[PDF] Top 20 Crystal structure of μ peroxido κ4O1,O2:O1′,O2′ bis[(nitrato κO)(2,2′:6′,2′′ terpyridine κ3N,N′,N′′)dioxidouranium(VI)]
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Crystal structure of μ peroxido κ4O1,O2:O1′,O2′ bis[(nitrato κO)(2,2′:6′,2′′ terpyridine κ3N,N′,N′′)dioxidouranium(VI)]
... solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for ... See full document
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μ Oxalato κ4O1,O2:O1′,O2′ bis[aqua(diethylenetriamine κ3N)nickel(II)] bis(tetraphenylborate)
... el(II) complex cation in which the oxalate ligand bridges the Ni atoms in a bis-bidentate fashion. The distorted octahedral environment of each Ni atom is completed by the three N atoms of the diethylenetriamine ... See full document
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Crystal structure of μ oxalato κ2O1:O2 bis[(dimethyl sulfoxide κO)triphenyltin(IV)]
... the crystal, and no strong interactions are ...C1 O2, are the unique potential acceptor groups for hydrogen bonding, and indeed, weak intermolecular C— H O contacts are formed (Table 1): two molecules ... See full document
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Bis(μ 3 carboxy 2 oxidobenzoato) κ3O1,O2:O3;κ3O3:O1,O2 bis[aqua(2,2′ bipyridine κ2N,N′)copper(II)]
... ion is coordinated by two N atoms from a bipyridine ligand, three O atoms from two 3- carboxy-2-oxidobenzoate dianions and the O atom of the water molecule in a distorted octahedral geometry. The Cu—- O(H) coordination ... See full document
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Poly[[hexaaqua(μ2 oxalato κ4O1,O2:O1′,O2′)bis(μ3 pyridine 2,4 dicarboxylato κ4N,O1:O1′:O4)dicerium(III)] monohydrate]
... formed by three pyridine-2,4-dicarboxylate anions, one oxalate anion and three water molecules. The mid-point of the oxalate anion is located on an inversion center. The oxalate and pyridine-2,4-dicarboxylate anions ... See full document
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μ Oxalato κ4O1,O2:O1′,O2′ bis[aqua(2,2′ bipyridyl κ2N,N′)copper(II)] bis(hydrogen squarate)
... The crystal structure shows alternating complex cations and cyclic anionic units, arranged in two different levels and linked through an extended network of O(water)—H O(Hsq) hydrogen bonds (Table ... See full document
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The cocrystal μ oxalato κ4O1,O2:O1′,O2′ bis(aqua(nitrato κO){[1 (2 pyridyl κN)ethylidene]hydrazine κN}copper(II)) μ oxalato κ4O1,O2:O1′,O2′ bis((methanol κO)(nitrato κO){[1 (2 pyridyl κN)ethylidene]hydrazine κN}copper(II)) (1/1)
... plane. In one molecule, a monodentate nitrate anion and a water molecule occupy the axial sites, and in the other, a monodentate nitrate anion and a methanol molecule occupy these sites. In the crystal ... See full document
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Poly[tetraaqua(5 hydroxypyridin 1 ium 3 carboxylato κO3)tris(μ oxalato κ4O1,O2:O1′,O2′)dieuropium(III)]
... constructing transition metal (Yang et al., 2011) and rare earth metal (Zhang et al., 2012) organic frameworks. The research interest in europium(III) coordination polymers with the ligands comes from their luminescent ... See full document
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Crystal structure and spectroscopic analysis of a new oxalate bridged MnII compound: catena poly[guanidinium [[aquachloridomanganese(II)] μ2 oxalato κ4O1,O2:O1′,O2′] monohydrate]
... ecule. A bond-valence-sum calculation, assuming Mn—O and Mn—Cl bonds, gives a BVS value (Brown & Altermatt, 1985) of 2.05 (7), confirming the +II oxidation state of Mn and ensuring electrical neutrality of the formed ... See full document
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catena Poly[[dibutyltin(IV)] μ 3,4,5,6 tetrafluorobenzene 1,2 dicarboxylato κ4O1,O1′:O2,O2′]
... Organotin complexes have attracted more attention in recent years, partly due to their established or potential pharma- ceutical value (Vadapalli et al., 2005). The substitution of hydrogen by fluorine significantly ... See full document
7
Bis(μ 3 nitrobenzene 1,2 dicarboxylato) κ4O1,O2:O1,O1′;κ4O1,O1′:O1,O2 bis[triaqua(6 carboxy 2 nitrobenzoato κ2O1,O6)neodymium(III)] dihydrate
... Geometry . All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of ... See full document
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Di μ chlorido bis{[2 (8 quinolyloxy)acetato κ3N,O1,O2]copper(II)}
... (8-quinolyloxy)acetate anion acts as a tridentate chelating ligand. In the crystal structure, adjacent quinolyl rings are involved in strong – stacking interactions, with interplanar distances of 3.549 (5) ... See full document
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μ Oxalato κ4O1,O2:O1′,O2′ bis[aqua(2,2′ bipyridine κN)(nitrato κ2O,O′)lead(II)]
... Geometry . All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, ... See full document
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Crystal structure of bis[μ 2 (diisopropylphosphoryl)propan 2 olato κ3O1,O2:O1]bis[chloridooxidovanadium(IV)]
... Data collection: APEX2 (Bruker, 2015); cell refinement: SAINT-Plus (Bruker, 2015); data reduction: SAINT-Plus (Bruker, 2015); program(s) used to solve structure: SUPERFLIP (Palatinus & Chapuis, 2007); ... See full document
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Poly[di μ aqua diaquabis(μ7 oxalato κ9O1:O1:O1,O2:O2:O2′:O2′,O1′:O1′)calciumdicaesium]
... isostructural with Co(II) analogue (Schwendtner & Kolitsch, 2004), owing to the corresponding ionic radii which are approximately equal [0.65 and 0.72 Å for Co(II) and Mg(II), respectively]. However, the single ... See full document
14
Poly[[diaquabis(μ oxalato κ4O1,O2:O1′,O2′)bis(μ3 5 oxidopyridin 1 ium 3 carboxylato κ3O3:O3′:O5)diholmium(III)] dihydrate]
... solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: DIAMOND (Branden- burg, 1999); software used to prepare material for publication: ... See full document
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Poly[aqua μ bromido (μ2 5 methylpyrazine 2 carboxylato κ4N1,O2:O2,O2′)lead(II)]
... Geometry . All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of ... See full document
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cis (2,2′ Bipyridine)bis[2 (2 pyridyl) 4 methoxycarbonylquinoline]ruthenium(II) hexafluorophosphate
... During the structure refinement, the atoms of the ester group (C15, O1, O2 and C16) all had very large anisotropic displacement parameters. There was an improvement in the refinement when these atoms ... See full document
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Superexchange mediated negative thermal expansion in Nd doped BiFeO3
... Conventional Rietveld refinements showed that all Fe-O bond lengths contract on cooling as expected, Figure 8 (see also Figure 9 for naming of O-atoms). However, the contraction is not completely linear over the studied ... See full document
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Vol 1, No 6 (2012)
... of crystal structure were made by using Diamond Molecular Structure version ...single crystal structural data of pure cobalt cyclotetraphosphates including atomic coordinates of monoclinic ... See full document
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