymmetric unit of (I) contains one Sr 2+ ion, one glycine ligand, one and a half water molecules and one bromide anion (Fig. 1). The Sr 2+ cation and one of the water molecules (O4) are located on special ... See full document
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Crystal structure of a polymeric calcium levulinate dihydrate: catena poly[[diaquacalcium] bis(μ2 4 oxobutanoato)]
... ion lies on a twofold rotation axis and is octacoordinated by two aqua ligands and six O atoms from four symmetry-related carboxylate ligands, giving a distorted square-antiprismatic coordination stereochemistry [Ca—O ... See full document
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Crystal structure of catena poly[[[(2 ethoxypyrazine κN)copper(I)] di μ2 cyanido] [copper(I) μ2 cyanido]]
... (Grifasi et al., 2016; Pike, 2012). Mixed-valence Cu I /Cu II coordination complexes with cyanide and amine ligands having different supramolecular architectures and their luminescence properties have also been reported ... See full document
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Crystal structure of catena poly[[copper(II) μ2 salicylato [diaquacopper(II)] μ2 salicylato] dihydrate]
... Compound (I) forms coordination chains extending parallel to [001] with a Cu Cu distance of 4.0478 (4) A ˚ . The coordi- nating water molecule O4 acts as a donor of hydrogen bonds with the carboxylate oxygen O1 ... See full document
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Poly[[diaquatris(μ2 4,4′ bipyridine)bis[μ2 2 (carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1 3 hydrate]
... bridged by 4,4′-bipy linkers to generate a final three-dimensional structure (Fig. 2). The disordered water molecules are situated in the free space of the resulting network. The 4,4′-bipy molecule that is ... See full document
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Bis(tetrabutylammonium) bis(3,4,5 trioxocyclopent 1 ene 1,2 dithiolato κ2S,S′)cadmate(II) 0 25 hydrate
... anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5- trioxocyclopent-1-ene-1,2-dithiolate (dtcroc) group forming a distorted tetrahedral configuration around the Cd II ... See full document
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Crystal structure of poly[μ2 aqua aqua(μ2 4 nitro 2,5,6 trioxo 1,2,5,6 tetrahydropyridin 3 olato)hemi μ4 oxalato barium(II)]
... (Fig. 1), the tenfold coordination of the Ba1 atom (Table 1) is formed by the O2, O5, O1 and O2 atoms of two 4-nitro-2,3,5,6- tetraoxopyridine-4-ide anions (L), the O7, O8 and O7A atoms of two ... See full document
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catena Poly[[silver(I) μ2 1,1′ dimethyl 2,2′ biimidazole κN3:N3′] nitrate 1 167 hydrate methanol 0 33 solvate]
... Experimental . X-ray crystallographic data for I were collected from a single-crystal sample, which was mounted on a loop fiber. Data were collected using a Bruker Platform diffractometer, equipped with a Bruker ... See full document
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Crystal structure of anhydrous poly[bis(μ2 sarcosinato κ3O,N:O′)copper(II)]
... sarcosinate anion with copper(II). The central metal cation is located on a center of inversion. It is six-coordinate and has a distorted octahedral [4 + 2] coordination sphere characteristic for Jahn–Teller ... See full document
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Bis(1H benzimidazole κN3)bis(4 hydroxybenzoato κO)zinc(II) 0 25 hydrate
... A partially overlapped arrangement is observed between parallel N23-imidazole and N23 iv -imidazole rings (see Fig. 2 for symmetry code). The face-to-face separation of 3.28 (4) A ˚ indicates the existence of – ... See full document
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Crystal structure of ethylenedioxytetrathiafulvalene 4,5 bis(thiolbenzoic acid) 0 25 hydrate
... (Fig. 1). The TTF core adopts a boat conformation, as usually observed in neutral TTF derivatives. The central plane A (S1/ S2/C5/C6/S3/S4) and the adjacent planes B (S3/S4/C7/C8/S5/ S6) and C (S1/S2/C3/C4/O1/O2) ... See full document
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Bis{4 [(E) 2 (1H indol 3 yl)ethenyl] 1 methylpyridinium} 4 fluorobenzenesulfonate nitrate 0 25 hydrate†
... of 1- methyl-4-(2-(4-(dimethylamino)phenyl)ethynyl)pyridinium p-toluenesulfonate (DAST) and its analogues exhibit second- order nonlinear optical properties (Dittrich et ...its crystal ... See full document
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2′,6′ Bis(4 carboxyphenyl) 4,4′ bipyridin 1 ium nitrate 0 25 hydrate
... (Fig. 1), the central pyridine ring of the cation is almost coplanar with one benzene ring, making a dihedral angle of ...[0 1 0] (Fig. 2). The crystal structure also exhibits ... See full document
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Bis(benzimidazole)bis(4 hydroxybenzoato)cobalt(II) 0 25 hydrate
... Aromatic – stacking is an important intermolecular inter- action which is correlated with electron transfer in some biosystems (Deisenhofer & Michel, 1989). In order to inves- tigate further the nature of – stacking, ... See full document
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Poly[[μ2 aqua tetraaquahexakis(μ4 naphthalene 2,6 dicarboxylato)tetraholmium(III)] 1 75 hydrate]
... It is important to stress that a considerable smeared-out electron density was found surrounding the water molecules O1W and O5W. Attempts to model this disorder (during the last stages of the overall structural ... See full document
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Bis[1,3 bis(1 methyl 1H benzimidazol 2 yl) 2 oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0 25 hydrate
... O11 0.23974 (9) 0.58200 (10) 0.38755 (8) 0.0403 (4) O12 0.21537 (8) 0.56317 (10) 0.45331 (9) 0.0420 (4) O13 0.35914 (9) 0.63635 (11) 0.66491 (8) 0.0412 (4) O14 0.39345 (8) 0.74662 (11) 0.67826 (8) ... See full document
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